Phys 603

Download as docx, pdf, or txt
Download as docx, pdf, or txt
You are on page 1of 2

Phys 603:Thermodynamics and Statistical Mechanics

(3Cr.Hrs/ 6 ECTS)

Instructional Objective

1. The course is to understand the basics of thermodynamics and Statistical systems

2. Understand the various laws of thermodynamics.

3. Acquire the knowledge of various statistical distributions.

4. To comprehend the concepts of enthalpy, phase transitions and thermodynamic functions.

UNIT I: BASIC ELEMENTS OF STATISTICAL MECHANICS

Foundations of statistical mechanics-Bridging microscopic and macroscopic behavior -Contact between


statistics and thermodynamics- Free energy-Partition function of an ideal monatomic gas -Partition
function of a diatomic molecule- Classical ideal gas- Entropy of mixing and Gibb’s paradox-Sackur –
Tetrod equation-The semi-classical perfect gas- Specific heat of solids -Saha’s ionization formula.

UNIT II: THEORY OF ENSEMBLES

 Ensembles- Microcannonical ensemble-Phase space- Trajectories and density of states-


Liouville’s theoremCanonical ensemble -Thermodynamic properties of the canonical ensemble-
Evaluation of the total partition
 function-Partition function in the presence of interactions-Fluctuation of the assembly energy in
a canonical
 ensemble- Grand canonical ensemble- The grand partition function and its evaluation-
Fluctuations in the
 number of systems-The chemical potentials in the equilibrium state.

UNIT III: STATISTICAL DISTRIBUTIONS AND APPLICATIONS

Maxwell-Boltzmann distribution- Determination of undetermined multipliers β α-equipartition of


energyBose-Einstein statistics-Bose-Einstein condensation-Fermi-Dirac statistics- The electron gas-White
dwarfs and their limiting mass, statistical ( Thomas - Fermi) model of atom-Comparison of the 3
statistics.

UNIT IV: LAWS OF THERMODYNAMICS AND THERMODYNAMIC PROCESSES

Ideal gases: Equation of state- Internal energy- Specific heats -Entropy- isothermal and adiabatic
processesCompressibility and expansion coefficient-.Real gases: Deviation from the ideal gas equation-
Zeroth and first law of thermodynamics-Reversible and irreversible processes- Carnot theorem- Second
law of thermodynamicsClausius inequality- Entropy changes in reversible and irreversible processes-
Temperature-entropy diagramsUnavailable energy-Thermal death of the universe.
UNIT V: THERMODYNAMIC POTENTIALS AND PHASE

TRANSITIONS

Thermodynamic potentials: Enthalpy- Gibbs and Helmholtz functions- Maxwell relations and their
applicationsMagnetic work- Magnetic cooling by adiabatic demagnetization-Approach to absolute zero-
Change of phase- Equilibrium between a liquid and its vapour- Clausius-clapeyron- Phase transitions-
Landau theory of phase transition-Equilibrium between phases-Pomeranchuk cooling.

TEXTBOOKS

• Pathria R.K., Statistical Mechanics, 2nd Edition, Elsevier, 2000

• F. Reif, Fundamentals of Statistical and Thermal Physics, Wave Land Price

References

• K. Huang, Statistical Physics, 2nd edition, John Wiley’s and Sons.

• R. K. Pathria, Statistical Mechanics, 2nd edition, Butterworth Heinemann.

• F. Reif, Fundamentals of Statistical and Thermal Physics, Wave Land Price

You might also like