Who Was Larmor and How Did He Discover His Famous Frequency?

Download as docx, pdf, or txt
Download as docx, pdf, or txt
You are on page 1of 2

Larmor Frequency

Who was Larmor and how did he discover his


famous frequency?  

Sir Joseph Larmor was an Irish-born mathematical physicist whose career


spanned from the late 19th to the early 20th Century. For many years he served
as the Lucasian Professor of Mathematics at St. John's College, Cambridge.  His
contemporaries included such notables as J.J. Thomson, Lord Kelvin, and James
Clerk Maxwell. 

Sir Joseph Larmor (1857-1942)


[Right] The first page of
Larmor's famous 1897 paper
from Philosophical Magazine.
Larmor worked in an era when the basic structure of the atom was still being
elucidated and quantum mechanics had yet to be developed.  His famous
equation of 1897 had nothing to do with NMR, as this phenomenon was still
several decades away from being discovered.  Instead it arose from attempts to
explain the curious splitting of optical spectral lines by an external magnetic
field described by Pieter Zeeman one year previously.  

Larmor's theory was that Zeeman's spectral lines were produced by charged
particles (electrons) moving in elliptical orbits.  Larmor demonstrated
mathematically that these electrons should precess around the direction of the
applied magnetic field.  He further calculated that the frequency of precession
was directly proportional to the strength of the applied field times a constant.
Larmor's constant was directly related to the particle's charge/mass ratio.
In later years as more became known about atomic
structure,
Particles with γ > 0 precess according to the left-hand rule
(ie, in the same direction as one's curled fingers when left
thumb points along Bo). Particles with γ < 0 precess in
opposite

 Larmor's equation was found to apply to any particle with


spin or angular momentum, taking the form we recognize
today: 
fo  =  γ Bo
where fo is the precession frequency, Bo is the strength of d
the externally applied field, and γ is the gyromagnetic
ratio, a constant specific to each specific nucleus or
particle.

The table (right) gives values of the gyromagnetic ratio (γ)


for various nuclei and particles.  Negative values
for γ mean that direction of precession is opposite to that
of ¹H. 
We see from the table that among nuclei, ¹H has the highest gyromagnetic ratio.
The resonance frequency of any particle at a certain field strength can easily be
calculated using this table and the Larmor equation.  For example, in a field
(Bo) of 1.5T, the resonance frequency of ¹H would be (42.58 MHz/T) x (1.5T)
= 63.87 MHz.  At 3.0T the resonance frequency would be twice as fast, or
127.74 MHz.

By comparison, an the precession frequency of an electron in a field of 1.0T


would be 27,204 MHz (or 27.204 GHz) and in a direction opposite to that of ¹H.
Thus to study electron paramagnetic resonance (EPR) frequencies in the
microwave region must be used.

Advanced Discussion (show/hide)»

References
     Bruen R. Sir Joseph Larmor. 2007.
(http://www.lucasianchair.org/20/larmor.html)
     Larmor J. LXIII. On the theory of the magnetic influence on spectra; and on
the radiation from moving ions. Phil Mag 1897; Series 5, Vol 44 (271): 503-
512.
     Tubridy N, McKinstry CS. Neuroradiological history: Sir Joseph Larmor and
the basis of MRI physics. Neuroradiology 2000; 42:852-855.

You might also like