Chemistry, Mathematics & Physics All India Internal Test Series

ALL INDIA INTERNAL TEST SERIES
CHEMISTRY, MATHEMATICS & PHYSICS

SET – A
APT - 4 080165.1 Ai2TS-7
Time Allotted : 3 Hours Maximum Marks: 312
INSTRUCTIONS
 Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
 You are not allowed to leave the Examination Hall before the end of the test.
Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR sheet before
attempting the paper. Wrong CODE or no CODE will give wrong results.
A. General Instructions
 Attempt ALL the questions. Answers have to be marked on the OMR sheets.
 This question paper contains Three Sections.
 Section – I is “Chemistry”, Section – II is “Mathematics” and Section – III is “Physics”.
 Each Section is further divided into two Parts: Part – A & Part – B.
 Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
 Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic devices,
in any form, are not allowed.
B. Filling of OMR Sheet

CLASS XII
1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on OMR
sheet.
2. On the OMR sheet, darken the appropriate bubble with HB pencil for each character of your Enrolment
No. and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
C. Marking Scheme For All Three Parts.
(i) PART-A (01 – 08) contains 8 Multiple Choice Questions which have Only One Correct answer. Each
question carries +4 marks for correct answer and –2 marks for wrong answer.
PART-A (09 – 16) contains 4 Paragraphs. Based upon each paragraph, 2 Multiple Choice Questions have to
be answered. Each question has Only One Correct answer and carries +3 marks for the correct answer and
–1 mark for a wrong answer.
(ii) PART-B (01 – 04) contains 4 Matrix Match Type Question which have statements given in 2 columns.
Statements in the first column have to be matched with statements in the second column. There may be
One or More Than One Correct choices. Each question carries +12 marks for all correct answer however
for each correct row +3 marks will be awarded and –1 mark for each row matched incorrectly.
Name of Candidate :
Batch ID : Date of Examination : / / 2 0 1
Enrolment Number :
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, SarvapriyaVihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
Website: www.fiitjee.com, Mail :[email protected]
2
Ai TS – 7 ( XII ) | SET – A | APT – 4 | Page |1
Section – I (CHEMISTRY)
PART – A
(Single Correct Choice Type)
This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which ONLY ONE is
correct.
1. Which of the following derivatives of benzene would undergo hydrolysis most readily with aq. KOH?
Cl
Cl
O2N NO2
(A) (B)
NO2
NO 2
Cl Cl
NO2
(C) (D)
NO2
N
NO2 H3C CH3
2. CH3
H3C
18
O   A, A is
H2O
H
CH3 CH3
H3C H3C
18OH OH OH OH
(A) (B) 18
CH3 CH3
H3C H3C
O CH3 OH O CH3
OH
(C) Both are correct (D) None is correct
Space for rough work
2
3. What is A in the following reaction?

O
Cl O
t  BuOK
 
t  BuOH
A
O
H5C 2
O O
H3C
O
(A) (B)
C 2 H5 -
C2I
O
O
OH
(C) (D)
O
O C 2 H5
4. O
CH3
is the final product obtained when one of the following is reacted with base.
O O O O
(A) (B)
H3C CH3 H3C CH3
O O
O O
(C) H3C (D)
CH3
H3C CH3
2
5. End product of the following sequence of reaction is

O
1. I2  NaOH,
 
C—CH3 2. H ,
O
O
(A) (B)
Yellow ppt. of CHI3,
Yellow ppt. of CHI3,
COOH
CHO
O
COOH
(C) Yellow ppt. of CHI3, (D) Yellow ppt. of CHI3,
COOH
6. The end product (Z) of the following reaction is


N2Cl 
Cu / KCN
 (X) 
H / H2O
 (Y) 
NaOH
CaO, 
 (Z)
(A) a cyanide (B) a carboxylic acid
(C) an amine (D) an arene
7. An example of a condensation polymer is

(A) PVC (B) terylene
(C) polypropylene (D) polystyrene
8. Sucrose on hydrolysis yields a mixture which is

(A) Optically inactive (B) Dextrorotatory
(C) Laevorotatory (D) Racemic
FIITJEE Ltd., FIITJEE House, 29-A, KaluSarai, SarvapriyaVihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
2
Paragraph
Paragraph (9 – 10)
O

NaOEt / 
Cl

H
 P 
2
h
 Q   R 
NBS
 S 
NaOH
T
9. Compound ‘T’ is
OH OH
(A) (B)
OH OH
OH OH
(C) (D)
OH OH
10. Compound ‘Q’ is

OH OH
(A) (B)
Cl Cl
OH
Cl
(C) (D)
Cl
2

aq.HCl

THF
  X
H3C CxHy O
O O 40o C
CH3
11. The organic compound [X] is
O
(A) (B)
O HO
(C) (D)
O H OH
12. Which of the following describes the correct sequence of organic reactions during the formation of
‘X’?
(A) Acetal hydrolysis first, followed by tautomerisation and then finally acid catalysed aldol
condensation.
(B) Acid catalysed hydration first, then hemiacetal and acetal decomposition and finally acid catalyst
aldol condensation.
(C) Cleavage of ether first, then acid catalysed hydration and finally acid catalysed aldol
condensation.
(D) Acid catalysed hydration first, followed by tautoumerisation and finally acid catalysed alodol
condensation.
2

A carbene is a molecule containing a neutral carbon atom with a valence of two and two unshared valence
electron. Carbene is important reactive species because carbenes are ambiphilic properties. Some
carbenes are aromatic too. Substituents have a profound effect on the reactivity of carbenes, Donor
substituents lower the energy more if they are conjugated to empty P-orbital and electron withdrawing
substituents lower the energy more if they are conjugated to the filled P-orbital.
13. In the following reaction

MeO O
Ph ?
MeO Cl
The product(s) is/are
MeO O O OMe
(A) C (B) C
MeO Cl Cl OMe
O
H O
(C) C (D) C  C  OMe  Me  Cl
MeO OMe Cl
O
14. In the following reaction

Me
+S ?
Me
Which of the following statement is correct for above reaction condition?
(A) There will be no reaction, since the carbene is aromatic and the reagent is nucleophilic.
(B) An adduct is formed in which carbene acts as nucleophile and reagent acts as electrophile due
to availability of vacant d-orbital on central s-atom.
(C) An adduct is formed in which carbene acts as electrophile and thioether acts as nucleophile.
(D) Dimethylthioether undergoes SN2 reaction
2

O
1) H C C Cl AlCl3 CH3OH  Solvent 
Br
3
+
[ U ] 
 V
H2SO4 Cat
 
2) H3O
Mg D2O H3O / H2O
   W    X   Y
ether
15. The compound [X] is

D
O O
(A) H3C C D (B) H3C C D
D
OD OCH3
(C) H3C C D (D) H3C C D
H OCH3
16. The compound [Y] is

D
O O
(A) H3C C D (B) D3C C D
D
O O
(C) D3C C (D) H3C C D
PART – B
(Matrix Match Type)
1. Column-I contains the activated complex of initial reactants and Column-II reflects the effect of
increased solvent polarity on reaction rate. Match the column, now
Column – I Column – II
(A) Y  R X  (P) SN 2, large decrease
(B) (Q) E2, large decrease
Y  R X
(C) (R) SN2, large increase
Y H C C X
(D) (S) SN2, small decrease
Y H C C X
(T) E2, large increase
2
2. Match the column–I with column–II and mark the correct option from the codes given below:
(A) OH (P) OH
Cl  Conc.H2SO4 
Cl2 / AlCl3
 Dil
H SO


2 4
(B) OH (Q) OH
Cl 
Cl2 / AlCl3
CS

2
(C) OH (R) NO 2

Cl2 / AlCl3
 
SnCl2
 
NaNO2 /HCl
H O  

2
Cl
(D) OH (S) NH2
Cl Cl

Cl2 /H2O
 
NaNO2 /HCl
H O  

2
Cl
3. Match the column–I with column–II and mark the correct option from the codes given below:
(A) OH (P) Carbocation
CHCl3
 
KOH, 
CH3
(B) C  CH (Q) Carbanion
2
Hg , H2SO4

H2O
(C) CHCH 2CHO (R) Carbene

dil.NaOH
 
OH 
CH3
(D) CH3 3 C  CH2OH 
Conc.H SO
 2 4 (S) Enol
2
4. Match the columns:

O
(A) Base
 ? (P) Cyclic –  – diketone
CO 2Et
(B) O
PPA,100o C
(Q)  – diketone
 ?
HOAC
OH
O
O Cl
(i )
(C) (R) Bicyclic diketone
?
N ( ii ) H /H2O
O
(D)  i NaNO2  dilHCl (S) Bridged bicyclic diketone
 ?
ii Hydrolysis
2
Ai TS – 7 ( XII ) | SET – A | APT – 4 | P a g e | 10
Section – II (MATHEMATICS)
PART – A
correct.
1. Let a, b, c be three distinct complex numbers such that a  b  c  b  c  a  1, then 3  b  c is

equal to
(A) 1 (B) 2
(C) 3 (D) 4
2. If b  0 , then the roots x1 and x 2 of the equation 2x2  6x  b  0, satisfy the condition
 x1   x 2 
      k , then which of the following values can ‘k’ never exceed.
 x 2   x1 
(A) –3 (B) –5
(C) –6 (D) –2
3. Let bi  1 for i  1,2,.....,101. Suppose loge b1,loge b2 ,.....,loge b101 are in Arithmetic Progression
(A.P.) with the common difference loge 2 . Suppose a1,a2 ,......a101 are in A.P. such that a1  b1 and
a51  b51 . If t  b1  b2  ......  b51 and s  a1  a2  ......  a51 , then
(A) s  t and a101  b101 (B) s  t and a101  b101
(C) s  t and a101  b101 (D) s  t and a101  b101
4. A committee consisting of at least three members is to be formed from a group of 6 boys and 6 girls
such that it always has a boy and a girl. The number of ways to form such committee is:
(A) 212  27  13 (B) 211  26  13
(C) 212  27  35 (D) 211  27  35
 
n
1
Suppose m and n are positive integers and let S    1
k n
5. Ck and
k 0 k  m 1
 
m
1
T    1
k m
Ck ,
k 0 k  n  1
then S  T is equal to:
(A) 0 (B) nm  mn
(C) n  1  m  1 (D) 1  n  1  m
m n m n
6. Let F denote the set of all onto functions from A  a1,a2 ,a3 ,a4  to B  x, y,z . A function f is
chosen at random from F. The probability that f 1 x consists of exactly one element is
2 1
(A) (B)
3 3
1
(C) (D) 0
6
2
3n n
7. Let n  N, Sn   3n Cr and Tn   3n C3r , then Sn  3Tn equals
r 0 r 0
(A) 1 (B) 2
(C) 3 (D) 0
n
8. Suppose a,d   0,   and an  a  n  1 d  n  N . Least value of 
k 1
ak2  ak ak 1  ak21 is
n 1 n
n 1
(A)  ak
n  1 k 1
(B)  ak
n  1 k 1
n n n n1
(C)  ak
n  1 k 1
(D)  ak
n  1 k 2
Paragraph
  i
Let , ,  be three real numbers such that 2  2   2    0 and z 
1 
2
9. z equals
(A)  (B) 1 
 1 
(C) (D)
1  
10.  equals
zz z  z i
 
(A) (B)
2 1 z
2

2 1 z
2

(C)
z  z i (D) none of these

2 1 z
2

A polynomial p  x   a0 xn  a1xn1  .....  an1x  an,a0  0 is said to be a reciprocal equation if
n 
ai  ani for 0  i    where [x] denote the greatest integer  x .
2  
11. If p(x) is a reciprocal polynomial of odd degree, then one of the roots of p  x   0 is
(A) –1 (B) 1
(C) 0 (D)
n  1
2
2
12. If p(x) is a reciprocal equation and a  0 is a root of p  x   0 , then which one of the following is also
a root of p(x) = 0?
1
(A) –a (B)
a
(C) a  1 (D) none of these

Football teams T1 and T2 have to play two games against each other. It is assumed that the
outcomes of the two games are independent. The probabilities of T1 winning, drawing and losing a
1 1 1
game against T2 are , and , respectively. Each team gets 3 points for a win, 1 point for a
2 6 3
draw and 0 point for a loss in a game. Let X and Y denote the total points scored by teams T1 and
T2 , respectively, after two games.
13. P  X  Y  is
1 5
(A) (B)
4 12
1 7
(C) (D)
2 12
14. P  X  Y  is
11 1
(A) (B)
36 3
13 1
(C) (D)
36 2

Let a1,a2 ,a3 ,...... be a harmonic progression such that a1  5 and a20  25
15. Value of n for which an is maximum is

(A) 22 (B) 23
(C) 24 (D) 25
16. Least value of n for which an  0 is

(A) 22 (B) 23
(C) 24 (D) 25
2
PART – B
(Matrix Match Type)
1. Match the equations in column I with their properties in column II
Column-I Column-II
(A) a,b,c  R are such that a  b  c  0 . Equation is (P) has real roots
3ax2  2bx  c  0
(B) a,b,c  R are such that 2a  3b  6c  0 . Equation is (Q) has discriminant > 0
ax  bx  c  0
2
(C) a,b,c  R are such that  a  c   b2 . Equation is (R) has at least one root
2
in (0, 1)
ax2  bx  c  0
(D) b c (S) has a root in
a,b,c  R are such that 1    0 . Equation
a a  ,  1 or a root in
ax  bx  c  0
2
1, 
2. Match the equations in column I with the number of solutions in column II
Column-I Column-II
(A) z2  z  0 (P) 1
(B) 2
z2  z  0 (Q) 3
(C) z2  8z  0 (R) 4
(D) z  2  1 and z  1  2 (S) Infinite
3. Letters of the word INDIANOIL are arranged at random. Probability that the word formed
Column-I Column-II
(A) contains the word INDIAN (P) 1
9
C5
(B) contain the word OIL (Q) 1
 5
C2  7

C2  9!
(C) begins with I and ends with L (R) 1
9
C4
(D) has vowels at the odd places (S) 1
 7
C3  9
C2 
4. The greatest integer contained in
Column-I Column-II
(A)
  (P) 0
2n
2 1
(B)
2  3  (Q) is of the form 4k  1
2n
(C)
2  3  (R) is of the form 2k  1
2n
(D)
 2  1 (S) 2n1  1
2n
2
Section – III (PHYSICS)

PART – A
correct.
1. A block of side  is floating half submerged in water of

density w present in a cubical container of side 2. Height of
free surface of liquid n the container is 1.5 as shown in the
figure. Find of work done by external agent to push the block
slowly just inside the liquid.
3 4  w g 3 4  w g
(A) (B)
5 32
3  w g
4
 w g
4
(C) (D)
16 2
2. A circuit shown consists of two resistances R1 and R2 of

equal and fixed values, a variable resistance R, a capacitor
of capacitance C and an alternating voltage source. If the
variable resistance is made to vary over a wide range, how
does the peak voltage between the terminals A and B
change?
(A) First decreases then increases. (B) First increases then decreases.
(C) Decreases to a constant value. (D) Remains constant
3. Two spherical bodies of masses M and 5M and radii R and 2R respectively are released in free
space with initial separation between their centres equal to 12R. If they attract each other due to
gravitational force only, then the distance covered by smaller body just before collision is
(A) 1.5 R (B) 2.5 R
(C) 4.5 R (D) 7.5 R
R
4. A frictionless tunnel is dug along a chord of the earth at a perpendicular distance from the centre
2
of earth (where R is radius of earth). An object is released from one end of the tunnel. The correct
graph, showing the variation of acceleration of particle with its distance r from centre of earth is
a a
(A) (B)
r r
R R R R
2 2
a a
(C) (D)
r r
R R R R
2 2
2
5. A small solid ball of density  is held inside at point A a cubical

container of side L, filled with an ideal liquid of density 4 as
shown in the figure. Now, if the container starts moving with
constant acceleration a horizontally and the ball is released from Q
P
point A simultaneously, then choose the correct alternative.
L/2
(A) For ball to hit the top of container at end Q, a = 3g
A a
(B) For ball to hit the top of container at end Q, a = 2g
L/2
L
(C) Ball hits the top of container at end Q after a time t = R L S
g
2L
(D) Ball hits the top of container at end Q after a time t =
3g
6. A very long current carrying wire is placed along z-axis

having current of magnitude i1 towards negative z-axis. A i2 y
semicircular wire of radius R and having current i2 is R
placed in x-y plane, such that line joining two end points i1
of the semicircular wire passes through long wire as  R x
shown in figure. Nearest distance of semicircular wire

from long wire is R. Net magnetic force on semicircular
wire will be
 0 i1i2  0 i1i2 3  0 i1i2
(A) ln 3 (B) ln (C) zero (D)
2 2 2 2
7. A charge particle enters into a region containing uniform electric field (E) and uniform magnetic field
(B) along x-axis and y-axis respectively. If it passes the region unaccelerated, the velocity of charge
particle is given by
E E E
(A) 2iˆ + k̂ (B) 2jˆ  kˆ (C) – k̂ (D) none of these
B B B
8. At t = 0 two way switch is connected to point 1 as

shown in the figure so that current growth start in the
LC circuit. At the time t = t0 the switch is shifted
towards point 2. Which of the following cannot be the
possible value of maximum charge which can be
attained by the 8F capacitor.
(A) 15 C (B) 20 C
(C) 35 C (D) 50 C
2
Paragraph
One mole of a monatomic gas undergoes the cycle shown in the
B
diagram: The pressure, volume and temperature at A are P0, V0 2P0
and T0 respectively; the pressure at B is 2P0 and the volume at D
C
is 2V0. The processes AB and CD are isochoric. During BC DA,
the gas undergoes the processes such that during an A
P0
infinitesimal contraction or expansion, the heat absorbed dQ, the
change in internal energy dU and dW, the work done satisfy the D
relation:
1 2
dQ dU dW V0 2V0
2 3
For the process BC, DA, we can write
1 2
dQ = dU  dW  dU  dW
2 3
1 1 1 3 1
or,  dU   dW ; or,  RdT   dW
2 3 2 2 3
13
pdV + Vdp  RdT ; or, pdV + Vdp = 0
9
13
or, pV 9 = constant
9. Find the temperature at C

(A) 2T0 (B) 3T0
(C) 25/9 T0 (D) 35/9 T0
10. What is the efficiency of the cycle? Assume 25 / 9 1.5,24 / 9 4 / 3 approximately

(A) 24% (B) 30%
(C) 36% (D) 42%
2
In a vertical plane, a metal rod of length L and mass m is placed over two conducting platforms A and B. A
region of magnetic field B  B0kˆ starting from line joining A and B and lying over it, is switched on. Now, at
t = 0 switch S is closed such that the charge q passes through the rod in time dt due to which magnetic field
exert an impulsive force which causes the rod to jump with certain velocity and since the gravitational field
is present the rod comes back to AB after some time and collides inelastically and the process is repeated

         B
    L    y
    m    
A B x
S  R
11. The maximum height reached by the rod is

2q2L2B02 q2L2B02 q2L2B02 q2L2B02
(A) (B) (C) (D)
m2 g 2m2 g m2 g 4m2 g
12. The maximum emf induced in the rod is

B02L2 q B02L2 q 2B02L2 q 4B02L2 q
(A) (B) (C) (D)
m 2m m m

y
A uniform conducting ring of mass  kg and
radius 1 m is kept on smooth horizontal table.
A uniform but time varying magnetic field x
B  (iˆ  t 2 ˆj) Tesla is present in the region.
(Where t is time in seconds). Resistance of ring is z
2. Then, (g = 10 m/s2)
(x - z plane is horizontal plane)

13. Time (in second) at which ring start toppling is
10 20 5 25
(A) (B) (C) (D)
   
14. Heat generated (in kJ) through the ring till the instant when ring start toppling is
1 2 2 1
(A) (B) (C) (D)
3  3 
2

A constant current flows through a cylindrical wire of uniform cross-section due to which unit volume
of wire generate thermal power P which is transferred to the surroundings through heat conduction.
If steady state temperature of surface of wire is To
15. Find temperature distribution as a function of r.

P 2 2 To
(A) T  To  (R  r )
4k
P 2 2
(B) T  To  (R  r )
2k r
R
P 2 2
(C) T  To  (R  r )
2k
P Thermal conductivity = k
(D) T  To  (R2  r 2 )
k
16. If a solid conducting sphere is taken in place of the cylinder (assuming all conditions same as
previous question), temperature as function of r will be
P 2 2 P 2 2
(A) T  To  (R  r ) (B) T  To  (R  r )
4k 6k
P 2 2 P 2 2
(C) T  To  (R  r ) (D) T  To  (R  r )
3k 2k
PART – B
(Matrix Match Type)
1. A horizontal thermally insulated cylinder of length 2l is
separated by a thin insulating piston dividing the cylinder in
two equal parts. The piston is connected by ideal springs l l
and initially springs are non-deformed. Left part contains
2 moles of H2 and right part contains 2 moles of O2 at same
initial temperature. The left part of the cylinder is fitted with a
thermostat which maintains the constant temperature of the
gas and through which only heat transfer can take place.
The following two processes are performed on the given
system. After process I, the system is brought back to its
initial state.
Process I: Heat Q is supplied to the right part and piston is displaced to the left by a distance l/2.
Process II: Heat Q is given to the right part and as a result piston displaces to the left by a distance
l/2. The gas on the left dissociates into its atoms.
Column-I Column-II
(A) In process I (P) Temperature of the gas on left remains
constant.
(B) In process I, if piston displaces to (Q) Heat is rejected by the gas on the left.
the right by same amount.
(C) In process II (R) Total work done by both the gases is
positive.
(D) In process II if partial dissociation (S) Heat is absorbed by the gas on the left.
has taken place
2
2. Magnetic field B0 is present in the region X = 0 to X = L y

along –ve z-axis. A charge particle having charge q   
and mass m enters in magnetic along x-axis with speed   
mv 0    x
v0. If L  , angle of deviation is 1 and time spent   
2qB0
  
3 mv 0
in magnetic field is t1 and if L  angle of X=0 X=L
2 qB0
deviation is 2 and time spent in magnetic field is t2,
then
Column-I Column-II
(A) 1 is (P) m
6qB
(B) 2 is (Q) m
3qB
(C) t1 is (R) /3
(D) t2 is (S) /6
(T) /2
3. The central cross-section of a long cylindrical 

 V

region containing uniform but time varying     
magnetic field B is shown. A particle of constant 
    q, m
mass and variable positive charge moves in a 
   
circle in the plane, so that the radius of the circle 
 
remains constant.  
Column-I Column-II
(A) If the magnetic field is increased by (P) decrease
2%, the speed of the particle will
(B) If the magnetic field is decreased by (Q) increase
4%, the speed of the particle will
(C) If the magnetic field is increased by (R) change by 1%
2%, the charge of the particle will
(D) If the magnetic field is decreased by (S) change by 2%
4%, the charge of the particle will
2
4. Match the statements in Column I with the result in Column II.
(A) A thin uniform spherical shell of surface area S has an (P) Is independent of S
initial temperature more than its surrounding
atmosphere. Then magnitude of rate of change of its
temperature with time
(B) A soap bubble initially in equilibrium is given a charge (Q) Depends on S
Q, which distributes uniformly over its surface. The
centre of the bubble is always fixed. For the duration
the bubble having surface area S expands the
magnitude of electric potential at a fixed point always
lying outside the bubble
(C) A container with open top and filed with ideal liquid is (R) Remains constant
placed at rest on a smooth horizontal table. A small
hole of area S is drilled at the bottom of a side wall of
container. The magnitude of force exerted by escaping
liquid on the container
An infinitely long straight current carrying wire lies (S) Decrease with time
along the axis of a closed cylindrical surface of total
(D) surface area S is space. As the magnitude of current in
the wire is continuously increased, the magnitude of the
magnetic flux through the surface of this cylinder

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ALL INDIA INTERNAL TEST SERIES

CHEMISTRY, MATHEMATICS & PHYSICS

B. Filling of OMR Sheet

C. Marking Scheme For All Three Parts.

Batch ID : Date of Examination : / / 2 0 1

Space for rough work

3. What is A in the following reaction?

Space for rough work

5. End product of the following sequence of reaction is

6. The end product (Z) of the following reaction is

7. An example of a condensation polymer is

8. Sucrose on hydrolysis yields a mixture which is

10. Compound ‘Q’ is

Space for rough work

Paragraph (11 – 12)

Paragraph (13 – 14)

13. In the following reaction

14. In the following reaction

Paragraph (15 – 16)

15. The compound [X] is

(A) H3C C D (B) H3C C D

(C) H3C C D (D) H3C C D

16. The compound [Y] is

(C) CHCH 2CHO (R) Carbene

Space for rough work

4. Match the columns:

Space for rough work

1. Let a, b, c be three distinct complex numbers such that a  b  c  b  c  a  1, then 3  b  c is

Paragraph (13 – 14)

Paragraph (15 – 16)

15. Value of n for which an is maximum is

16. Least value of n for which an  0 is

Space for rough work

Section – III (PHYSICS)

1. A block of side  is floating half submerged in water of

2. A circuit shown consists of two resistances R1 and R2 of

5. A small solid ball of density  is held inside at point A a cubical

6. A very long current carrying wire is placed along z-axis

shown in figure. Nearest distance of semicircular wire

8. At t = 0 two way switch is connected to point 1 as

Space for rough work

9. Find the temperature at C

10. What is the efficiency of the cycle? Assume 25 / 9 1.5,24 / 9 4 / 3 approximately

Space for rough work

Paragraph (11 – 12)

11. The maximum height reached by the rod is

12. The maximum emf induced in the rod is

Paragraph (13 – 14)

(x - z plane is horizontal plane)

Paragraph (15 – 16)

15. Find temperature distribution as a function of r.

2. Magnetic field B0 is present in the region X = 0 to X = L y

3. The central cross-section of a long cylindrical 

Space for rough work

4. Match the statements in Column I with the result in Column II.

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