Conforms to 91/155/EEC - 2001/58/EC - United Kingdom (UK)

SAFETY DATA SHEET

AGK-100 Phosphate Ampoules
1. Identification of the substance/preparation and of the
company/undertaking
Product name : AGK-100 Phosphate Ampoules
Material Uses : Industrial applications: Analytical reagent.

Manufacturer / Supplier :
Drew Marine Drew Marine
Ashland Specialty Chemical Company Ashland Specialty Chemical Company
Schorpioenstraat 63 One Drew Plaza
3067 GG Rotterdam Boonton, NJ 07005
Netherlands United States
Tel. No.: Tel. No.:
+31-10-289 1950 +1 (973) 263 7600
Fax: Fax:
+31-10-289 1962 +1 (973) 263 4491
Emergency telephone number
(Germany) : +49 621 60-43333
Fax:
(Germany) : +49 621 60-92664

2. Composition/information on ingredients
Substance/Preparation : Preparation
Chemical name* CAS no. % EC Number Classification
Sodium hydrogensulphate 7681-38-1 60-95 231-665-7 Xi; R41
Ammonium molybdate 13106-76-8 2.5-3 236-031-3
Antimony potassium tartrate 28300-74-5 0.5-1 213-067-8 Xn; R20/22
N; R51/53
See Section 16 for the full text of the R Phrases declared
above

* Occupational Exposure Limit(s), if available, are listed in Section 8

3. Hazards identification
The preparation is classified as dangerous according to Directive 1999/45/EC and its amendments.
Classification : Irritant
R41- Risk of serious damage to eyes.
Effects and symptoms
Eye Contact : Very hazardous in case of eye contact (irritant). Inflammation of
the eye is characterized by redness, watering and itching.
Target Organs : Contains material which causes damage to the following organs:
mucous membranes, skin, eye, lens or cornea.

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 AGK-100 Phosphate Ampoules

4. First aid measures

First-Aid measures
Inhalation : If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Obtain medical
attention.
Ingestion : Do NOT induce vomiting unless directed to do so by medical
personnel. Never give anything by mouth to an unconscious
person. Loosen tight clothing such as a collar, tie, belt or
waistband. Get medical attention if symptoms appear.
Skin contact : In case of contact, immediately flush skin with plenty of water.
Remove contaminated clothing and shoes. Cold water may be
used. Wash clothing before reuse. Clean shoes thoroughly
before reuse. Obtain medical attention.
Eye Contact : Check for and remove any contact lenses. In case of contact,
immediately flush eyes with a copious amount of water for at least
15 minutes. Cold water may be used. Obtain medical attention
immediately.

5. Fire-fighting measures
Extinguishing Media
Suitable : Not applicable.
Hazardous thermal : These products are carbon oxides (CO, CO2) and water, nitrogen
decomposition products oxides (NO, NO2...), sulphur oxides (SO2, SO3, etc.). Some
metallic oxides.
Protection of fire-fighters : Fire-fighters should wear self-contained positive pressure
breathing apparatus (SCBA) and full turnout gear.

6. Accidental release measures

Personal Precautions : Splash goggles. Full suit. Boots. Gloves. Suggested protective
clothing might not be sufficient; consult a specialist BEFORE
handling this product.
Environmental precautions and : Use a shovel to put the material into a convenient waste disposal
cleanup methods container. Finish cleaning by spreading water on the
contaminated surface and allow to evacuate through the sanitary
system.
Note: See section 8 for personal protective equipment and section 13 for waste disposal.

7. Handling and storage

Handling : Do not breathe dust. Keep away from incompatibles such as
alkalis. Use only in accordance with Drew Test Procedures.
Storage : Keep container tightly closed. Keep container in a cool,
well-ventilated area.
Packaging materials
Recommended use : Use original container.

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 AGK-100 Phosphate Ampoules

8. Exposure controls/personal protection

Engineering measures : Use process enclosures, local exhaust ventilation, or other
engineering controls to keep airborne levels below recommended
exposure limits. If user operations generate dust, fume or mist,
use ventilation to keep exposure to airborne contaminants below
the exposure limit.
Hygiene measures : Wash hands after handling compounds and before eating,
smoking, using lavatory, and at the end of day.
Occupational Exposure Limits

Ingredient Name Occupational Exposure Limits

Ammonium molybdate EH40-OES (United Kingdom (UK), 2002).
STEL: 10 mg/m3 15 minute(s).
TWA: 5 mg/m3 8 hour(s).
Antimony potassium tartrate EH40-MEL (United Kingdom (UK), 2002).
TWA: 0.5 mg/m3 8 hour(s).
Personal protective equipment
Skin and body : Lab coat.
Eyes : Splash goggles.

9. Physical and chemical properties

Physical state : Solid. ((powder) Ampoule)
Colour : Off-white. / Bluish-grey.
Odour : Ammoniacal.
Boiling point : Decomposition Temperature: >200°C (392°F)
Melting point : Decomposition Temperature: >200°C (392°F)
Density : 2 g/cm3
Solubility : Easily soluble in cold water.
pH : Not available.
Flash point : Not applicable.

10. Stability and reactivity

Stability : The product is stable.
Materials to avoid : Reactive with oxidising agents, alkalis.
Flammable hydrogen gas may be produced on prolonged contact
with metals such as aluminium, zinc, etc.
Hazardous decomposition : These products are carbon oxides (CO, CO2) and water, nitrogen
products oxides (NO, NO2...), sulphur oxides (SO2, SO3, etc.). Some
metallic oxides.

11. Toxicological information

Acute toxicity
Ingredient Name Test Result Route Species
Sodium hydrogensulphate LD50 2500 mg/kg Oral Rat
Ammonium molybdate LDLo 1870 mg/kg Oral Rabbit
LDLo 1600 mg/kg Oral Cat
LDLo 2200 mg/kg Oral Guinea pig
Antimony potassium tartrate LD50 115 mg/kg Oral Rat
LD50 115 mg/kg Oral Rabbit
LDLo 2 mg/kg Oral human
LDLo 600 mg/kg Oral Mouse

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Chronic toxicity : Repeated or prolonged exposure is not known to aggravate

medical condition.
Eye irritation : Very hazardous in case of eye contact (irritant).
Carcinogenic effects : Not available.
Mutagenic Effects : Not available.
Reproduction toxicity : Not available.
Teratogenic effects : Not available.

12. Ecological information

Additional Information :

13. Disposal considerations

Methods of disposal ; Waste of : Waste must be disposed of in accordance with federal, state and
residues ; Contaminated local environmental control regulations.
packaging
European Waste Catalogue : 16 05 06*
(EWC)
Hazardous Waste : The classification of the product may meet the criteria for a
hazardous waste
Additional Information : 16 05 06 laboratory chemicals, consisting of or containing
dangerous substances, including mixtures of laboratory chemicals

14. Transport information

International transport regulations
Land - Road/Railway
UN number : Not regulated.
Proper shipping name : -
ADR/RID Class : -
Packing group : -
Other information : Remarks
Not controlled under ADR (Europe).
Sea
UN number : Not regulated.
Proper shipping name : -
IMDG Class : -
Packing group : -
Other information : Remarks
Not controlled under IMDG.

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15. Regulatory information

EU Regulations
Hazard symbol(s) :

Irritant

Risk Phrases : R41- Risk of serious damage to eyes.

Safety Phrases : S26- In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
S39- Wear eye/face protection.
Product Use : Classification and labelling have been performed according to EU
directives 67/548/EEC, 1999/45/EC, including amendments and
the intended use.
- Industrial applications.

16. Other information

Full text of R phrases referred to in : R20/22- Harmful by inhalation and if swallowed.
Sections 2 and 3 - United Kingdom R41- Risk of serious damage to eyes.
(UK) R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.

Full text of classifications referred to in : Xn - Harmful

Sections 2 and 3 - United Kingdom Xi - Irritant
(UK) N - Dangerous for the environment.

HISTORY
Date of printing : 2/26/2004.
Date of issue : 2/20/2004.
Date of previous issue : 10/16/2002.
Version : 3.2
AGK® 100 is a registered trademark of Ashland Inc.
Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above
named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness
of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may
present unknown hazards and should be used with caution. Although certain hazards are described herein,
we cannot guarantee that these are the only hazards that exist.
Date of issue Version
2/20/2004. 3.2 Page: 5/5