Project On Name Reaction PDF
Project On Name Reaction PDF
Project On Name Reaction PDF
in 8445151733
1. SANDMEYER REACTION
The DIAZONIUM (C6H5N2Cl) is prepared by treating ice cold solution of ANILINE
(C6H5NH2) in excess of dilute HCl with an aqueous solution of NaNO2 at low
temperature (0-5)°C and the reaction is known as DIAZOTIZATION REACTION.
BROMO and CHLORO ALKANES can be prepared by treating a freshly prepared
DIAZONIUM SALT with CUPPEROUS BROMIDE or CUPPEROUS CHLORIDE and
this reaction is called as SANDMEYER REACTION.
2. GATTERMANN REACTION
This Reaction is same as SANDMEYER REACTION. But the only difference
between both of them is that here we use COPPER POWDER (Cu) in the presence
of HCl/HBr, and in SANDMEYER REACTION we use Cu2Cl2/Cu2Br2 as catalyst.
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3. BALZ-SCHIEMANN REACTION
It is a method of preparation of FLOUROBENZENE. In this method DIAZONIUM
SALT is reacted with FLOUROBORIC ACID, followed by heating the complex
compound formed.
4. FINKELSTEIN REACTION
ALKYL IODIDE (R-I) are often prepared by the Reaction of ALKYL CHLORIDE (R-
Cl) or ALKYL BROMIDE (R-Br) with SODIUM IODIDE (NaI) in Dry Acetone.
5. SWARTZ REACTION
FLOUROALKANE (ex. – CH3CH2F) are prepared by treating ALKYL CHLORIDE
(ex. – CH3CH2Cl) or BROMIDE (ex. – CH3CH2Br) in the presence of metallic
FLOURIDES such as AgF, Hg2F2, CoF2 etc.
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6. WURTZ REACTION
ALKYL HALIDE/HALOALKANE react with metallic SODIUM in the presence of DRY
ETHER to form ALKANE containing double the no. of CARBON atom as present
in parent ALKYL HALIDE.
7. FITTIG REACTION
Aryl Halides prepared with Sodium (Na) in dry ether to give analogous
compounds where two aryl groups joined.
8. WURTZ-FITTIG REACTION
When a mixture of Alkyl Halide and Aryl Halide gets treated with sodium in dry
ether, we get an Alkyl Arene.
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9. KOLBE-SCHMITT REACTION
SODIUM PHENOXIDE (C6H5ONa) when heated with CARBON DIOXIDE (CO2) at
400 Kelvin under a pressure of (4-7)atm followed by acidification gives
2-HYDROXYBENZOIC ACID (SALICYLIC ACID) as the main product. This Reaction
is called KOLBE’S REACTION.
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22. WILLIAMSON SYNTHESIS
It is an important Laboratory method for the preparation of Symmetrical and
Unsymmetrical ETHER. In this method an ALKYL HALIDE is allowed to react with
SODIUM ALKOXIDE.
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29. COUPLING REACTION
Benzene diazonium chloride gets reacted with phenol in which the phenol
molecule at its para position is mixed with the diazonium salt to give p-
hydroxyazobenzene.
Preparation of Iodobenzene
Replacement of the DIAZONIUM Group by IODINE is done simply by Shaking the
DIAZONIUM SALT with KI.
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