Tannery Industry Waste Production Notes
Tannery Industry Waste Production Notes
Tannery Industry Waste Production Notes
MANAGEMENT IN
TANNERY INDUSTRY
By:
Dhiraj kumar
MT/MEC/10006/19
INTRODUCTION
GENERAL
The main reason for the development and growth of the leather
industry in the country is its large animal population. India enjoys nearly 10%
of the total global availability of raw hides and skins which are the basic raw
material for the leather industry. The raw material availability in Indian as per
the 2003 raw material survey report is presented in Table 1.1 (Chandramouli
2005).
Table 1.1 Availability of Hides and Skins in India in 2003
Table 1.3 Water usages for Processing Raw to Semi-Finish and Semi-
Finish to Finished Leather
Water Usage*
Sl.
Name of the Stream Tamil Other States
No.
Nadu in India
1 Water usage for raw to semi-finish
12-14 12-14
process
2 Water usage for Washing 8-10 14-18
Total water usage for Raw to Semi-Finish
20-24 26-32
Operations
3 Water usage for semi-finish to finish
4-6 4-6
process
4 Water usage for Washing 6-8 10-12
Total water usage for Semi-Finish to
10-14 14-18
Finished Leather
5 Water usage for raw to finish process 16-20 16-20
6 Water usage for Washing 14-18 24-30
Total water usage for Raw to Finished
30-38 40-50
Leather Operations
* Water consumption in m3 for processing one tonne of raw hides/ skins
ENZYMES
FLESHING (WASTEWATER in
WATER FLESHING
(Manual/Mechanical) the case of mechanical
operation)
WATER
BASIC CHROMIUM SULPHATE CHROME WASTEWATER, SULPHATE,
SODIUM SALTS TANNING CHLORIDE, CHROMIUM,TDS
WATER
SODIUM BICARBONATE/ NEUTRALISATION WASTEWATER,
(Drums) TDS DRYING &
SODIUM FORMATE WATER, DYES, WASTEWATER,TDS
FAT LIQUOR FAT LIQUORING COD,BOD
(Drums) SULPHATE
DRY FINISHING
FINISHED LEATHER
FINISHED LEATHER
(a) For Processing Vegetable Tanned EI Leather (b) For Processing Chrome Tanned Leather
Figure 1.3 Wastewater Generated in Processing Semi-Finish to Finished Leather (Source:
8
Comprehensive Industry Document on Tanneries (COINDS), CPCB, 2010)
9
Water and material used for processing 1000 kg of raw hides/skins into
finished leather are presented in Table 1.4.
Table 1.4 Water and Material Used for Processing of Raw Hides/skins into
Finished Leather
Water
including
Process
Washing Chemical Quantity (kg)
Description
(cubic
meter)
Raw material 1000
Before soak
Wetting agent - 1-3
soaking 6-9 Preservative 0.1 - 1
Surfactant 2-4
Calcium Hydroxide 35-40
liming 6-11 Sodium Sulphide 20-25
Calcium Hydroxide
Re-Liming 2-3 5-10
Ammonium salts 25-27
Deliming and Acids 8-10
3-4
bating Enzyme 3-5
NaCl 50-55
H2SO4/HCOOH 10-12
Pickling and Chrome extract 80-90
3-5 (25% Cr2O3)
Chrome tanning
MgO/NaHCO3 6-8
Reaction salts
NaHCO3/ HCOONa 6-8
Chrome extract 10-13
(25% Cr2O3)
Post tanning 8-14 Organic tannins 15-20
Fat liquors 12-15
Dyestuffs 3-4
Acids 3-4
Grain leather crust 170-190
finishing 2-4
Solvent 25
Source: Comprehensive Industry Document on Tanneries (COINDS), CPCB, 2010
During the beam–house operations, a huge quantity of water is used in
proportion to the weight of the pelts and this contributes immensely to the
pollution load from the tannery. Comparatively, the BOD and COD loads are 50–
70% of the total load from a tannery wastewater while total solids (TS) (lime
sludge, fleshings and hair) load accounts for 15–20% (Ramasami and Prasad
1991). Post tanning activities are mechanical operations (e.g. sammying,
splitting, shaving and trimming), wet work, drying and finishing. These
operations will yield a combination of solid wastes, squeezed-out water and
unfixed tanning chemicals with the finishing process producing mostly air
emission of solvents (UNEP 1994).
Though the Indian leather industry has been able to surmount many of
the challenges with huge investment on pollution control, there are still three
lingering problems viz., compliance to total dissolved solids (TDS) norm of 2100
mg/L in treated wastewaters, compliance with zero liquid discharge (ZLD)
requirement of regulatory authorities and securitization of solid waste generated
(Rajamani 2007). The tannery sector in India is being compelled to comply with
rigorous norms for TDS (Ramasami et al 1999). The threat of salt burden in land
locked areas can lead to the leather sector being phased out of such areas. The
tannery clusters may need to consider various options to reduce salt burden. It
has been estimated that the salt burden on soil and water on account of tanning
activity is about 0.5 million tonnes in terms of neutral salts (Ramanujam and
Mariappan 1999). Hence, the leather industry is under close scrutiny of the
environmentalists.
1.5.1 Characteristics of Composite Wastewater
For (i) raw to semi-finish, (ii) semi-finish to finished leather and (iii)
raw to finished leather, the characteristics of composite wastewater are presented
Table 1.5.
Dusting Dusted sa lt
Hide, salt, water,
biocides, Soaking
Reliming
(Paddle or Drums)
Pickling
Hide, Water, Sulfuric acid
Chrome tanning
Hide, Water, BCS (wet blue)
sodium salts
Splitting Splits
Figure 1.5 Solid Wastes Generated during Processing of Raw Hides/ Skins
into Finished Leather (Vegetable Tanning)
(Source: Comprehensive Industry Document on Tanneries (COINDS),
CPCB, 2010)
Fleshings and non-tanned split are putrescible material consisting of protein and
fat.
Tanned Splits can be generated after liming or after tanning operations. The
flesh side of the splitting also referred to as the split, can be used to make leather
without a grain.
Shavings which are generated in leveling the surface of the leather are smaller
pieces than splits. Splits from tanned leather, shavings and dust from milling
buffing contain the tanning chemicals. Any further re-use and treatment depends
on the particular chemical composition.
The present modes of reuse and disposal of solid wastes are given in
Table 1. 7.
Table 1.7 Reuse and Disposal Options for the Solid Wastes
b. Quality of raw material used (i.e. wet salted, dry salted, semi
finished etc).
e. Quantity and quality of chemicals used (i.e. lime, barks and nuts
for vegetable tanning etc).
COMPOSITE
TANNERY
WASTEWATER
FLASH
MIXER FLOCCULATOR
SLUDGE
HOLDING
TANK
TREATED
TANNERY
WASTEWATER
FILTRATE
Figure 1.6 A Typical Process Flow Diagram for Treatment of Tannery Wastewater
(Source: Comprehensive Industry Document on Tanneries (COINDS), CPCB, 2010)
18
19
Raw to
Semi-finish to Raw to
Description Semi-
Finished Finished
finish
Primary sludge generation 60 - 90 10 - 30 140-190
(range in kg)
Secondary sludge generation 28-33 16-19 39-46
(range in kg)
Total sludge production ( kg) 88-123 26-49 179-236