Dissolving Pulp and Viscose Manufacturing
Dissolving Pulp and Viscose Manufacturing
Dissolving Pulp and Viscose Manufacturing
www.wikipedia.com
SE Biomaterials November 30, 2015 4
Dissolving pulp is not only one grade
Extractives
Lignin Acacia
Eucalyptus
Spruce
Hemicellulose Pine
Birch
Cellulose
0 10 20 30 40 50 60
• Raw material
• Wood pulp
• HW
• SW
• Cotton linter
• Bamboo
• Production process
• Sulfite
• Pre-hydrolysis
• Alkaline extraction
Sirpa Välimaa
SE Biomaterials November 30, 2015 13
The pulp production process
Wood Oxygen
Wood Cooking Bleaching Drying Pulp
room treatment
Lime Evaporation
Causticizing
kiln plant
Concentrated
Green liquor waste liquor
Soda
recovery
plant
Energy
production for
Bark the process
Bark
boiler
• Pre-hydrolysis
• Neutralization
• Hot filling
• Cooking
• Displacement
• Unbleached pulp
• In the neutralization
1. the organic acids in the pulp are neutralized with white liquor by pushing it through
the chip bed in the digester
2. Oligo- and monosaccharides are subjected to extensive fragmentation reactions
and solubilized in the neutralization liquor
• The process variable is the white liquor amount. White liquor consistency is constant.
• The degradation of the hydrolytically cleaved hemicelluloses which started in the pre-
hydrolysis still continues during the neutralization step
• Neutralization requires a sufficient supply of effective alkali to ensure the complete
extraction of the polysaccharides and to prevent re-condensation and re-precipitation
of both carbohydrates and lignin compounds
• Delignification starts immediately after introduction of the neutralization liquor
• improved permeability of the cell wall due to increased pore volume
• Improved penetration of the cooking liquor and the partial hydrolytic cleavage
of lignin structures and lignin-carbohydrate bonds
• The neutralization step is immediately succeeded by a hot liquor filling
2 3
• Cellulose chain consists of glucose-anhydrite-units which bound together with β1,4 bonds
• The solubility of the native cellulose (cellulose I) is low as it has a dense crystalline structure and a
lot of hydrogen bonds.
• Solubility and reactivity can be increased through chemical handlings – modification can be carried
out in the hydroxyl-units (cellulose I > cellulose II).
• Reactivity means the ability of the dissolving pulp to participate various chemical reactions in the
production process of regenerated cellulose.
• Each glucose-anhydrite-units has three hydroxyl-groups in three positions; 2, 3 and 6. The most
impact on reactivity has the positions 2 and 3.
• Reactivity is connected with accessibility and substitution:
– Accessibility = the ability of cellulose to react with NaOH in the mercerization and activate the
pulp
– Substitution = how many of the hydroxyl-groups is reacting
• Reactivity is both affected by the raw material used in the process as well as the dissolving pulp
production process.
R.Isotalo: Wood and pulp chemistry. Helsinki 1996.
H.Sixta: Handbook of Pulp. Chapter 4.2. Kraft Cooking process.
22
P.Stenius: Forest Products Chemistry. Book 3 in the series of Papermaking Science and Tehnology. Fapet Oy. Jyväskylä 2000.
A-S. Jääskeläinen & H.Sundqvist: Puun rakenne ja kemia. Otatieto. Helsinki 2007.
2.Viscose staple fiber manufacturing
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Few puzzles to be solved in the textile industry…
IT IS YOUR LEGACY!
36
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