Safety Data Sheet: Section 1: Identification of The Substance/Mixture and of The Company/Undertaking

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According to EC Regulation 1907/2006 (Reach), Regulation EU No.

453/2010

Safety Data Sheet

Issue Date: 18-Sep-2013 Revision Date: 15-Oct-2014 Version: 1

Section 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE


COMPANY/UNDERTAKING
1.1. Product identifier
Product Name: Agrocote Max 43-0-0
Product Code E93098HRL

1.2. Relevant identified uses of the substance or mixture and uses advised against
Recommended Use: Fertilizer
Restricted to professional users
Uses Advised Against: Consumer use.

1.3. Details of the supplier of the safety data sheet


Manufacturer
Everris International BV
Nijverheidsweg 1-5; 6422 PD Heerlen (NL)
Tel: +31 (0) 45-5609100; Fax: +31 (0) 45-5609190

For further information, please contact


[email protected]

1.4. Emergency telephone number


IN CASE OF AN EMERGENCY CALL: +44 1235 239 670 (24h)

Section 2: HAZARDS IDENTIFICATION


2.1. Classification of the substance or mixture
Mixture

Regulation (EC) No 1272/2008

This mixture is classified as not hazardous according to regulation (EC) 1272/2008 [EU-GHS]

Classification according 67/548/EC and 88/379/EC or 1999/45/EC


Full text of R-phrases: see section 16

2.2. Label elements


Product Identifier:
This mixture is classified as not hazardous according to regulation (EC) 1272/2008 [EU-GHS]
Signal Word:
None

EUH204 - Contains isocyanates. May produce an allergic reaction


EUH210 - Safety data sheet available on request

Other hazards (UN-GHS)


Causes mild skin irritation.

Section 3: COMPOSITION/INFORMATION ON INGREDIENTS

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3.1 Substances

Ingredients EC-No. CAS-No Weight % Classification Classification according to REACH registration


according to Regulation (EC) No. number
67/548/EEC 1272/2008 [CLP]
200-315-5 57-13-6 80 - 100% NE Not classified 01-2119463277-33
Urea
203-559-0 108-19-0 1 - 5% Xi;R36/37/38 STOT SE 3 (H335) no data available
Biuret; C6H8O7 Skin Irrit. 2 (H315)
Eye Irrit. 2 (H319)

Full text of R-phrases: see section 16


Full text of H- and EUH-phrases: see section 16

Section 4: FIRST AID MEASURES


4.1. Description of first aid measures

General Advice: First aid measures should be executed by trained personnel only.

Inhalation: Move to fresh air in case of accidental inhalation of vapours or decomposition products. If
not breathing, give artificial respiration.

Skin Contact: Extensive and prolonged contact with skin may cause irritation. If a person feels unwell or
symptoms of skin irritation appear, consult a physician. Wash hands and exposed skin after
use / handling.

Eye Contact: Rinse thoroughly with plenty of water, also under the eyelids.

Ingestion: Never give anything by mouth to an unconscious person. Clean mouth with water and drink
afterwards plenty of water.

Protection of First-Aiders: Low hazard for usual industrial or commercial handling.

4.2. Most important symptoms and effects, both acute and delayed

Symptoms: None under normal processing

4.3. Indication of any immediate medical attention and special treatment needed

Notes to Physician: None under normal processing.

Section 5: FIRE FIGHTING MEASURES


5.1. Extinguishing media
Suitable extinguishing media:
Coordinate fire extinguishing measures to fire in surrounding area. Use dry chemical, CO2, water spray or "alcohol" foam.

Unsuitable extinguishing media:


Not Applicable.

5.2. Special hazards arising from the substance or mixture


Thermal decomposition can lead to release of irritating and toxic gases and vapors.

5.3. Advice for firefighters


In the event of fire, wear self-contained breathing apparatus.

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Section 6: ACCIDENTAL RELEASE MEASURES


6.1. Personal precautions, protective equipment and emergency procedures
Personal Precautions: Ensure adequate ventilation.
For Emergency Responders: Use personal protection recommended in Section 8.

6.2. Environmental precautions


Do not release in the sewers/surface waters/subterranean waters.

6.3. Methods and material for containment and cleaning up


Methods for Containment: Prevent further leakage or spillage if safe to do so.
Methods for Cleanup: Take up mechanically and collect in suitable container for disposal.

6.4. Reference to other sections


§ 8, 12, 13.

Section 7: HANDLING AND STORAGE


7.1. Precautions for safe handling
General hygiene considerations: Handle in accordance with good industrial hygiene and safety
practice. Use personal protection recommended in Section 8.
When using, do not eat, drink or smoke.

7.2. Conditions for safe storage, including any incompatibilities


Technical measures/storage conditions: For quality reasons: Keep out of reach of direct sunlight, store
under dry conditions, partly used bags should be closed well.
LGK (Germany) Exempt
Packaging Materials: Bags or Bulk.

7.3. Specific end use(s)


Specific use(s) Fertilizer; Read and follow label instructions; www.everris.com

Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION


8.1. Control parameters

Exposure Limits This product, as supplied, does not contain any hazardous materials with occupational
exposure limits established by the region specific regulatory bodies.
Urea
Latvia - Occupational Exposure Limits - TWAs 10 mg/m3 TWA
Bulgaria - Occupational Exposure Limits - TWAs 10.0 mg/m3 TWA
Norway TWA: 30 µg Hg/g Creatinine
STEL: 45 µg Hg/g Creatinine

Derived No Effect Level (DNEL)


No data available

Predicted No Effect Concentration (PNEC)


No data available.

8.2. Exposure controls


Engineering Measures to Reduce Ensure adequate ventilation, especially in confined areas.
Exposure:

Personal protective equipment


Eye/Face Protection: Safety glasses
Hand protection: PVC or other plastic material gloves.
Respiratory Protection: No personal respiratory protective equipment normally required
Skin and Body Protection: Wear normal, light working clothing

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Hygiene Measures: Follow good housekeeping practices. When using, do not eat, drink or smoke. Wash hands
before stopping and immediately after handling. Keep away from food, drink and animal
feeding stuffs.

Environmental exposure controls Do not release in the sewers/surface waters/subterranean waters.

Section 9: PHYSICAL AND CHEMICAL PROPERTIES


9.1. Information on basic physical and chemical properties
Physical State: Solid
Appearance: granules
Color: yellow, white.
Odor: Not significant
pH: No information available
Melting Point/Freezing Point: no data available
Boiling Point/Range: Solid, not applicable
Flash Point: No information available
Evaporation Rate: Solid, not applicable
Flammability (solid, gas): Non-flammable
Vapor Pressure: Solid, not applicable
Vapor Density: Solid, not applicable
Specific Gravity: no data available
Water Solubility: Soluble in water
Solubility(ies) no data available
Partition Coefficient: Solid, not applicable
Autoignition Temperature: not applicable
Decomposition Temperature: no data available
Explosive Properties: Doesn't present explosion hazard. Based on data of ingredients.

9.2. Other information


Bulk density: 740 - 890 kg/m3

Section 10: STABILITY AND REACTIVITY


10.1. Reactivity
Not reactive.

10.2. Chemical stability


Stable under recommended storage conditions.
10.3. Possibility of hazardous reactions
Hazardous Decomposition Products:
Thermal decomposition can lead to release of irritating and toxic gases and vapors.
Possibility of Hazardous Reactions:
None under normal processing.

10.4. Conditions to avoid


For quality reasons: Keep out of reach of direct sunlight, store under dry conditions, partly used bags should be closed well.

10.5. Incompatible materials


None.

10.6. Hazardous decomposition products


None under normal processing.

Section 11: TOXICOLOGICAL INFORMATION


11.1. Information on toxicological effects
Acute Toxicity
Product Information:
Inhalation: May cause irritation of respiratory tract.
Eye Contact: May cause irritation.

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Skin Contact: May cause irritation.


Ingestion: Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea.
Unknown Acute Toxicity: 0% of the mixture consists of ingredient(s) of unknown toxicity.

Component Information:

Skin Corrosion or Irritation See also section 3.


Serious Eye Damage or Eye Irritation See also section 3.
Sensitization See also section 3.
Mutagenic effects See also section 3.
Carcinogenicity The table below indicates whether each agency has listed any
ingredient as a carcinogen.

Reproductive Toxicity

Teratogenicity No data available.


STOT - Single Exposure No known effects under normal use conditions.
STOT - Repeated Exposure None under normal use conditions.
Aspiration Hazard No data available.

Section 12: ECOLOGICAL INFORMATION


12.1. Toxicity
Do not allow product to enter the environment uncontrolled.

6.78% of the mixture consists of components(s) of unknown hazards to the aquatic environment.

Ingredients Algae/aquatic plants Fish Crustacea


Urea 16200 - 18300: 96 h Poecilia 3910: 48 h Daphnia magna mg/L
reticulata mg/L LC50 EC50 Static

12.2. Persistence and degradability


No data available.

12.3. Bioaccumulative potential


None known
Ingredients LOGPOW
Urea -1.59

12.4. Mobility in soil


No data available.

12.5. Results of PBT and vPvB assessment


No data available.

12.6. Other adverse effects


not applicable

Section 13: DISPOSAL CONSIDERATIONS


13.1. Waste treatment methods
Disposal of Wastes: Disposal should be in accordance with applicable regional,
national and local laws and regulations.
Contaminated Packaging: Do not re-use empty containers. Dispose of as unused product.
Other Information: Use up product completely. Packaging material is industrial
waste.

Section 14: TRANSPORT INFORMATION

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IMO / IMDG
14.1
UN-No: Not regulated
14.2
Proper shipping name: Not regulated
14.3
Hazard Class: Not regulated
14.4
Packing group: Not regulated
14.5
Marine Pollutant: Not regulated
14.6
Special Provisions None
14.7
Transport in bulk according to Annex II of MARPOL 73/78 Not regulated
and the IBC Code

ADR/RID
14.1
UN-No: Not regulated
14.2
Proper shipping name: Not regulated
14.3
Hazard Class: Not regulated
14.4
Packing group: Not regulated
14.5
Environmental Hazard Not regulated
14.6
Special Provisions None

IATA
14.1
UN-No: Not regulated
14.2
Proper shipping name: Not regulated
14.3
Hazard Class: Not regulated
14.4
Packing group: Not regulated
14.5
Environmental Hazard Not regulated
14.6
Special Provisions None

Section 15: REGULATORY INFORMATION


15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

National regulations
France
ICPE (FR): Not regulated

Germany
Gefahrstoffverordnung (Germany) TRGS 511 Not regulated

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LGK (Germany) Exempt


Water Endangering Class (WGK): 1 (Everris classification )

Component German WGK Section


Urea class 1
57-13-6 ( 80 - 100% )

European Union
Take note of Directive 2000/39/EC establishing a first list of indicative occupational exposure limit values

15.2. Chemical safety assessment


Not required. Substance(s) usage is covered according to Reach regulation 1907/2006.

Section 16: OTHER INFORMATION


Text of R Phrases mentioned in Section 3
R36/37/38 - Irritating to eyes, respiratory system and skin

Full text of H-Statements referred to under sections 2 and 3


H335 - May cause respiratory irritation
H315 - Causes skin irritation
H319 - Causes serious eye irritation

Key or legend to abbreviations and acronyms used in the safety data sheet
RID: Regulations Concerning the International Transport of Dangerous Goods by Rail
ICAO: International Civil Aviation Organization
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonized System of Classification and Labeling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
PNEC: Predicted No Effect Concentration
DNEL: Derived No-Effect Level
Reach: Registration, Evaluation, authorization of Chemicals
CLP: EU-GHS; Classification, Labelling and Packaging
OEL: Occupational Exposure Limit
TWA: Time Weighted Average
ATE: Acute Toxicity Estimate
EUH statement: CLP (EU) specific hazard statement.

Classification procedure: - Calculation method


- Expert judgment and weight of evidence determination

Key literature references and sources for data According to EC Regulation 1907/2006 (Reach), Regulation EU
No. 453/2010
Regulation (EC) No 1272/2008

Prepared by: Regulatory Affairs Department ([email protected])

Issue Date: 18-Sep-2013

Revision Date: 15-Oct-2014

Reason for revision: *** Indicates changes since the last revision. This version
replaces all previous versions.

This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006

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This information contained herein is, to the best of Everris' knowledge and belief, accurate and reliable as of the date of preparation
of this document. However, no warranty or guarantee, express or implied, is made as to the accuracy or reliability, and Everris shall
not be liable for any loss or damage arising out of the use thereof. No authorization is given or implied to use any patented
invention without a license. In addition, Everris shall not be liable for any damage or injury resulting from abnormal use, from any
failure to adhere to recommended practices or from any hazards inherent in the nature of the product.

End of Safety Data Sheet

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