Method 13a - Determination
Method 13a - Determination
Method 13a - Determination
1.1 Analytes.
Analyte CAS No. Sensitivity
Total fluorides
as Fluorine 7782-41-4 Not determined
2.0 Summary.
4.0 Interferences.
5.0 Safety.
burn.
producing hydrogen.
amounts of water.
body tissue. Will cause third degree burns. Eye damage may
condensation is a problem.
monitoring purposes.
respectively.
849
samples, 1 liter.
temperature conditions.
path.
7.1.1 Filters.
for use.
respectively.
analysis:
and 50 ml of water.
daily.
Transport.
(1.0 cfm). For each run, record the data required on a data
the sample. Do not cap off the probe tip tightly while the
site, remove the probe from the sample train, wipe off any
from the filter holder inlet, and cap this inlet. Remove
the umbilical cord from the last impinger, and cap the
impinger. After wiping off any silicone grease, cap off the
samples as follows:
Catches).
nearest ml, and record the volume of the water in the first
water. Use less than 500 ml for the entire wash. Add the
856
as follows:
with a Nylon bristle brush, and rinse until the rinse shows
squirting the water into the upper end of the probe, tilt
wetted with water. Let the water drain from the lower end
underneath the lower end of the probe, and catch any water
brush.
holder.
the lid so that water will not leak out when it is shipped
contents.
Quality Control
Section Measure Effect
8.4, Sampling equipment Ensure accurate
10.1 leak-check and measurement of stack gas
calibration flow rate and sample
volume
10.2 Spectrophotometer Evaluate analytical
calibration technique, preparation of
standards
11.3.3 Interference/recovery Minimize negative effects
efficiency check of used acid
during distillation
Section 9.2.
10.2 Spectrophotometer.
each. These standards will contain 0, 10, 20, 30, 40, 50,
analyzing.
standard curve.
during the evaporation, add CaO until the color turns red
again.
862
completely.
H2SO4 with water. Slowly add the acid to the flask with
constant swirling.
11.3 Distillation.
(347 EF). During heatup, play the burner flame up and down
0.1 µg/ml.
spectrophotometer.
field.
results.
12.1 Nomenclature.
development, ml.
volume.
(gr/dscf).
µg.
EK ( ER).
dilution, ml.
K Vt V d Fc
Ft ' Eq. 13A-1
At Ad
where:
equation:
868
Ft
Cf ' Eq. 13A-2
Vm(std)
Section 12.11.
F-/ml.
samples.
870
17.0 References.
50:5306. 1958.
December 1977.
Connecting Tube
12 mm ID
T 24
S
40
Thermometer
T 24
S
40
With
T 10
S 30 S 24
T
40
Adapter
Adapter
T 24
S
40
Condenser
1-Liter
Flask
500-ml
Erlenmeyer
Flask