MUGAS, Audrey Assuming Raoult's law to be valid, prepare a P-x-y diagram for a temperature of 90°C abd a t-x-y di

10.2 (a) Benzene(1)/ethylbenzene(2); (2) 1-Chlorobutane(1)/chlorobenzene(2)

A B C t in °C P*
Benzene 13.7819 2726.81 217.572 90 136.496783577
Ethylbenzene 13.9726 3259.93 212.3 90 24.2603212057

𝑦_𝑛=(𝑥_𝑛 〖𝑃∗〗 _𝑛 )/𝑃_𝑇 𝑥_1 + 𝑥_2=1

𝑃_𝑇=𝑥_1 〖𝑃∗〗 _1 + 𝑥_2 〖𝑃∗〗 _2

x1 x2 PT y1 y2
0 1 24.26032120574 0 1 160

0.1 0.9 35.48396744289 0.384671707855 0.615328292145 140

0.2 0.8 46.70761368005 0.584473377348 0.415526622652 120

Pressure (kPa)
0.3 0.7 57.9312599172 0.706855592848 0.293144407152 100
0.4 0.6 69.15490615435 0.789513231484 0.210486768516 80
0.5 0.5 80.3785523915 0.849087097964 0.150912902036 60
0.6 0.4 91.60219862866 0.894062275496 0.105937724504
40
0.7 0.3 102.8258448658 0.929219192206 0.070780807794
20
0.8 0.2 114.049491103 0.957456502487 0.042543497513
0
0.9 0.1 125.2731373401 0.980634059527 0.019365940473 0 0.2
1 0 136.4967835773 1 0

𝑡= 𝐵/(𝐴−ln⁡(𝑃) )−𝐶

A B C P t
Benzene 13.7819 2726.81 217.572 90 76.1991122336
Ethylbenzene 13.9726 3259.93 212.3 90 131.83619288
T 104.017652557

𝑃_𝑇=𝑥_1 〖𝑃∗〗 _1 + 𝑥_2 〖𝑃∗〗 _2 𝑥_1=(𝑃_𝑇− 𝑦_𝑛=(𝑥_𝑛 〖𝑃∗〗 _𝑛 )/𝑃_𝑇

𝑥_1 + 𝑥_2=1 〖𝑃∗〗 _2 )/
( 〖〖𝑃∗〗 _
t1 P*1 P*2 PT 1 x1 x2
76.19911 89.99999364832 14.48308021112 −𝑃∗ 〗 _2 )
90 1.000000084109 -8.410932E-08
77.19911 92.87910909581 15.05955547389 90 0.96300275494 0.03699724506
78.19911 95.82992079095 15.65476905748 90 0.927285191672 0.07271480833
79.19911 98.85364288079 16.26918039775 90 0.892792873931 0.10720712607
80.19911 101.9514977722 16.90325588639 90 0.859473899669 0.14052610033
81.19911 105.1247159982 17.55746888145 90 0.827278845731 0.17272115427
82.19911 108.3745360823 18.23229971624 90 0.796160636534 0.20383936347
83.19911 111.7022044021 18.92823570666 90 0.766074420365 0.23392557963
84.19911 115.1089750512 19.64577115696 90 0.73697745281 0.26302254719
85.19911 118.5961096998 20.38540736383 90 0.708828986866 0.29117101313
86.19911 122.1648774538 21.14765261896 90 0.681590169336 0.31840983066
87.19911 125.8165547137 21.93302221 90 0.655223943098 0.3447760569
 88.19911 129.5524250308 22.74203841994 90 0.629694954903 0.3703050451
89.19911 133.373778964 23.57523052493 90 0.604969468353 0.39503053165
90.19911 137.2819139343 24.43313479048 90 0.581015281751 0.41898471825
91.19911 141.2781340791 25.31629446615 90 0.557801650523 0.44219834948
92.19911 145.3637501054 26.22525977869 90 0.535299213935 0.46470078606
93.19911 149.5400791418 27.1605879236 90 0.513479925851 0.48652007415
94.19911 153.8084445903 28.12284305519 90 0.49231698929 0.50768301071
95.19911 158.1701759772 29.11259627505 90 0.471784794551 0.52821520545
96.19911 162.6266088028 30.13042561911 90 0.451858860703 0.5481411393
97.19911 167.1790843915 31.17691604312 90 0.432515780235 0.56748421976
98.19911 171.8289497399 32.25265940662 90 0.413733166682 0.58626683332
99.19911 176.5775573661 33.35825445549 90 0.395489605056 0.60451039494
100.19911 181.426265157 34.49430680301 90 0.377764604915 0.62223539508
101.19911 186.376436216 35.66142890943 90 0.360538555925 0.63946144407
102.19911 191.4294387103 36.86024006015 90 0.343792685761 0.65620731424
103.19911 196.5866457173 38.09136634242 90 0.32750902022 0.67249097978
104.19911 201.8494350718 39.35544062065 90 0.311670345421 0.68832965458
105.19911 207.2191892117 40.65310251037 90 0.296260171965 0.70373982804
106.19911 212.6972950244 41.98499835067 90 0.281262700959 0.71873729904
107.19911 218.285143693 43.35178117543 90 0.266662791781 0.73333720822
108.19911 223.9841305419 44.75411068309 90 0.252445931505 0.74755406849
109.19911 229.795654883 46.19265320512 90 0.238598205882 0.76140179412
110.19911 235.7211198614 47.66808167316 90 0.225106271798 0.7748937282
111.19911 241.7619323014 49.1810755849 90 0.211957331123 0.78804266888
112.19911 247.9195025526 50.73232096857 90 0.199139105879 0.80086089412
113.19911 254.1952443362 52.3225103463 90 0.186639814645 0.81336018536
114.19911 260.5905745908 53.95234269612 90 0.174448150148 0.82555184985
115.19911 267.1069133198 55.62252341277 90 0.162553257961 0.83744674204
116.19911 273.7456834373 57.33376426731 90 0.150944716252 0.84905528375
117.19911 280.5083106162 59.08678336553 90 0.139612516535 0.86038748347
118.19911 287.3962231347 60.88230510513 90 0.128547045357 0.87145295464
119.19911 294.4108517246 62.72106013184 90 0.117739066882 0.88226093312
120.19911 301.5536294197 64.60378529433 90 0.107179706319 0.89282029368
121.19911 308.8259914039 66.53122359802 90 0.09686043415 0.90313956585
122.19911 316.2293748608 68.50412415782 90 0.086773051117 0.91322694888
123.19911 323.7652188229 70.52324214976 90 0.076909673926 0.92309032607
124.19911 331.4349640223 72.58933876155 90 0.067262721635 0.93273727836
125.19911 339.240052741 74.70318114219 90 0.057824902689 0.94217509731
126.19911 347.1819286626 76.86554235044 90 0.048589202559 0.95141079744
127.19911 355.262036724 79.0772013024 90 0.039548871975 0.96045112802
128.19911 363.4818229682 81.33894271803 90 0.0306974157 0.9693025843
129.19911 371.8427343976 83.6515570668 90 0.022028581832 0.97797141817
130.19911 380.3462188283 86.01584051236 90 0.013536351601 0.9864636484
131.19911 388.9937247446 88.43259485624 90 0.005214929636 0.99478507036
131.836192879681 394.578671058 90 90 0 1
ture of 90°C abd a t-x-y diagram for a pressure of 90kPA for one of the following systems:
)

ln⁡(𝑃∗)=𝐴 −𝐵/(𝑡+𝐶)

160 P-x-y
140
120
Pressure (kPa)

100
80
60
40
20
0
0 0.2 0.4 0.6 0.8 1 1.2
mol fraction of benzene

ln⁡(𝑃∗)=𝐴 −𝐵/(𝑇+𝐶)

P*
200.8865595
39.12358934

=(𝑥_𝑛 〖𝑃∗〗 _𝑛 )/𝑃_𝑇

y1 y2
1.000000014 -1.353513E-08
0.99380931 0.0061906896 T-x-y
0.98735185 0.01264815035 140
T-
0.98062031 0.01937968971 x1
0.973607237 0.02639276258 130 T-
y1
0.966305041 0.03369495879
120
0.958705996 0.0412940041
0.950802239 0.04919776121
110
0.942585769 0.05741423079
T in C

0.934048448 0.06595155239 100

0.925181995 0.07481800544
0.91597799 0.08402201015 90

80

70
0 0.2 0.4 0.6 0.8 1 1.2
 T in C
100

90
0.906427872 0.09357212847
0.896522935 0.10347706498 80
0.886254332 0.11374566773
0.875613071 0.1243869292 70
0 0.2 0.4 0.6 0.8 1 1.2
0.864590013 0.13540998704 mol frac
0.853175875 0.14682412501
0.841361226 0.15863877369
0.829136489 0.17086351136
0.816491935 0.18350806474
0.80341769 0.19658230973
0.789903728 0.21009627218
0.775939871 0.22406012862
0.761515793 0.23848420691
0.746621013 0.25337898698
0.731244899 0.26875510147
0.715376664 0.28462333636
0.699005368 0.30099463165
0.682119918 0.31788008189
0.664709063 0.33529093683
0.646761398 0.35323860198
0.628265361 0.37173463914
0.609209233 0.39079076695
0.589581139 0.41041886138
0.569369044 0.43063095625
0.548560756 0.45143924369
0.527143925 0.47285607459
0.505106041 0.49489395907
0.482434433 0.51756556684
0.459116272 0.54088372765
0.435138568 0.56486143162
0.41048817 0.58951182966
0.385151766 0.61484823376
0.359115883 0.64088411733
0.332366884 0.66763311551
0.304890975 0.69510902545
0.276674193 0.72332580658
0.247702419 0.75229758083
0.217961367 0.78203863291
0.18743659 0.81256341048
0.156113476 0.84388652435
0.123977251 0.87602274868
0.091012979 0.90898702107
0.057205557 0.9427944428
0.022539721 0.97746027885
0 1
 T-
x1
T-
y1

0.8 1 1.2
0.8 1 1.2
 MUGAS, Audrey Assuming Raoult's law to be valid, prepare a P-x-y diagram for a temperature of 90°C abd a t-x-y di
10.2 (a) Benzene(1)/ethylbenzene(2); (2) 1-Chlorobutane(1)/chlorobenzene(2)

A B C t in °C P*
1-chlorobutane 13.7965 2723.73 220.618 90 152.590080091
chlorobenze 13.8635 3174.78 218.265 90 35.3265132215

𝑦_𝑛=(𝑥_𝑛 〖𝑃∗〗 _𝑛 )/𝑃_𝑇 𝑥_1 + 𝑥_2=1

𝑃_𝑇=𝑥_1 〖𝑃∗〗 _1 + 𝑥_2 〖𝑃∗〗 _2

x1 x2 PT y1 y2
0 1 35.32651322152 0 1 180

0.1 0.9 47.05286990844 0.324294948188 0.675705051812 160

0.2 0.8 58.77922659537 0.519197304657 0.480802695343 140

120

Pressure (kPa)
0.3 0.7 70.5055832823 0.649268070643 0.350731929357
100
0.4 0.6 82.23193996922 0.742242394612 0.257757605388
80
0.5 0.5 93.95829665615 0.812009612356 0.187990387644
60
0.6 0.4 105.6846533431 0.86629463369 0.13370536631
40
0.7 0.3 117.41101003 0.909736284836 0.090263715164
20
0.8 0.2 129.1373667169 0.945288472083 0.054711527917
0
0.9 0.1 140.8637234039 0.974921496914 0.025078503086 0 0.2
1 0 152.5900800908 1 0

𝑡= 𝐵/(𝐴−ln⁡(𝑃) )−𝐶

A B C P t
1-chlorobutane 13.7965 2723.73 220.618 90 72.3604582915
chlorobenze 13.8635 3174.78 218.265 90 120.787220676
T 96.5738394839

𝑃_𝑇=𝑥_1 〖𝑃∗〗 _1 + 𝑥_2 〖𝑃∗〗 _2 𝑥_1=(𝑃_𝑇− 𝑦_𝑛=(𝑥_𝑛 〖𝑃∗〗 _𝑛 )/𝑃_𝑇

𝑥_1 + 𝑥_2=1 〖𝑃∗〗 _2 )/
( 〖〖𝑃∗〗 _
t1 P*1 P*2 PT 1 −𝑃∗ 〗 _2 x1
) x2
72.3604582914854 90 18.9072043623 90 1 0
73.3604582914854 92.89161497308 19.6288788349 90 0.960530890252 0.03946910975
74.3604582914854 95.85557984938 20.37288259051 90 0.922424872692 0.07757512731
75.3604582914854 98.89312690581 21.13972915586 90 0.885623944893 0.11437605511
76.3604582914854 102.0054969007 21.92993902456 90 0.850072890916 0.14992710908
77.3604582914854 105.1939389379 22.74403965177 90 0.815719132838 0.18428086716
78.3604582914854 108.4597103293 23.58256544707 90 0.782512590935 0.21748740907
79.3604582914854 111.8040764563 24.44605776581 90 0.750405551967 0.24959444803
80.3604582914854 115.2283106292 25.33506489877 90 0.719352545075 0.28064745493
81.3604582914854 118.7336939457 26.25014206031 90 0.689310224792 0.31068977521
82.3604582914854 122.3215151481 27.19185137486 90 0.660237260744 0.33976273926
83.3604582914854 125.9930704789 28.1607618618 90 0.632094233616 0.36790576638
84.3604582914854 129.7496635356 29.1574494189 90 0.604843537001 0.395156463
85.3604582914854 133.5926051243 30.18249680405 90 0.578449284771 0.42155071523
86.3604582914854 137.5232131123 31.23649361558 90 0.552877223633 0.44712277637
87.3604582914854 141.5428122792 32.32003627096 90 0.528094650558 0.47190534944
88.3604582914854 145.6527341678 33.43372798404 90 0.504070334782 0.49592966522
89.3604582914854 149.8543169338 34.57817874077 90 0.480774444113 0.51922555589
90.3604582914854 154.1489051944 35.75400527346 90 0.458178475279 0.54182152472
91.3604582914854 158.5378498764 36.96183103353 90 0.436255188081 0.56374481192
92.3604582914854 163.022508064 38.20228616288 90 0.414978543126 0.58502145687
93.3604582914854 167.6042428447 39.47600746375 90 0.39432364292 0.60567635708
94.3604582914854 172.284423156 40.78363836724 90 0.374266676141 0.62573332386
95.3604582914854 177.0644236308 42.12582890035 90 0.354784864888 0.64521513511
96.3604582914854 181.9456244423 43.50323565174 90 0.335856414747 0.66414358525
97.3604582914854 186.9294111486 44.91652173605 90 0.3174604675 0.6825395325
98.3604582914854 192.0171745369 46.3663567569 90 0.299577056334 0.70042294367
99.3604582914854 197.2103104674 47.85341676859 90 0.2821870634 0.7178129366
100.360458291485 202.5102197167 49.3783842365 90 0.265272179597 0.7347278204
101.360458291485 207.9183078212 50.94194799614 90 0.248814866438 0.75118513356
102.360458291485 213.43598492 52.54480321104 90 0.232798319902 0.7672016801
103.360458291485 219.064665598 54.1876513293 90 0.21720643614 0.78279356386
104.360458291485 224.8057687286 55.87120003902 90 0.202023778944 0.79797622106
105.360458291485 230.6607173166 57.59616322242 90 0.18723554888 0.81276445112
106.360458291485 236.6309383407 59.36326090888 90 0.172827553985 0.82717244602
107.360458291485 242.7178625966 61.17321922675 90 0.158786181945 0.84121381806
108.360458291485 248.9229245395 63.02677035407 90 0.145098373681 0.85490162632
109.360458291485 255.2475621274 64.92465246813 90 0.131751598254 0.86824840175
110.360458291485 261.6932166639 66.86760969402 90 0.118733829016 0.88126617098
111.360458291485 268.2613326418 68.856392052 90 0.106033520962 0.89396647904
112.360458291485 274.9533575866 70.8917554039 90 0.093639589181 0.90636041082
113.360458291485 281.7707419001 72.97446139849 90 0.081541388384 0.91845861162
114.360458291485 288.7149387051 75.10527741579 90 0.069728693423 0.93027130658
115.360458291485 295.7874036892 77.28497651046 90 0.058191680769 0.94180831923
116.360458291485 302.9895949507 79.51433735421 90 0.046920910881 0.95307908912
117.360458291485 310.3229728429 81.79414417726 90 0.035907311435 0.96409268857
118.360458291485 317.7889998208 84.12518670891 90 0.025142161351 0.97485783865
119.360458291485 325.3891402868 86.5082601172 90 0.014617075592 0.98538292441
120.360458291485 333.1248604382 88.94416494772 90 0.004323990683 0.99567600932
120.78722067633 336.4678127077 90 90 0 1
ture of 90°C abd a t-x-y diagram for a pressure of 90kPA for one of the following systems:
)

ln⁡(𝑃∗)=𝐴 −𝐵/(𝑡+𝐶)

180 P-x-y
160
140
120
Pressure (kPa)

100
80
60
40
20
0
0 0.2 0.4 0.6 0.8 1 1.2
mol fraction

ln⁡(𝑃∗)=𝐴 −𝐵/(𝑇+𝐶)

P*
183.0004142
43.80177052

=(𝑥_𝑛 〖𝑃∗〗 _𝑛 )/𝑃_𝑇

y1 y2
1 0
0.99139184 0.0086081597 T-x-y
0.982439678 0.01756032178 130
T-
0.97313468 0.0268653203 x1
0.963467863 0.03653213734 120 T-
y1
0.953430096 0.04656990389
0.943012099 0.05698790065 110
0.932204441 0.06779555883
0.920997539 0.07900246094
T in C

100
0.909381658 0.09061834151
0.897346912 0.10265308787
90
0.884883259 0.11511674083

80

70
0 0.2 0.4 0.6 0.8 1 1.2
 100

T in
90

0.871980505 0.12801949536
80
0.858628299 0.14137170128
0.844816136 0.15518386388
0.830533355 0.16946664456 70
0 0.2 0.4 0.6 0.8 1 1.2
0.815769139 0.1842308614 mol frac
0.80051251 0.19948748976
0.784752337 0.2152476628
0.768477328 0.23152267205
0.751676032 0.24832396785
0.73433684 0.26566315992
0.716447982 0.28355201772
0.697997529 0.30200247095
0.67897339 0.32102660995
0.659363314 0.34063668608
0.639154888 0.36084511208
0.618335538 0.38166446241
0.596892526 0.40310747361
0.574812955 0.42518704455
0.552083763 0.44791623671
0.528691726 0.47130827446
0.504623455 0.49537654526
0.4798654 0.52013459987
0.454403847 0.54559615255
0.428224919 0.57177508121
0.401314572 0.59868542753
0.373658603 0.6263413971
0.34524264 0.65475735953
0.316052152 0.68394784847
0.286072438 0.71392756168
0.255288639 0.74471136111
0.223685727 0.7763142728
0.191248513 0.80875148699
0.157961642 0.84203835797
0.123809596 0.8761904041
0.088776692 0.91122330768
0.052847085 0.94715291489
0.016004764 0.98399523564
0 1
 T-
x1
T-
y1

0.8 1 1.2
0.8 1 1.2