Dated: 02-01-2019 TIME: 3 Hours M.M.: 360 (Full Test - 8) (Jee-Main)
Dated: 02-01-2019 TIME: 3 Hours M.M.: 360 (Full Test - 8) (Jee-Main)
Dated: 02-01-2019 TIME: 3 Hours M.M.: 360 (Full Test - 8) (Jee-Main)
[ CHEMISTRY ]
1. A sample of ammonia phosphate (NH4 )3 PO4 contains 3.18 moles of H atoms. The number of moles of O
atoms in the sample is
(a) 0.265 (b) 0.795 (c) 1.06 (d) 3.18
2. Consider following compounds
I : K 4 [Fe(CN)6 ], II : NH4Cl, III : H2 SO4
Ionic, covalent and coordinate bonds are present in
(a) I, II and III (b) I and III (c) II and III (d) I and II
3. PCl 5 has a shape of trigonal bipyramid whereas IF5 has the shape of a square pyramid. It is due to
(a) presence of unshared electron pair I which is oriented so as to minimise repulsion while P in PCl 5 has
no unshared pair
(b) octet of P is complete while that of I is incomplete
(c) P and I are of different groups
(d) F and Cl have different extent of repulsion
4. The electron affinities of N, O, S and Cl are such that
(a) N < O < S < Cl (b) O < N < Cl < S (c) O Cl N S (d) O < S < Cl < N
5. Permanent hardness is due to SO24 and Cl of Ca2 and Mg 2 and is removed by the addition of
Na2 CO3
NaSO4 Na2 CO3
CaCO3 Na2 SO4
CaCl 2 Na2CO3 CaCO3 2NaCl
If hardness is 100 ppm CaCO3 , amount of Na2 CO3 required to soften 10 L of hard water is
(a) 2.12 g (b) 0.106 g (c) 10.6 g (d) 1.06 g
1
6. Molality of 18MH2 SO4 (d 1.8g mL ) is
(a) 36mol kg 1 (b) 200mol kg 1 (c) 500mol kg 1 (d) 18mol kg 1
7. Given :
(i) MnO4 8H 5e
Mn 2 4H2O E0 x 1 V
(ii) MnO2 4H 2e
Mn 2 2H2O E0 x 2 V
Find E0 for the following reaction :
MnO4 4H 3e MnO2 2H2O
5x1 2x2 2x1 5x2
(a) x2 x1 (b) x1 x2 (c) (d)
3 3
8. Ionisation constant of each HA (weak acid) and BOH (weak base) are 3.0 107 each at 298K. The
percentage degree of hydrolysis of BA at the dilution of 10L is:
(a) 25 (b) 50 (c) 75 (d) 40
1
9. In a gaseous phase reaction, A 2 (g)
B(g) C(g) . The increase in pressure from 100 mm to 110 mm is
2
observed in 5 minute. The rate of disappearance of A 2 in mm min 1 is:
(a) 4 (b) 8 (c) 16 (d) 2
10. A crystal is made of particle X, Y & Z. X forms FCC packing, Y occupies all octahedral voids of X and Z
occupies all tetrahedral voids of X, if all the particles along one body diagonal are removed then the
formula of the crystal would be:
(a) XYZ2 (b) X 2 YZ2 (c) X8 Y4 Z5 (d) X 5 Y4 Z8
11. Alkali metals dissolve in liquid NH3 , then which of the following observation are true?
(a) H2 gas is liberated
(b) Solution is blue due to the presence of solvated electrons
(c) Solution is conducting
(d) All of the above are correct
12. A metal M readily forms water soluble MSO4 . It also forms oxide MO which becomes inert on heating.
Hydroxide M OH 2 is insoluble in water but soluble in NaOH solution. What is M ?
(a) Mg (b) Ba (c) Ca (d) Be
13. H2 O2 can be obtained when following reacts with H2 SO 4 except with
(a) PbO2 (b) BaO2 (c) Na2 O2 (d) SrO2
14. Borax Na2 Ba4O7·10H2O is actually
(a) Na2 [B4O5 (OH)2 ]·8H2O (b) Na2 [B4O4 (OH)6 ]·7H2O
(c) Na2 [B4O3 (OH)8 ]·6H2O (d) Na2 [B4O2 (OH)10 ]·5H2O
15. Holme’s signals can be given by using
(a) CaC2 CaCN2 (b) CaC2 Ca3P2 (c) CaC2 CaCO3 (d) Ca3P2 CaCN2
16. NH3 can’t be obtained by
(a) heating NH4NO3 or NH4NO2
(b) heating of NH4Cl or (NH4 )2 CO3
(c) heating of NH4NO3 with NaOH
(d) reaction of AlN or Mg 3N2 or CaCN2 with H2 O
17. Which of the following statements concerning lanthanides elements is false?
(a) Lanthanides are separated from one another by ion-exchange method
(b) Ionic radii of trivalent lanthanides steadily increase with increase in the atomic number
(c) All lanthanides are highly dense metals
(d) More characteristic oxidation state of lanthanides elements is +3
18. Among Ni(CO)4 ,[Ni(CN)4 ]2 and NiCl 24
(a) Ni(CO)4 and [Ni(CN)4 ]2 are diamagnetic and NiCl 24 is paramagnetic
(b) Ni(CO)4 and NiCl 24 are diamagnetic and [Ni(CN)4 ]2 is paramagnetic
(c) Ni(CO)4 is diamagnetic and [Ni(CN)4 ]2 and NiCl 24 are paramagnetic
(d) NiCl 24 and [Ni(CN)4 ]2 are diamagnetic and Ni(CO)4 is paramagnetic
19. KCl concH2 SO4 K2Cr2O7 ( X) NaOH
(Y ) .
( X ) is reddish brown coloured gas soluble in NaOH forming (Y ),( X ) and (Y ) are
(a) Cr2OCl 2 ,Na2CrO3 (b) Cr2 O2 Cl 2 ,Na2 CrO3 (c) CrO2 Cl,Na2CrO4 (d) CrO2 Cl 2 ,Na2CrO4
20. IUPAC name of the following compound is
(a) Two optically active and one meso (b) One optically active and one meso
(c) Four optically active (d) Two optically active and two meso
22. Identify the major species in solution for reaction.
(a) (b) (c) (d)
23. What is the final product of the reaction?
(CH3 )2 C CHCH2 CH3 (i)BH3 /THF
(ii)H O /OH
PCC
CH2 Cl 2
(i)CH3MgBr
(ii)H O
2 2 3
[ MATHEMATICS ]
31. A function f() sin 2 3sin cos 5cos2 is defined R . Another function g() f at the
2
1
point , where f() is minimum then value of is
g()
1 11 2
(a) (b) (c) (d) 2
2 2 11
32. Let position vectors of points A, B and C of triangle ABC respectively be i j 2k,i 2j k and 2i j k .
Let l1 , l2 and l3 be the lengths of perpendiculars drawn from the orthocentre ‘O’ on the sides AB, BC and
CA, then (l1 l2 l3 ) equals
2 3 6 6
(a) (b) (c) (d)
6 6 2 3
x y -1 z -1 x y -1 z -1
33. If the projection of the line on a plane P is . Then the distance of plane P
2 2 1 1 1 1
from origin is
6 2
(a) 3 (b) (c) 6 (d)
2 3
x1 y 1 z1
34. The centroid of the triangle formed by (0, 0, 0) and the point of intersection of with x =
1 2 1
0 and y = 0 is
1 1 1 1 1 1 1 1 1
(a) (1, 1, 1) (b) , , (c) , , (d) , ,
6 3 6 6 3 6 3 3 3
35. A class has three teachers, Mr X, Ms Y and Mrs Z and six students A, B , C, D, E, F. Number of ways in
which they can be seated in a line of 9 chairs, if between any two teachers there are exactly two students is
(a)18 × 6! (b) 12 × 6! (c) 24 × 6! (d) 6 × 6!
36. The sum of first 25 terms of an A.P., whose all the terms are natural numbers, lies between 1900 and 2000
and its 9th term is 55. Then the first term of the A.P. is
(a) 5 (b) 6 (c) 7 (d) 8
1 1 1
4 4
37. If a cos i sin , then 1 a a 2 is
3 3
1 a2 a
(a) Purely real (b) purely imaginary (c) zero complex number (d) none of these
38. A number is selected at random from the first twenty five natural numbers, if it is a composite number,
then it is divided by 5. But if it is not a composite number, it is divided by 2. The probability that there will
be no remainder in the division is
11 2 3 1
(a) (b) (c) (d)
30 5 5 5
3 tan 3x 4 tan 2x tan x
39. lim is equal to
x 0 4x 2 tan x
(a) 0 (b) 1 (c) 3 (d) 4
40. The value of I x(sin 2 (sin x) cos 2 (cos x))dx is equal to
0
2 2
(a) 2
(b) (c) (d)
2 4
41. The following figure shows the graph of a continuous function y f (x) on the interval [1, 3]. The point
A, B and C have coordinates (1, 1), (3, 2), (2, 3), respectively, and the lines L1 and L2 are parallel, with L1
being tangent to the curve at C . If the area under the graph of y f (x) from x 1 to x 3 is 4 square
units, then the area of the shaded region is
3 3 4 4
(a) (b) 2 (c) (d) 2
e e e e
(2 x 3)dx 1
43. If C where f ( x ) is of the form of ax bx c , then the value of f (1) is
2
3 3i i 3 3i
(a) lies on real axis (b) lies on imaginary axis
(c) lies in first quadrant (d) lies in second quadrant
51. The Boolean expression ( p ~ q) q (~ p q) is equivalent to
(a) ~ p q (b) p q (c) p q (d) p ~ q
52. The first three terms of a geometric sequence are x , y , z and these have the sum equal to 42. If the middle
5y
term y is multiplied by 5/4, the numbers x , , z now form an arithmetic sequence. The largest possible
4
value of x is
(a) 6 (b) 12 (c) 25 (d) 20
53. If f (x 6x 6) f (x 4x 4) 2xx R then f (3) f (9) 5 f (1)
2 2
[ PHYSICS ]
61. A block of mass m is at rest on the another block of same mass as shown in figure. Lower block is
attached to the spring then the maximum amplitude of motion so that both that block will remain in
contact is
mg mg 2mg 3mg
(a) (b) (c) (d)
2k k k 2k
62. The work done in moving an electron of charge e and mass m from A to B along the circular path
shown by arrow in the vertical plane in the field of charge Q is:
2Qe
(a) 2mgr (b) 2Qe / r (c) 2mgr (d) zero
r
63. A police car moving at 22 m/s, chases a motorcyclist. The police man sounds his horn at 176 Hz, while
both of them move towards a stationary siren of frequency 165 Hz. Calculate the speed of the motorcycle,
if it is given that he does not observes any beats
(a) 33 m/s (b) 22 m/s (c) Zero (d) 11 m/s
64. A rod of glass ( 1.5) and of square cross section is bent into the shape shown in figure. A parallel beam
of light falls on the plane flat surface A as shown in the figure. If d is the width of a side and R is the
d
radius circular arc then for what maximum value of light entering the glass slab through surface A
R
emerges from the glass through B
13 11 3 1
(a) sin (b) sin (c) sin (d) sin
11 13 2 2
66. The radiation force experienced by body exposed to radiation of intensity I , assuming surface of body to
be perfectly absorbing is:
R 2 I R 2 I IRH IRH
(a) (b) (c) (d)
c 2c 2c c
67. The field at the centre of a loop of radius R due to the current of I ampere in the loop as shown in figure
will be:
0 2 I 2 I 2I
(a) zero (b) (c) 0 (d) 0 [ 1]
4 R 4 R 4 R
68. If light of wavelength 1 is allowed to fall on a metal, then kinetic energy of photoelectrons emitted is E1 .
If wavelength of light changes to 2 , then kinetic energy of electrons changes to E2 . Then work function
of the metal is
E E ( 2 ) E E2 2 E E2 2 EE
(a) 1 2 1 (b) 1 1 (c) 1 1 (d) 1 2 1 2
1 2 ( 1 2 ) ( 2 1 ) ( 2 1 )
69. When one of the slits of Young’s experiment is covered with a transparent sheet of thickness 4.8 mm, the
central fringe shifts to a position originally occupied by the 30th bright fringe. What should be the
thickness of the sheet if the central fringe has to shift to the position occupied by 20th bright fringe?
(a) 3.8 mm (b) 1.6 mm (c) 7.6 mm (d) 3.2 mm
70. If the wavelength of the first line of the Balmer series of hydrogen is 6561 Å, the wavelength of the second
line of the series should be
(a) 13122 Å (b) 3280 Å (c) 4860 Å (d) 2187 Å
71. A nucleus of 82 210
Po originally at rest emits -particle with speed v . What will be the recoil speed of the
daughter nucleus?
(a) 4v /206 (b) 4v /214 (c) v /206 (d) v /214
72. In hydrogen atom, the electron is revolving about the nucleus in a circular orbit of radius ‘ a ’ and at
angular frequency ‘ ’ . The ratio of magnetic moment due to orbital motion and the orbital angular
momentum is:
e e e e
(a) (b) (c) (d)
m 2m 2 ma ma
73. A radioactive sample of U 238 decay to Pb through a process for which half-life is 4.5 109 years. The ratio
of number of nuclei of Pb to U-238 after a time of 1.5 109 years. is (given 21/3 1.26 )
(a) 0.12 (b) 0.26 (c) 1.2 (d) 0.37
74. A glass flask of volume one litre at 0ºC is filled, level full of mercury at this temperature. The flask and
mercury are now heated to 100ºC. How much mercury will spill out if the coefficient of volume expansion
of mercury is 1.8 104 /ºC and linear expansion of glass is 1.0 104 /ºC , respectively?
(a) 21.2 cc (b) 15.2 cc (c) 1.52 cc (d) 2.12 cc
75. Figure shows a square conducting loop of side 8 cm being taken out of a uniform magnetic field of B = 1.5
T which is directed perpendicular and into the plane of the loop. The loop is connected to a circuit as
shown in the figure. Resistance of loop is 2 and that of the wires which connect the loop with the
network of resistances is negligible. Speed of the loop such that current through it has a steady value
2mA, is:
11
(a) 2m / s2 (b) m / s2 (c) 1m / s2 (d) none of these
2
82. In the system shown in the figure the friction coefficient between ground and bigger block is . There is
no friction between both the blocks. The string connecting both the block is light; all three pulleys are light
and frictionless. Then the minimum limiting value of so that the system remains in equilibrium is
1 1 2 3
(a) (b) (c) (d)
2 3 3 2
83. A particle of mass m r
is moving in a horizontal circle of radius under a centripetal force equal to K / r 2
, where K is a constant. The total energy of the particle is
K K K K
(a) (b) (c) (d)
2r 2r r r
84. A solid cube ABCD of side a and mass M is placed on a rough horizontal surface. A bullet of mass m
and speed V is shot at the top of the cube so that cube rotates about point D. The bullet sticks to the cube,
m M . Find the angular velocity of the cube.
6mV 3 MV 2 MV 2mV
(a) (b) (c) (d)
5 Ma 2ma 3ma 3 Ma
85. A U-tube base length ‘ l ’ filled with same volume of two liquids of densities and 2 is moving with an
acceleration ‘ a ’ on the horizontal plane. If the height difference between the two surfaces (open to
atmosphere) becomes zero, then the height h is given by
a 3a a 2a
(a) l (b) l (c) l (d) l
2g 2g g 3g
86. Three plates A, B and C are placed close to each other with Q charge given to the middle plate. The
inner surfaces of A and C can be connected to earth through plate D and keys K 1 and K 2 . The plates D
is a dielectric slab with dielectric constant K , then the charge that will flow through plate D when K 1 is
closed and K 2 is open is
1 Q 1
(a) Q (b) Q /2 (c) Q 1 (d) 1
K 2 K
87. If each resistance in the figure is of 9 , then reading of ammeter is
(a) 1 A, 1 A, zero (b) 0.5 A, 0.25 A, 0.25 A (c) 0.5 A, zero, 0.5 A (d) 1 A, zero, 1 A