Material Safety Data Sheet

Naphthalene
ACC# 16120
Section 1 - Chemical Product and Company Identification

MSDS Name: Naphthalene

Catalog Numbers: AC164210010, AC164210025, AC180200010, AC180200050,
AC180202500, AC180900010, AC180902500, S76307, S763071, S93309, N134-500, N7-
500
Synonyms: Coal tar camphor; Tar camphor; Naphthalin; White tar; Naphthene; Moth
flakes: Moth balls.
Company Identification:
Fisher Scientific
1 Reagent Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887

Section 2 - Composition, Information on Ingredients

CAS# Chemical Name Percent EINECS/ELINCS

91-20-3 Naphthalene >98 202-049-5

Section 3 - Hazards Identification

EMERGENCY OVERVIEW

Appearance: white solid. Flash Point: 78 deg C.

Warning! Flammable solid. Harmful if inhaled or swallowed. Causes eye, skin, and
respiratory tract irritation. May be harmful if absorbed through the skin. May cause blood
abnormalities. Hygroscopic (absorbs moisture from the air).
Target Organs: Blood, respiratory system, eyes, skin.

Potential Health Effects

Eye: Naphthalene is an eye irritant. The vapor causes eye irritation at 15 ppm. Eye contact
with the solid material may result in conjunctivitis, superficial injury to the cornea,
diminished visual acuity, and other effects. It may cause cataracts.
Skin: Causes mild skin irritation. May be absorbed through the skin in harmful amounts.
Incidence of skin hypersensitivity is not widespread in the general population &, based on
the long history of use of naphthalene as a consumer product, this effect is mostly confined
to industrial exposure where coal tar contamination may be present.
Ingestion: Harmful if swallowed. May cause liver and kidney damage. May cause
methemoglobinemia, cyanosis (bluish discoloration of skin due to deficient oxygenation of
the blood), convulsions, and death. May cause severe digestive tract irritation with
abdominal pain, nausea, vomiting and diarrhea. Ingestion of large quantities may cause
severe hemolytic anemia and hemoglobinuria.
Inhalation: Harmful if inhaled. Causes respiratory tract irritation. Readily absorbed when
inhaled. Material volatilizes at room temperature. Hemolytic anemia (destruction of red
blood cells) is the primary health concern for humans exposed to naphthalene for either
short or long periods of time. Other effects may include nausea, profuse perspiration,
vomiting, kidney damage and liver damage. Optic neuritis (inflammation of the optic nerve)
has been observed. Cataracts have also occurred.
Chronic: Prolonged or repeated skin contact may cause dermatitis. May cause liver and
kidney damage. May cause anemia and other blood cell abnormalities. Animal studies have
reported that fetal effects/abnormalities may occur when maternal toxicity is seen. Effects
may be delayed. Chronic exposure may cause lung damage. Laboratory experiments have
resulted in mutagenic effects. Chronic exposure may cause corneal injury, optical neuritis,
blurred vision, and possible cataract formation. Chronic inhalation, skin absorption or
ingestion of naphthalene have caused severe hemolytic anemia.

Section 4 - First Aid Measures

Eyes: In case of contact, immediately flush eyes with plenty of water for a t least 15
minutes. Get medical aid.
Skin: In case of contact, flush skin with plenty of water. Remove contaminated clothing and
shoes. Get medical aid if irritation develops and persists. Wash clothing before reuse.
Ingestion: If swallowed, do not induce vomiting unless directed to do so by medical
personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Get medical aid.
Notes to Physician: Individuals with a glucose-6-phosphate dehyrogenase deficiency are
hypersensitive to the effects of naphthalene.

Section 5 - Fire Fighting Measures

General Information: As in any fire, wear a self-contained breathing apparatus in

pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Water
runoff can cause environmental damage. Dike and collect water used to fight fire. During a
fire, irritating and highly toxic gases may be generated by thermal decomposition or
combustion. Use water spray to keep fire-exposed containers cool. Flammable solid. Dusts
may be an explosion hazard if mixed with air at critical proportions and in the presence of
an ignition source. Volatile solid that gives off flammable vapors when heated.
Extinguishing Media: Water or foam may cause frothing. Use water spray, dry chemical,
carbon dioxide, or appropriate foam.
Flash Point: 78 deg C ( 172.40 deg F)
Autoignition Temperature: 526 deg C ( 978.80 deg F)
Explosion Limits, Lower:0.90 vol %
Upper: 5.90 vol %
NFPA Rating: (estimated) Health: 2; Flammability: 2; Instability: 0

Section 6 - Accidental Release Measures

General Information: Use proper personal protective equipment as indicated in Section

8.
Spills/Leaks: Avoid runoff into storm sewers and ditches which lead to waterways. Clean
up spills immediately, observing precautions in the Protective Equipment section. Scoop up
with a nonsparking tool, then place into a suitable container for disposal. Avoid generating
dusty conditions. Remove all sources of ignition. Provide ventilation. Do not let this chemical
enter the environment.

Section 7 - Handling and Storage

Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before
reuse. Minimize dust generation and accumulation. Avoid breathing dust, mist, or vapor.
Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Use only with
adequate ventilation.
Storage: Keep away from sources of ignition. Store in a tightly closed container. Store in a
cool, dry, well-ventilated area away from incompatible substances. Storage under a nitrogen
blanket has been recommended. Store protected from moisture. Separate from oxidizing
materials.

Section 8 - Exposure Controls, Personal Protection

Engineering Controls: Use explosion-proof ventilation equipment. Facilities storing or

utilizing this material should be equipped with an eyewash facility and a safety shower. Use
adequate general or local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
 Chemical Name ACGIH NIOSH OSHA - Final PELs
10 ppm TWA; 15 ppm
STEL; Skin - potential
10 ppm TWA; 50 mg/m3 10 ppm TWA; 50 mg/m3
Naphthalene significant contribution
TWA 250 ppm IDLH TWA
to overall exposure by
the cutaneous r oute

OSHA Vacated PELs: Naphthalene: 10 ppm TWA; 50 mg/m3 TWA

Personal Protective Equipment
Eyes: Wear chemical splash goggles.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and
ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever
workplace conditions warrant respirator use.

Section 9 - Physical and Chemical Properties

Physical State: Solid

Appearance: white
Odor: mothball-like
pH: Not available.
Vapor Pressure: 0.05 mm Hg @ 20 deg C
Vapor Density: 4.4 (air=1)
Evaporation Rate:<1.0 (butyl acetate=1)
Viscosity: Not available.
Boiling Point: 218 deg C
Freezing/Melting Point:79 - 82 deg C
Decomposition Temperature:540 deg C
Solubility: Insoluble.
Specific Gravity/Density:0.9900g/cm3
Molecular Formula:C10H8
Molecular Weight:128.17

Section 10 - Stability and Reactivity

Chemical Stability: Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid: Ignition sources, dust generation, moisture, excess heat, exposure to
moist air or water, steam.
Incompatibilities with Other Materials: Strong oxidizing agents.
Hazardous Decomposition Products: Carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide.
Hazardous Polymerization: Will not occur.

Section 11 - Toxicological Information

RTECS#:
CAS# 91-20-3: QJ0525000
LD50/LC50:
CAS# 91-20-3:
Draize test, rabbit, eye: 100 mg Mild;
Inhalation, rat: LC50 = >340 mg/m3/1H;
Oral, mouse: LD50 = 316 mg/kg;
Oral, rat: LD50 = 490 mg/kg;
Skin, rabbit: LD50 = >20 gm/kg;
Skin, rat: LD50 = >2500 mg/kg;
.

Carcinogenicity:
CAS# 91-20-3:

 ACGIH: Not listed.

 California: carcinogen, initial date 4/19/02
 NTP: Suspect carcinogen
 IARC: Group 2B carcinogen

Epidemiology: Incidents in which blankets or clothing containing naphthalene caused acute

hemolysis in infants, in some cases fatal, have been described.The percutaneous absorption
and systemic intoxication with naphthalene can be facilitated by oily vehicles.
Teratogenicity: Naphthalene and its metabolites have been reported to cross the human
placenta in amounts sufficient to cause fetal toxicity.Oral, rat: TDLo = 4500 mg/kg (female
6-15 day(s) after conception).Effects on Embryo or Fetus - fetotoxicity (except death, e.g.,
stunted fetus) and Specific Developmental Abnormalities - other developmental
abnormalities.Intraperitoneal, rat: TDLo = 5925 mg/kg (female 1-15 day(s) after
conception) Specific Developmental Abnormalities - musculoskeletal system and
cardiovascular (circulatory) system.
Reproductive Effects: No information available.
Mutagenicity: Micronucleus Test: Human, Lymphocyte = 30 mg/L.; Cytogenetic Analysis:
Hamster, Ovary = 30 mg/L.; Sister Chromatid Exchange: Hamster, Ovary = 15 mg/L.
Neurotoxicity: No information available.
Other Studies:

Section 12 - Ecological Information

Ecotoxicity: Fish: Rainbow trout: LC50 = 1.60 mg/L; 96 Hr; Flow-through at 15 CFish:
Fathead Minnow: LC50 = 6.14 mg/L; 96 Hr; Flow-through at 24.5 CWater flea Daphnia:
EC50 = 2.16-8.60 mg/L; 48 Hr; UnspecifiedBacteria: Phytobacterium phosphoreum: EC50
= 0.93 mg/L; 30 min; Microtox testFish: Pink salmon: LC50 = 1.24 mg/L; 96 Hr; (fry)
Static bioassay at 12°C Releases into water are lost due to volatilization, photolysis,
adsorption, and biodegradation. The principal loss processes will depend on local conditions
but half-lives can be expected to range from a couple of days to a few months. When
adsorbed to sediment, biodegradation occurs much more rapidly than in the overlying water
column. When spilled on land, naphthalene is adsorbed moderately to soil and undergoes
biodegradation. However, in some cases it will appear in the groundwater where
biodegradation still may occur if conditions are aerobic.
Environmental: Bioconcentration occurs to a moderate extent but since depuration and
metabolism readily proceed in aquatic organisms, this is a short term problem. transport
and disposal of fuel oil, coal tar, etc. In the atmosphere, naphthalene rapidly photodegrades
(half-life 3-8 hr). Naphthalene shows low biological oxygen demand and is expected to
cause little O2 depletion in aquatic systems.
Physical: Log P (oct) = 3.01 - 3.59
Other: Harmful to aquatic life in very low concentrations.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a

hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR
Parts 261.3. Additionally, waste generators must consult state and local hazardous waste
regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series:
CAS# 91-20-3: waste number U165.

Section 14 - Transport Information

US DOT Canada TDG

Shipping Name: NAPHTHALENE, CRUDE NAPHTHALENE
Hazard Class: 4.1 4.1
UN Number: UN1334 UN1334
Packing Group: III III

Section 15 - Regulatory Information

US FEDERAL
TSCA
CAS# 91-20-3 is listed on the TSCA inventory.
Health & Safety Reporting List
CAS# 91-20-3: Effective 6/1/87, Sunset 6/1/97
Chemical Test Rules
CAS# 91-20-3: 40 CFR 799.5115
Section 12b
CAS# 91-20-3: Section 4
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
CAS# 91-20-3: 100 lb final RQ; 45.4 kg final RQ
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 91-20-3: immediate, delayed, fire.
Section 313
This material contains Naphthalene (CAS# 91-20-3, >98%),which is subject to the
reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.
Clean Air Act:
CAS# 91-20-3 is listed as a hazardous air pollutant (HAP).
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 91-20-3 is listed as a Hazardous Substance under the CWA. CAS# 91-20-3 is
listed as a Priority Pollutant under the Clean Water Act. CAS# 91-20-3 is listed as a
Toxic Pollutant under the Clean Water Act.
OSHA:
None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 91-20-3 can be found on the following state right to know lists: California, New
Jersey, Pennsylvania, Minnesota, Massachusetts.

California Prop 65
The following statement(s) is(are) made in order to comply with the California
Safe Drinking Water Act:
WARNING: This product contains Naphthalene, a chemical known to the state of California
to cause cancer.
California No Significant Risk Level: CAS# 91-20-3: 5.8 æg/day NSRL

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
XN N
Risk Phrases:
R 22 Harmful if swallowed.
R 40 Limited evidence of a carcinogenic effect.
R 50/53 Very toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.

Safety Phrases:
S 36/37 Wear suitable protective clothing and gloves.
 S 46 If swallowed, seek medical advice immediately and show this con
tainer or label.
S 60 This material and its container must be disposed of as hazardou
s waste.
S 61 Avoid release to the environment. Refer to special instructions
/safety data sheets.

WGK (Water Danger/Protection)

CAS# 91-20-3: 2
Canada - DSL/NDSL
CAS# 91-20-3 is listed on Canada's DSL List.
Canada - WHMIS
not available.
This product has been classified in accordance with the hazard criteria of the Controlled
Products Regulations and the MSDS contains all of the information required by those
regulations.
Canadian Ingredient Disclosure List
CAS# 91-20-3 is listed on the Canadian Ingredient Disclosure List.

Section 16 - Additional Information

MSDS Creation Date: 5/14/1999

Revision #7 Date: 11/28/2006
The information above is believed to be accurate and represents the best information currently available to us. However,
we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and
we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third
party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if
Fisher has been advised of the possibility of such damage