3.1 Redox Reaction

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Chapter 3

Oxidation and Reduction

3.1 Redox reaction


1. Redox reactions are chemical reactions involving reduction and oxidation
occurring simultaneously.

2. Oxidation can be defined in terms of :


(a) gain of oxygen
(b) loss of hydrogen
(c) loss of electrons
(d) increase in the oxidation number of the element

3. In contrast, reduction can be defined in terms of :


(a) loss of oxygen
(b) gain of hydrogen
(c) gain of electrons
(d) decease in the oxidation number of the element

4. An oxidising agent undergoes reduction in a reaction.

5. An oxidising agent is a substance that oxidise another substance.

6. A reducing agent undergoes oxidation in a reaction.

7. A reducing agent is a substance that reduce another substance.

8. Both oxidizing agent and reducing agent are reactants for a reaction.

i) Redox reactions based on loss or gain of oxygen

Ca(s) + ZnO(s)  CaO(s) + Zn(s)


reducing oxidising
agent agent

(a) Ca undergoes oxidation. This is because Ca gains oxygen to form CaO.

Therefore, Ca is a reducing agent.

(b) ZnO undergoes reduction. This is because ZnO loses oxygen to form Zn.

Hence, ZnO is an oxidising agent.

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ii) Redox reactions based on loss or gain of hydrogen

2NH3(g) + 3Cl2(g)  N2(g) + 6HCl(g)


reducing oxidising
agent agent

(a) NH3 undergoes oxidation. This is because NH3 loses hydrogen to form N2.

Therefore, NH3 is a reducing agent.

(b) Cl2 undergoes reduction. This is because Cl2 gains hydrogen to form HCl.

Hence, Cl2 is an oxidising agent.

iii) Redox reactions based on transfer of electrons

2K(s) + Br2(g)  2KBr(s)


reducing oxidising
agent agent

Half – equations :

Oxidation : K → K+ + e⁻

Reduction : Br2 + 2e⁻ → 2Br⁻

(a) K undergoes oxidation . This is because K atom loses electron to form K+ .

Therefore, K is a reducing agent .

(b) Br2 undergoes reduction. This is because Br2 gains electrons to form Br⁻ .

Hence, Br2 is an oxidising agent .

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