"Tailor made reagents"

CHEM-LAB NV
Industriezone “De Arend” 2
B-8210 ZEDELGEM - BELGIUM
Tel.: (32)-50-288320
Fax.: (32)-50-782654

SAFETY DATA SHEET

1. Identification of the substance / preparation and company.

1.1 Product identifier

Product Nr. CL02.1207
Trade name Luff-Schoorl reagent
REACH A registration number is not available for this substance as the substance or its use are
Registration exempted from registration according to Article 2 REACH Regulation (EC) No 1907/2006, the
Number annual tonnage does not require a registration or the registration is envisaged for a later
registration deadline.
1.2 Relevant identified uses of the substance or mixture and uses adviced against
Identified uses: Reagent for analysis
In compliance with the conditions described in the annex to this safety data sheet.
1.3 Information provided by CHEM-LAB NV product service.
Responsible department: e-mail: [email protected]
1.4 Emergency telephone: 00 (32) 50.28.83.20

2. Hazard identification

2.1 Classification of the substance or the mixture (EG 1272/2008)

Hazardous to the aquatic environment, Categorie 3, H412

For the full text of H-sentences mentioned in this Section, see Section 16

Classification (REGULATION (EC) No 1272/2008) (67/548/EEG or 1999/45/EF)

N Dangerous for environnement R52/53

For the full text of R-sentences mentioned in this Section, see Section 16

2.2 GHS-Labelling
GHS-Labelling Labelling (REGULATION (EC) No 1272/2008) (EG 1272/2008)
Hazard pictograms:

Signal word:

Hazard statements:
H412 Harmful to aquatic life with long lasting effects.

Precautionary statements:
P273 Avoid release to the environment.

Reduced labelling
Hazard pictograms:

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 Signal word:

3. Composition / Information on ingredients.

3.1 Substance
Not applicable

3.2 Mixture
Formula 0.1 N Cu in 2 N Na2CO3

4. First aid measures.

4.1 Description of first aid measures

General advice

First-aid personnel: ensure self-protection!

After inhalation: Fresh air.

After contact with skin: Wash off with plenty of water. Remove contaminated clothing.

After contact with eyes: Rinse out with plenty of water with the eyelid held wide open.

After ingestion: Never give anything by mouth to an unconscious person. Immediately make victim drink water
(two glasses at most). Call in physician.

4.2 Most important symptoms and effects, both acute and delayed

The most important known symptoms and effects are described in the labeling (see section 2.2) and/or in
section 11

4.3 Indication of any immediate medical attention and special treatment needed

no data available

5. Fire fighting measures.

5.1 Extinguishing media

Suitable extinguishing media
In adaption to materials stored in the immediate neighbourhood.
Unsuitable extinguishing media
Not of application.

5.2 Special hazards arising from substance or mixture

Non-combustible.

5.3 Advice for firefighters

Do not stay in dangerous zone without self-contained breathing apparatus.

5.4 Further information

no data available

6. Accidental release measures.

6.1 Peronal precautions, protective equipment and emergency procedures

Do not inhale vapours/aerosols. Avoid substance contact. Ensure supply of fresh air in enclosed rooms.
For personal protection see section 8.

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 For personal protection see section 8.

6.2 Environmental precautions

Do not allow to enter sewerage system.

6.3 Methods and materials for containment and cleaning up

Absorb on vermiculite, sand or a pillow from Chemical Spill Center.

6.4 Reference to other sections

For disposal see section 13.

7. Handling and storage.

7.1 Precautions for safe handling

No special measures necessary. The product should be handled with the care usual when dealing with
chemicais.
For precautions see section 2.2

7.2 Conditions for safe storage, including any incompatibilities

Tightly closed.
Recommended storage temperature see product label.

7.3 Specific end use(s)

Apart from the uses mentioned in section 1.2 no other specific uses are stipulated.

8. Exposure controls - Personal protection.

8.1 Control parameters

8.2 Exposure controls

Engineering measures
Protective clothing should be selected specificlly for the working place, depending on concentration and
quantity of the hazardous substances handled. The resistance of the protective clothing to chemicals should be
ascertained with the respective supplier.

See section 7.1

Individual protection measures

Immediately change contaminated clothing. Wash hands after working with substance.

Respiratory protections
Required when vapours/aerosols are generated.
The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are
carried out according to the instructions of the producer. These measures have to be properly documented.

Eye protection
Required.

Hand protection
Required.

Body protection
Not required.

Environmental exposure controls

Do not allow to enter sewerage system.

9. Physical and chemical properties.

9.1 Information on basis physical

Appearence
Form: liquid

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 Form: liquid
Colour: blue
Odour: odourless
Changes in physical state
Melting Point:
Boiling point:
Flash point: -
Ignation temperature:
Mol. Weight:
Density: 1,14 g/ml
pH value: pH > 9
Solubility in water: soluble
Explosion limits:
9.2 Other data
No further relevant information available.

10. Stability and reactivity.

10.1 Reactivity

See section 10.3

10.2 Chemical stability

No further relevant information available.

10.3 Possibility of hazardous reactions

Dangerous reactions are not expected handling the product according to its intended use.

10.4 Conditions to avoid

No further relevant information available.

10.5 Incompatible materials

No further relevant information available.

10.6 Hazardous decomposition products

No further relevant information available.

11. Toxicological information.

11.1 Information on toxicological effects

Acute oral toxity

Quantitative data on the toxicity of this product are not available.

Acute inhalation toxity

No further relevant information available.

Acute dermal toxity

No further relevant information available.

Skin irritation
No further relevant information available.

Eye irritation
No further relevant information available.

Sensitisation
No further relevant information available.

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 No further relevant information available.

Germ cell mutagenicity

No further relevant information available.

Carcinogenicity
No further relevant information available.

Reproductive toxity
No further relevant information available.

Teratogenicity
No further relevant information available.

Specific target organ toxity - single exposure

No further relevant information available.

Specific target organ toxity - repeated exposure

No further relevant information available.

Aspiration hazard
No further relevant information available.

11.2 Further information

No further relevant information available.
Further data:
Handle in accordance with good industrial hygiene and safety practice..

12. Ecological information.

12.1 Toxity
No further relevant information available.
12.2 Persistence and degradability
No further relevant information available.

12.3 Bioaccumulative potential

No further relevant information available.

12.4 Mobility in soil

No further relevant information available.

12.5 Results of PBT and vPvB assessment

No further relevant information available.

12.6 Other adverse effects

Do not allow to enter waters, waste water, or soil!

13. Disposal considerations.

Product: Chemicals must be disposed of in compliance with the respective national regulations. Packaging: Chem-lab
product packaging must be disposed of in compliance with the country-specific regulations or must be passed to a
packaging return system.

14. Transport information.

Land Transport (ADR/RID)

14.1 UN number UN 3082
Environmentally hazardous
14.2 Proper shipping name substance, liquid, n.o.s.
14.3 Class 9
14.4 Packing group III
14.5 Environmentally hazardous yes
14.6 Special precautions for user

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 14.6 Special precautions for user no
Tunnel restriction code (E)

Inland waterway transport (ADN)

Not relevant

Air Transport (IATA)

14.1 UN number UN 3082
Environmentally hazardous
14.2 Proper shipping name substance, liquid, n.o.s.
14.3 Class 9
14.4 Packing group III
14.5 Environmentally hazardous yes
14.6 Special precautions for user no

Sea Transport (IMDG)

14.1 UN number UN 3082
Environmentally hazardous
14.2 Proper shipping name substance, liquid, n.o.s.
14.3 Class 9
14.4 Packing group III
14.5 Environmentally hazardous yes
14.6 Special precautions for user no

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not relevant

15. Regulatory information.

15.1 Safety, health and environmental regulations/legislation speficic for the substance or mixture
For this product an assessment was not carried out.

15.2 Chemical Safety Assesment

For this product an assessment was not carried out.

16. Other information.

The information and recommendations in this MSDS are to the best of our knowledge, information and belief accurate
at the date of publications. Although outmost care has been taken in the composition of this text, the publisher cannot
be held responsible for any damage resulting from any possible error in this publications.

Full text of H-Statements referred to under sections 2 and 3.

H412 Harmful to aquatic life with long lasting effects.

Full text of R-phrases reffered to under section 2 and 3.

R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

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