SAFETY DATA SHEET

PARAGON
Revision Date: 29-Sep-2016 Revision Number: 13

1. Product Identifier & Identity for the Chemical

Statement of Hazardous Nature Hazardous according to the criteria of the 3rd Revised Edition of the Globally Harmonised
System of Classification and Labelling of Chemicals (GHS), Dangerous Goods according to
the criteria of ADG.

1.1. Product Identifier

Product Name PARAGON

Other means of Identification

Synonyms None
Hazardous Material Number: HM001162

Recommended use of the chemical and restrictions on use

Recommended Use Solvent
Uses advised against No information available

Supplier's name, address and phone number

Manufacturer/Supplier Halliburton Australia Pty. Ltd.
15 Marriott Road, Jandakot, WA 6164
Australia
ACN Number: 009 000 775
Telephone Number: + 61 1 800 686 951
Fax Number: 61 (08) 9455 5300
E-mail Address [email protected]

Emergency phone number

+ 61 1 800 686 951
Global Incident Response Access Code: 334305
Contract Number: 14012

Australian Poisons Information Centre

24 Hour Service: - 13 11 26
Police or Fire Brigade: - 000 (exchange): - 1100

2. Hazard Identification
Statement of Hazardous Nature Hazardous according to the criteria of the 3rd Revised Edition of the Globally Harmonised
System of Classification and Labelling of Chemicals (GHS), Dangerous Goods according to
the criteria of ADG.

Classification of the hazardous chemical

Aspiration Toxicity Category 1 - H304
Acute toxicity - Dermal Category 4 - H312
Skin Corrosion/Irritation Category 2 - H315
Serious Eye Damage/Irritation Category 2 - H319
Specific Target Organ Toxicity - (Single Exposure) Category 3 - H335
Specific Target Organ Toxicity - (Repeated Exposure) Category 2 - H373
Acute Aquatic Toxicity Category 2 - H401
Flammable liquids. Category 3 - H226

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Label elements, including precautionary statements

Hazard Pictograms

Signal Word DANGER

Hazard Statements: H226 - Flammable liquid and vapor

H304 - May be fatal if swallowed and enters airways
H312 - Harmful in contact with skin
H315 - Causes skin irritation
H319 - Causes serious eye irritation
H335 - May cause respiratory irritation
H373 - May cause damage to organs through prolonged or repeated exposure
H401 - Toxic to aquatic life

Precautionary Statements

Prevention P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources.
No smoking.
P233 - Keep container tightly closed
P240 - Ground and bond container and receiving equipment.
P241 - Use explosion-proof electrical/ventilating/lighting/equipment
P242 - Use only non-sparking tools
P243 - Take action to prevent static discharges.
P260 - Do not breathe dust/fume/gas/mist/vapors/spray
P264 - Wash face, hands and any exposed skin thoroughly after handling
P271 - Use only outdoors or in a well-ventilated area
P273 - Avoid release to the environment
P280 - Wear protective gloves/protective clothing/eye protection/face protection
Response P301 + P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician
P331 - Do NOT induce vomiting
P302 + P352 - IF ON SKIN: Wash with plenty of water.
P312 - Call a POISON CENTER/doctor/physician if you feel unwell
P363 - Wash contaminated clothing before reuse
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing
P312 - Call a POISON CENTER or doctor/physician if you feel unwell
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing
P337 + P313 - If eye irritation persists: Get medical advice/attention
P314 - Get medical attention/advice if you feel unwell
P370 + P378 - In case of fire: Use water spray for extinction
Storage P403 + P233 - Store in a well-ventilated place. Keep container tightly closed
P403 + P235 - Store in a well-ventilated place. Keep cool
P405 - Store locked up
Disposal P501 - Dispose of contents/container in accordance with
local/regional/national/international regulations

Contains

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Substances CAS Number
Xylene 1330-20-7
Ethyl benzene 100-41-4

Other hazards which do not result in classification

This mixture contains no substance considered to be persistent, bioaccumulating nor toxic (PBT).
This mixture contains no substance considered to be very persistent nor very bioaccumulating (vPvB).

For the full text of the H-phrases mentioned in this Section, see Section 16

3. Composition/information on Ingredients
Substances CAS Number PERCENT (w/w) GHS Classification -
Australia
Xylene 1330-20-7 60 - 100% Acute Tox. 4 (H312)
Acute Tox. 4 (H332)
Skin Irrit. 2 (H315)
Eye Irrit. 2 (H319)
STOT SE 3 (H335)
Asp. Tox. 1 (H304)
Aquatic Acute 2 (H401)
Flam. Liq. 3 (H226)
Ethyl benzene 100-41-4 10 - 30% Acute Tox. 4 (H332)
Skin Irrit. 2 (H315)
Eye Irrit. 2 (H319)
STOT SE 3 (H336)
STOT RE 2 (H373)
Asp. Tox. 1 (H304)
Aquatic Acute 2 (H401)
Aquatic Chronic 3 (H412)
Flam. Liq. 2 (H225)

4. First aid measures

Description of necessary first aid measures
Inhalation If inhaled, move victim to fresh air and seek medical attention.
Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of
water for at least 15 minutes and get medical attention immediately after flushing.
Skin In case of contact, immediately flush skin with plenty of soap and water for at least
15 minutes. Get medical attention. Remove contaminated clothing and launder
before reuse.
Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent
aspiration. Rinse mouth. Never give anything by mouth to an unconscious person.

Symptoms caused by exposure

Harmful if inhaled. Harmful if swallowed. Causes eye irritation. Causes skin irritation. May cause respiratory irritation.
Aspiration into the lungs may cause chemical pneumonitis including coughing, difficulty breathing, wheezing,
coughing up blood and pneumonia, which can be fatal. May cause damage to organs through prolonged or repeated
exposure.

Medical Attention and Special Treatment

Notes to Physician Treat symptomatically

5. Fire Fighting Measures

Suitable extinguishing equipment
Suitable Extinguishing Media
Water fog, carbon dioxide, foam, dry chemical.
Extinguishing media which must not be used for safety reasons

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None known.

Specific hazards arising from the chemical

Special exposure hazards in a fire
May be ignited by heat, sparks or flames Use water spray to cool fire exposed surfaces. Closed containers may explode in fire.
Decomposition in fire may produce harmful gases.

Special protective equipment and precautions for fire fighters

Special protective equipment for firefighters
Full protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.

6. Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
Use appropriate protective equipment. Wear self-contained breathing apparatus in enclosed areas. Remove sources of ignition.
Avoid contact with skin, eyes and clothing. Avoid breathing vapors. Ensure adequate ventilation. All equipment used when handling
the product must be grounded

6.2. Environmental precautions

Prevent from entering sewers, waterways, or low areas.

6.3. Methods and material for containment and cleaning up

Isolate spill and stop leak where safe. Remove ignition sources and work with non-sparking tools. Contain spill with sand or other
inert materials. Scoop up and remove.

7. Handling and storage

7.1. Precautions for safe handling
Handling Precautions
Use appropriate protective equipment. Remove sources of ignition. Avoid contact with eyes, skin, or clothing. Avoid breathing
vapors. Ensure adequate ventilation. Wash hands after use. Launder contaminated clothing before reuse. Ground and bond
containers when transferring from one container to another.
Hygiene Measures
Handle in accordance with good industrial hygiene and safety practice.

7.2. Conditions for safe storage, including any incompatibilities

Storage Information
Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container closed when not in use. Product has a shelf
life of 60 months.
Other Guidelines
No information available

8. Exposure Controls/Personal Protection

Control parameters - exposure standards, biological monitoring
Exposure Limits
Substances CAS Number Australia NOHSC ACGIH TLV-TWA
Xylene 1330-20-7 TWA: 80 ppm TWA: 100 ppm
TWA: 350 mg/m3 STEL: 150 ppm
STEL: 150 ppm
STEL: 655 mg/m3
Ethyl benzene 100-41-4 TWA: 100 ppm TWA: 20 ppm
TWA: 434 mg/m3
STEL: 125 ppm
STEL: 543 mg/m3

Appropriate engineering controls

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas without
good cross ventilation. Use approved industrial ventilation and local exhaust as required to
maintain exposures below applicable exposure limits.

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Personal protective equipment (PPE)

Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures, the
selection and proper use of personal protective equipment should be determined by an
industrial hygienist or other qualified professional based on the specific application of this
product.
Respiratory Protection Organic vapor respirator.
In high concentrations, supplied air respirator or a self-contained breathing apparatus.
Hand Protection Impervious rubber gloves.
Skin Protection Rubber apron.
Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.
Other Precautions None known.
Environmental Exposure Controls Do not allow material to contaminate ground water system

9. Physical and Chemical Properties

9.1. Information on basic physical and chemical properties
Physical State: Liquid Color Clear to water white
Odor: Aromatic hydrocarbon Odor Threshold: No information available

Property Values
Remarks/ - Method
pH: 7
Freezing Point / Range No data available
Melting Point / Range No data available
Boiling Point / Range 137 °C / 279 °F
Flash Point 27 °C / 81 °F PMCC
Upper flammability limit 7%
Lower flammability limit 1%
Evaporation rate No data available
Vapor Pressure 5 mmHg
Vapor Density No data available
Specific Gravity 0.87
Water Solubility Insoluble in water
Solubility in other solvents No data available
Partition coefficient: n-octanol/water No data available
Autoignition Temperature 498 °C / 928.4 °F
Decomposition Temperature No data available
Viscosity No data available
Explosive Properties No information available
Oxidizing Properties No information available

9.2. Other information

Molecular Weight 90.08 g/mol
VOC Content (%) No data available

10. Stability and Reactivity

10.1. Reactivity
Not expected to be reactive.
10.2. Chemical stability
Stable
10.3. Possibility of hazardous reactions
Will Not Occur
10.4. Conditions to avoid
Keep away from heat, sparks and flame.
10.5. Incompatible materials
Strong oxidizers.
10.6. Hazardous decomposition products
Carbon monoxide and carbon dioxide.

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11. Toxicological Information
Information on routes of exposure
Principle Route of Exposure Eye or skin contact, inhalation.

Symptoms related to exposure

Most Important Symptoms/Effects
Harmful if inhaled. Harmful if swallowed. Causes eye irritation. Causes skin irritation. May cause respiratory irritation.
Aspiration into the lungs may cause chemical pneumonitis including coughing, difficulty breathing, wheezing,
coughing up blood and pneumonia, which can be fatal. May cause damage to organs through prolonged or repeated
exposure.

Toxicology data for the components

Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation

Xylene 1330-20-7 3523 mg/kg bw (Rat) >4200 mg/kg (rabbit) 27.6 mg/L (Rat, 4h, vapor)

Ethyl benzene 100-41-4 3500 mg/kg-bw (rat) 15400 mg/kg (rabbit) 17.8 mg/L (Rat, 4h, vapor)

Immediate, delayed and chronic health effects from exposure

Inhalation Harmful if inhaled. May cause respiratory irritation. May cause central nervous system
depression including headache, dizziness, drowsiness, incoordination, slowed reaction
time, slurred speech, giddiness and unconsciousness.
Eye Contact Causes eye irritation.
Skin Contact Causes skin irritation.
Ingestion Harmful if swallowed. Aspiration into the lungs may cause chemical pneumonitis including
coughing, difficulty breathing, wheezing, coughing up blood and pneumonia, which can be
fatal. Irritation of the mouth, throat, and stomach. May cause headache, dizziness, nausea,
vomiting, gastrointestinal irritation and central nervous system depression.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause central nervous system and brain
effects.

Exposure Levels
No data available

Interactive effects
Skin disorders. Eye ailments. Lung disorders.

Data limitations
No data available

Substances CAS Number Skin corrosion/irritation

Xylene 1330-20-7 Causes skin irritation.
Ethyl benzene 100-41-4 Causes mild skin irritation

Substances CAS Number Serious eye damage/irritation

Xylene 1330-20-7 Causes moderate eye irritation (Rabbit)
Ethyl benzene 100-41-4 Causes mild eye irritation.

Substances CAS Number Skin Sensitization

Xylene 1330-20-7 Did not cause sensitization on laboratory animals (mouse)
Ethyl benzene 100-41-4 Not regarded as a sensitizer.

Substances CAS Number Respiratory Sensitization

Xylene 1330-20-7 No information available
Ethyl benzene 100-41-4 No information available

Substances CAS Number Mutagenic Effects

Xylene 1330-20-7 In vitro tests did not show mutagenic effects. In vivo tests did not show mutagenic effects.

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Ethyl benzene 100-41-4 In vitro tests did not show mutagenic effects. In vivo tests did not show mutagenic effects.

Substances CAS Number Carcinogenic Effects

Xylene 1330-20-7 Did not show carcinogenic effects in animal experiments
Ethyl benzene 100-41-4 Not regarded as carcinogenic.

Substances CAS Number Reproductive toxicity

Xylene 1330-20-7 Did not show teratogenic effects in animal experiments. Animal testing did not show any effects on
fertility.
Ethyl benzene 100-41-4 Animal testing did not show any effects on fertility. Adverse developmental effects were only observed
at maternally toxic doses.

Substances CAS Number STOT - single exposure

Xylene 1330-20-7 May cause respiratory irritation.
Ethyl benzene 100-41-4 May cause anesthetic or narcotic effects. May cause disorder and damage to the Central Nervous
System (CNS) May cause headache, dizziness, and other central nervous system effects.

Substances CAS Number STOT - repeated exposure

Xylene 1330-20-7 No significant toxicity observed in animal studies at concentration requiring classification.
Ethyl benzene 100-41-4 Causes damage to organs through prolonged or repeated exposure if inhaled: Ears

Substances CAS Number Aspiration hazard

Xylene 1330-20-7 Aspiration into the lungs may cause chemical pneumonitis including coughing, difficulty breathing,
wheezing, coughing up blood and pneumonia, which can be fatal.
Ethyl benzene 100-41-4 Aspiration into the lungs may cause chemical pneumonitis including coughing, difficulty breathing,
wheezing, coughing up blood and pneumonia, which can be fatal.

12. Ecological Information

Ecotoxicity

Substance Ecotoxicity Data

Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity to Toxicity to Invertebrates
Microorganisms
Xylene 1330-20-7 EC50 (72h) = 4.9 NOEC (56d) > 1.3 mg/L No information available LC50 (24h) =
mg/L(Pseudokirchnerella (Oncorhynchus mykiss) 1mg/L(Daphnia magna)
subcapitata) LC50 (96h) 2.6 mg/L
(Oncorhynchus mykiss)
Ethyl benzene 100-41-4 EC50 (96 h) 3.6 mg/L LC50 (96 h) 4.2 mg/L EC50 (24h) 96 mg/L EC50 (48 h) 1.8 mg/L
(Pseudokirchneriella (Oncorhynchus mykiss) (Nitrosomonas sp.) (Daphnia magna)
subcapitata) NOEC (7 d) 0.96 mg/L
EC50 (8 d) 4.8 mg/L (Ceriodaphnia dubia)
(Pseudokirchneriella
subcapitata)

12.2. Persistence and degradability

Not readily biodegradable
Substances CAS Number Persistence and Degradability
Xylene 1330-20-7 Readily biodegradable (87.8% @ 28d)
Ethyl benzene 100-41-4 Readily biodegradable (79% @ 28d)

12.3. Bioaccumulative potential

Substances CAS Number Log Pow

Xylene 1330-20-7 Log Pow 2.8-3.22.8-3.22.8
Ethyl benzene 100-41-4 LogPow 3.6

12.4. Mobility in soil

Substances CAS Number Mobility

Xylene 1330-20-7 KOC = 537
Ethyl benzene 100-41-4 KOC = 520

12.6. Other adverse effects

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Endocrine Disruptor Information
This product does not contain any known or suspected endocrine disruptors

13. Disposal Considerations

Safe handling and disposal methods
Disposal should be made in accordance with federal, state, and local regulations.

Disposal of any contaminated packaging

Follow all applicable national or local regulations.

Environmental regulations
Not applicable

14. Transport Information

Transportation Information
Australia ADG
UN Number UN1307
UN proper shipping name: Xylenes
Transport Hazard Class(es): 3
Packing Group: III
Environmental Hazards: Not applicable

IMDG/IMO
UN Number UN1307
UN proper shipping name: Xylenes
Transport Hazard Class(es): 3
Packing Group: III
Environmental Hazards: Not applicable
EMS: EmS F-E, S-D

IATA/ICAO
UN Number UN1307
UN proper shipping name: Xylenes
Transport Hazard Class(es): 3
Packing Group: III
Environmental Hazards: Not applicable

Special precautions during transport

None

HazChem Code
3Y

15. Regulatory Information

Safety, health and environmental regulations specific for the product

International Inventories
Australian AICS Inventory All components are listed on the AICS or are subject to a relevant exemption, permit, or
assessment certificate.
New Zealand Inventory of All components are listed on the NZIoC or are subject to a relevant exemption, permit, or
Chemicals assessment certificate.
EINECS (European Inventory of This product, and all its components, complies with EINECS
Existing Chemical Substances)
US TSCA Inventory All components listed on inventory or are exempt.
Canadian Domestic Substances List All components listed on inventory or are exempt.
(DSL)

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Poisons Schedule number
S6

International Agreements
Montreal Protocol - Ozone Depleting Substances: Does not apply
Stockholm Convention - Persistent Organic Pollutants: Does not apply
Rotterdam Convention - Prior Informed Consent: Does not apply
Basel Convention - Hazardous Waste: Does not apply

16. Other information

Date of preparation or review

Revision Date: 29-Sep-2016

Revision Note
SDS sections updated:
2

Full text of H-Statements referred to under sections 2 and 3

H225 - Highly flammable liquid and vapor
H226 - Flammable liquid and vapor
H304 - May be fatal if swallowed and enters airways
H312 - Harmful in contact with skin
H315 - Causes skin irritation
H319 - Causes serious eye irritation
H332 - Harmful if inhaled
H335 - May cause respiratory irritation
H336 - May cause drowsiness or dizziness
H373 - May cause damage to organs through prolonged or repeated exposure
H412 - Harmful to aquatic life with long lasting effects

Additional information For additional information on the use of this product, contact your local Halliburton
representative.

For questions about the Safety Data Sheet for this or other Halliburton products, contact
Chemical Stewardship at 1-580-251-4335.

Key abreviations or acronyms used

bw–bodywei ght
CAS–Chemi calAbst ractsService
EC50–Ef fect iveConcent rat
ion50%
LC50–Let halConcent r
ati
on50%
LD50–Let halDose50%
LL50–Let halLoadi ng50%
mg/ kg–mi l
li
gr am/kilogram
mg/ L–mi ll
igram/ li
ter
NOEC–NoObser vedEf fectConcentr
ati
on
OEL–Occupat i
onalEx posureLimit
PBT–Per sistentBi oaccumul at
iveandTox i
c
ppm –par tspermi l
lion
STEL–Shor tTerm Ex posureLimit
TWA–Ti me- Wei ght edAv erage
vPv B–v eryPer sistentandv er
yBioaccumulat
i
ve
h - hour
mg/m3 - milligram/cubic meter
mm - millimeter
mmHg - millimeter mercury
w/w - weight/weight
d - day

Key literature references and sources for data

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www.ChemADVISOR.com/

Disclaimer Statement
This information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is obtained
from various sources including the manufacturer and other third party sources. The information may not be valid under all
conditions nor if this material is used in combination with other materials or in any process. Final determination of suitability of any
material is the sole responsibility of the user.

End of Safety Data Sheet

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