Chemistry
Chemistry
Chemistry
Kukatpally, Hyderabad.
1) T1 T2 T3 2) T3 T1 T2 2) 17.54 mmHg
3) 35.08 mmHg
3) T1 T2 T3 4) T1 T2 T3
4) between 8.77 and 17.54 mmHg
02. Given at 350K P o 300 torr and
A 04. A sample of air is saturated with benzene
PBo 800 torr, the composition of the (vapor pressure = 100 mmHg at 298 K) at
mixture having a normal boiling point 298 K, 750 mm Hg pressure. If it is
of 350 K is: isothermally compressed to one third of
1) X A 0.08 2) X A 0.06 its initial volume, the final pressure of the
3) X A 0.04 4) X A 0.02 system is
03. The vapour pressure of water at 200 C 1) 2250 torr 2) 2150 torr
vapour pressure of the water in the 05. Assuming the formation of an ideal
apparatus shown after the piston is solution, determine the boiling point of a
1) 900 C 2) 1000 C
3)1100 4) 1200 C 1) C2 C3 2) C1 C2
06. Barium ions, CN and Co 2 form an 3) C1 C3 4) Both (1) and (2)
ionic complex. If that complex is 08. When only a little quantity of HgCl2 s is
supposed to be 75% ionized in water added to excess KI(aq) to obtain a clear
with vant Hoff factor ‘i’ equal to four, solution, which of the following is true
2
then the coordination number of Co for this solution ? (no volume change on
in the complex can be: mixing). The reaction is
1) Six 4KI aq HgCl2 s K2 HgI4 aq. 2KCI aq.
2) Five
1) Its boiling and freezing points remains
3) Four
same
4) Six and Four both
2) Its boiling point is lowered
07. Dry air is slowly passed through three
3) Its vapour pressure become lower
solutions of different concentrations,
4) Its freezing point is lowered.
at (– 1.86o C). Assuming molality equal with 500 ml of 0.4M Na 2SO4 solution
to molarity, pH of CH3COOH solution
3) 0.3M glucose solution
is:
4) 0.1M Ba 3 PO4 2
solution.
1) 2 2) 3
3) 3.2 4) 4.2
space for rough work Page 5
19. pH of a saturated solution of silver salt 21. What is the maximum concentration of
of monobasic acid HA is found to be Mg 2
that can be introduced into a
9. Select the option(s) which is / are solution containing 0.1 M NH3 and
10
correct. Given: K a HA 10
0.01 M NH4 without causing
a) Solubility of the silver salt is precipitation of Mg OH 2
? K b of
1.1 10 5 mol / lit NH3 10 6 , K sp of Mg OH 2
1.2 10 12
of the function. f(x) = x2 + 2x – 1 and 36. The point (4, 1) undergoes the following
A point P is taken on ‘L’ such that moves on the line 2 x 3 y 1 , then the
2 1 1 locus of the vertex C is the line
then the locus of P is
OP OA OB
1) 2 x 3 y 9 2) 2 x 3 y 7
1) 3x 3 y 40 2) 3x 3 y 40 0
3) 3x 2 y 5 4) 3x 2 y 3
3) 3x 3 y 40 4) 3 y 3x 40
space for rough work Page 11
48. The coordinate axes are rotated are exhausted. Then the coordinates of
through an angle 220 about the origin, the final point so obtained is
If the equation lx1 mx2 kx3 ly1 my2 ky3
1) ,
l m k l m k
4 x 2 12 xy 9 y 2 6 x 9 y 2 0 changes
x1 y1
to ax2 2hxy by 2 2 gx 2 fy c 0 then 2) ,
n 1 n 1
h 3 h
1) 2) 3
a 5 c xi yi
3) ,
g 1 a i i
3) 4) 4
c 2 c
xi yi
4) ,
49. The coordinate axes are rotated n n
through an angle about the origin in
51. Let S1 , S2 ,..... be the squares such that for
anticlock wise sense, If the equation
each n 1 the length of the side Sn is
2 x 2 3xy 6 x 2 y 4 0 changes to
equal to length of the diagonal of Sn 1 . If
2 2
ax 2hxy by 2 gx 2 fy c 0 then
the length of the side of S1 is 10 cm, then
a+b=
the least value of n for which area of
1)1 2)0
Sn 1 sq.cm given by
3)2 4)3
1) 7 2) 8
50. A1 , A2 , A3..... An are n points whose
3) 9 4) 10
coordinates are
52. If the square ABCD where
x1 , y1 , x2 , y2 , x3 , y3 ..... xn , yn . A1 A2 is
A 0, 0 , B 2, 0 , C 2, 2 and D 0, 2
bisected at G1.G1 A3 divided in the ratio
undergoes the following three
1:2 at G2 .G2 A4 is divided in the ratio
transformations successively
1:3 at G3 and so on until all the points
i) f1 x, y y, x
1) xy 2 x 4 y 64 the points x1 , y1 , x2 , y2 , x3 , y3 , x4 , y4
2) xy 2 x 4 y 0 are
3) xy 4 x 2 y 8 0 1) The vertices of a rectangle
4) xy 4 x 2 y 72 2) Collinear
55. P and Q are two variable points on the 3) The vertices of a trapezium
axes of x and y respectively such that 4) Rhombus
59. The maximum area of the triangle particles travels along a straight line.
8m1m2
1) M
4Mmg 2Mmg m1 m2
1) M0g 2) M0g
M m M m 4m1m2
2) m0
4Mmg 2Mmg m1 m2
3) M0g 4) M0g
M m M m
3) If the string just above m2 is cut all
70. A block is slides down a smooth
remaining masses fall with different
accelerations
The maximum value of its horizontal
4) If the string just above m2 is cut all
component of acceleration is
remaining masses fall with same
1) gcos 2) g/2
acceleration
g cos
3) 4) g/4
2
1) 2Sdg 2) Sdg
3) Sdg/2 4) None
figure. The spring and the strings are 4…… have masses
observed that the level of water contact force between the blocks 1 and 2
L 2L
3) 4)
g 2 g
1) 2L/3 2) 2L/5
3) L/2 4) L/5
79. In the system shown all the surface of
1) 0.2 2) 0.4 contact are smooth and the pulleys are
3) 5 4) 2.5 ideal and the string is light. Block on the
78. In the system shown in the figure the incline surface of A is ‘m’. Mass of A
two springs S1 and S2 have force and B are respectively ‘4m’ and ‘2m’.
constant ‘K’ each. Initially the system The acceleration of the wedge ‘A’ when
is in equilibrium with spring S1 the system is released from rest is
stretched and the spring S2 relaxed.
The end A of the string is pulled down
slowly through a distance ‘L’. The
distance by which the block of mass
‘M’ moves is
1) 6g/47 2) 9g/47
3) 3g/47 4) 2g/47
mv2
100/6 ms-2
directed towards the center
r 4) Acceleration of 4kg block is 5ms-2
4) The resultant of the other forces 82. In the figure there are two particles A and
varies in direction not in magnitude B each of mass ‘m’. A is connected to the
81. In the given diagram the pulley is ceiling by a light inextensible string OA
friction less and massless. Both the and B is connected to A by light
springs are having same force constant inextensible string AB. Initially the line
10N/m. Initially with the string OB is vertical. System is released from
attached to the ground the total system
is at rest. Now the string is cut, then 5
respectively. Then the value of
2
immediately after cutting the string
pick out the INCORRECT option of is
the following.
1) 4 2) 5
3) 7 4) 6
85. Block A is on a frictionless horizontal
table. A massless and inextensible string
fixed at one end passes over a smooth
1) Velocity of block C is 25/6 ms-1
nail fixed with the block A. The other end
2) Velocity of the block C is 30 ms-1
space for rough work Page 22
is connected to block B of mass m as
shown in the figure. Initially the block
0
. The
magnitude of the acceleration of the
block B just after the it is released is --
-----ms-2(take g=10ms-2)
F02 T2
1) u 2) u
2m 8m
F0T F0T
3) u 4) u
4m 2m
87. Two masses m and M are attached with
strings as shown. For the system to be in
equilibrium we have
1) 2 2) 4
3) 3 4) 5
86. A particle of mass m, initially at rest, is
acted upon by a variable force F for a
brief interval of time T. It begins to
move with a velocity u after the force
2M 2m
stops acting. F is shown in the graph as 1) tan 1 2) tan 1
m M
a function of time. The curve is an M m
3) tan 1 4) tan 1
2m 2M
ellipse.
88. A string of negligible mass going over a
clamped pulley of mass m supports a
block of mass M as shown in the figure.
2
4) M m M2 g
4) g sin a0 cos
1 1 1 1
1) tan 2) tan
2 2 3
1 1 1 1
3) tan 4) tan
3 3 4 3
space for rough work Page 24
Master JEE CLASSES
Kukatpally, Hyderabad.
IIT-JEE-MAINS PAPER-3
Max. Marks: 360
KEY SHEET
CHEMISTRY
1 1 2 1 3 2 4 3 5 2 6 2
7 4 8 2 9 1 10 2 11 3 12 1
13 4 14 1 15 2 16 2 17 1 18 3
19 4 20 2 21 1 22 3 23 3 24 2
25 3 26 4 27 2 28 2 29 1 30 3
MATHS
31 1 32 3 33 3 34 2 35 4 36 3
37 2 38 1 39 3 40 2 41 2 42 4
43 1 44 4 45 1 46 1 47 1 48 2
49 3 50 4 51 2 52 2 53 3 54 2
55 2 56 4 57 1 58 2 59 1 60 1
PHYSICS
61 2 62 4 63 2 64 1 65 3 66 1
67 4 68 1 69 1 70 2 71 3 72 3
73 1 74 2 75 1 76 1 77 1 78 2
79 1 80 2 81 3 82 1 83 3 84 2
85 1 86 3 87 1 88 4 89 3 90 4
SOLUTIONS:
CHEMISTRY
1. P K m X
1
As T Km i.e. slope
Km
T3 T2 T1
2. P0 300 torr
A
P0 800 torr
B
500X A 40
40
XA 0.08
500
3. po 17.54
v
After V2 , V.P of H 2O does not change
2
v
vapour corresponding to and P 17.54 mm and T 200 C is converted to liquid
2
4. Pair 750 Pdryair Pbenzene
2 1 0
1000 PB0 PCB
3 3
3000 2PB0 0
PCB at that T
Page 2
at 900 C, 2 1000 200 3000
1000 C
6. i 1 n 1
4 1 n 1 0.75
3
n 1 3 n 5 no. of ions
4
Baa Co CN x b
2a 2 x b 0 1 0x. nos.
a b 5 2 from n 5
2 a b bx 0
2 5 bx 0 bx 10 3
P1 P2 C1 C2
P3 P2 C3 C2
50
1.24
1000
i 1 association
0.849
34.3
271
Hg 2 Cl 2
20 x 24 1.2x
2
x 1.8mL
1.1
Final volume in beaker 1 = 20 1.8 18.2 mL
Beaker 2= 20+1.8 = 21.8 mL
11. CST
n W kg ST
ST
v V m3 M
ST 8.314 293 3
slope = 8.314 10
M M kg/mol
15. Tf iKf m
pH = 3
16. Tf kf m
Tf 0 0.93 0.930 C
17. Conceptual
18. max. freezing point less effective conc.
1) 0.4 4 1.6M
2) BaSO4 is ppted out. Left over ions :
Cl 0.2
SO 24 0.1
Na 0.4
0.7 M
3) 0.3 M
4) 0.1 5 0.5M
3
AgA s Ag A
19.
x x y
Page 5
A H 2O HA OH
x y y y
y2 kw 10 14
4
x x y Ksp ; 10
10
x y ka 10
14
10 5
OH 9
10
10
5
y 10
5 2
10
4
10
A
10
10 6
A 4
10 x y
10
6
x 10 105 1.1 10 5
Ag
5 6
Ag Ag 1.1 10 10
11
1.1 10
Ag A
20. mmoles of M CN 2
10
mmoles of H2SO 4 5
2
M CN 2
M 2CN
=2 8 16
H 2SO 4 2H SO4 2
=1 8 4
H CN HCN
8 16
-8 -8 +8
------------------------------------
8 8
it’s a buffer of HCN
Page 6
CN
pH pK a log 14 6 log1
HCN
=8
NH 4
21. buffer poH= pK b log
NH3
0.01
= 6 log 5
0.1
5
OH 10
2 2
Mg OH Ksp
12
1.2 10
2 2
Mg 10
1.2 10
10
2
22. PbSO4 Pb
S2 4 10 10
S 2 10 5 mol / lit
5
solubility in 5 lit of H 2 O 2 10 5
4
i.e weight = 303 10 0.0303gm
= 30.3mg
23. 1) pH at eq pt of CH3COOH & NH4OH 7 (beyond range)
2) pH of 0.1 M NaOH = 13 red
0.001M NaOH = 11 red
3) NH 4Cl acidic, CH3COONa basic
yellow blue
5 log 5 3 log 5
7
2
7 1 8
Page 7
25. 1st Inflection pt 1st neutralization pt
half way HA H 2A
HA
pH = pKa1 log pKa1
H2 A
7
Ksp 1.8 10
1) BaF2 2
= 3
Ba 10
10
1.5 10
2) CaF2 3
10
7
7.1 10
3) PbF2 3
10
HgCl 2 s Hg 22 2Cl
27.
s 2s
2
Ksp s 2s
= 4s3
28. effective conc. of NaCl sol = 0.1 2 0.2M
effective conc. of BaCl2 soln 0.05 3 0.15M
Nacl Bacl2
29. X B 1/ 2 XT 1/ 2
PB0 75 PT0 22
YB PB0 XB 75 1
1
YT PT0 XT 22 1
Page 8
YB YT
x 1
MATHS
2
31. A2 B B 2C B C B B 2C BC CB
33. B KA B Kn A
n
1 K 1
A Kn B 1
B1 A 1
34. Conceptual
T
35. XY YT X T YX SINCE X T X YT Y
R 1 2, 4 ie, R(3, 4)
OR OR ' 5
Page 9
1 1 1 1
5 cos sin ,5 cos sin
2 2 2 2
1 7
,
2 2
x y
37. Equation of L is 1 and let the axis be rotated through an angle and let
a b
X, Y be the new coordinates of any point P x, y in the plane, then
x X cos Y sin , y X sin Y cos , the equation of the line with reference to
x y
original coordinates is 1
a b
X cos Y sin X sin Y cos
ie, 1 ………………(i)
a b
and with reference to new coordinates is
X Y
1 ……………………(ii)
p q
sin cos 1
…………………….(iv)
a b q
38. Let the coordinates of A be (a, 0). Then the slope of the reflected ray is
3 0
tan say …………………..(i)
5 a
Then the slope of the incident ray
2 0
tan ……………………(ii)
1 a
From Eqs. (i) and (ii),
tan tan
Page 10
3 2
0
5 a 1 a
13
3 3a 10 2a 0; a
5
13
Thus, the coordinate of A is , 0
5
39. Let C h, k be the centre of the circle passing through the end points of the rod AB
and PQ of lengths a and b respectively, CL and CM be perpendiculars from C on AB
and PQ respectively. Then CA=CP (radii of the same circle)
a2 b2
k2 h2 ( AL a / 2 and MP b / 2)
4 4
4 h2 k 2 a 2 b2
A a cos , a sin
M a a cos , a sin
x a a cos
x a a cos .......... i
Page 11
x2 y 2 2ax 0
x2 y2 2ax
41. a2 a 42 0
a 7 or 6
If a 7 b 4 or 3
P 7, 4 or 7,3
If a 6 not possible
2 2
42. pA pB
x 7
2 2
pB AB
2 2
x 7 x 12 80
x 20 satisfies
Page 12
45. A point on y+5 =0 is B , 5 , p x, y divides AB in the ratio 2:1,
d 2 3 5 3y 5
x ,y
3 3 3
9x 3 y 5
6
2 2
But l 2 AB 2 3 10
1 2 2
Or l 2 3x 3 y 5 9 y 3
4
46. p is the ortho center of ABQ
BRA 90o
R lies on the circle with AB as a diameter
the locus of R is the circle
x 0 x 7 y 5 y 0 0
Or, x 2 y 2 7 x 5 y 0
47. Let x, y be coordinate of vertex C and x1 , y1 be coordinates of centroid of the triangle.
x1 2 2 y 3 1
x1 and y1
2 3
x y 2
x1 and y1
3 3
The centroid x1 , y1 lies on the line 2 x 3 y 3 So, x1 and y1 satisfies the equation of line
2 x1 3 y1 1
x y 2
2 3 1
3 3
48. a 4, c 2, g 3, h 6
x1 x2 y1 y2 x1 x2 x3 y1 y2 y3 xi yi
50. G1 , G2 , .........Gn ,
2 2 3 3 n n
2
10
51. n 1
1 100 2n 1
n 8
2
Page 13
52. under the transformations f1 , f 2 and f3 , A 0, 0 0, 0 0, 0 A1 0, 0
B 2, 0 0, 2 6, 2 B1 2, 4 C 2, 2 8, 2 C1 3,5
D 0, 2 2, 0 2, 0 D1 1,1
Clearly A1B1 D1C1 B1C1 A1D1 and A1C1 is nor perpendicular to B1D1 . Therefore A1B1C1D1 is
parallelogram
x y 1 3
53. let the line be 1. If passes through 1,3 1 A(a, 0) B o, b
a b a b
1 3
The locus of p a, b is x, y . 1
x y
x y
54. Let the equation of AB 1 1 . Let p h, k locus of midpoint of AB. a 2h, b 2k
a b
x y 1
substitute in (1) 1 kh hy hk and passes through the point
2h 2k 2
x, y 8, 4
1
8k 4h hk 2h 4k hk 2x 4y xy . The locus of p is xy 2 x 4 y 0
2
x2 y2 x2 y2
III ly a 0 0, 0 , P , 0 , Q 0,
x y
y 0 y 0
1 y2 x x y2 x x2
x 0 x a
x2 y2 x2 y2
x2 y 2 ax
x y
x2 y2 x2 y2
Since a a x2 y2 x y axy
x y
y 1 y y
56. RQP RPQ 2 tan tan tan 2
x a x a a x
y y
1 y 1 y 1 y 1 a x a x
2 , tan 2 tan tan 2 tan
a x a x a x y y
1 .
a x a x
y a x a x
tan 2 a2 x2 y2 2 xy cot 2
a2 x2 y 2
Page 14
x2 y 2 a2 2 xy cot 2
x2 y 2 2 xy cot 2 a2 0
57. Let A x1 , y1 , B x2 , y2 , C x3 , y3 , D x4 , y4
1 1 2 2
Now, the area of OAB is cot tan 2 tan cot
2 2
1 1
2 tan cot 2 2 2 2
2 2
Least value of s 2
2 2
59. Let the verties be O 0, 0 , A , 0 , and B 1 , 1 , where 0 1 and 1 1 1 4
1
A sin 2 A sin 2 B sin 2C 2sin A sin B sin C 1 cos 2 A sin 2 A
2
1
A sin 2 A sin 2 B sin 2C 2sin A sin B sin C sin 2 A sin 2 A cos 2 A 0
2
4 least non negative value is 0
PHYSICS
61. Conceptual.
62. Just before the impact with ceiling retardation = 2g
If ‘R’ is the resistance then
R mg 2mg R mg
Page 15
F
63. Acceleration a , where ‘m’ is mass of each cart.
Nm
Let T, be the tension between 4th & 5th cart.
Considering last (N – 4) carts, T1 N 4 ma
Similarly T2 N 8 ma
Given T1 2T2
N 12
F 40
64. Acceleration of system a 4 ms 2
M 10
Contact force 4 4 16 N
65. m1 m2 g T1 m1 m2 a T1 m1 m2 g a
T2 m2 g a
Given T1 3T2
m1 m2 3m2
m1 2m2
T M x g M x a
Eliminating ‘x’
g a
T 1 M g a
g a g a
M g 2 a2
T
2g
Page 16
24
T Mg
50
M g 2 a2 24
Mg
2g 50
a2 24 a2 1 g
1 aMin
2 25 2 25 5
g g
67.
V0 a1t1 a2t2
1 w
a1 n 1 g
M
a2 g when tension is zero
V0 1 gt1 gt2
1
V0 t1 t2 h
2
1
t1 1 t1 1 gt1 h
2
1
1 g t12 h
2
2h
t1
g 1
t Min t1 t2
t1 1 t1 t1
2 h
tMin
g n 1
68. mA M
mB M m
2L 2M m L
t
arelative Mg
69. Conceptual.
70. Conceptual.
2m1m2
71. Tension in the string connecting m1 and m2 is T g
m1 m2
4 m1m2
m0 g 2T m0
m1 m2
8m1m2
Mg 4T M
m1 m2
72.
N1
For A: N1 sin 30 F F
2
3mg
RA mg N1 cos30
2
N2
For B: N 2 sin 30 F F
2
mg
RB mg N 2 cos30
2
For C: N1 N 2
RC N1 cos 30 mg N2 cos30
RC mg
RA : RB : RC 3:1: 2
Page 18
m 2 sxd (x is w.r.t. container)
Kx 2sx dg
K 2s dg
2M
N1 Mg sin Ma …. (1)
For M0
M 0 g N1 M 0a sin
3 g sin 2
acceleration of blocks a1 a sin
1 2sin 2
Considering mass of M (i.e. 1)
Mg N12 Ma1
Mg cos 2
N12
1 2sin 2
F
75. Acceleration of A B 2ms 2
9
2
In the frame of A B acceleration of ‘C’ is 2ms towards right.
Time to travel 4m is
Page 19
2 4
t1 2sec
2
Now the block ‘C’ falls of the edge. In the frame considered time needed to fall 2m is
2.2
t2 0.4 0.63sec
10
1 2
Horizontal distance covered is s 4 0.63 2 0.63
2
2.92m
2.92 2.75
76. F 3mg
For block
a0 is acceleration of wedge.
For wedge
Page 20
5g
a0
3
2g
a
3
1 1 2
at
2 2
3L
t
2g
77. Use free body diagram and apply the condition for static equilibrium.
78. Let initial extension of S1 be x0.
Kx0 Mg
For equilibrium of M
Kx0 Kx1 Mg 2 Kx2
x1 2 x2
L 2L
x2 , x1
5 5
79. Use constraint equations and Newton’s laws.
80. Conceptual.
81. Use Newton’s laws of motion.
82. Conceptual.
83. Use constraint equations.
84. Conceptual.
85. Use constraint equations and Newton’s laws.
86. Impulse is the area under F-t graph, as well as the change in momentum. So,
F0 T
mu
2 2
F0T
u
4m
87. mg 2T sin 45
mg 2T ….. (1)
Page 21
T1 cos T cos 45
T mg mg
T1 cos T
2 2 2
88.
Three forces are acting on the pulley T (horizontally), T (vertically downward) and the
weight of the pulley (also acting vertically downwards) i.e. Force Mg acts horizontally
and M m g acts vertically downwards. So, total force acting on the pulley is
2
Fnet M 2g2 M m g2
2
Fnet M2 M m g
Page 22
Resolving vertically 2 N1 cos30o W
W
N1 ….. (1)
3
When the arrangement is on the point of collapsing, the reaction between A and B is
zero.
Free body diagram of A
Resolving horizontally and vertically
N 2 sin N1 sin 30o
W
N 2 sin ….. (2)
2 3
3W
N 2 cos W N1 cos 30o ….. (3)
2
Dividing (3) by (3), we get
1
tan
3 3
1
tan 1
3 3
90.
a g sin a0 cos
Page 23