Experiment 1 Predicting Molecular Shape and Polarity Using VSEPR Theory

Download as pdf or txt
Download as pdf or txt
You are on page 1of 5

EXPERIMENT 1

Predicting Molecular Shape and Polarity Using VSEPR Theory

Objectives

1. To draw Lewis structures of several compounds and make models of these


structures in order to help you visualize the molecular shape based on Valence
Shell Electron Pair Repulsion (VSEPR) theory.

2. To predict the molecular polarity for each compound.

Introduction

Valence Shell Electron Pair Repulsion (VSEPR) theory allows one to predict the
electronic and molecular geometries of a molecule from its Lewis structure. In order to
get correct answers from VSEPR theory, you must first have a correct Lewis structure.
Therefore, the procedures for drawing Lewis structures from the textbook and lectures
must be mastered. Remember that you must account for all valence electrons and you
must show all of these electrons in the Lewis structure.

Molecular geometry describes the arrangement of atoms in a molecule. The


non-bonding pairs do not fit into this description. Hence, if there are non-bonding pairs
present in the molecule, they are ignored when describing the molecular geometry.
For example, the electronic geometry of H2O is tetrahedral, but two are lone pairs at
the central atom, thus they are ignored. Therefore, the molecular geometry of water
(the arrangement of the H, O, and H atoms) is best described as “bent”. (If there are
no non-bonding pairs, then the molecular geometry is also the electronic geometry of
the molecule.)

Both the polarity of bonds and molecular geometry must be considered in


determining whether a molecule is polar or not. There are three cases:

 There are no polar bonds. The molecule is not polar.

 There are polar bonds, but in the molecular geometry, they cancel each other
out. The molecule is not polar.

 There are polar bonds present and they do not cancel each other out. The
molecule is polar.

Apparatus
Molecular model kit.
Procedure

For each compound given in the observations/data/report table, follow the following
steps.

1. Draw the Lewis structure. You may want to work on the Lewis structure on a sheet
of scratch paper first before filling in the table.

2. Count the number of bonding pair and lone pair in the Lewis structure and predict
the electronic geometry.

3. Assemble the model which has the correct electronic geometry and remove one
attached atom for every lone pair that is present on the central atom of your Lewis
structure. (Do not count the lone pairs when determining the molecular shape –
they are “invisible”.) You now have a model, showing the shape of the molecule
(the molecular geometry).

4. Draw the structure representing the molecular geometry using wedges and dashes
wherever necessary to show the bonds that are not in the plane of the paper.
(Tetrahedral molecules are not flat and require using the wedged or dashed bond
representation to properly show their three-dimensional shape. See Bettelheim.)

5. Finally, decide which of the category above correctly describe the type of
molecular polarity that fits the molecule.
DATA SHEET

EXPERIMENT 1

Predicting Molecular Shape and Polarity Using VSEPR Theory

Name :
Student ID :
Date of Experiment :

RESULTS

Table 1: Molecular shape and polarity prediction using VSEPR theory

Formula Sketch Number of Number of Electronic Sketch Molecular geometry Molecular


Lewis structure bonding pair lone pair geometry and bond angles polarity
CS2

PF3
Formula Sketch Number of Number of Electronic Sketch Molecular geometry Molecular
Lewis structure bonding pair lone pair geometry and bond angles polarity

SO3

SiCl4

ICl4-

AsF5
Formula Sketch Number of Number of Electronic Sketch Molecular geometry Molecular
Lewis structure bonding pair lone pair geometry and bond angles polarity

TeF5-

SCl2

IOF5

IF4+

You might also like