Safety Data Sheet

ANTITEK
Safety Data Sheet dated 25/11/2011, version 3.6

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1. Product Identifier
Mixture identification:
Trade name: ANTITEK
Trade code: 10610/05K

1.2. Relevant identified uses of the substance/mixture and uses advised against
Recommended use:
Pressurized air for cleaning (Aerosol)
1.3. Details of the supplier of the safety data sheet
Company:
SILICONI COMMERCIALE SPA - Via Francia 4 Z.I. 36053 Gambellara (VI) ITALY tel n. +39 0444 649766
Competent person responsible for the safety data sheet:
[email protected]
1.4. Emergency telephone number
SILICONI COMMERCIALE SPA - ph n. +39 0444 649766

2. HAZARDS IDENTIFICATION
2.1. Classification of the substance or mixture
Directive criteria, 67/548/CE, 99/45/EC and following amendments thereof:
Properties / Symbols:
The product is not classified as dangerous according to 67/548/CE and 1999/45/CE.
It contains 5% of flamme substances

Adverse physicochemical, human health and environmental effects:

No other hazards

2.2. Label elements

R Phrases:
None
S Phrases:
S2 Keep out of reach of children.
S23 Do not breathe aerosols.
S51 Use only in well-ventilated areas.
Special Provisions:
Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50 °C.
Do not pierce or burn, even after use.Avoid to inhale directly and to spray into for eyes
Do not spray on a naked flame or any incandescent material. Keep away from sources of ignition - No smoking.
Keep out of reach of children.

2.3. Other hazards

vPvB Substances: None - PBT Substances: None
Other Hazards:
No other hazards
3. COMPOSITION/INFORMATION ON INGREDIENTS
3.1. Substances
N.A.
3.2. Mixtures
Hazardous components within the meaning of EEC directive 67/548 and CLP regulation and related classification:

3% - 5% Hydrocarbons, C3-4; Petroleum gas

Index number: 649-199-00-1, CAS: 68476-40-4, EC: 270-681-9
F+; R12; substance with a Community workplace exposure limit
2.5 Press. Gas H280

2.2/1 Flam. Gas 1 H220

K Note
For the wording of the listed risk phrases refer to section 16

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4. FIRST AID MEASURES
4.1. Description of first aid measures
In case of skin contact:
Wash with plenty of water and soap.
In case of eyes contact:
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
In case of Ingestion:
N.A. as aerosol preparation.
In case of Inhalation:
Remove casualty to fresh air and keep warm and at rest.
4.2. Most important symptoms and effects, both acute and delayed
None
4.3. Indication of any immediate medical attention and special treatment needed
Treatment:
None
5. FIRE-FIGHTING MEASURES
5.1. Extinguishing media
Suitable extinguishing media:
Water.
Carbon dioxide (CO2).
Extinguishing media which must not be used for safety reasons:
None in particular.
5.2. Special hazards arising from the substance or mixture
Do not inhale explosion and combustion gases.
Burning produces heavy smoke.
5.3. Advice for fire-fighters
Use suitable breathing apparatus .
Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
Move undamaged containers from immediate hazard area if it can be done safely.

6. ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures
Wear personal protection equipment.
Remove persons to safety.
See protective measures under point 7 and 8.
6.2. Environmental precautions
Do not allow to enter into soil/subsoil. Do not allow to enter into surface water or drains.
Retain contaminated washing water and dispose it.
In case of gas escape or of entry into waterways, soil or drains, inform the responsible authorities.
Suitable material for taking up: absorbing material, organic, sand
6.3. Methods and material for containment and cleaning up
Wash with plenty of water.
6.4. Reference to other sections
See also section 8 and 13
7. HANDLING AND STORAGE
7.1. Precautions for safe handling
Pressurized container. Do not perforate or burn even after use.
Do not use near fire or other possible sources of ignition. During work phase do not smoke.
Avoid contact with skin and eyes, inhaltion of vapours and mists.
Contamined clothing should be changed before entering eating areas.
Do not eat or drink while working.
See also section 8 for recomened protective equipment.
7.2. Conditions for safe storage, including any incompatibilities
Keep away from food, drink and feed.
Incompatible materials:
None in particular. See also section 10
Instructions as regards storage premises:
Adequately ventilated premises.
7.3. Specific end use(s)
None in particular

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8. EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Control parameters
1,1,1,2-Tetrafluoroethane - CAS: 811-97-2
OEL 8h: 1000 ppm
Hydrocarbons, C3-4; Petroleum gas - CAS: 68476-40-4
TLV TWA: 1000 ppm
DNEL Exposure Limit Values
N.A.
PNEC Exposure Limit Values
N.A.
8.2. Exposure controls
Eye protection:
Wear goggles with lateral protection EN166 .
If exposure to vapours cause a sense of bother to eyes, use antigas mask with complete facial.
Protection for skin:
It is not necessary in case of brief contact except for wearing antistatic clean and covering garments.
In case of long and frequent contact use protective and waterproof garments to this material.
Choosing specific protection as peak, gloves, boots, overalls depends on the type of operations.
Protection for hands:
During normal manipulation it is not necessary a particular protection.
In case of frequent contacts protect hands with gloves resistant to solvents (OVC,PE, neoprene, not natural rubber).
Respiratory protection:
The levels of air concentration should be maintained under the exposure limits. If inhalation are over exposure limit
use a supplied air respirator with cartridge filter. Filter type EN 141.
Thermal Hazards:
The aerosol container if overheated, deforms, breaks and it can be thrown a considerable distance
Environmental exposure controls:
Keep the container and use the product only in well ventilated place. A located ventilation may be necessary for
some operations.

9. PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties
Appearance and colour: pressurized container with base and liquefied gas
Odour: Characteristic
Odour threshold: N.A.
pH: N.A.
Melting point / freezing point: N.A.
Initial boiling point and boiling range: N.A.
Solid/gas flammability: No
Upper/lower flammability or explosive limits: N.A.
Vapour density: N.A.
Flash point: N.A.
Evaporation rate: N.A.
Vapour pressure: 3-8 bar
Relative density: N.A.
Solubility in water: Partial
Lipid solubility: Partal
Partition coefficient (n-octanol/water): N.A.
Auto-ignition temperature: N.A.
Decomposition temperature: N.A.
Viscosity: N.A.
Explosive properties: N.A.
Oxidizing properties: N.A.
9.2. Other information
Miscibility: N.A.
Fat Solubility: N.A.
Conductivity: N.A.
Substance Groups relevant properties N.A.

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10. STABILITY AND REACTIVITY
10.1. Reactivity
Stable under normal conditions
10.2. Chemical stability
Stable under normal conditions
10.3. Possibility of hazardous reactions
None
10.4. Conditions to avoid
Keep away from sunlight, overheating. Keep at temperature not exceeding 50°C. Keep away from oxidant agents.
Avoid contact with alkaline metals (Li, Na,K) or alkaline-earth metals (Ca, Mg,Ba) and its associations.
10.5. Incompatible materials
None in particular.
10.6. Hazardous decomposition products
None.

11. TOXICOLOGICAL INFORMATION

11.1. Information on toxicological effects
Toxicological information of the mixture:
N.A.
Toxicological information of the main substances found in the mixture:
N.A.
If not differently specified, the information required in Regulation 453/2010/EC listed below must be considered as N.A.:
a) acute toxicity;
b) skin corrosion/irritation;
c) serious eye damage/irritation;
d) respiratory or skin sensitisation;
e) germ cell mutagenicity;
f) carcinogenicity;
g) reproductive toxicity;
h) STOT-single exposure;
i) STOT-repeated exposure;
j) aspiration hazard.

12. ECOLOGICAL INFORMATION

12.1. Toxicity
Adopt good working practices, so that the product is not released into the environment.
It doesn't Contain CHLORINE-FLUORINE-CARBIDE.
12.2. Persistence and degradability
Degradation for photolysis through diffusion in atmosphere.
None dangerous effect for ozone: DOP= zero
12.3. Bioaccumulative potential
Absent
12.4. Mobility in soil
It evaporates
12.5. Results of PBT and vPvB assessment
vPvB Substances: None - PBT Substances: None
12.6. Other adverse effects
None

13. DISPOSAL CONSIDERATIONS

13.1. Waste treatment methods
Disposal should be in accordance with local, state or national legislation. Aerosol container can explode at temperature
Above 50°C if contains little gas residue. Spray all the aerosol content before disposal.
The product has to be considered: special dangerous disposal.
Waste disposal key:
The aerosol as a domestic waste is excluded from the application of such a normative for industrial activity, the empty
aerosol for professional use can be classified as follow: 15.01.10: packaging containing residues of dangerous
substances or residues contaminated by these substances.

14. TRANSPORT INFORMATION

14.1. UN number
ADR-UN number: 1950

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IATA-Un number: 1950
IMDG-Un number: 1950
14.2. UN proper shipping name
ADR-Shipping Name: AEROSOLS, Limited Quantity: max 1000ml Total gross mass of package
not exceed 30 kg LQ2
IATA-Technical name: AEROSOLS,
IMDG-Technical name: AEROSOLS
14.3. Transport hazard class(es)
ADR-Class: 2, 5A
ADR-Label: <UN1950 AEROSOLS>
IATA-Class: 2.2
IATA-Label: <UN1950 AEROSOLS>
IMDG-Class: 2
14.4. Packing Group
14.5. Environmental hazards
Marine pollutant: No
14.6. Special Precautions for User
IMDG-Technical name: AEROSOLS
IMDG-EMS: F-D
IMDG-MFAG: S-U
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
N.A.

15. REGULATORY INFORMATION

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Dir. 67/548/EEC (Classification, packaging and labelling of dangerous substances). Dir. 99/45/EEC (Classification, packaging
and labelling of dangerous preparations). Dir. 98/24/EC (Risks related to chemical agents at work). Dir. 2000/39/EC
(Occupational exposure limit values); Dir. 2006/8/CE. Regulation (CE) n. 1907/2006 (REACH), Regulation (CE) n. 1272/2008
(CLP), Regulation (CE) n. 790/2009 (1° ATP CLP), Regulation (EU) n. 453/2010 (Annex I).
Where applicable, refer to the following regulatory provisions :
Directive 2003/105/CE ('Activities linked to risks of serious accidents') and subsequent amendments.
Regulation (EC) nr 648/2004 (detergents).
1999/13/EC (VOC directive)

15.2. Chemical Safety Assessment

No

16. OTHER INFORMATION

Full text of phrases referred to in Section 3:
R12 Extremely flammable.

H280 Contains gas under pressure; may explode if heated.

H220 Extremely flammable gas.

Main bibliographic sources:

ECDIN - Environmental Chemicals Data and Information Network - Joint Research Centre, Commission of the
European Communities
SAX's DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS - Eight Edition - Van Nostrand Reinold
CCNL - Appendix 1
Insert further consulted bibliography
The information contained herein is based on our state of knowledge at the above-specified date. It refers solely to the
product indicated and constitutes no guarantee of particular quality.
It is the duty of the user to ensure that this information is appropriate and complete with respect to the specific use intended.
This MSDS cancels and replaces any preceding release.

ADR: European Agreement concerning the International Carriage of Dangerous Goods by

Road.
CAS: Chemical Abstracts Service (division of the American Chemical Society).
CLP: Classification, Labeling, Packaging.
DNEL: Derived No Effect Level.
EINECS: European Inventory of Existing Commercial Chemical Substances.
GefStoffVO: Ordinance on Hazardous Substances, Germany.
GHS: Globally Harmonized System of Classification and Labeling of Chemicals.

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IATA: International Air Transport Association.
IATA-DGR: Dangerous Goods Regulation by the "International Air Transport Association" (IATA).
ICAO: International Civil Aviation Organization.
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO).
IMDG: International Maritime Code for Dangerous Goods.
INCI: International Nomenclature of Cosmetic Ingredients.
KSt: Explosion coefficient.
LC50: Lethal concentration, for 50 percent of test population.
LD50: Lethal dose, for 50 percent of test population.
LTE: Long-term exposure.
PNEC: Predicted No Effect Concentration.
RID: Regulation Concerning the International Transport of Dangerous Goods by Rail.
STE: Short-term exposure.
STEL: Short Term Exposure limit.
STOT: Specific Target Organ Toxicity.
TLV: Threshold Limiting Value.
TWATLV: Threshold Limit Value for the Time Weighted Average 8 hour day. (ACGIH Standard).
WGK: German Water Hazard Class.

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