Amines: Elnora Listianto Nabilla Savitri Wulan Sutardiman
Amines: Elnora Listianto Nabilla Savitri Wulan Sutardiman
Amines: Elnora Listianto Nabilla Savitri Wulan Sutardiman
AMINES
ELNORA LISTIANTO
NABILLA SAVITRI
WULAN SUTARDIMAN
WHAT ARE AMINES?
WHAT ARE AMINES? SUB-TOPICS
AROMATIC
Nitrogen bonded to aryl groups
Question 1:
Can you determine which one is
a heterocyclic aliphatic amine?
Answer:
Neither. Both are heterocyclic
aromatic amines.
Purine and Imidazole.
How Amines
are named?
Alkanamines (Aliphatic Amines)
Replacing suffix -e in parent alkane with -amine
2- Butanamine 1-Phenylethanamine
Aromatic Amines
simplest ; Aniline (C6H5NH2)
derivatives ; named with prefixes ( -o,-m,-p ) or numbers
to locate the substituent + suffix - aniline
N -methylbutanamine N , N -dimethyl-butanamine
AMINES HAS
THE LOWEST
PRIORITY
than alcohol
Priority and
2-AMINOPROPANOL
carboxylic
acid
USE PREFIX
AMINO- AMINOETHANOIC ACID
COMMON NAMES
ALKYLAMINES
TERT-BUTYLAMINE DICYCLOHEXYLNAMINE
AMMONIUM SALT
Characteristics
and Physical
Properties of
Amines ?
AMINES ARE..
POLAR SOLUBLE IN
COMPOUNDS Presentations are WATER
communication tools
that can be used as
demonstrations.
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AMINE'S HYDROGEN BOND AND
BOILING POINT
BASE PROPERTIES OF
AMINES?
All amines = weak
bases.
Aqueous solutions of
amines are basic.
Proton-transfer
reaction happens
(nitrogen is a proton
acceptor).
Kb = base ionization
constant
IN SHORT,
Electron-
ALIPHATIC AROMATIC withdrawing
groups
1 2
How do Amines AMINES + STRONG ACIDS
React with Acid? WILL PRODUCE WATER-
SOLUBLE SALT!
Question 5
Answer :
HOW DO AMINES
ACT AS
NUCLEOPHILES?
amines
are moderate
nucleophiles.
Step 1
REACTION OF AN
ELECTROPHILE AND A
NUCLEOPHILE
nucleophile electrophile
Step 2
TAKE A PROTON AWAY
unreacted starting
material
Step 3
REACTION OF AN
ELECTROPHILE AND A
NUCLEOPHILE
unreacted starting
material
Q U E S T I O N 6
AMINE IS
CHATEGORIZED AS ...
NUCLEOPHILE
AMINE IS
CHATEGORIZED AS ...
NUCLEOPHILE