Revision date: 04/06/2015 Revision: 8

APPENDIX 8 - Material Safety Data Sheet (MSDS)

SAFETY DATA SHEET

CEBEX 100

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name CEBEX 100

Product number 1046002UK9,1046016UK9

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Expanding and plasticising grout admixture.

1.3. Details of the supplier of the safety data sheet

Supplier PT FOSROC INDONESIA
Jl Akasia II
Delta Silicon Industrial Park Lippo Cikarang Bekasi,
Indonesia 17550 [email protected] Tel.
+62 (0) 21 897 2103; +44 (0) 1827 262222 (Head Office UK)
Fax. +62 (0) 21 897 2107

1.4. Emergency telephone number

Emergency telephone +62 (0) 21 897 2103 (08.30 to 17.00hrs Mon - Thu; 08.30 to 16.00hrs Fri)

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification
Physical hazards Not Classified

Health hazards Not Classified

Environmental hazards Not Classified

Classification (67/548/EEC or Xi;R36.

1999/45/EC)

Human health Dust may irritate the respiratory system. Symptoms following overexposure may include the
following: Coughing. Frequent inhalation of dust over a long period of time increases the risk
of developing lung diseases.

Environmental The resultant material is not biodegradable.

2.2. Label elements

Hazard statements NC Not Classified

2.3. Other hazards

This product does not contain any substances classified as PBT or vPvB.

SECTION 3: Composition/information on ingredients

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CEBEX 100

3.2. Mixtures

SILICA SAND 60-100%

CAS number: 14808-60-7 EC number: 238-878-4

Classification Classification (67/548/EEC or 1999/45/EC)

Not Classified -

ALUMINIUM POWDER (STABILIZED) 1-5%

CAS number: 7429-90-5 EC number: 231-072-3

Classification Classification (67/548/EEC or 1999/45/EC)

Flam. Sol. 1 - H228 F;R11,R15
Water-react. 2 - H261

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation Move affected person to fresh air at once.

Ingestion Rinse mouth thoroughly with water. Get medical attention if any discomfort continues.

Skin contact Remove contaminated clothing immediately and wash skin with soap and water.

Eye contact Remove any contact lenses and open eyelids wide apart. Remove any contact lenses and
open eyelids wide apart. Continue to rinse for at least 15 minutes. Get medical attention if any
discomfort continues.

4.2. Most important symptoms and effects, both acute and delayed
Inhalation Irritation of nose, throat and airway.

Ingestion No specific symptoms known.

4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor No specific recommendations. If in doubt, get medical attention promptly.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media The product is not flammable. Use fire-extinguishing media suitable for the surrounding fire.

Unsuitable extinguishing Water. Foam. Carbon dioxide (CO2).

media

5.2. Special hazards arising from the substance or mixture

Specific hazards In contact with water releases flammable gases which may ignite spontaneously.

Hazardous combustion Irritating gases or vapours.

products

5.3. Advice for firefighters

Protective actions during Wear self-contained breathing apparatus.
firefighting

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CEBEX 100

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions Avoid contact with skin and eyes. For personal protection, see Section 8.

6.2. Environmental precautions

Environmental precautions Avoid release to the environment.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up Collect powder using special dust vacuum cleaner with particle filter or carefully sweep into
suitable waste disposal containers and seal securely.

6.4. Reference to other sections

Reference to other sections Wear protective clothing as described in Section 8 of this safety data sheet.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Usage precautions Avoid inhalation of dust and contact with skin and eyes. Avoid spread of dust.

7.2. Conditions for safe storage, including any incompatibilities

Storage precautions Store in tightly-closed, original container in a dry and cool place. Seal opened containers and
use up as soon as possible To be stored out of reach of children in its original packaging in a
dry place. Store away from the following materials: Liquid chlorinated hydrocarbons Keep
away from oxidising materials, heat and flames. Protect from humidity and water.

7.3. Specific end use(s)

Specific end use(s) The identified uses for this product are detailed in Section 1.2.

SECTION 8: Exposure Controls/personal protection

8.1. Control parameters

Occupational exposure limits
SILICA SAND
Long-term exposure limit (8-hour TWA): WEL 0,1 mg/m³
ALUMINIUM POWDER (STABILIZED)
Long-term exposure limit (8-hour TWA): WEL 10 mg/m³ inhalable dust
Long-term exposure limit (8-hour TWA): WEL 4 mg/m³ respirable dust
WEL = Workplace Exposure Limit

ALUMINIUM POWDER (STABILIZED) (CAS: 7429-90-5)

DNEL Workers - Oral; Long term systemic effects: 3 mg/m³

8.2. Exposure controls

Protective equipment

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CEBEX 100

Appropriate engineering Atmospheric levels of dust must be maintained within the Occupational Exposure Limit.
controls Where mechanical methods are inadequate or impractical, appropriate personal protective
equipment must be used. As this product contains ingredients with exposure limits, process
enclosures, local exhaust ventilation or other engineering controls should be used to keep
worker exposure below any statutory or recommended limits, if use generates dust, fumes,
gas, vapour or mist.

Personal protection Personal protection equipment should be chosen according to the CEN standards and in
discussion with the supplier of the personal protective equipment.

Eye/face protection The following protection should be worn: Wear tight-fitting, dust-resistant, chemical splash
goggles if airborne dust is generated.

Hand protection Barrier cream applied before work may make it easier to clean the skin after exposure, but
does not prevent absorption through the skin. It is recommended that gloves are made of the
following material: Guantes de cuero. The breakthrough time for any glove material may be
different for different glove manufacturers. Considering the data specified by the glove
manufacturer, check during use that the gloves are retaining their protective properties and
change them as soon as any deterioration is detected.

Other skin and body Wear appropriate clothing to prevent repeated or prolonged skin contact. Wear anti-static
protection protective clothing if there is a risk of ignition from static electricity. Appropriate footwear and
additional protective clothing complying with an approved standard should be worn if a risk
assessment indicates skin contamination is possible. Use barrier creams to prevent skin
contact.

Hygiene measures Do not smoke in work area. Wash hands at the end of each work shift and before eating,
smoking and using the toilet. Wash promptly if skin becomes contaminated. Promptly remove
any clothing that becomes contaminated. Use appropriate skin cream to prevent drying of
skin. When using do not eat, drink or smoke. This product contains silica sands.
The grain size distribution of silica sand present means that it is not classified as hazardous.
However, any respirable crystalline dust generated by secondary processing may may cause
health effects.
Prolonged and /or massive inhalation of respirable crystalline silica dust may cause lung
fibrosis, commonly referred to as silicosis. Principal symptoms of silicosis are cough and
breathlessness.
Occupational exposure to respirable crystalline silica dust should be monitored and controlled

Respiratory protection No specific recommendations. Respiratory protection may be required if excessive airborne
contamination occurs.

SECTION 9: Physical and Chemical Properties

9.1. Information on basic physical and chemical properties

Appearance Powder.

Colour Silver.

pH Not applicable.

Relative density 1,12

Solubility(ies) Slightly soluble in water.

Explosive properties Not considered to be explosive. Vapours may form explosive mixtures with air.

Explosive under the influence Not considered to be explosive.

of a flame

9.2. Other information

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Other information Not available.

SECTION 10: Stability and reactivity

10.1. Reactivity
Reactivity Can react with water, liberating hydrogen gas. The following materials may react with the
product: Oxidising agents. Acids. Alkalis. Hydrocarbons - halogenated. See Section 10.3
(Possibility of hazardous reactions) for further information.

10.2. Chemical stability

Stability Stable under the prescribed storage conditions.

10.3. Possibility of hazardous reactions

Possibility of hazardous The following materials may react with the product: Acids. Alkalis. Hydrocarbons -
reactions halogenated. Oxidising agents.

10.4. Conditions to avoid

Conditions to avoid Not relevant.

10.5. Incompatible materials

Materials to avoid Acids. Alkalis. Hydrocarbons - halogenated.

10.6. Hazardous decomposition products

Hazardous decomposition Does not decompose when used and stored as recommended.
products

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Inhalation Dust in high concentrations may irritate the respiratory system. Symptoms following
overexposure may include the following: Coughing.

Ingestion May cause discomfort if swallowed.

Skin contact Prolonged and frequent contact may cause redness and irritation.

Eye contact Dust in the eyes will cause irritation.

SECTION 12: Ecological Information

Ecotoxicity The product is not expected to be toxic to aquatic organisms.

12.1. Toxicity
Toxicity Irrelevante

12.2. Persistence and degradability

Persistence and degradability Irrelevante

12.3. Bioaccumulative potential

Bioaccumulative potential Irrelevante.

12.4. Mobility in soil

Mobility Despreciable.

12.5. Results of PBT and vPvB assessment

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Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB.
assessment

12.6. Other adverse effects

Other adverse effects None known.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

General information Do not empty into drains, sewers or water courses.

Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of the
local Waste Disposal Authority. Empty containers must not be punctured or incinerated
because of the risk of an explosion. Do not pressurise, cut, weld, drill, grind or otherwise
expose containers to heat or sources of ignition. Note that fully cured material is not
considered as hazardous waste.

SECTION 14: Transport information

General The product is not covered by international regulations on the transport of dangerous goods
(IMDG, IATA, ADR/RID).

14.1. UN number
Not applicable.

14.2. UN proper shipping name

Not applicable.

14.3. Transport hazard class(es)

No transport warning sign required.

14.4. Packing group

Not applicable.

14.5. Environmental hazards

Environmentally hazardous substance/marine pollutant

No.

14.6. Special precautions for user

Not applicable.

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78
and the IBC Code

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations The Control of Substances Hazardous to Health Regulations 2002 (SI 2002 No. 2677) (as
amended).

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CEBEX 100

EU legislation Commission Regulation (EU) No 453/2010 of 20 May 2010.

Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16
December 2008 on classification, labelling and packaging of substances and mixtures (as
amended).
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18
December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals (REACH) (as amended).

Guidance Workplace Exposure Limits EH40.

Approved Classification and Labelling Guide (Sixth edition) L131.

15.2. Chemical safety assessment

No chemical safety assessment has been carried out.

SECTION 16: Other information

General information The user must be instructed in the proper work procedure and be familiar with the contents of
these instructions.

Revision comments NOTE: Lines within the margin indicate significant changes from the previous revision.

Revision date 04/06/2015

Revision 8

SDS number 22140

Risk phrases in full NC Not classified.

R11 Highly flammable.
R15 Contact with water liberates extremely flammable gases.
R36 Irritating to eyes.

Hazard statements in full H228 Flammable solid.

H261 In contact with water releases flammable gases.

The information on this data sheet represents our current data and is reliable provided that the product is used under the
prescribed conditions and in accordance with the application specified on the packaging and/or in the technical guidance
literature. Any other use of the product which involves using the product in combination with any other product or any other
process is the responsibility of the user.

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