AL/2020/02/T

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mwpTWj;jy;fs; :
 ,t;tpdhj;jhs;fs; 7 gf;fq;fspy; 10 gy;Nju;T> 1 mikg;Gf;fl;Liu> 1 fl;Liu tpdhf;fis
nfhz;lJ.
 vy;yh tpdhf;fSf;Fk; tpil jUf.
 jug;gl;Ls;s ,lj;jpy; ckJ Rl;nlz;iz vOJf.
 gFjp-I 1 njhlf;fk; 10 tiuahd tpdhf;fs; xt;nthd;wpYk; (1),(2),(3),(4),(5) vd
,yf;fkplg;gl;l tpilfspy; rupahd my;yJ kpfg; nghUj;jkhd tpilia njupT nra;f.
mfpy thA khwpyp R = 8.314 J K-1mol-1
mtfhjNuh khwpyp NA = 6.022×1023 mol-1
gpshq;fpd; khwpyp h = 6.626×10-34 Js
xspapd; Ntfk; c = 3×108 ms-1

gFjp-I
1. gpd;tUk; mad;fspy; vjd; fyg;Gepiy Vidatw;wpy; ,Ue;J NtWgLfpd;wJ?

(1) CO2-
3 (2) NO-3 (3) IO-3 (4) BO3-
3 (5) NO-2

−1
2. gpd;tUk; %yfq;fspy; vJ(3,2,0, ) vDk; rf;jpr;nrhl;nlz; njhilia nfhz;bUf;f
2
$baJ?
(1)Si (2)Mg (3)P (4)As (5)Cl

3. jug;gl;l Nru;itapd; IUPAC ngauPL ahJ?

O O
║ ║
H−C≡C−C−CH2−CH2−C−O−CH3

(1) 1-methylhex-5-yn-1,4-dione.
(2) methyl 4-oxohex-5-yn oate.
(3) methyl 4-onehex-5-ynoate.
(4) methyl 4-formylhex-5-ynoate.
(5) methyl 5-oxohex-6-ynoate.

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4. mNwhkw;wpf; Nru;it(A) C8H8O2 vDk; %yf;$w;Wr; #j;jpuj;ij cilaJ. ,r;Nru;it

gpd;tUk; jhf;fq;fis fhl;Lk;.
 Na cld; jhf;fj;jpy; H2(g) I cUthf;Fk;.
 Na2CO3 cld; jhf;fk; GupahJ.
 eLepiyahd Fe3+ fiurYld; nrt;T+jh epwj;ij jUk;.
Nru;it AMf ,Uf;f $baJ?

COOCH3 CH2COOH COOH O−CH=CH2 O−CH=CH−CH3

(1) (2) (3) (4) (5)

CH3 OH

5. gpd;tUk; jhf;fj;ijf; fUJf.

X2(g) +Y2(g) 2XY(g)
,JNthu; xUgb kPSk; jhf;fkhFk;. Kw;jhf;fj;jpdJk; gpw;jhf;fj;jpdJk; Vtw;rf;jpfs;
KiwNa 250kJ mol-1 ,170 kJ mol-1MFk;. xU Fwpj;j Cf;fpapd; Nru;f;ifahy; Vtw;rf;jp
90 kJ mol-1 My; Fiwe;jJ. Cf;fp Kd;dpiyapy; jhf;fj;jpd; ntg;g cs;Siw khw;wk;?
(1) -80 kJ mol-1 (2) -30 kJ mol-1 (3)+80 kJ mol-1 (4)+190 kJ mol-1 (5)+30 kJ mol-1
6. gpd;tUk; Nru;itr; Nrhbfspy; vJ ePu;ff
; iury; epiyapy; ePyg;ghrpr;rhaj;jhis rptg;ghf
khw;Wk;?
(1)NH4NO3,NH4ClO3 (2)CH3COONa,Na2CO3 (3)NH4Cl,HCOONa
(4)Na3PO4,NH4NO3 (5)CH3COONH4,CH3COONa
7. gpd;tUk; $w;Wf;fSs; rupahdit?
a) ve;jpugp mjpfupg;Gld; epfOk; xU Gw ntg;gj;jhf;fk; vg;nghOJk; Rakw;wJ.
b) ve;jpugp FiwTld; epfOk; xU mf ntg;gj;jhf;fk; vg;nghOJk; RakhdJ.
c) ve;jpugp mjpfupg;Gld; epfOk; xU mf ntg;g khw;wk; cau; ntg;gepiyapy;
RakhdJ.
d) ve;jpugp FiwTld; epfOk; xU Gw ntg;g khw;wk; jho; ntg;gepiyapy; RakhdJ.
OH
dil NaoH │
8. CH3CHO ሱۛۛۛۛሮ CH3−CH−CH2−CHO vDk; jhf;fj;ij fUJf.
(p) (q)
gpd;tUk; $w;Wf;fspy; rupahdit?
(a) CH3CHO ,y; ehd;F 𝛼 [jurd;fs; cs;sd.
(b) C(p) ,Ys;s 𝛼 [jurd;fs; ,yFtpy; fhuj;jhy; mfw;wg;glyhk;.
(c) ,J xU fUehl;l $l;ly; jhf;fk;.
(d) C(q)fhgd; mZthdJ sp3fyg;gpy; cs;sJ.

9. $w;W 1− ve;epge;jidapYk; Zn MdJ H2SO4 cld; jhf;fp H2 thAit tpLtpf;Fk;.

$w;W 2− kpd; ,urhad njhlupy; Zn IjurDf;F NkNy cs;sJ.
10. $w;W 1− ,urhad rkepiy xd;wpy; QC>KC vdpy; jhf;fk; Kd;Ndhf;fpa jpirapy;
rhjfkhf;fg;gLk;.
$w;W 2− XH rkdpiyj;jhf;fj;jpw;fhd Kc MdJ ntg;gepiyapy; kl;LNk jq;fpAs;s khwpyp
MFk;.

*****
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gFjp II
mikg;G fl;Liu tpdh
a)gpd;tUk; %yfq;fisf; fUj;jpw; nfhs;f.

Cr, Be, B, Cl, N, F, C, Ne ,S

NkNy jug;gl;l %yfq;fisf; nfhz;L gpd;tUk; ntw;wplq;fis epug;Gf.

1. %d;W gpwjpUg;gq;fisf; nfhz;l %yfk; ....................

2. vk; %yfj;jpd; FNshiul;L ePUld; jhf;Fk; NghJ cUthFk; gjhu;j;jk; ntspw;Wk;

,ay;Gfisf; fhl;Lk; ....................

3. NaOH cldhd jhf;fj;jpd; NghJ vupaf;$ba thAit ntsptpLk; %yfk; ....................

4. xNu xl;rpNaw;w vz;izAk; NtWgl;l epwq;fisAk; nfhz;l ,uz;L xl;rp

mdad;fis cUthf;Fk; %yfk; ....................

5. mjp cau; xl;rpNaw;w epiyapYs;s %yfq;fis cUthf;Fk; %yfk;. ....................

6. malkhd epakpg;gpy; gad;gLj;Jk; Nru;it xd;iw Na2SO3 cld; cUthf;Fk;

%yfk;. ...............

b) (i)%yf;$W C2H3N3O ,w;F Vw;Wf;nfhs;sj;jf;f Yhapapd; fl;likg;ig tiuf.mjd;

mbg;gilf; fl;likg;G fPNo jug;gl;Ls;sJ.
H O
│ │
H – C − C−N−N−N
│
H
̂ N gpizg;Gf; Nfhzk; mz;zsthf 1180 kw;Wk; N−N gpizg;G ePsq;fs;
Fwpg;G : CN
xd;Wf;nfhd;W rkdw;wJ vdTk; fUJf.

(ii)Nru;it C2H3O5N ,w;F kpfTk; cWjpahd Yhapapd; Gs;sp-Nfhl;Lf; fl;likg;G

jug;gl;Ls;sJ.,k;%yf;$Wf;F NkYk; ,U gupTf;fl;likg;Gf;fis tiuf. tiue;j
fl;likg;gpy; cWjpaw;w fl;likg;gpd; fPo; “cWjpaw;wJ” vd vOJf.
H :O: :O:
‫ ║ ׀‬.. .. ║ ..
/ / – O – O −N−O
H−C – C /
‫׀‬ . . . . + . . :-
H

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(iii)gpd;tUk; Yhaprpd; fl;likg;ig mbg;gilahff; nfhz;L gpd;tUk; ml;ltizapy;

jug;gl;Ls;s N,C,O mZf;fspd;,

1)mZitr;Rw;wpAs;s VSEPR Nrhbfspd; vz;zpf;if

2)mZitr;Rw;wpAs;s ,yj;jpud; Nrhbf;Nfj;jpuf;fzpjk;

3)mZitr;Rw;wpAs;s tbtk;

4)mZtpd; fyg;ghf;fk;

vd;gtw;iw vOJf.
.. - .. .. ..
.N. = .C –O–O–O−H
+
/

/. . . . . . .
mZf;fs; gpd;tUkhW ,yf;fkplg;gl;Ls;sd.
1 2 3 4 5
N
1 − C1 – O
1 – O1 – O1− H

mZ N1 C2 O3 O5
mZitr;Rw;wpAs;s
VSEPRNrhbfspd;
vz;zpf;if
,yj;jpud;
Nrhbf;Nfj;jpuf;fzpjk;
mZitr;Rw;wpAs;s
tbtk;
mZtpd; fyg;ghf;fk;

(iv)NkNy (iii) ,y; jug;gl;l Yhaprpd; fl;likg;gpy; gpd;tUk; 𝜎gpizg;Gfspd;

cUthf;fj;Jld; rk;ge;jg;l;l mZ fyg;gpd xgpw;wy;fis ,dq;fhz;f.

(mZf;fis ,yf;fkply; (iii) ,y; cs;sthwhFk;)

1)N1 − C2 N1 C2

2)C2 − O3 C2 O3

3)O3 − O4 O3 O4

4)O4 − O5 O4 O5

5)O5 − H O5 H

(v) NkNy (iii) ,y; jug;gl;l Yhaprpd; fl;likg;gpy; gpd;tUk; 𝜋gpizg;Gfspd;

cUthf;fj;Jld; rk;ge;jg;l;l mZ xgpw;wy;fis ,dq;fhz;f.
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(mZf;fis ,yf;fkply; (iii) ,y; cs;sthwhFk;)

1)N1 − C2 N1 C2

2)O3 − O4 O3 O4

c)gpd;tUk; Nru;itfis milg;Gf;Fwpfspy; jug;gl;l mtw;wpd; ,ay;Gfs; mjpfupf;Fk;

tupirapy; vOJf.

(i) H2O2 , HF , NH3 , H2O (nfhjpepiy)

(ii) CO , CO2 ,CO32- , C2O42- (C-O gpizg;G ePsk;)

(iii)Li, Na, Mg, Ca (2k; madhf;fw;rf;jp)

*****

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gFjp II
fl;Liu tpdh
1) (a) M vd;gJ 3𝑑 njhFg;ig Nru;e;j jhz;ly; cNyhfk;. ,J Ijhd 𝐻𝐶𝑙 cld; jhf;fk; Gupe;J
,sk; rptg;G epwkhd 𝐴 vDk; fiuriyAk; 𝐵 vDk; epwkw;w thAitAk; cUthf;Fk;. fiury;
𝐴, 𝑃𝑏2 𝑂 Kd;dpiyapy; nrwpe;j 𝐻𝑁𝑂3 cld; gupfupf;f nra;ag;gLk; NghJ 𝐶 vDk; Cjh epwkhd
mad; fiury; Njhd;Wk;. fiury; 𝐶 kpifahd nrwpe;j 𝐾𝑂𝐻(𝑎𝑞) cld jhf;fkilar; nra;Ak;
;NghJ gr;ir epwf;fiury; 𝐷 IAk; epwkw;w thA E IAk; jUk;. fiury; A ,w;F KOH(aq) ,d;
xU gFjp Nru;f;Fk; NghJ ntz;zpw tPo;gbT F ngwg;gLk;. F ,w;F H2O2 fiury; Nru;j;j NghJ
G vDk; fgpy epw tPo;gbT Njhd;wpaJ. G, Conc HCl cld; epwkw;w thA H Ij; jUk;. ngwg;gl;l
gr;ir epw fiury; D ,w;F mkpyk; Nrh;f;Fk; NghJ kPz;Lk; Cjh epwf; fiury; C Ak; fgpy epw
tPo;gbT G Ak; Njhd;wpaJ.
(i) A,B,E,F,G,H tiuahd Nru;itfisAk; C,D Mfpa mad;fisAk; ,dq;fhz;f.
(ii) eilngw;w vy;yh jhf;fq;fSf;Fkhd rkd; nra;ag;gl;l rkd;ghLfisj; jUf.
(7.0Gs;spfs;)
(b) fw;wad;fs; %d;Wk; xU md;daDk; mlq;fpAs;s X vDk; ePu;f;fiury;> gpd;tUk; Kiwf;Nfw;g
gupNrhjidfSf;F cl;gLj;jg;gl;lJ. X ,y; mlq;fpAs;s mk;%d;W fw;waidAk; xU
md;daidAk; ,dq;fhz;f.
gupNrhjid mtjhdk;
X ePu;f;fiurYf;F (CH3COO)2Pb fiury; nts;is epw tPo;gbT fpilj;jJ.
(1)
Nru;f;fg;gl;lJ. gpd; ntg;gNkw;wg;gl;lJ. ntg;gNkw;wpaJk; tPo;gbT fiue;jJ.
X fiurYf;F NH4Cl/NH4OH fiury; epw tPo;gbTk; epwkw;w fiurYk;
(2)
Nru;j;J gpd; tbf;fg;gl;lJ. fpilj;jJ.
NkNy (2) ,y; tbf;fg;gl;l nts;is epw tPo;gbT fpilj;jJ.
(3)
fiurypD}lhf H2S thA nrYj;jg;gl;lJ.
NkNy (2) ,y; ngwg;gl;l epwtPo;gbT nrq;fgpy tPo;gbTk; epwkw;w
(4)
NaOH,Ds; fiuj;J tbf;fg;gl;lJ. tbjputKk; fpilj;jJ.
NkNy (4) ,y; ngwg;gl;l nrq;fgpy
tPo;gbTIjhd H2SO4 ,y; fiuj;J
(5) Cjh epwf; fiury; fpilj;jJ.
ngwg;gl;l fiurYf;F ryprpypf;fkpyk;
Nru;f;fg;gl;lJ.
NkNy(4) ,y; fpilj;j epwkw;w
(6) nts;is epw tPo;gbT fpilj;jJ.
fiurYf;F NH4Cl Nru;f;fg;gl;lJ.
NkNy (6) ,y; ngwg;gl;l nts;is epw tPo;gbT fiue;J epwkw;w fiury;
(7)
tPo;gbTf;F kpif NaOH Nru;f;fg;gl;lJ. fpilj;jJ.
NkNy (3) ,y; ngwg;gl;l nts;is epw
(8) tPo;gbT HCl ,y; fiuj;J NaOH nts;is epw tPo;gbT fpilj;jJ.
Jspj;Jspahfr; Nru;f;fg;gl;lJ.
mtjhdq;fis tpsf;fp>
(i) md;dad;fis ,dq;fhz;f.
(ii) %d;W fw;wad;fis ,dq;fhz;f. (4.0 Gs;spfs;)

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(c) H2S fhuzkhfj; Ju;ehw;wk; tPrpa fpzw;W ePu; khjpupnahd;wpy; H2S ,d; nrwpT 68ppm Mff;
fhzg;gl;lJ. 2000dm3 ,f;fpzw;W ePiuf; nfhz;Ls;s ePu;j;jhq;fpnahd;wpDs; Cl2(g) nrYj;jg;gl;L
H2S Kw;whf mfw;wg;gl;lJ. ,jd; NghJ kpifahd msT Cl2(g) nrYj;jg;gl;lJ. kpifahfr;
nrYj;jg;gl;l Cl2(g) fzpg;gjw;F gpd;tUk; nray;Kiw nra;ag;gl;lJ. 50.0cm3 ,e;ePiu vLj;J
kpifahd KI(aq) Nru;f;fg;gl;lJ. ntspNaWk; maBd; 0.01moldm-3 Na2S2O3 fiurYld; khg;nghUs;
fhl;b Kd;dpiyapy; epakpj;j NghJ mjd; 10.0 cm3 Njitg;gl;lJ.
i. NkYs;s gbKiwapy; eilngWk; jhf;fq;fSf;F rkd; nra;j rkd;ghLfisj; jUf.
ii. H2S ,id mfw;wj; Njitahd Mff; Fiwe;j Cl2(g) d; msT fpuhkpy; ahJ?
iii. NkYs;s gbKiwapy; Nkyjpfkhf tpepNahfpf;fg;gl;l Cl2(g) d; jpzpT fpuhkpy; ahJ?
iv. nkhj;jkhf tpepNahfpf;fg;gl;l Cl2(g) d; jpzpT ahJ? (Cl=35.5)

(4.0 Gs;spfs;)

*****