Silicone Materials For Electronic Devices and Component Assemblies
Silicone Materials For Electronic Devices and Component Assemblies
Silicone Materials For Electronic Devices and Component Assemblies
Electronic Devices
and Component Assemblies
Contents Silicone Product Condensation Cure
Profile Condensation cure silicone
Overview..................................................................................1-2 products cure when exposed
The products introduced in
to moisture in the environment
Industry Overview................................................................3-4 this selector guide consist
at room temperature. These
Product Index of RTV (Room Temperature
materials are categorized into
Adhesives and Sealants....................................................5-6 Vulcanizing) silicone products
Alkoxy, Acetoxy, or Oxime
Grease........................................................................................7 that are commonly found
based on the byproducts that
Coating Materials.................................................................7-8 in Electric and Electronic
occur during cure.
Encapsulants / Potting Materials....................................9-10 applications and component
assemblies. This family of
Selection Guide.................................................................11-12 Heat (Addition) Cure
silicone products consists
Product Details of both Room Temperature Heat cure grades cure upon
1 Part Condensation Cure.............................................13-17 Cure and Heat (Addition) exposure to elevated heat or
1 Part Heat (Addition) Cure...........................................18-20 Cure grades. room temperature.
2 Part Room Temperature. Cure.................................21-22
2 Part Heat (Addition) Cure...........................................23-24 Momentive Performance
1 Part & 2 Part Gels.......................................................25-26 Materials offers a
Junction Coating Resin (JCR) Grades..............................27 comprehensive portfolio of
Grease.....................................................................................28 silicone solutions to help meet
a broad array of handling
UL Certifications............................................................29-30
and performance needs in
Technical Information....................................................31-32 electronic components and
FAQ.............................................................................................33 assemblies. Selection of
the appropriate type of RTV
depends upon the required
manufacturing process,
handling requirements, curing
conditions, equipment, and
desired material properties.
Millable
Silicone Rubber
2 Part Condensation Cure
1
Sealing & Adhesion or meter mix dispensing, Coating coating. Selection of a
depending on production silicone coating material for a
Silicones are used in a wide The Coating process involves
volume and post-mix material particular application involves
array of applications for the application of silicone
properties. the consideration of various
bonding components, and in a thin protective layer to
performance and processing
sealing against moisture or a component surface by
criteria.
environmental contaminants. methods such as dip, flow,
A comprehensive portfolio of spray, and selective robotic
1 Part and 2 Part Adhesives
and Sealants, many of which
Performance Considerations
are excellent candidates for Performance Considerations
- Temperature Resistance
- Temperature Resistance
assembly applications on or - Dielectric Resistance
- Dielectric Resistance
- Flame Retardancy
near sensitive electrical and - Low Volatility
- Flame Retardancy
- Low Volatility
electronic components, are - Adhesion
- Mechanical Strength
available. These materials - Hardness
are applied by a variety - Thermal Conductivity Process Considerations
of methods ranging from - Viscosity
- Cure Mechanism
manual dispensing to auto- Process Considerations - Cure Temperature
dispensing units for tube, - Viscosity - Cure Time
- Cure Mechanism - Pot Life
cartridge, pail, or drum - Cure Temperature
packages. Mixing for 2 Part - Cure Time
- Pot Life
grades may be accomplished
by either manual processes
Potting & performance, many of which
offer enhancements for
Encapsulation
thermal cycling protection,
Silicone rubber and gels are
stress relief, material strength,
widely used in electronics
flame retardancy, or optical
to ensure mechanical and
clarity.
environmental protection.
A full range of products
are offered in various cure
speeds, viscosities, and
Performance Considerations
- Temperature Resistance
- Dielectric Resistance
- Flame Retardancy
- Low Volatility
- Adhesion
- Stress Relief
- Release Properties
- Thermal Conductivity
Process Considerations
- Viscosity
- Cure Mechanism
- Cure Temperature
- Cure Time
- Pot Life
2
Industries Served
3
Automotive Electronics Typical Applications: Aviation and Aerospace Typical Applications:
The automotive industry - ECU potting, sealing, Avionics and frame assembly - Avionics
plays a critical role in coating needs in Aviation and - Circuit and terminal
integrating new electronic - Wire connector sealing Aerospace are served protection
technologies. As more and - Sealing, encapsulation in through silicone adhesives, - Wire sealants
more components migrate to a broad range of sensors coating, encapsulation
- Engine gasketing
electronic solutions, silicones and potting materials that
- HVAC system sealing - Cargo door, window
play an increasingly important help withstand stress and
role in helping deliver material - Vibration dampening temperature extremes. sealing
solutions that contribute to - Headlamp assemblies - Weatherstrip adhesives
design flexibility and long- - Aviation lighting
term component reliability
- Ventilation ducts
under harsh operating
conditions.
4
Product Overview: Adhesives & Sealants
Cure Cured
Type Grade Feature
Chemistry Property
RTV133 Alkoxy Rubber UL certified non-flowable sealant.
RTV167 Alkoxy Rubber High-strength paste adhesive with UL certification and Mil Spec.
TSE385 Alkoxy Rubber Paste adhesive.
TSE3853-W Alkoxy Rubber UL certified, semi-flowable paste.
TSE3854DS Alkoxy Rubber UL certified paste adhesive.
TN3005 Alkoxy Rubber Fast tack, low volatile paste paste adhesive.
TN3085 Alkoxy Rubber Fast tack, low volatile paste paste adhesive. UL certified
TSE3941M Alkoxy Rubber Fast tack, thermally conductive flowable sealant.
TSE3944 Alkoxy Rubber Low volatile, UL certified flowable sealant.
1 Part Condensation Cure
TN3305 Alkoxy Rubber Fast tack, low volatile flowable adhesive / sealant. UL certified
TSE3971 Alkoxy Rubber Flowable adhesive / sealant.
TSE3976-B Alkoxy Rubber Low volatile, temperature resistant sealant. UL certified.
XE11-B5320 Alkoxy Rubber Fast tack, low volatile, thermally conductive adhesive. UL certified.
FRV1106 Acetoxy Rubber Fuel, solvent, chemical, and temperature-resistant fluoro sealant.
RTV100 series Acetoxy Rubber FDA, USDA, and NSF compliant paste adhesive. Mil Spec.
RTV106 Acetoxy Rubber Temperature-resistant adhesive. FDA, USDA, & NSF compliant. Mil Spec.
RTV116 Acetoxy Rubber Temperature-resistant flowable sealant. FDA, USDA, & NSF compliant. Mil Spec.
RTV157 Acetoxy Rubber High strength paste / adhesive.
RTV159 Acetoxy Rubber High strength paste / adhesive. Temperature-resistant.
TSE370 Acetoxy Rubber Fast tack, general purpose paste adhesive.
TSE382 Oxime Rubber Fast tack, general purpose adhesive paste. UL certified.
TSE3826 Oxime Rubber Fast tack adhesive for high-temperature applications.
TSE3843-W Oxime Rubber UL certified general purpose adhesive / sealant.
TSE384-B Oxime Rubber UL certified general purpose adhesive / sealant.
TSE387 Oxime Rubber General purpose flowable adhesive / sealant.
TSE3877-B Oxime Rubber Flowable sealant for high-temperature applications.
TSE388 Oxime Rubber Flowable general purpose adhesive / sealant.
TSE3212 Heat Rubber Thixotropic adhesive / sealant.
TSE322 Heat Rubber Flowable adhesive / sealant.
TSE3221S
1 Part Heat Cure
TSE3380 Heat Rubber Thermally conductive adhesive. Fast cure at elevated temperatures.
1
TSE326M-EX in Europe and the Americas
5
Regulatory restrictions may apply to products in certain countries.
Please contact a Momentive Performance Materials sales representatives for availability in specific regions.
Performance
Product
Flame Low Thermally High Temp. Low Temp. FDA Detail
Flowability MIL-Spec
Retardancy Volatility Conductive Resistance Resistance Compliant
Non-flowable UL94 V-0 P. 13
Non-flowable UL94 HB MIL-A-46146B P. 13
Non-flowable P. 13
Semi-flowable UL94 V-0 P. 14
Non-flowable UL94 V-0 P. 13
Non-flowable • P. 13
Non-flowable UL94 V-0 • • P. 13
Flowable • P. 14
Semi-flowable UL94 V-0 • P. 14
Flowable UL94 HB • P. 14
Flowable P. 14
Flowable UL94 HB • • P. 14
Non-flowable UL94 HB • • P. 13
Non-flowable • P. 16
Non-flowable • MIL-A-46106B P. 17
Non-flowable • • MIL-A-46106B P. 17
Flowable • • MIL-A-46106B P. 17
Non-flowable P. 17
Non-flowable • P. 17
Non-flowable P. 17
Non-flowable UL94 HB P. 15
Non-flowable • P. 16
Semi-flowable UL94 V-1 • P. 16
Non-flowable UL94 V-0 P. 16
Flowable P. 16
Flowable • P. 16
Flowable P. 16
Semi-flowable P. 18
Flowable P. 18
Flowable P. 19
Semi-flowable UL94 HB P. 18
Flowable UL94 HB • P. 19
Flowable • P. 18
Flowable • P. 20
Flowable • P. 19
Flowable • P. 19
Non-flowable P. 18
Non-flowable P. 18
Non-flowable • P. 21
Semi-flowable • P. 21
Non-flowable P. 23
Flowable • P. 23
6
Product Overview: Coating Materials
Cure Cured
Type Grade Feature
Chemistry Property
ECC3010 Alkoxy Rubber Fast cure conformal coating material. Solvent free
ECC3050S Alkoxy Rubber Fast cure conformal coating material. Low volatile. Solvent free
ECS0600 Alkoxy Rubber High purity repairable electrode coating. Fast tack.
ECS0601 Alkoxy Rubber High purity, non-repairable type electrode coating. UL certified.
ECS0609FR Alkoxy Rubber High purity, non-repairable type electrode coating. UL certified.
1 Part Condensation Cure
7
Regulatory restrictions may apply to products in certain countries.
Please contact a Momentive Performance Materials sales representatives for availability in specific regions.
Performance
Product
Flame Low Thermally High Temp. FDA Detail
Flowability JCR Grade MIL-Spec
Retardancy Volatility Conductive Resistance Compliant
Flowable P. 15
Flowable • P. 15
Flowable • P. 15
Flowable UL94 HB • P. 15
Flowable UL94 V-0 • P. 14
Flowable UL94 HB P. 14
Flowable • P. 14
Semi-flowable UL94 V-0 • P. 14
Flowable UL94 HB • P. 14
Flowable P. 14
Flowable UL94 HB • • P. 14
Flowable P. 15
Flowable • P. 15
Flowable UL94 V-1 • • P. 14
Flowable • MIL-A-46106B P. 17
Flowable P. 16
Flowable • P. 16
Flowable P. 16
Flowable UL94 HB P. 16
Flowable P. 20
Flowable P. 19
Flowable P. 20
Flowable P. 20
Semi-flowable P. 20
Semi-flowable P. 20
Flowable P. 20
Semi-flowable • P. 27
Semi-flowable • P. 27
Semi-flowable • P. 27
Semi-flowable • P. 27
Flowable • P. 22
Flowable P. 24
Flowable UL94 V-0 • P. 24
Flowable UL94 V-0 • P. 24
Flowable UL94 V-0 • P. 24
Semi-flowable • P. 27
Semi-flowable • P. 27
8
Product Overview: Encapsulants and Potting Materials
Cure Cured
Type Grade Feature
Chemistry Property
RTV160 Alkoxy Rubber UL certified flowable encapsulant.
Cond. Cure
TN3705 Alkoxy Rubber Low volatile, low viscosity potting / coating material.
XE11-A5133S Alkoxy Rubber Low volatile, UL certified, thermally conductive coating & potting.
RTV110 series Acetoxy Rubber General purpose coating / encapsulant. FDA, USDA, and NSF compliant. Mil Spec.
RTV116 Acetoxy Rubber Temperature-resistant flowable sealant. FDA, USDA, and NSF compliant. Mil Spec.
TSE325 Heat Rubber Flowable coating / encapsulant.
1 Part Heat
9
Regulatory restrictions may apply to products in certain countries.
Please contact a Momentive Performance Materials sales representatives for availability in specific regions.
Performance
Product
Flame Low Thermally High Temp. Low Temp. FDA Detail
Flowability MIL-Spec
Retardancy Volatility Conductive Resistance Resistance Compliant
Flowable UL94 HB P. 14
Flowable P. 15
Flowable • P. 15
Flowable UL94 V-1 • • P. 14
Flowable • MIL-A-46106B P. 17
Flowable • • MIL-A-46106B P. 17
Flowable P. 20
Flowable P. 20
Flowable P. 20
Flowable P. 25
Flowable UL94 V-1 P. 25
Flowable P. 25
Flowable • P. 22
Flowable • P. 22
Flowable • • • P. 21
Flowable • P. 21
Flowable P. 22
Flowable UL94 HB P. 22
Flowable UL94 V-0 P. 22
Flowable • P. 23
Flowable P. 23
Flowable P. 24
Flowable UL94 V-0 • P. 24
Flowable UL94 V-0 • P. 24
Flowable UL94 V-0 • P. 24
Flowable UL94 V-0 • P. 24
Flowable UL94 V-0 • P. 24
Flowable UL94 V-0 P. 24
Flowable P. 24
Flowable P. 23
Flowable • • P. 23
Flowable UL94 V-0 • • P. 23
Flowable P. 26
Flowable P. 26
Flowable P. 26
10
Selection Guide
1 Part Grades BLACK=Rubber RED=Gels Alkoxy Acetoxy Oxime Heat
Performance
Viscosity
Range Thermally Low UL Temp. FDA General
Conductive Volatility Certified Resistant Compliant Purpose
TN3085 TN3005 TSE3854DS TSE385
XE11-B5320 TN3085 TN3085
XE11-B5320 RTV133
RTV167
Non-
FRV1106 RTV100 RTV157
Flowable
RTV106 RTV106 TSE370
TSE382 TSE3826
TSE384-B
XE13-B3208
TSE3976-B TSE3853-W TSE3976-B TSE3971
TSE3976-B
High RTV159
Viscosity TSE3843-W TSE3843-W TSE3877-B
TSE3212
TSE322
TSE3941M TSE3944 TSE3944 TSE398
XE11-A5133S XE11-A5133S XE11-A5133S
TN3305 RTV160
TN3305
RTV110 RTV116 RTV110
Medium
RTV116
Viscosity
TSE387
TSE388
TSE3280-G TSE322S TSE326 TSE3221S
TSE3281-G TSE325 TSE3261-G
TSE326M
ECC3050S ECS0601 ECC3010
ECS0600 ECS0609FR
ECS0601
ECS0609FR
TN3705
TSE389
Low
TSE3051FR TSE3051
Viscosity
TSE3051-L
TSE325
TSE3250
TSE3251
TSE3251-C
TSE325-B
11
2 Part Grades BLACK=Rubber RED=Gels Heat Room Temperature
Performance
Viscosity
Range Thermally Low UL Temp. FDA General
Conductive Volatility Certified Resistant Compliant Purpose
Non-Flowable TSE3360
RTV577
High Viscosity
RTV88
TSE3380
Medium RTV566 RTV31 RTV11
Viscosity RTV566
RTV60
TSE3331 TIA222G TSE3331 RTV615 RTV6136-D1
TSE3331K TIA216G TSE3331K TSE3032
TSE3431 TSE3431 TSE3033
TSE3431-H TSE3431-H TSE3062
Low
TIA222G XE14-B7892 TSE3070
Viscosity
TIA216G TIA222G TSE3330
YE5822
TSE3661 TSE3663
TSE3664K
Non-Flowable
High Viscosity Medium Viscosity Low Viscosity Viscosity and flowability of
Flowable Flowable Flowable
the silicone material are often
key factors in the selection of
a material for use in sealing,
coating, and encapsulation /
potting applications. A broad
array of material performance
and viscosity combinations
are provided to help match
the requirements of many
applications.
Shallow Cavity / Small Mass Complex Design - Deep Cavity / Large Mass Enclosed System
Exposed Surface
6mm
12mm 12mm
6mm
12mm 25mm
12
Product Details - 1 Part Condensation Cure Grades
Adhesive / Sealant • • • • • • •
Application
Coating
Encapsulant / Potting
Viscosity (23oC) Pa.s (P) - - - - - - -
Application Rate g/min 180 650 - - - - -
Tack Free Time min 240 60 90 15 7 7 5
Specific Gravity (23oC) 1.12 1.23 1.10 1.33 1.04 1.63 2.59
Hardness 37 46 35 45 22 46 80
Tensile Strength MPa (psi) 5.5 (800) 4.5 (650) 2.9 (420) 3.0 (435) 1.8 (260) 2.3 (335) 3.6 (520)
Elongation % 600 250 390 300 330 150 40
Adhesive Strength MPa (psi) 1.2 (175) - 2.0 (290) 2.2 (320) 1.2 (175) 1.3 (190) 1.3 (190)
Thermal Conductivity W/m.K - - 0.17 0.34 0.18 0.7 1.3
Volume Resistivity MΩ.m 3.0x107 3.0x107 5.0x107 2.0x106 2.0x107 4.0x106 2.0x107
Dielectric Strength kV/mm 20 20 22 25 26 23 17
Dielectric Constant (60Hz) 2.8 2.8 (100Hz) 3.0 3.1 2.7 4.0 2.6
Dissipation Factor (60Hz) 0.0026 0.001 (100Hz) 0.001 0.02 0.002 0.04 0.005
Low Molecular Siloxane (D4-D10) wt% - - - - 0.01 0.01 0.010
Flame Retardancy UL94 HB UL94 V-0 UL94 V-0 UL94 V-0 UL94 HB
Low Volatility • • •
Temperature Resistance
Thermally Conductive • •
FDA
MIL-Spec3 MIL-A-46106B4
White • • • • •
Clear •
Color
Black • •
Gray • •
Tube • • • •
Cartridge • • • • • •
Packaging
Can
Pail
See Page 15 for details •
1
JIS K 6249 2 ASTM D2196 3 Testing is performed in accordance with current Momentive Performance Materials quality test methods, laboratory conditions,
procedures, frequency and sampling. 4 MIL-A-46106B Group I Type I
8
Cure Properties: TN3305 (Alkoxy)
30oC, 60%RH
15 TSE382 (Oxime) 50oC, 90%RH
50oC, 60%RH
Condensation cure grades cure 7
50oC, 30%RH
with exposure to atmospheric 6 12
moisture. The cure process
Cure Depth mm
Cure Depth mm
13
TSE3944 TSE3853-W TSE3971 TSE3976-B XE11-A5133S TSE3941M TN3305 RTV160 ECS0609FR
• • • • • •
• • • • • • • •
• •
- 400 (4000) 1 100 (1000) 1 100 (1000) 1 60 (600) 1 50 (500) 1 47 (470) 1 38 (380)2 18 (180) 1
- - - - - - - - -
5 15 10 5 10 5 9 240 7
1.31 1.31 1.04 1.08 1.64 1.64 1.04 1.04 1.22
38 34 16 30 63 63 14 25 28
1.5 (220) 2.3 (335) 1.5 (220) 1.7 (245) 3.9 (565) 3.2 (465) 1.5 (220) 1.9 (275) 2.4 (350)
170 270 350 210 100 70 400 230 250
1.0 (145) 1.3 (190) 1.1 (160) 1.3 (190) 1.3 (190) 1.4 (205) 1.0 (145) - 1.2 (175)
0.36 0.34 0.18 0.18 0.83 0.83 0.18 - -
1.0x107 2.0x106 2.0x107 1.0x107 4.0x106 4.0x106 2.0x107 4.0x106 1.0x105
22 20 21 20 20 21 26 20 20
3.8 3.1 2.9 3.5 4.0 4.0 2.7 2.8 3.1
0.02 0.02 0.005 0.01 0.04 0.04 0.002 0.001 0.05
0.028 - - 0.025 0.025 - 0.01 - -
UL94 V-0 UL94 V-0 UL94 HB UL94 V-1 UL94 HB UL94 HB UL94 V-0
• • • • •
•
• •
• • • • • • •
•
• • •
• •
• • • • • •
• • • • • • • •
•
•
Typical property data values should not be used as specifications
including electronic
y)
im
10 achieved in up to 7
(A
0.2
x
30oC, 90%RH
(O
days.
5
30oC, 60%RH 8
00
3
)
2
E3
xy
TN S
lko
T
(A
10oC, 90%RH E
10 C, 60%RH TS
10oC, 30%RH 0
0
24 48 72 96 1 2 3 4 5 6 7 8 9 10
Cure Time h Cure Time h
14
Product Details - 1 Part Condensation Cure Grades
Adhesive / Sealant •
Application
Coating • • • • • •
Encapsulant / Potting • •
Viscosity (23oC) Pa.s (P) 17 (170) 1 5.0 (50) 1 1.5 (15) 1 1.4 (14) 1 0.55 (5.5) 1 0.11 (1.1) 1 -
Application Rate g/min - - - - - - -
Tack Free Time min 10 7 7 7 5 3 10
Specific Gravity (23oC) 1.04 1.03 1.01 1.01 0.98 0.99 1.04
Hardness 14 20 13 25 22 35 28
Tensile Strength MPa (psi) 1.3 (190) 1.2 (175) 0.4 (60) 0.8 (115) - - 1.9 (275)
Elongation % 230 450 130 150 - - 380
Adhesive Strength MPa (psi) 0.7 (100) - 0.2 (30) 0.3 (45) - - 1.7 (245)
Thermal Conductivity W/m.K 0.18 - 0.18 - - - 0.18
Volume Resistivity MΩ.m 2.0x107 4.0x107 2.0x107 2.0x107 1.0x107 1.0x107 1.0x107
Dielectric Strength kV/mm 23 20 26 20 20 20 23
Dielectric Constant (60Hz) 3.0 2.8 2.7 2.6 2.60 2.78 2.9
Dissipation Factor (60Hz) 0.01 0.001 0.002 0.002 0.001 0.001 0.004
Low Molecular Siloxane (D4-D10) wt% - 0.01 0.01 0.01 0.01 - -
Flame Retardancy UL94 HB UL94 HB
Low Volatility • • • •
Temperature Resistance
Thermally Conductive
FDA
MIL-Spec
White • • • • •
Clear • • • •
Color
Black • • •
Gray •
Red
Tube •
Cartridge • • •
Packaging
Can • •
Pail • •
See Page 15 for details • •
1
JIS K 6249
Packaging Supplement
Tube Cartridge Can Pail
Grade
W C B W C B G W C B W C B
TN3005 • • • • • • • •
TN3305 • • • • • • • • •
TN3705 • • • • • • • • • • • •
TSE382 • • • • • • • •
TSE387 • • • • • • •
TSE389 • • • • •
W: White, C: Clear, B: Black, G: Gray
15
TSE3826 TSE384-B TSE3843-W TSE3877-B TSE387 TSE388 TSE389 FRV1106
• • • • • • •
• • • •
• • •
•
• • • •
• •
• • • •
•
• •
• • •
• • • • • •
•
• •
Typical property data values should not be used as specifications
16
Product Details - 1 Part Condensation Cure Grades
RTV100 RTV110
Properties RTV157 RTV159 RTV106 TSE370 RTV116
series series
Cure Chemistry Acetoxy Acetoxy Acetoxy Acetoxy Acetoxy Acetoxy Acetoxy
Flowability Non-Flowable Non-Flowable Non-Flowable Non-Flowable Non-Flowable Flowable Flowable
High strength paste High temperature, Paste adhesive with High temperature Fast tack paste High temperature resistant, Flowable adhesive
adhesive high strength, paste FDA, USDA, NSF, resistant paste adhesive flowable adhesive. FDA, with FDA, USDA,
Features and Benefits adhesive and MIL-A-46106B adhesive. FDA, USDA, USDA, NSF, MIL-A-47040, NSF, MIL-A-46106B
NSF, MIL-A-46106B MIL-A-46106B
Adhesive / Sealant • • • • • •
Application
Coating •
Encapsulant / Potting • •
Viscosity (23oC) Pa.s (P) - - - - - 25 (250) 1 20 (200) 1
Application Rate g/min 155 175 400 400 - - -
Tack Free Time min 45 45 20 20 5 30 20
Specific Gravity (23oC) 1.09 1.09 1.05 1.07 1.04 1.09 1.05
Hardness 28 20 30 30 22 20 25
Tensile Strength MPa (psi) 6.2 (900) 7.0 (1,025) 2.75 (400) 2.55 (370) 2.5 (365) 2.45 (355) 2.20 (320)
Elongation % 825 350 450 400 530 350 325
Adhesive Strength MPa (psi) 1.3 (183) - 1.4 (200) 1.4 (200) 2.2 (320) 0.9 (125) 0.7 (100)
Thermal Conductivity W/m.K - - - - 0.18 - -
Volume Resistivity MΩ.m 7.5x106 1.1x107 3.0x107 3.0x106 1.0x107 2.0x106 6.0x106
Dielectric Strength kV/mm 20.7 19.7 20 20 22 16 16
Dielectric Constant (60Hz) 2.9 2.6 2.8 2.8 3.0 2.8 2.8
Dissipation Factor (60Hz) 0.0009 0.0007 0.001 0.001 0.003 0.001 0.001
Low Molecular Siloxane (D4-D10) wt% - - - - - - -
Flame Retardancy
Low Volatility
Temperature Resistance • • •
Thermally Conductive
FDA • • • •
2 3 3 3
MIL-Spec MIL-A-46106B MIL-A-46106B MIL-A-46106B MIL-A-46106B3
White RTV102 • RTV112
Clear RTV108 • RTV118
Black RTV103
Color
Gray •
Red • • •
Aluminum RTV109
Tube • • • • • • •
Packaging
Cartridge • • • •
Can
Pail • • • • • •
1
ASTM D2196 2Testing is performed in accordance with current Momentive Performance Materials quality test methods, laboratory conditions,
procedures, frequency and sampling 3MIL-A-46106B Group III Type I
Typical property data values should not be used as specifications
17
Product Details - 1 Part Heat Cure Grades
Adhesive / Sealant • • • • • •
Application
Coating
Encapsulant / Potting
Viscosity (23oC) Pa.s (P) 670 (6700) 1 280 (2800) 1 150 (1500) 1 110 (1100) 1 70 (700) 1 50 (500) 1
Cure Condition o
C/h 150/1 150/1 125/1.5 150/1 150/1 150/1
Specific Gravity (23 C) o
1.08 1.26 1.10 1.27 1.26 1.48
Hardness 50 52 65 45 37 52
Tensile Strength MPa (psi) 4.4 (640) 3.7 (535) 6.5 (950) 3.4 (495) 3.6 (520) 4.9 (710)
Elongation % 430 240 120 230 230 160
Adhesive Strength MPa (psi) 3.7 (535) 2.6 (375) 5.0 (730) 2.5 (365) 2.5 (365) 2.0 (290)
Thermal Conductivity W/m.K 0.20 0.29 0.2 0.29 0.29 0.41
Volume Resistivity MΩ.m 1.0x107 2.0x107 6.0x107 2.0x107 1.0x107 2.0x107
Dielectric Strength kV/mm 23 20 22 20 25 22
Dielectric Constant (60Hz) 3.1 3.2 2.9 3.1 3.1 3.9
Dissipation Factor (60Hz) 0.001 0.001 0.01 0.006 0.006 0.005
Flame Retardancy UL94 HB
Temperature Resistance •
Thermally Conductive
White •
Clear •
• •
Color
Black
Gray •
Blue • •
Tube • •
Packaging
Cartridge • • • • •
Can • • •
Pail • • • • •
1
JIS K 6249 Typical property data values should not be used as specifications
Cure Properties:
The cure performance of
1 Part Heat Cure grades Hardness & Adhesion &
is demonstrated by the Cure Time - TSE322 Cure Time - TSE322
relationship between
temperature and hardness,
and temperature and 50 3
Shear Adhesive Strength MPa
150oC 150oC
adhesive strength of TSE322
when placed in an oven at 40 120oC
100oC 100oC
temperatures ranging from 120oC 2
Hardness
30
80oC to 150oC.
20 80oC
1 80oC
10
0 0
1 2 3 4 5 6 7 8 1 2 3 4 5 6 7 8
Cure Time h Cure Time h
18
Product Details - 1 Part Heat Cure Grades
• • • •
Application
Adhesive / Sealant
Coating •
Encapsulant / Potting
Viscosity (23oC) Pa.s (P) 60 (600) 1 60 (600) 1 58 (580) 1 28 (280) 1
Cure Condition o
C/h 150/1 150/1 150/1 150/1
Specific Gravity (23 C) o
2.10 2.70 1.03 1.45
Hardness 62 84 28 43
Tensile Strength MPa (psi) 3.2 (465) 4.5 (655) 2.8 (405) 3.4 (495)
Elongation % 110 50 370 170
Adhesive Strength MPa (psi) 2.0 (290) 2.5 (365) 2.5 (365) 2.0 (290)
Thermal Conductivity W/m.K 0.88 1.68 0.18 0.41
Volume Resistivity MΩ.m 2.5x106 4.8x106 6.0x107 2.0x107
Dielectric Strength kV/mm 21 15 23 22
Dielectric Constant (60Hz) 4.3 5.2 2.8 3.3
Dissipation Factor (60Hz) 0.002 0.002 0.001 0.02
Flame Retardancy UL94 HB
Temperature Resistance •
Thermally Conductive • •
White
Clear •
Color
Black
Gray • •
Red •
Tube • • •
Packaging
Cartridge • •
Can • • • •
Pail • •
1 2 3
JIS K 6249 ASTM D2196 TSE326M EX in Europe and the Americas.
Storage Stability:
TSE322 Viscosity and Storage Temperature
Storage under low temperature
conditions is important 400
particularly for 1-part heat cure
grades to prevent viscosity o
25 C
Viscosity Pa. s
300
increase.
200
o
5 C
100
1 2 3 4 5 6
Storage Time months
19
TSE326M3 TSE3251 TSE3251-C TSE325 TSE325-B TSE3250 ECC4865
•
• • • • • •
• • •
16 (160) 1 8.5 (85) 1 7.0 (70) 1 4.0 (40) 1 3.5 (35) 1 1.3 (13) 1 0.25 (2.5) 2
200/0.5 150/1 150/1 150/1 150/1 150/1 -
1.46 1.02 1.02 1.02 1.02 0.97 1.19
38 16 16 12 20 9 35
2.9 (420) 0.7 (100) 0.7 (100) 0.7 (100) 0.9 (130) - -
180 200 200 200 200 - -
1.5 (220) 0.4 (60) 0.4 (60) 0.4 (60) 0.4 (60) 0.1 (15) -
0.41 0.18 0.18 0.18 0.18 0.17 -
2.0x107 2.0x107 2.0x107 2.0x107 2.0x107 2.0x107 -
22 20 20 21 21 21 20
3.3 2.8 2.8 2.9 2.9 2.8 2.4
0.02 0.002 0.001 0.001 0.001 0.001 0.01
• •
• • •
•
• • • • • •
• •
Typical property data values should not be used as specifications
20
Product Details - 2 Part Room Temperature Cure Grades
• •
Application
Adhesive / Sealant
Coating
Encapsulant / Potting • •
Mixing Ratio ((A):(B) by weight) 100:0.5 100:0.5 100:0.5 100:0.1
Color (mixed) White Red Red Red
Viscosity (mixed) (23oC) Pa.s (P) 700 (7000) 2 880 (8800) 2 47 (470) 2 43 (430) 2
Pot Life (23oC) h 2 0.75 2 1.5
Cure Condition o
C/h 25/24 25/24 25/24 25/24
Specific Gravity (23oC) 1.35 1.47 1.48 1.49
Hardness 48 58 57 61
Tensile Strength MPa (psi) 3.0 (440) 5.8 (840) 6.9 (995) 5.5 (795)
Elongation % 150 120 120 120
Adhesive Strength MPa (psi) - - - 3.2 (465)
Thermal Conductivity W/m.K 0.31 0.31 0.31 0.31
Volume Resistivity MΩ.m 5.6x106 2.8x106 4.4x106 2.0x106
Dielectric Strength kV/mm 18.5 17.4 17.7 21.2
Dielectric Constant (60Hz) 3.98 (1kHz) 4.3 (1kHz) 4.0 (1kHz) 3.9 (1kHz)
Dissipation Factor (60Hz) 0.02 (1kHz) 0.03 (1kHz) 0.02 (1kHz) 0.02 (1kHz)
Flame Retardancy
Low Volatility •
Temperature Resistance • • • •
FDA
Bottle
Packaging
Can
Pail
Kit • • • •
1 2 3
JIS K 6249 ASTM D2196 Sub-Zero long-term storage required.
Cure Speed:
The cure speed of 2 Part
TSE3663 - Mixing Ratios & Viscosity
Condensation Cure grades (23oC)
can be changed by adjusting
the amount of the catalyst 60
component. However, the 100 : 2.5
40
achieved under standard mixing
ratios, and therefore adequate
30
testing and confirmation prior to
use in an application is required.
20
10
0
1 2
Time - h
21
RTV31 RTV11 TSE3663 TSE3661 TSE3664K
RTV313 DBT RTV113 DBT TSE3663(A) TSE3663(B) TSE3661(A) TSE3661(C) TSE3664(A) TSE3664(B)
•
• • • • •
100:0.5 100:0.5 100:2 100:3 100:7.5
Red White Off-White Blue Green Gray
25 (250) 2 11 (110) 2 4.0 (40)1 3.5 (35)1 3.0 (30)1
2 1.5 0.5 0.1 0.1
25/24 25/24 23/72 23/72 23/72
1.42 1.19 1.19 1.20 1.41
54 41 42 30 60
5.9 (870) 2.1 (300) 1.4 (205) 1.1 (160) 3.0 (435)
170 160 110 120 70
- - 0.9 (130) 0.8 (115) 1.0 (145)
0.31 0.29 0.27 - 0.42
1.6x106 1.1x107 1.0x107 1.0x107 5.0x107
17 20.3 20 20 26
4.4 (1kHz) 3.3 (1kHz) 3.1 3.2 3.1
0.03 (1kHz) 0.006 (1kHz) 0.025 0.02 0.01
UL94 HB UL94 V-0
•
•
• • •
• • •
• • •
• •
Typical property data values should not be used as specifications
22
Product Details - 2 Part Heat Cure Grades
Components TSE3360(A) TSE3360(B) TSE3380(A) TSE3380(B) TIA222G(A) TIA222G(B) FRV138(A) FRV138(B) TIA216G(A) TIA216G(B) RTV615(A) RTV615(B) TSE3032(A) TSE3032(B)
Adhesive / Sealant • •
Application
Coating
Encapsulant / Potting • • • • •
Mixing Ratio ((A):(B) by weight) 100:100 100:100 100:100 100:100 100:100 100:10 100:10
Color (mixed) White Gray Gray Translucent Gray Transparent Transparent
Viscosity (mixed) (23oC) Pa.s (P) 640 (6400) 1 40 (400) 1 20 (200) 1 13 (130) 8 (80) 1 4.0 (40) 2 4.0 (40) 1
Pot Life (23oC) h 24 8 4 8 0.5 4 4
Cure Condition o
C/h 150/1 150/0.5 70/0.5 150/1 70/0.5 150/0.25 100/1
Specific Gravity (23oC) 1.12 2.70 2.81 1.3 2.69 1.02 1.02
Hardness 42 70 45 (type E) 55 (shore 00) 45 (type E) 44 35
Tensile Strength MPa (psi) 5.4 (785) 2.5 (365) 0.3 (44) 0.3 (44) 0.2 (29) 6.3 (920) 4.5 (655)
Elongation % 380 100 40 73 40 120 210
Adhesive Strength MPa (psi) 3.1 (450) 1.5 (220) - - - - -
Thermal Conductivity W/m.K 0.23 1.68 2.1 - 1.6 0.19 0.17
Volume Resistivity MΩ.m 1.0x107 2.1x106 4.8x106 1.6x102 4.8x106 1.8x107 2.0x107
Dielectric Strength kV/mm 21 15 20 - 18 19.7 21
Dielectric Constant (60Hz) 3.0 5.7 5.3 7.2 5.0 2.7 (1kHz) 2.8
Dissipation Factor (60Hz) 0.001 0.002 0.002 - 0.002 0.0006 (1kHz) 0.001
Low Molecular Siloxane (D4-D10) wt% 0.02 0.02
Flame Retardancy UL94 V-0
Thermally Conductive • • •
FDA •
Bottle •
Packaging
Can • • • • •
Pail • • • • • • • • •
Kit • •
1 2 3 4
JIS K 6249 ASTM D2196 TSE3331K unavailable in Europe and the Americas TSE3331K EX unavailable in Asia
Pot Life:
5 TSE3331 Viscosity Change After Mixing
The pot life of a 2 Part Heat
Viscosity Pa.s
0
2 4 6 8
Time - h
6 23oC
4
0
0.5 1 1.5 2
Time - h
23
TSE3331 TSE3431 TSE3331K EX4 TSE3331K 3 TSE3431-H XE14-B7892 YE5822 TSE3033
TSE3331(A) TSE3331(B) TSE3431(A) TSE3431(B) TSE3331KEX(A) TSE3331KEX(B) TSE3331K(A) TSE3331K(B) TSE3431-H(A) TSE3431-H(B) XE14-B7892(A) XE14-B7892(B) YE5822(A) YE5822(A) TSE3033(A) TSE3033(B)
• • • •
• • • • • • • •
100:100 100:10 100:100 100:100 100:10 100:100 100:10 100:100
Gray Black Dark Gray Dark Gray Black Black Transparent Transparent
3.5 (35) 1 3.3 (33) 1 3.0 (30) 1 2.6 (26) 1 2.6 (26) 1 1.3 (13) 1 1.0 (10) 1 0.9 (9) 1
8 1.5 8 8 1.5 2 4 6
120/1 100/1 120/1 120/1 100/1 60/1 100/1 150/0.5
1.51 1.50 1.43 1.43 1.52 1.39 0.97 1.01
60 70 50 45 70 60 27 30
2.9 (420) 4.9 (710) 3.0 (440) 3.1 (450) 4.1 (595) 3.5 (510) 0.4 (58) 1.0 (145)
70 70 100 120 60 100 130 130
1.3 (190) - 1.6 (230) 1.6 (230) - - - 0.3 (44)
0.63 0.63 0.53 0.53 0.63 0.44 0.17 0.17
2.0x106 5.0x107 6.0x106 6.0x106 5.0x106 2.0x107 2.0x107 2.0x107
26 26 22 22 27 27 21 21
3.4 3.4 3.1 3.1 3.5 3.1 2.8 2.8
0.017 0.014 0.015 0.015 0.014 0.01 0.001 0.001
UL94 V-0 UL94 V-0 UL94 V-0 UL94 V-0 UL94 V-0 UL94 V-0
• • • • •
• • •
• • • • • • • • • • • • • • •
• • • • • • • •
50
30 60 90 120
Cure Time - min
24
Product Details - 1 Part Gels
Viscosity (23oC) Pa.s (P) 0.7 (7) 1 0.7 (7) 1 0.7 (7) 1
Cure Condition o
C/h 125/2 150/1 125/2
Specific Gravity (23 C) o
0.97 0.97 0.97
Penetration 85 85 65
Thermal Conductivity W/m.K 0.17 0.17 0.17
Volume Resistivity MΩ.m 1.0x107 5.0x107 1.0x107
Dielectric Strength kV/mm 18 18 18
Dielectric Constant (60Hz) 2.8 2.8 2.8
Dissipation Factor (60Hz) 0.001 0.001 0.001
Flame Retardancy UL94 V-1
White •
Color
Transparent • • •
1kg can See below matrix • •
Pkg
15kg can • •
1
JIS K 6249 Typical property data values should not be used as specifications
TSE3051 W C
1kg bottle • •
4kg can •
15kg can •
20kg pail •
W: White, C: Clear
25
Product Details - 2 Part Gels
Pail • • •
1
JIS K 6249 2ASTM D2196
Typical property data values should not be used as specifications
26
Product Details - 1 Part JCR Grades
27
Product Details - Grease
Can • • • • • • •
Pail • • •
Typical property data values should not be used as specifications
28
UL Certifications source: Underwriters Laboratories Inc.
RTI: Relative Temperature Index PLC: Performance Level Category HWI: Hot Wire Ignition HAI: High-Current Arc Ignition
HVTR: High-Voltage Arc Tracking Rate D495: D495 High-Voltage Dry Arc Resistance CTI: Comparative Tracking Index
29
Thickness RTI Flame HWI HAI HVTR D495 CTI
Type Grade Color File No.
mm Elec. Mech. Class (PLC) (PLC) (PLC) (PLC) (PLC)
30
Typical Adhesion Performance
Condensation Cure Grades
Alkoxy Acetoxy Oxime
Substrate Primer- Primer- Primer-
less
ME121 ME123 XP80-A5363
less
ME121 ME123
less
ME121 ME123 XP80-A5363
Copper • • • 1
• 1
▲1 • 1
Steel • • ▲ • • •
Brass • • ▲1 ▲1 ▲1 • 1
Metals
Stainless Steel • • ▲ • • •
Aluminum • • • • • •
Galvanized Steel • • • • •
Tin • • • • • •
Acrylic Resin • • × • • •
Phenol Resin • • • • • •
Epoxy Resin • • • • • •
Polycarbonate • • • •
Soft Polyvinyl Chloride • • × • × × •
Rigid Polyvinyl Chloride • • • • • • •
Polyester Film • • ▲ • • • •
Unsaturated Polyester • • • • • • •
Plastic
Polyamide • • • • • • •
Nylon 66 • • • • •
PBT • • ▲ •
PPS • • ▲ • •
ABS • • • • • • •
Polypropylene × × • × × × •
Polyethylene × × ▲ × × × × ×
Fluorocarbon Resin × × × × × × ×
Silicone Resin Laminate • • • • • •
Chloroprene Rubber ▲ • ▲ • ▲ •
Nitrile Rubber ▲ • • • ▲ •
Rubber
Glass
Ceramic • • • • • •
• Adheres completely, ▲ Adheres, but separates from surface when pulled, × Does not adhere
1
May corrode under some usage conditions
Appearance Yellow Yellow Yellow Pink Yellow Clear Yellow Yellow Clear
Transparent Transparent Transparent Colorless Transparent Colorless
Metals, Metals,
Substrates Glass, Plastic, Polylefins Metals Metals Plastic Glass, Metals, -
Plastic Rubber Plastic, Glass
Ceramic
Specific Gravity (23OC) 0.85 0.86 0.88 0.85 0.85 0.98 0.87 0.71 0.82
Non-Volatile Content 15% 15% 7% 15% 15% 6% 24% 7.5% 3%
Drying Time (23OC) min 30 30 20 30 30 15 30 30 30
31
Shear Adhesion Test Method Typical Heat Resistance
substrate
1-Part Condensation Cure Adhesive (Alkoxy Type)
A
50
%
-20
-40
Typical Chemical Resistance
20
Chemical Volume Change 0
Concentrated Hydrochloric Acid ◎ -20
%
Hydrochloric Acid (3%) ◎ -40
-60
Concentrated Sulphuric Acid Decomposition
-80
Sulphuric Acid (10%) ◎ 7 14 30 90 180 360
Elapsed Time days
Concentrated Nitric Acid △
Acid
Castor Oil Conditions 40OC, 95%RH 25OC Immersed 40OC, 95%RH 25OC Immersed
◎
Flax Seed Oil ◎ Initial 1.6x107 1.6x107 29 29
o
Silicone Oil (35 C, 70h) △ 1 Day 2.9x10 6
2.2x106 27 25
Acetone △ 3 Days 2.5x10 6
3.6x10 6
29 22
Butyl Alcohol ○ 7 Days 2.7x106 1.9x106 24 23
Solvent
Ethyl Alcohol ◎
Gasoline X
Mineral Spirit X
Toluene X
Water (room temperature) ◎
Water
32
Other Electronic Frequently Although some heat cure products
can cure at room temperature,
reactive fluids or an RTV with a
lower viscosity.
Solutions from Asked higher heat greatly accelerates the
What can I do to improve
Momentive Questions cure. 1-part heat cure products
typically have an inhibitor in the the adhesion of the silicone
Performance formulation that stops the product adhesive to my parts?
What does RTV mean? from curing until an activation The first step to good adhesion
Materials RTV stands for Room Temperature temperature, greater than room is to have clean surfaces for the
Vulcanization (cure). Despite the temperature, is achieved and the silicone to bond to. For difficult-
low-temperature connotations inhibitor is driven off and the cure to-bond-substrates, Momentive
conveyed by this name, RTV reaction is allowed to proceed. Performance Materials offers a
silicones consist of both Room number of primers that can be
Temperture Cure and Heat Cure What does "tack free time" used to improve and maximize
grades. mean? adhesion.
Tack free refers to the amount of
What is the cure mechanism time it takes for a condensation How do I ensure that air
of a condensation cure cure silicone product to form a is removed from 2-part
product? grades?
cured outer layer (the cured outer
Condensation cure silicone layer is not tacky like uncured If you are hand mixing, air may
products cure when exposed to material). become added to the material
atmospheric moisture. Moisture during the mixing process.
in the air is generally required to What is "mix ratio"? Vacuum de-airing is most effective
cure (or vulcanize) condensation in removing air prior to use.
Mix ratio is a term used to state
cure products. The cure process Automated mixing equipment
the amount of each material to
begins from the outer surface, that utilizes a static mixer can
be in a multi-component material.
Provides detailed information and therefore time is required eliminate the need to de-air prior to
The mix ratios for 2-part products
on silicone materials used for complete cure. The cure dispensing.
are described on the individual
for thermal management time is affected by the reaction
product data sheets and are On complex high-density
applications in electronics and mechanism and viscosity of the
given as a ratio by weight of each electronics, air can sometimes be
micro-electronics. Includes material. Generally, at 25C and
material. trapped under components during
SilCool* grease & adhesives, and 50%RH, condensation cure RTV
silicones cure through in 24 to 48 the potting process. Where this is
conventional grades for adhesion, What does "pot life" or a concern, potting under vacuum
encapsulation and potting. hours. Full physical properties "work life" mean?
may take up to 7 days to develop. or vacuum de-airing after potting
The amount of time after a 2-part can remove the trapped air. An
What is the depth (bead grade is mixed with its curing alternate approach may be to use
thickness) limit for a agent that it will remain useful or a grade with a low viscosity and
condensation cure grade? pliable. longer potlife and to cure at lower
temperatures (if heat-cure grade),
For 1-part, condensation How do I remove silicone? allowing entrapped air to escape
cure products, the depth Before it is cured: use a putty knife prior to the cure of the material.
(bead thickness) limitation is to remove any of the uncured
approximately 6mm (1/4"). paste. Wipe the area clean with What is cure inhibition, and
For 2-part, condensation isopropyl alcohol to remove any how do I prevent it?
cure products, the depth leftover residue. After it is cured: Cure inhibition is a phenomenon
(bead thickness) limitation is First mechanically remove as that may be observed in addition-
approximately 25mm (1"). much of the silicone as you can cure grades. These materials
Can I accelerate the cure with either a knife or a razor. A use a platinum catalyst to drive
time of a 1-part product? solvent (mineral spirits, toluene, the curing reaction. Surfaces
xylene, acetone) can them be containing water, sulphur,
Condensation cure silicone cure
used to remove any oily residue or nitrogen compounds, organic
rates depend on humidity, silicone
any remaining silicone, It may be metal compounds, or phosphate
thickness, and to a smaller degree
necessary to soak the silicone in a compounds, may inhibit cure.
Provides opto-electronic heat. Increasing the relative
solutions for LED Packages and solvent overnight to break it down.
humidity around the silicone or Cure inhibition is characterized
Assemblies. Includes InvisiSil* reducing the thickness of the by a gummy or sticky appearance
LED encapsulants, Glob Top, material will reduce the time to cure
Can I thin a silicone?
of the silicone at the interface
Lens fabrication materials, Die the material. Increased heat (not Silicone can be thinned using a between the silicone and
Attach adhesives, and Dot Matrix over 50C) will somewhat reduce solvent in which the silicone is offending substrate. Inhibition
assembly materials. cure time but as mentioned will do miscible, generally an aromatic can be prevented by application
so to a much smaller degree than solvent such as toluene or xylene. of a barrier coat, cleaning of
humidity or thickness. As always, be sure to follow the the offending material prior to
producer's instructions when application of the silicone material,
What is the cure using solvent products and always replacing the offending material
mechanism of an addition use in a well-ventilated area. The with a suitable alternative, or
cure product? shrinkage of the silicone and the selection of a condensation cure
Addition cure silicone RTV cure time will increase with the grade.
products may be 1 or 2-part addition of solvent. Alternative
and cure when exposed to heat. suggestions would include non-
33
Dispensing Equipment Examples
Small Can Pump and Dispensing Unit Pail Can Pump Unit
34
Customer Service Centers
Patent Status
Nothing contained herein shall be construed to imply the nonexistence of any relevant patents or to constitute the permission, inducement or recommendation
to practice any invention covered by any patent, without authority from the owner of the patent.
Limitations
Customers must evaluate Momentive Performance Materials products and make their own determination as to fitness of use in their particular applications.
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Copyright 2011-2013 Momentive Performance Materials Inc. All rights reserved. MPM 140-045-10E-GL 06/13 Printed in U.S.A.