+M - M
+M - M
+M - M
TOPIC: GOC
6. The correct decreasing order of electron density in aromatic ring of following compounds is :
O O O
|| || ||
C–H O–C–H NH – CH3 C – NH – CH3
+ m group increases electron density and – m group decreases electron density in aromatic ring.
7. Draw the resonance structures for the following compounds. Show the electron shift using curved arrow
notation.
(a) C6H5OH (b) C6H5NO2 (c) CH3CH=CHCHO (d) C6H5–CHO
10. Write decreasing order of electron density in aromatic ring in following compounds.
PART- B OBJECTIVE QUESTIONS
11. Which of the following group show –m and –I effect ?
(A) –NO2 (B) –NH2 (C) –OH (D) –Cl
16. The correct order of + m effect of ‘N’ containing functional group on benzene ring, amongst the given compounds
is
(A) I > II > IV > III (B) II > I > III > IV (C) I > II > III > IV (D) IV > III > II > I
17. In which case the -bond pair and bond pair of electrons both are attracted in the same direction,
(towards same atom.) :
(A) H2C = CH — Cl (B) CH3 – CH2 – NH2 (C) H2C = CH – CH = O (D) H2C = CH – OCH3
22. Which of the following is not the correct resonating structure of C6H5NH2 ?
(A) III > II > I (B) II > III > I (C) I > III > II (D) III > I > II
25. The correct order of electron density in aromatic ring of following compounds is :
I II III IV
(A) IV > III > II > I (B) I > II > III > IV
(C) IV > II > I > III (D) IV > II > III > I
(A) (II) > (III) > (IV) > (I) (B) (IV) > (I) > (II) > (III)
(C) (IV) > (I) > (III) > (II) (D) (I) > (III) > (IV) > (II)
28. The most unlikely representation of resonance structures of p-nitrophenoxide ion is: