Superior® Smoke Generator

Safety Data Sheet

according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Date of issue: 04/29/2015 Revision date: 04/29/2015 Supersedes: 01/18/2011

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier
Product form : Mixture
Trade name : Superior® Smoke Generator
CAS No : NA
Product code : NA
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Restricted to professional users
1.3. Details of the supplier of the safety data sheet
SUPERIOR SIGNAL COMPANY LLC
P.O. Box 96
Spotswood, NJ 08884
Phone: 732-251-0800
Fax: 732-251-9442
Email: [email protected]
1.4. Emergency telephone number
Emergency number : 732-251-0800

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
Classification (GHS-US)
Carc. 1B H350
Full text of H-phrases: see section 16
NOTE: Exposure is highly unlikely when product is used as directed. Product is sealed in heavy cardboard tube or metal canister. After ignition, product
slowly combusts and hexachloroethane is consumed. Direct contact with product does not occur.
2.2. Label elements
GHS-US labeling
Hazard pictograms (GHS-US) :

GHS08
Signal word (GHS-US) : Danger
Hazard statements (GHS-US) : H350 - May cause cancer (Dermal, oral)
Precautionary statements (GHS-US) : P201 - Obtain special instructions before use
P202 - Do not handle until all safety precautions have been read and understood
P280 - Wear protective clothing
P308+P313 - If exposed or concerned: Get medical advice/attention
P405 - Store locked up
P501 - Dispose of contents/container to in accordance with local regulations

2.3. Other hazards

Other hazards not contributing to the : After ignition, Smoke Generator emits smoke (mild Zinc Chloride solution) that can be irritating
classification to the eyes, respiratory tract, and mucous membranes. When used as directed exposure
should be limited, and normally poses no hazard. Persons with known respiratory sensitivity
should not be exposed to smoke. Moderate exposure may temporarily result in irritation,
inflammation, and difficulty breathing – moving to fresh air will reverse these effects. Heavy
exposure may result in coughs, chills, fever, and pulmonary edema, requiring medical
treatment. Overwhelming exposure can be dangerous and is to be avoided. Persons who will
be exposed to sustained heavy smoke should wear Self Contained Breathing Apparatus
(SCBA).
2.4. Unknown acute toxicity (GHS-US)
Not applicable

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Superior® Smoke Generator
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

SECTION 3: Composition/information on ingredients

3.1. Substance
Not applicable
3.2. Mixture
Name Product identifier % Classification (GHS-US)
Hexachloroethane (CAS No) 67-72-1 30 - 55 Carc. 1B, H350
Full text of H-phrases: see section 16
Remaining product components are not considered hazardous.

SECTION 4: First aid measures

4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical
advice (show the label where possible).
First-aid measures after inhalation : Allow victim to breathe fresh air. Allow the victim to rest.
First-aid measures after skin contact : Remove affected clothing and wash all exposed skin area with mild soap and water, followed
by warm water rinse.
First-aid measures after eye contact : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness
persist.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries : May cause cancer.
4.3. Indication of any immediate medical attention and special treatment needed
No additional information available

SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing media : Carbon dioxide. Dry powder. Sand. Foam. Water spray.
Unsuitable extinguishing media : Do not use a heavy water stream. Do not use extinguishing media containing water.
5.2. Special hazards arising from the substance or mixture
Reactivity : May react with water, producing smoke.
5.3. Advice for firefighters
Firefighting instructions : Fight fire with normal precautions from a reasonable distance. Use water spray or fog for
cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-
fighting water from entering environment.
Protection during firefighting : Self-contained breathing apparatus. Do not enter fire area without proper protective equipment,
including respiratory protection.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.

6.1.2. For emergency responders

Protective equipment : Equip cleanup crew with proper protection.
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up : On land, sweep or shovel into suitable containers. Minimize generation of dust. Store away
from other materials.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection.

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Superior® Smoke Generator
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Additional hazards when processed : After ignition, Smoke Generator emits smoke that can be irritating to the eyes, respiratory tract,
and mucous membranes (mild Zinc Chloride solution). When used as directed exposure
should be limited, and normally poses no hazard.
Precautions for safe handling : Persons with known respiratory sensitivity should not be exposed to smoke. Moderate
exposure may temporarily result in irritation, inflammation, and difficulty breathing – moving to
fresh air will reverse these effects. Heavy exposure may result in coughs, chills, fever, and
pulmonary edema, requiring medical treatment. Overwhelming exposure can be dangerous
and is to be avoided. Persons who will be exposed to sustained heavy smoke should wear Self
Contained Breathing Apparatus (SCBA). Wash hands and other exposed areas with mild soap
and water before eating, drinking or smoking and when leaving work. Provide good ventilation
in process area to prevent formation of vapor. Obtain special instructions before use. Do not
handle until all safety precautions have been read and understood.
Safe use of the product : Generate smoke to obscure, signal, trace airflow, or for other visual effects.
Hygiene measures : Do not eat, drink or smoke when using this product. Always wash hands after handling the
product. Wash contaminated clothing before reuse.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking. Keep away from ignition sources. Keep only in original container. Store in a dry place.
Store in original container. Prevent moisture contact. Keep only in the original container in a
cool, well ventilated place away from ignition sources. Keep container closed when not in use.
Incompatible products : Strong bases. Strong acids.
Incompatible materials : Mixture may be water reactive, releasing smoke (mild zinc chloride solution). Sources of
ignition.
7.3. Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection

8.1. Control parameters
Superior® Smoke Generator (NA)
ACGIH Not applicable
OSHA Not applicable

Hexachloroethane (67-72-1)
ACGIH ACGIH TWA (ppm) 1 ppm
OSHA OSHA PEL (TWA) (mg/m³) 10 mg/m³
OSHA OSHA PEL (TWA) (ppm) 1 ppm

8.2. Exposure controls

Personal protective equipment : Avoid all unnecessary exposure.

Hand protection : Wear protective gloves.

Eye protection : Chemical goggles or safety glasses.
Respiratory protection : Wear appropriate mask.
Other information : Do not eat, drink or smoke during use. NOTE: Exposure is highly unlikely when product is used
as directed. Product is sealed in heavy cardboard tube or metal canister. After ignition, product
slowly combusts and hexachloroethane is consumed. Direct contact with product does not
occur.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state : Solid
Appearance : Powder contained in sealed tube or canister.
Color : Gray
Odor : Mothballs
Odor threshold : No data available
pH : No data available
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Superior® Smoke Generator
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Melting point : No data available

Freezing point : No data available
Boiling point : No data available
Flash point : No data available
Relative evaporation rate (butyl acetate=1) : No data available
Flammability (solid, gas) : No data available
Explosion limits : No data available
Explosive properties : No data available
Oxidizing properties : No data available
Vapor pressure : No data available
Relative density : No data available
Relative vapor density at 20 °C : No data available
Solubility : No data available
Log Pow : No data available
Log Kow : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Viscosity : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available

9.2. Other information

Minimum ignition energy : ≈

SECTION 10: Stability and reactivity

10.1. Reactivity
May react with water, producing smoke.
10.2. Chemical stability
Product is stable. Not established.
10.3. Possibility of hazardous reactions
Not established.
10.4. Conditions to avoid
Moisture. High temperature. High humidity.
10.5. Incompatible materials
Strong acids. Strong bases.
10.6. Hazardous decomposition products
zinc chloride. Smokes. Carbon monoxide. Carbon dioxide.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity : Not classified

Hexachloroethane (67-72-1)
LD50 oral rat 4460 mg/kg
LD50 dermal rabbit 32000 mg/kg
ATE US (oral) 4460.000 mg/kg body weight
ATE US (dermal) 32000.000 mg/kg body weight
Skin corrosion/irritation : Not classified
Serious eye damage/irritation : Not classified
Respiratory or skin sensitization : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : May cause cancer (Dermal, oral).

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Superior® Smoke Generator
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Hexachloroethane (67-72-1)
IARC group 2B - Possibly carcinogenic to humans
National Toxicology Program (NTP) Status 1 - Evidence of Carcinogenicity, 3 - Reasonably anticipated to be Human Carcinogen
In OSHA Hazard Communication Carcinogen Yes
list
Reproductive toxicity : Not classified
Specific target organ toxicity (single exposure) : Not classified

Specific target organ toxicity (repeated : Not classified

exposure)

Aspiration hazard : Not classified

Potential Adverse human health effects and : Based on available data, the classification criteria are not met.
symptoms

SECTION 12: Ecological information

12.1. Toxicity

Hexachloroethane (67-72-1)
LC50 fish 1 967 - 1250 μg/l (Exposure time: 96 h - Species: Pimephales promelas)
LC50 fish 2 712 - 1030 μg/l (Exposure time: 96 h - Species: Lepomis macrochirus)

12.2. Persistence and degradability

Superior® Smoke Generator (NA)
Persistence and degradability Not established.

12.3. Bioaccumulative potential

Superior® Smoke Generator (NA)
Bioaccumulative potential Not established.
Hexachloroethane (67-72-1)
Log Pow 4.14

12.4. Mobility in soil

Superior® Smoke Generator (NA)
Ecology - soil None.

12.5. Other adverse effects

Effect on the global warming : No known ecological damage caused by this product.

Other information : Avoid release to the environment.

SECTION 13: Disposal considerations

13.1. Waste treatment methods
Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to ...
Ecology - waste materials : Avoid release to the environment.

SECTION 14: Transport information

Department of Transportation (DOT)
In accordance with DOT
Not regulated for transport
Additional information
Other information : No supplementary information available.

ADR
No additional information available

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Superior® Smoke Generator
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Transport by sea
No additional information available
Air transport
No additional information available

SECTION 15: Regulatory information

15.1. US Federal regulations
All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic
Substances Control Act (TSCA) inventory
Hexachloroethane (67-72-1)
SARA Section 313 - Emission Reporting 0.1 %
Zinc (7440-66-6)
RQ (Reportable quantity, section 304 of EPA's 1000 lb
List of Lists)
SARA Section 313 - Emission Reporting 1.0 % (dust or fume only)

15.2. International regulations

CANADA
All components listed on the Canadian DSL (Domestic Sustances List)

EU-Regulations
All components listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances)

Classification according to Regulation (EC) No. 1272/2008 [CLP]

No additional information available

Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]

Not classified

National regulations
All components listed on the AICS (Australian Inventory of Chemical Substances)
All components listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China)
All components listed on the Japanese ENCS (Existing & New Chemical Substances) inventory
All components listed on the Korean ECL (Existing Chemicals List)
All components listed on NZIoC (New Zealand Inventory of Chemicals)
All components listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances)
All components listed on INSQ (Mexican national Inventory of Chemical Substances)

15.3. US State regulations

Hexachloroethane (67-72-1)
U.S. - California - U.S. - California - U.S. - California - U.S. - California - No significance
Proposition 65 - Proposition 65 - Proposition 65 - Proposition 65 - risk level (NSRL)
Carcinogens List Developmental Toxicity Reproductive Toxicity - Reproductive Toxicity -
Female Male
Yes No No No 20 µg/day

Hexachloroethane (67-72-1)
U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List
U.S. - Pennsylvania - RTK (Right to Know) List

Zinc (7440-66-6)
U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List
U.S. - Pennsylvania - RTK (Right to Know) List

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Superior® Smoke Generator
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Zinc oxide (1314-13-2)

U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List
U.S. - Pennsylvania - RTK (Right to Know) List

SECTION 16: Other information

Full text of H-phrases:
------ Carc. 1B Carcinogenicity Category 1B
------ H350 May cause cancer

Revision date : 04/29/2015

Other information : DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we
believe are reliable. However, the information is provided without any warranty, express or
implied, regarding its correctness. The conditions or methods of handling, storage, use or
disposal of the product are beyond our control and may be beyond our knowledge. For this and
other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage
or expense arising out of or in any way connected with the handling, storage, use or disposal of
the product. This SDS was prepared and is to be used only for this product. If the product is
used as a component in another product, this SDS information may not be applicable.

SDS US (GHS HazCom 2012)

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as
guaranteeing any specific property of the product

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