Synthesis of Biodiesel From Vegetable Oil
Synthesis of Biodiesel From Vegetable Oil
Synthesis of Biodiesel From Vegetable Oil
FROM
VEGETABLE OIL
MASTER OF SCIENCE
IN
CHEMISTRY
BY
SMRUTI REKHA DASH
DEPARTMENT OF CHEMISTRY
NATIONAL INSTITUTE OF TECHNOLOGY
ROURKELA
2007
NATIONAL INSTITUTE OF TECHNOLOGY
ROURKELA
CERTIFICATE
To the best of my knowledge, the matter embodied in the thesis has not been submitted to
any other University / Institute for the award of any Degree or Diploma.
Date
Prof .K .M Purohit.
H .O.D, Dept. of Chemistry
National Institute of Technology
Rourkela- 769008
ACKNOWLEDGEMENT
The author expresses her sincere gratitude and indebtedness to Prof. Kishore Mohan
Purohit, professor & HOD of deptt. of Chemistry, NIT, Rourkela for suggesting the
problem, and his invaluable guidance, advice & kind interest throughout the work.
Sincere thanks of author are also to Dr. Mrs. Mahuya Dasgupta Adak, guest faculty &
research scholar of deptt. Of Chemistry , NIT, Rourkela & Mr. Rabindra Nath Barik of
the same deptt. for the help rendered by them as & when required to carry out the
experiments smoothly & systematically.
The author would like to recall her deep sense of adoration towards her friend Jyotismita
Mohakud & all the staff members of the deptt. for their assitance. The author is thankful
to Mrs. Sushila Singh for typing the manuscript neatly.
The author takes this opportunity to express her gratitude to her parents.
Finally she offers her grateful thanks to the authorities of NIT, Rourkela for the
laboratory facilities provided by them.
My project deals with the synthesis of biodiesel from palm oil a cheaper vegetable oil of
the market.
Palm oil is choosen as the raw material due to its high carbon content, kinetic viscosity &
density. Alkali transesterification procedure is used for the conversion. After production
the newly produced biodiesel is used for characterisation & it is found that it is a
suitable alternate diesel at a relatively higher temperature due to high pour point &
viscosity. It is found that 72-80% conversions make it cost effective alternate diesel fuel.
CONTENTS
1. Introduction
2. History of biodiesel
3. Literature survey
4. Objective
5. Experimental details
6. Result and discussion
7. Biodiesel: fuel of the future
8. conclusion
9. References
CHAPTER-1
INTRODUCTION
INTRODUCTION
1.1 Introductory idea of biodiesel
India is a high energy importing nation where maximum percent of our energy is supplied
by imported fuels since 2006. The diversification of kinds and sources of primary fuel is
becoming vital energy issues in the country .
But the common fossil fuels are not so plentiful and there is a chance to run out
eventually. If an alternative can be found that would convert. plant material to usable
fuels it would demonstrate the green chemistry principle of using renewable starting
materials such as substances derived from the growing plants rather than materials like
fossil fuels that are irreplaceable in short term.
One such process is the manufacture of ‘Bio diesel’ an alternative to diesel fuel from veg-
etable. oil.
Dr. Ruddolf Diesel developed first engine to run on vegetable. oil in 1895 . He
demonstrated his engine at world Estimation is 1900 using peanut as fuel. Before world
war II bio diesel was introduced in south Africa to power heavy duty vehicles. Of late,
environmental and economic concern has renewed the interest in biodiesel throughout
the world, especially in Europe where it is in use from 20 years.
In this regard, biomass energy like biodiesel fuel from waste edible oil is thus
becoming attractive due to the environmental and energy policies for promoting
sustainable development and environmental pollution mitigation. Of the many energy
productions from food wastes or food processing wastes, especially in waste edible oils,
seem to be attractive based on bioresource sustainability, environmental protection and
economic consideration. The energy obtained from waste edible oils is a from of
renewable energy and in principle, utilizing this energy does not add carbon dioxide,
which is one of the major green house gases to the atmospheric environment, in contrast
to fossil fuels. Due to extremely low content of sulphure and nitrogen in the food waste
its direct utilization as fuel in the combustion utilities (e.g internal combustion engine)
generally generates less environmental pollution and health risk as compared to fossil
fuels.
It is well known that the hydrocarbon in the diesel fuels includes a diversity of paraffins,
olefins, napthenes and aromatics. Therefore carbon numbers of theses hydrocarbons
present in the diesel fuels are mostly in the ranges of 12-22. Due to its high energy
conversion and power output in diesel energy conversion and power output in diesel
engines, diesel fuel has been extensively used in heavy trucks, city transport bus, electric
generator farm equipment, etc on the otherhand, edible oil including vegetable oil and
animal fats are principally glycerides (i.e triglycerides) formed from the glycerol and
higher fatty acids(C12-C22) such as Lauric , myristic, palmitic , stearic , oleic, linolenic
& linoleic acids. By way of transesterfication, the reaction of triglycerides with alcohol
(e.g methanol) under the caustic catalyst (e.g potassium hydroxide) is processed to
produce glycerol and monoalkyl esters which are known as biodiesel and can be
potentially used as alternative diesel fuel in compression ignition (diesel) engines. Bio-
diesel, one of green fuels and / or clean energies is compatible with traditional petroleum
based diesel and both can be completely blended without any stratification. From the
view point of its chemical composition and properties, bio-diesel fuels are biodegradable,
low toxic and emit less air pollutants than hydrocarbon based diesel.. However the use of
biodiesel shall face to its high cost relative to petroleum- based oils, and some problems
related to decrease power output and torque force and to the increase in NO x emissions
with increasing biodiesel content in the blends.
1.2 Role of oil to synthesize biodiesel
The catalytic conversion of waste edible oil by the transesterification process into
biodiesel fuel has the advantage of both economic and environmental benefits. In this
regard the biodiesel fuel has been demonstrated to be successfully produced from waste
edible oils by an alkali- catalyzed transesterification process and can be considered as
alternative fuels in diesel engines and other utilities. Because of increasing trend in crude
oil, prices, limited resources in fossil fuels and environmental concern in ambient air
quality, the objective of this paper will give a comprehensive review on the potential
feasibility and regulatory incentives for promoting biodiesel production.
The main subjects covered in this paper are described in the following key elements.
Demonstration case : biodiesel production from waste edible oils.
Due to the increase in the price of the petroleum based oil and the environmental
concerns about pollution coming from the car gases, biodiesel is becoming a developing
area of high concern. There are different ways of production, with different kinds of raw
materials: refine, crude or frying oils. Also there are different types of catalyst basic one
such as sodium or potassium hydroxides, acids such as sulphuric acid, ion exchange
resins, lipases and supercritical fluids.
One of the advantages of this fuel is that the raw materials used to produce it are natural
and renewable. All these type of oils come from vegetables or animal fat, making it
biodegradable and nontoxic.
Dilutedacid
Vegetable oils estirification
Transesterificatio
Methanol + n
KOH
Crude Glycerin
Methanol Crude Biodiesel
Recovery
residue
Glycerine Biodiesel
Biodiesel is manufactured from most vegetable oils of edible & non edible origin, animal
fat & recycled grease through a process called tranesterification. It is the process of
exchanging the alkoxy group of an ester compound by another alcohol. These reaction
are catalyzed by an acid as base.
R ' ' OH + R "O − C O − R → R " O H + R ' O − C O − R
Biodiesel monoalkyl ester is a cleaner burning diesel fuel made from natural,
renewable sources such as vegetable oils. Biodiesel operates in compression ignition
engines like petroleum diesel there by requiring no essential modification, monomer it
can maintain the payload capacity and range of conventional diesel. Biodisel fuel can be
made from new or used vegetable oils and animal fats.
1.4 Advantages of biofuel
The benefits of biodiesel are :
• The lifecycle production and use of biodiesel produces approximately 80% less
carbon dioxide. Combustion of biodiesel alone produces over a 90% reductions
in total unburned hydrocarbons and a 75-90% reduction in aromatic
hydrocarbons. Biodiesel further provides significant reduction in particulates and
carbon monoxide than conventional diesel fuel.
• Biodiesel is the only alternative fuel that runs in any conventional, unmodified
diesel engine.
• Needs no change in refueling infrastructures and spare part inventories.
• Maintains the payload capacity and range of conventional diesel engines.
• Diesel skilled mechanics can easily attend to biodiesel engines,
• 100% domestic fuel.
• Neat biodiesel is non- toxic and biodegradable based on Ames mutagenicity tests,
biodiesel provides or 90% reduction in cancer risk.
• Cetane number is significantly higher than that of conventional diesel fuel.
• Lubricity is improved over that of conventional diesel.
• Has a high flash pt of about 3000F compared to that of conventional diesel, which
has a flash pt of 125 F.
HISTORY OF BIODIESEL
HISTORY OF BIODIESEL
• A substitute for or an additive to diesel fuel that is derived from the oils and fats
of plants.
• A renewable, domestically produced liquid fuel that can help reduce . dependence
on foreign oil imports.
The concept of using vegetal oil as an engine fuel dates back to 1895 when Rudolf Diesel
(1858-1913) developed the first engine to run on peanut oil, as he demonstrated at the
World Exhibition in Paris in 1900. Unfortunately, R. Diesel died 1913 before his vision
of a vegetable oil powered engine was fully realized.
Rudolph Diesel
"The use of vegetable oils for engine fuels may seem insignificant today. But such oils
may become in the course of time as important as the petroleum and coal tar products of
the present time" Rudolph Diesel, 1912
In 1900, Rudolf Diesel demonstrated his compression ignition engine at the World's
Exhibition in Paris. In that prototype engine he used peanut oil, the first biodiesel.
Vegetable oils were used until the 1920's when an alteration was made to the engine
enabling it to use a residue of petroleum diesel. Although the diesel engine gained
worldwide acceptance, biodiesel did not. With superior price, availability, and
government subsidies, petroleum diesel quickly became the fuel of choice for the diesel
engine.
In the mid 1970s, fuel shortages revived interest in developing biodiesel as an alternative
to petroleum diesel. However, as the petroleum market was increasingly subsidized,
biodiesel was again relegated to a minority “alternative” status. This political and
economic struggle continues to limit the impact of the biodiesel industry today.
Now, increasing concerns about the potential of global climate change, declining air and
water quality, and serious human health concerns are inspiring the development of
biodiesel, as a renewable, cleaner burning diesel alternative. Biodiesel is made from
recycled vegetable oil and various feedstock (i.e.- soy beans). As part of an active carbon
cycle biodiesel feedstock production reduces the buildup of greenhouse gases, and in
turn, global warming.
Biodiesel was introduced in South Africa before World War II to power heavy-duty
vehicles. Recent environmental and domestic economic concerns have prompted a
resurgence in the use of biodiesel throughout the world. In 1991, The European
Community (EC) proposed a 90% tax deduction for the use of biofuels, including
biodiesel. Biodiesel plants are now being built by several companies in Europe; each of
these plants will produce up to 5.7 million liters (1.5 million gallons) of fuel per year.
In the United States, biodiesel is also being commercialized. Procter & Gamble Co. is
currently the only U.S. manufacturer of biodiesel (primarily made from soybean oils);
several U.S. demonstration programs, however, use biodiesel to fuel more than 200
vehicles, including buses, trucks, construction/maintenance equipment, and motor boats.
C H A P T E R -3
LITERATURE SURVEY
Literature survey
As biodiesel is gaining considerable global attention & market. Standard are vital
for its commercialization & market introduction.
Biodiesel is a fuel which is made from the organic oils. So, different group of scientists
tried their best to synthesize the biodiesel from different sources like rape seed oil,
soybean oil, fractionated lard & restaurant grease, waste palm oil, waste cooking oil, used
frying oil, olive oil, sunflower oil, recycled cooking oil. Not only the variation in raw
materials but optimization of process parameters can also be done by a host of scientists.
Otara concentrated on transesterification from triglycerides when Klass et. al & krawezyk
reported the transesterification of biomass from renewable energy sources. Fukuda, et.al
& Grabosky, et al pointed the esterification of triglyceride by alkali metal used when
alcohol transesterification was doe by Demirbas, et al.
Beside them analysis of fuel contents and properties of biodisel also attain the site
of other group of scientist like Lin,et al ,Barnwal, et al, Tsai,et al, Chow, et al.
C H A P T E R -4
OBJECTIVE
OBJECTIVE
Different types of vegetable oils are used by previous researchers. literature survey
reveals that palm oil contains better fuel properties yet very little literature survey have
been revealed on this field. Moreover according to the market price crude palm oil is the
cheapest example of vegetable oil which can be used as a source of biodiesel.And India is
the second largest producer of palm oil.
Table –3
Oil/ fat Methyl Iodine no Cetane no
ester
Palm kernel oil 20-26 8 12-18 70
Palm 20-38 14 44-58 65
Palm oleine 20-25 5 85-95 65
Palm stearic 35-40 21 20-45 85
• Table 3 shows it containes fatty manily range from C12 to C22 which is optimum
per production of biodiesel.
• High cetane no, flash point , cloud point, kinetic viscosity and relative density.
• Very easy to handle it.
• Relatively cheaper in market.
• Literature survey reveals very little information about it.
Table –4
Fuel properties of palm oil
Property Unit value
Ester-content % mass 98.5 to 99.5
Density at 150C kg/l 0.873-0.86
Viscosity at 400C mm2/sec 4.415-3.5
0
Flash point C 182-120
0
Cloud point C 15.2-18
0
Pour point C 15
Sulphur content % mass <0.001
Carbon residue % mass 0.02-0.03
Acid value mg KOH/g 58.3 –59
Monoglyceride content % mass <0.4
Diglyceride content % mass <0.2
Triglyceride content % mass <0.1
Total glycerol content % mass <0.01
C H A P T E R -5
EXPERIMENTAL DETAILS
EXPERIMENTAL DETAILS
5.1 METHODOLOGY
For a basic catalyst, either sodium hydroxide (NaOH) or potassium hydroxide (KOH)
should be used with methanol or ethanol and with any kind of oils like refine, crude or
frying. In this process it is better to produce the Alkoxy group before the reaction to
obtain a better globlal efficiency. The reaction is
The oils used could come from any vegetable e.g. corn, canola, peanut sun flower, soy
bean, olive, palm, palm kernel. The amount of catalyst that should be added to the
reactant varies from 0.5% to 1% w/w, but the prefered value lies between 0.005% and
0.35% w/w .
The last but not least important variable is the reaction temperature. The standard value
for the reaction to take place is 600c but depending on the type of catalyst different
temperature will give different degrees of conversion and for that reason the temperature
range should be from 25 to 1200c .
5.1TRANSESTERIFICATION
It is the process of exchanging the alkoxy group of an ester compound by another
alcohol. These reactions are catalysted by the addition of an acid or base.
Alcohol + ester different ester+ different alchol
In the transesterification process of converting vegetable oils to biodiesel the "R" groups
are the fatty acids, which are usually 12 to 22 carbons in length. The large vegetable oil
molecule is reduced to about 1/3 its original size, lowering the viscosity making it similar
to diesel fuel. The resulting fuel operates similar to diesel fuel in an engine. The reaction
produces three molecules of an ester fuel from one molecule of vegetable oil.
Acids can catalyse the reaction by donating a H+ to the carboxyl group, thus making it
more reactive, while bases can catalyse the reaction by removing H+ from the alcohol,
thus making it more reactive.
d [DG ]
dt
[ ]
= K 1 [TG ][ A] − K 2 [DG ][E ] − K 3 [DG ] A + K 4 [MG ][E ]
d [MG ]
dt
[ ]
= K 3 [DG ][ A] − K 4 [MG ][E ] − K 5 [MG ] A + K 6 [E ][GL]
d [TG ]
dt
[ ]
= K 1 [TG ][ A] − K 2 [DG ][E ] + K 3 [DG ] A − K 4 [MG ][E ] + K 5 [MG ][A]
3 3
− K 6 [GL ][E ] + K 7 [TG ][ A] − K 8 [E ] [GL ]
d [A] d [E ]
=−
dt dt
A is alcohol conc. and E denotes ester conc.. Kinetics parameter was estimated using the
equation
K (T) = AT n exp –E/RT
The limits of this technology are due to the sensitivity that this process has to purity of
reactants, to the fatty acid, as well as to the water concentration of the sample.
THEORY:
Carbon residue is expressed in terms of percentage of carbon and determines the amount
of carbon left behind on evaporating an oil sample under specified conditions in a given
apparatus. The result gives information about relative carbon forming property of an oil
which is useful for its use as a lubricant, fuel oil or gas manufacture.
PROCEDURE
The oil is taken in a porcelain or silica crucible of about 30 ml capacity with one or two
glass beads to prevent bumping during heating. The crucible is placed in a skidmore iron
crucible of capacity 65-82 ml containing sand so that the level of the two crucibles are
same. The skidmore crucible is placed in a bigger iron crucible containing sand so that
the level of all the crucible are same. The entire arrangement is placed on a sand and
covered with a hood with a chimney. The heating is done with a meker type burner.
Initially, it is heated strongly so that ignition starts within 10+1 minutes marking the pre
ignition period. When smoke appears over the chimney the burner is tilted so that the
sides of the crucible are heated and the vapours burn. The flame is so adjusted that the
vapours burn uniformly and the burning period is 13+ minutes. When vapour cease to
burn and no more blue smoke is observed the burner is readjusted to heat at the bottom as
in the beginning and heating is continued to red hot for exactly 7 minutes. Thus, the total
heating period is 30+2 minutes. After heating, the arrangement is allowed to cool until no
smoke appears. The hood is then removed and the porcelain crucible is cooled in a
dessicator and weighted.
OBSERVATION & CALCULATION: (Carbon residue)
Weight of crucible + bead = W1 g
Weight of crucible + bead + oil = W2 g (before heating)
Weight of crucible + bead + carbon residue = W3 g (after heating)
weight of carbon residue
% carbon residue = × 100
weight of oil
W 3 - W1
= × 100
W2 - W1
5.7.4 FLASH POINT OF AN OIL BY PENSKY – MARTEINS CLOSED CUP
FLASH POINT APPARATUS.
THEORY:
The flash point of an oil is defined as the minimum temperature at which it gives
sufficient vapours, which when mixed with air forms an inflammable mixture and gives
rise to a momentary flash of light on the application of a pilot flame.
This gives information regarding the volatility of the oil necessary to prevent fire hazards
PROCEDURE:
The oil is placed in the cup provided in the apparatus. The cup is then closed with the
cover and the thermometer placed in its position. The electrical heating system is adjusted
so that the rise in temperature is about 10C in two minutes. The pilot flame is then kept
burning. The heating is continued with constant stirring with the increase in temperature.
Readings are taken at every 50C interval to obtain the approximate flash point value.
Once the flash occurs the temperature is allowed to rise about 50c more and the heating is
then discontinued. Then it is allowed to cool with constant stirring and readings are taken
with every 100c fall to temperature till no flash occurs. Then minimum temp. at which the
flash occurs gives the flash point of the oil.
OBSERVATION
Temp. Remark Temp. Remark
400c No flash 600c Flash
450c No flash 650c Flash
500c No flash 640c Flash
550c No flash 630c Flash
620c Flash
610c Flash
600c Flash
590c Flash
580c Flash
570c No flash
OBSERVATION
Table (titration value)
CALCULATION :
Let the weight of oil dissolved in 100ml of alcohol = W g
Strength of KOH = 1.05 N/50
Titration value = X ml of 1.05 N/50 KOH
Free acid present in 10 ml of the oil solution = Xml of 1.05 N/50 KOH
Hence free acid present in 100ml of the oil solution = 10 Xml of 1.05 N/50 KOH
1000 ml of N KOH = 56 g of KOH
10Xml of 1.05 N/50 KOH =56 /1000 x 10X x 1.05 / 50 x 1000 mg of KOH = A mg of
KOH
Hence the free acid content of w g of the oil = A mg of KOH.
Therefore, free acid content of 1 g of oil = A/W mg of KOH.
RESULTS :
The result is expressed as the nearest whole number by convention.
CHAPTER–6
A. The performance of biodiesel with different properties synthesized from palm oil
was studied and the results are given in Table-7
TABLE 7. FUEL PROPERTIES OF NORMAL AND LOW POUR POINT PALM
DIESEL
Unit Normal Low pour EN 14214
Property ASTM
palm point palm
D6751
diesel deisel
Density at 150 c Kg litre-1 0.8783 0.87 to 0.89 0.86 to 0.90 -
Viscosity at 400c mm2s-1 4.415 4 to 5 3.5 to 5.0 1.9 to 6.0
0
Flash point c 182 150 to 200 120 (min) 130 (min)
0
Pour point c 15 -21 to 0 - -
Sulphur content % mass <0.001 <0.001 0.001 (max) 0.0015 (min)
(grade s15)
0.05 (min)
9grade s500)
Carbon residue % mass 0.02 0.02 to 0.03 0.3 (max) 0.05 (max)
Acid value mg KOH 0.08 <0.3 0.5 (max) 0.8 (max)
-1
g
It was found that flash pt of biodiesel increased as per the percentage of trighlyceride
content.
6.2.2 VISCOSITY:
Viscosity is the measure of a material's resistance to flow. Viscosity is a result of the
internal friction of the material's molecules. Materials with a high viscosity do not flow
readily; materials with a low viscosity are more fluid.SO, it is a Measure of the fluidity of
a substance.
Viscosity affects injector lubrication and fuel atomization. Fuels with low viscosity may
not provide sufficient lubrication for the precision fit of fuel injection pumps or injector
plungers resulting in leakage or increased wear. Fuel atomization is also affected by fuel
viscosity. Diesel fuel with high viscosity tend to form larger droplets on injection which
can cause poor combustion and increased exhaust smoke and emissions.The viscosity of
biodiesel is found to be in the range of 4.52 to 4.76.Which is in agreement with viscocity
of diesel (2.2 to 5.3 cSt at 40C).
The amount of free acid present in fat as measured by the milligrams of potassium
hydroxide needed to neutralize it is the acid value. As the glycerides in fat slowly
decompose the acid value increases. The acid value for biodiesel is1.2 -1.8.For general
diesel the acid no is 0.02. Synthesised kind is found to be in this range.
BIODIESEL:
FUEL OF THE FUTURE
BIODIESEL : FUEL OF THE FUTURE
CONCLUSION
CONCLUSION
In order to make the world greener , the renewable resource are used to replace non-
renewable starting materials. So an alternative way is required to convert the biomass
based energy to useable fuel. It is the principle of green chemistry.
This process deals with the manufacture of biodiesel an alternative to diesel fuel from
vegetable oils.
Biodiesel is a fuel made from organic oils & chemically known as free fatty acid methyle
ester (FAME) depending on the general characteristic value of the common vegetable oil
found in he market it is found that palm oil is the best alternative to produce the
biodiesel due to its high carbon content, could point , kinetic viscosity & relative density.
. Moreover, it is the relatively cheaper in the market.
Alkali transesterification procedure is adopted for the conversion & then the synthesized
biodiesel is used for characterisation .Due to larger fatty acid carbon chain of raw
material the produced biodiesel contains high carbon content & cetane no. Testing
indicated that there will be some problem with palm biodiesel in operating with low
temperature due to having higher pour point perhaps due to greater degree of saturation .
But high flash point & high viscosity indicate a high level of safety for biodiesel.
It is biodegradable & non-toxic in nature. The finished product may be less cost effective
than conventional diesel with respect to the present market price. So, this can be burnt in
normal diesel engine just like the usual diesel.
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