Hot Dip Coating, Cladding

Download as pdf or txt
Download as pdf or txt
You are on page 1of 18

Surface Coating Processes*

* Processes of covering surfaces with new


materials. This new materials can be metal,
ceramic, organic based (like paints and
plastics) or mixing of them (composite).
Hot dip coating

Hot dip coating of metals is the oldest, easiest and


cheapest technique.
For hot dip coating:
• Coating metal must have low melting point. (Zn, Sn,
Pb, Al)
• Properties of base metal must not change in bath
temperature. Steel is the base metal for hot dip
coating. Also, Sn coated Cu and Al coated Ti or Mo
are used for special purposes.
Advantages of hot dip coating
• Edges, corners and complex shapes can be coated
easily.
• Metallurgical bonding occurs between coating and
base metal and it has resistance to mechanical
damages.
• Corrosion resistance to against to many
atmospheres.
• Maintenance free.
• Long service life. (~70 years)
• Easy to paint.
* The last three of them are especially for hot dip galvanizing.
Hot dip galvanizing (Zinc coating)
It is a commonly used process to protect Fe based products
against to atmospheric, underground and underwater
corrosion.
Zinc coating protects steel in three ways:
1. Continuous zinc film separates steel from its
environment.
2. In case of any discontinuity, zinc behave as a sacrifice
anode for protect steel. (It is a kind of cathodic
protection, Zn is more active than Fe in EMF series.)
3. Zinc provides high corrosion resistance in many
atmospheres. In open air conditions, almost insoluble
zinc carbonate layer [3Zn(OH)2.2ZnCO3] occurs on
galvanized surfaces with time.
Process stages of hot dip galvanizing

• Surface cleaning of base metal.


• Fluxing.
• Galvanizing.
• Post galvanizing treatments.

Surface cleaning: Grease (oil) removing, shot or bead


blasting, alkali cleaning (caustic) and acid cleaning
(pickling).
Fluxing treatments:
Purpose of fluxing:
• Prevent oxidation of metal just before galvanizing
(after cleaning).
• To activate metal surface for easy reaction.
• Provide wetting of molten metal to base metal
surface.
Composition of flux: 87% ZnCl2 + 13% NH4Cl (solution)
• Fluxing in a different bath is called dry galvanizing.
• Fluxing combined with zinc coating is called wet
galvanizing.
Dry galvanizing
• After cleaning, part is dipped into flux solution then
dried and dipped into molten zinc
• Separated fluxing is an easy controlling process.
• It gives more consistent results.
• Dry galvanizing is necessary if zinc bath includes Al.
Wet galvanizing
• Cleaned part is directly dipped into molten zinc.
• Zinc bath is divided into two parts.
• Foamy flux layer is placed on the first part. Metal is
dipped from this part and got out from second part.
• It provides clean and bubble free coating surfaces.
Galvanizing process features
• Tm Zinc: 420 °C
• Molten zinc bath temperature: 445-465 °C
• An alloy layer forms between steel and molten zinc.
Nature and thickness of these alloy layers depend on; steel
composition, bath composition, bath temperature and dipping
time.
1. Steel composition
Si content of the steel is so important. (0.02-0.20)
High Si content causes thick and brittle coating layers.

2. Bath composition (for ordinary galvanizing)


• Purity of zinc must be 99.0% - 99.98%.
• To improve surface tension, small amount of Pb can be added.
• Total amount of additions must not be higher than 1.65%.
3. Bath temperature
• If bath contains 0.3% Al, temperature must be between 445-
465 °C.
• Galfan* (Zn - Al 5%) coating, bath temperature 420 °C.
• Galvalume** (Zn - Al 55%) coating, bath temperature 600
°C. (Take care of base material for structural changes.)

*Galfan: It is a kind of Zn-Al alloy includes 0.05 % Ce and


La, 5% Al. It is an eutectic alloy . It has higher corrosion
resistance also high plastic deformation capability. This coating
is applied in case of post deformation process is required.

**Galvalume coated steel panels are especially used for


roof sidings. It has smoother and brighter appearence than
ordinay galvanizing.
4. Dipping time
• Excessive time causes thicker coatings.
• Complex shape parts need more time.
• Addition of 0.2 – 0.4 % Al to zinc bath provide thin,
more ductile and more bright coatings.
• Reaction between Al and flux decreases quality of
flux. So, dry galvanizing is necessary if bath contains
Al.
Galvalume
Post galvanizing treatments
• Galannealing: Annealing of galvanized coating at ~500 °C.
It develops diffusion between Fe-Zn phases.
• The resulting coating has a matte appearance, and is hard
and brittle.
• Due to iron present in the surface alloy phase galvanneal
develops a reddish patina in moist environments - it is
generally used painted.
• It brings weldability, paintability, higher hardness and
higher resistance to heat. In comparison to a zinc
(galvanized) coating galvannealed has better spot
weldability, and is paintable.
• Phosphate, chromate coatings and painting can be carried
out.
Hot dip aluminium coating
Process temp ~700 °C. Base metal structure can be
changed. Thera are two types coating compositions.

• Type 1: Al-Si (5-11 %) alloy is used.


• Type 2: Commercial purity Al is used.

• Type 1 gives thinner coating and bath temperature is


lower
Cladding (Roll bonding)

Cladding refers to the metallurgical process of coating a


metal onto another metal under high temperature and
pressure so as to protect the inner metal from
corrosion.
Cladding may be done using, aluminium, stainless steel,
anodized aluminium or copper. Of the lot aluminium
cladding is traditionally preferred due to its features
like flexibility, lightweight and recyclable nature.

You might also like