PHYSICAL CHEMISTRY

Question Bank
Target IIT JEE-2021
WARRIOR
MOLE CONCEPT_PART-2
Fill in the blank:
(i) For the reaction,
2X + 3Y + 4Z  5W
Initially if 1 mole of X, 3 mole of Y and 4 mole of Z is taken. If 1.25 mole of W is obtained then % yield
of this reaction is _______.

(ii) The vapour density of a mixture of gas A (Molecular mass = 40) and gas B (Molecular mass = 80) is 25.
Then mole % of gas B in the mixture would be ________.

(iii) For the reaction

2A + 3B + 5C  3D
Initially if 2 mole of A, 4 mole of B and 6 mole of C is taken. With 25% yield, moles of D which can be
produced are _________.

(iv) 125 ml of 8% w/w NaOH solution (sp. gravity 1) is added to 125 ml of 10% w/v HCl solution. The
nature of resultant solution would be ________.

(v) Fill in the blanks in the following table:

Compound Grams Grams Molality Mole Fraction
Compd Water of Compd of Compd
Na2CO3 ______ 250 0.0125 ______
CH3OH 13.5 150 _____ ______
KNO 3 _____ 555 _____ 0.0934

Single Correct:
Q.1 The percentage by mole of NO2 in a mixture of NO2(g) and NO(g) having average molecular mass 34 is :
(A) 25% (B) 20% (C) 40% (D) 75%

Q.2 For the following reaction if equal mass of A and B are taken :
A + 2B  C
Which of the following is correct? (MA and MB are molar masses of A and B respectively)
(A) If MA = 2MB , then none of the reactant will be left.
MA
(B) If MB > , then A will be limiting reagent.
2
(C) If MA = MB, then A will be limiting reagent
(D) All are correct

Q.3 74 gm of a compoud on complete combustion gives 132 gm CO2 and 54 gm of H2O. The molecular
formula of the compound may be
(A) C5H12 (B) C4H10O (C) C3H6O2 (D) C3H7O2

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Q.4 The mass of CO2 produced from 620 gm mixture of C2H4O2 & O2, prepared to produce maximum
energy is (Combustion reaction is exothermic)
(A) 413.33 gm (B) 593.04 gm (C) 440 gm (D) 320 gm

Q.5 Maximum mass of sucrose C12H22O11 produced by mixing 84 gm of carbon, 12 gm of hydrogen and
56 lit. O2 at 1 atm & 273 K according to given reaction, is
C(s) + H2(g) + O2 (g)  C12H22O11(s)
(A) 138.5 (B) 155.5 (C) 172.5 (D) 199.5

Q.6 In the quantitative determination of nitrogen, N2 gas liberated from 0.42 gm of a sample of organic
100
compound was collected over water. If the volume of N2 gas collected was ml at total pressure
11
860 mm Hg at 250 K, % by mass of nitrogen in the organic compound is
[Aq. tension at 250 K is 24 mm Hg and R = 0.08 L atm mol–1 K–1 ]
10 5 20 100
(A) % (B) % (C) % (D) %
3 3 3 3

Q.7 If mass of 2 atoms is 4 × 10–23 gm. Then atomic mass of element will be : [Take : NA = 6×1023 / mole]
(A) 24 (B) 12 (C) 6 (D) 2

Q.8 Calculate percentage change in Mavg of the mixture, if PCl5 undergo 50% decomposition.
PCl5  PCl3 + Cl2
(A) 50% (B) 66.66 % (C) 33.33 % (D) Zero

Q.9 The number of carbon atoms present in a signature, if a signature written by carbon pencil weights
1.2 × 10–3 gm is
(A) 12.04 × 1020 (B) 6.02 × 1019 (C) 3.01 × 1019 (D) 6.02 × 1020

Q.10 The average atomic mass of a mixture containing 79 mole % of 24Mg and remaining 21 mole % of 25Mg
and 26Mg , is 24.31. % mole of 26Mg is
(A) 5 (B) 20 (C) 10 (D) 15

Q.11 An organic compound contains 14 atoms of carbon per molecule. If mass % of carbon in the compound
is 22.4 % then molecular mass of the compound will be
(A) 3000 (B) 750 (C) 12000 (D) 600

Q.12 An organic compound contains 8 % Oxygen and 4 % Sulphur by mass. Find the minimum possible
molecular weight of compound?
(A) 400 (B) 200 (C) 800 (D) 1600

Q.13 6 gm of silver salt of tribasic acid gives 4.32 gm silver on strong heating. The molar mass of acid is :
(A) 126 gm (B) 129 gm (C) 123 gm (D) 252 gm

Q.14 6.0 gm of silver salt of a tetrabasic acid gives 4.32 gm silver on strong heating. The molar mass of the
acid is (Ag = 108)
(A) 168 (B) 172 (C) 84 (D) 88

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Q.15 The number of moles of compound (KHC2O4)0.95 · H2C2O4 in its pure sample if sample contains
4 moles of oxygen atoms.
4 4
(A) 0.5 (B) 0.5 × 0.95 (C) (4  0.95  4) (D)
0.95

Q.16 20 gm of a mixture of NaCl and NaOH exactly requires 7.3 gm HCl for complete reaction. The mass
percent of NaCl in the original mixture is :
(A) 40% (B) 60% (C) 50% (D) 80%

Q.17 For a solution concentration can be expressed as 16% w/w as well as 20% w/v. What will be density of
solution?
(A) 1.25 gm/lit. (B) 0.8 gm/lit. (C) 1.25 gm/ml (D) 0.8 gm/ml

Q.18 In Delhi on a polluted day, concentration of SO2 in air is 40 ppm. Assuming density of air is 2gm/litre.
How many gram of SO2 is present in 100 litre of air?
(A) 4 mg (B) 4 gm (C) 8 × 10–3 kg (D) 8 mg

Q.19 The legal limit for human exposure to CO in the work place is 35 ppm. Assuming that the density of
air is 1.3 g/L, how many grams of CO are in 1.0L of air at the maximum allowable concentration?
(A) 4.55 ×10–5 gm (B) 3.5 ×10–5 gm (C) 2.69 ×10–5 gm (D) 7.2 ×10–5 gm

Q.20 150 ml of a solution containing 5 millimoles of A (special gravity = 1.2) is mixed with 250 ml of another
solution containing 10 millimoles of A (special gravity = 1.4). If on mixing the density of the solution
5.3
becomes gm/ml then what will be molarity of A in the final solution.
4.5
1 3 1 4
(A) M (B) M (C) (D)
30 80 20 85

Q.21 If 2M, 200 ml HCl, 2M, 100 ml CaCl2 and 5M, 200 ml AlCl3 is mixed then final concentration of Cl–
will be :
(A) 2.5 M (B) 3 M (C) 3.5 M (D) 7.6 M

Q.22 What volumes should you mix of 0.2 M NaCl and 0.1 M CaCl2 solution so that in resulting solution the
concentration of positive ion is 40% lesser than concentration of negative ion. Assuming total volume of
solution 1000 ml.
(A) 400 ml NaCl , 600 ml CaCl2 (B) 600 ml NaCl, 400 ml CaCl2
(C) 800 ml NaCl, 200 ml CaCl2 (D) None of these

Q.23 Assuming complete precipitation of AgCl, calculate the sum of the molar concentration of all the ions if 2
lit of 2M Ag2SO4 is mixed with 4 lit of 1 M NaCl solution is :
(A) 4M (B) 2M (C) 3 M (D) 2.5 M

Q.24 200 gm of an oleum sample (labelled as 109%) is mixed with 400 gm of another oleum sample (labelled
as 118%). The labelling of the new sample formed will be
(A) 115 % (B) 112 % (C) 122 % (D) 116 %
Q.25 How many litre of C7H16 will be required to react with 176 gm of oxygen. If density of C7H16 is
0.8 gm/L?
(A) 62.5 L (B) 40 L (C) 50 L (D) 80 L

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Q.26 Air contains 20% oxygen by volume, calculate the theoretical volume of air which will be required for
burning 200 m3 of acetylene gas completely. All volumes are measured under the same conditions of
temperature and pressure.
(A) 2500 m3 (B) 500 m3 (C) 2000 m3 (D) 3000 m3
Q.27 10 ml of a compound containing 'N' and 'O' is mixed with 30 ml of H2 to produce H2O (l) and 10 ml of
N2 (g). Molecular formula of compound if both reactants reacts completely, is
(A) N2O (B) NO2 (C) N2O3 (D) N2O5
Q.28 200 ml of a gaseous mixture containing CO, CO2 and N2 on complete combustion in just sufficient
amount of O2 showed contraction of 40 ml. When the resulting gases were passed through KOH
solution it reduces by 50 % then calculate the volume ratio of VCO : VCO : VN in original mixture.
2 2

(A) 4 : 1 : 5 (B) 2 : 3 : 5 (C) 1 : 4 : 5 (D) 1 : 3 : 5

Q.29 When 20 ml of mixture of O2 and O3 is heated, the volume becomes 29 ml and disappears in alkaline
pyragallol solution. What is the volume precent of O2 in the original mixture?
(A) 90% (B) 10% (C) 18% (D) 2%
Q.30 A mixture of C2H2 and C3H8 occupied a certain volume at 80 mm Hg. The mixture was completely
burnt to CO2 and H2O(l). When the pressure of CO2 was found to be 230 mm Hg at the same temperature
and volume, the fraction of C2H2 in mixture is
(A) 0.125 (B) 0.5 (C) 0.85 (D) 0.25
Q.31 20 mL of a mixture of CO and H2 were mixed with excess of O2 and exploded & cooled. There was a
volume contraction of 23 mL. All volume measurements corresponds to room temperature (27°C) and
one atmospheric pressure. Determine the volume ratio V1 : V2 of CO and H2 in the original mixture
(A) 6.5 : 13.5 (B) 5 : 15 (C) 9 : 11 (D) 7 : 13
Assertion Reason:
Q.32 Statement -1 : Molality of pure ethanol is lesser than pure water.
Statement -2 : As density of ethanol is lesser than density of water.
[Given : dethanol = 0.789 gm/ml; dwater = 1 gm/ml]
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
(C) Statement-1 is false, statement-2 is true.
(D) Statement-1 is true, statement-2 is false.
Q.33 Statement -1 : Mass of a solution of 1 litre of 2M H2SO4 [dsolution = 1.5 gm/ml] is greater
than the mass of solution containing 400 gm MgO which is labelled as
40% (w/w) MgO.
Statement -2 : Mass of H2SO4 in 1 litre 2M H2SO4 [dsolution = 1.5 gm/ml] is greater than
the mass of MgO in 1 litre 40% (w/w) MgO [dsolution =2 gm /ml] solution.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
(C) Statement-1 is false, statement-2 is true.
(D) Statement-1 is true, statement-2 is false.
More than one correct:
Q.34 For the reaction : MnO2 + 4HCl 100 %
 MnCl2 + Cl2 + 2H2O, 8.7 gm MnO2 is dissolved in 500 ml
of HCl solution containing 7.3 gm HCl per litre. (Mn = 55)
(A) HCl is the limiting reagent.
(B) MnO2 is the limiting reagent.
(C) 0.025 moles of MnCl2 will form.
(D) 560 ml Cl2 gas will liberate at 0°C and 1 atm.

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Q.35 Solution(s) containing 40 gm NaOH is/are
(A) 50 gm of 80% (w/w) NaOH
(B) 50 gm of 80% (w/v) NaOH [dsoln. = 1.2 gm/ml]
(C) 50 gm of 20 M NaOH [dsoln. = 1 gm/ml]
(D) 50 gm of 5m NaOH

Q.36 The incorrect statement(s) regarding 2M MgCl2 aqueous solution is/are (dsolution = 1.09 gm/ml)
(A) Molality of Cl¯ is 4.44 m
(B) Mole fraction of MgCl2 is exactly 0.035
(C) The conc. of MgCl2 is 19% w/v
(D) The conc. of MgCl2 is 19 × 104 ppm

Q.37 A sample of H2O2 solution labelled as 56 volume has density of 530 gm/L. Mark the correct option(s)
representing concentration of same solution in other units. (Solution contains only H2O and H2O2)
w
(A) M H = 6 (B) % = 17
2O 2 v
1000
(C) Mole fraction of H2O2 = 0.25 (D) m H 2O 2 =
72

Q.38 Two gases A and B which react according to the equation

aA(g) + bB(g)  cC(g) + dD(g)
to give two gases C and D are taken (amount not known) in an Eudiometer tube (operating at a constant
Pressure and temperature) to cause the above.
If on causing the reaction there is no volume change observed then which of the following statement is/
are correct.
(A) (a + b) = (c + d)
(B) average molecular mass may increase or decrease if either of A or B is present in limited amount.
(C) Vapour Density of the mixture will remain same throughout the course of reaction.
(D) Total moles of all the component of mixture will change.

Q.39 Which of the following is incorrect for 17 gm/L of H2O2 solution

(A) Volume strength is 5.6 V
(B) Molarity of solution is 0.5 M
(C) 1 ml of this solution gives 2.8 ml O2 at 273 K and 2 atm
(D) The molarity of solution is 2M

Match the column:

Q.40 Column I Column II
(Average molecular mass) (Gas mixture)
(A) 40 (P) mixture of O2 and SO3 having S and O-atoms in 1 : 5 ratio

(B) 32 (Q) Equimolar mixture of O3 and O2

(C) 56 (R) Mixture having CH4 and SO3 molecules in the ratio 3 : 1.

(S) Mixture of He and N2O5 in 1 : 27 mass ratio

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Q.41 Column I Column II
(A) 10 M MgO (P) Wsolvent = 120 gm per 100 ml of solution
(dsolution= 1.20 gm/ml)
Solute : MgO
Solvent: H2O
Assume MgO water soluble
(B) 40% w/v NaOH (Q) Wsolution = 150 gm per 100 gm solvent
(dsolution = 1.6 gm/ml)
Solute : NaOH
Solvent: H2O
(C) 8 m CaCO3 (R) Wsolute = 120 gm per 100 gm of solvent
Solute : CaCO3
Solvent: H2O
Assume CaCO3 water soluble
(D) 0.6 mol fraction of 'X' (S) Wsolvent = 125 gm per 100 gm of solute
(molecular mass = 20)
in 'Y' (molecular mass 25)
Solute : X
Solvent : Y

Q.42 Column-I Column-II

(A) 8 g-atoms of Hydrogen (P) 2 moles C3H4
(B) 6 g-atoms of Carbon (Q) 3 moles CH3COOH

(C) 6 g-atoms of Oxygen (R) 2 moles

(D) 4 g-molecules of Nitrogen (S) 4 moles N2H2
(T) 2 moles N2O3

Comprehension:
Paragraph for question no. 43 to 45
According to Dulong and Petit's Law, the product of atomic mass of solid element and its specific heat
capacity (in Cal/K-gm) is nearly 6.4. The specific heat capacity of any substance may be defined as the
amount of heat required to raise the temperature of unit mass of the substance by one Kelvin. If 'q' is the
amount of heat required to raise the temperature of 'm' mass of the substance by 'T' K, then the specific
heat capacity of the substance may be given as :
q
S = m . T
Dulong and Petit's Law give only the approximate atomic mass of element. But from other information
like valency (which should always be integer), we may determine the exact atomic mass of the element.

Q.43 If qA, qB, qC and qD are the amount of heat required to raise the temperature of 'm' gm of elements A, B,
C and D, respectively, each by 'T' K and qA > qB > qC > qD , then the correct order of approximate
atomic masses of elements should be :
(A) A > B > C > D (B) A < B < C < D (C) A = B = C = D (D) Data insufficient

Q.44 The specific heat capacity of an element is 0.63 J/°C - gm. The approximate atomic mass of the element
should be : [Given : 1 Cal = 4.2 J]
(A) 42.67 (B) 10.16 (C) 9.6 (D) 4.03

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 500
Q.45 The specific heat capacity of a metal is 0.158 Cal/K-gm. If the oxide of metal contains % metal, by
7
mass, the exact atomic mass of the metal is :
(A) 40.506 (B) 40.000 (C) 39.483 (D) 20.025

Paragraph for question nos. 46 to 48

Some faculty members of XYZ classes were trying to simplify a problem for students by mentioning data
explicitly about a gaseous mixture. Information given by them is as follow :
Faculty-1 : Mixture consist of three gases A, B and C.
Faculty-2 : Molar mass of B is twice of A & Molar mass of A is 4 times of C.
Faculty-3 : The gas that is neither heaviest nor lightest is 16% by mass.
Faculty-4 : Molar ratio of heaviest to lightest gas is 2 : 5.
Based on the above information, answer the questions that follows:

Q.46 Which of the following options correctly represents gases A, B and C respectively?
(A) O2, CH4, He (B) CH4, O2, He (C) O2, SO2, He (D) O2, SO2, CH4

Q.47 What is the molar ratio of A : B: C?

(A) 5 : 2 : 2 (B) 2 : 2 : 5 (C) 2 : 1 : 5 (D) 1 : 2 : 5
Q.48 What would be the average molar mass of mixture.
[Assuming answer of above question to be correct.]
400
(A) gm (B) 12.5 gm (C) 15 gm (D) 20 gm
67
Paragraph for question nos. 49 to 51
An organic compound contains 69.4 % C, 5.8 % H. A sample of 0.303 g of this compound is analysed
for nitrogen by Kieldahl's method. The ammonia evolved was absorbed in 50 mL of 0.05 M H2SO4.
The excess acid required 25 mL of 0.1 M NaOH for neutralization. Molecular weight of organic compound
is 121.
Q.49 What is percentage of 'N' in the compound?
(A) 7.4 % (B) 11.55% (C) 19.4 % (D) 21.6 %

Q.50 Number of hydrogen atoms in the molecular formula of the compound?

(A) 7 (B) 10 (C) 5 (D) 12

Q.51 0.303 g of the organic compound, in Duma's method on combustion gave 32.27 mL of moist nitrogen at
27°C and at P mm Hg pressure. If the vapour pressure at 27°C is 21 mm of Hg. Find the value of 'P'?
(A) 725 mm (B) 746 mm (C) 710 mm (D) 760 mm

Paragraph for question nos. 52 & 53

On a closed rigid vessel combustion of 2 moles of CH4 was carried out with 10 moles of O2.
At room temperature.
Q.52 After combustion was complete what will be the vapour density of contents of vessel.
(A) 35 (B) 70 (C) 17.5 (D) 15.8

Q.53 If 2 moles of N2 are added after combustions then what will be the change in vapour density of contents
of vessel. [Assume : N2 does not react with any gas]
(A) 2.1 (B) 4.2 (C) 2.93 (D) 0.7

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 ANSWER KEY
(i) 50% (ii) 25% (iii) 0.75 (iv) Acidic
(v) –4
0.331, 2.25 × 10 , 2.81, 0.0482, 321, 5.72
Q.1 A Q.2 A Q.3 C Q.4 C Q.5 B
Q.6 A Q.7 B Q.8 C Q.9 B Q.10 C
Q.11 B Q.12 C Q.13 B Q.14 B Q.15 C
Q.16 B Q.17 C Q.18 D Q.19 A Q.20 A
Q.21 D Q.22 D Q.23 B Q.24 A Q.25 A
Q.26 A Q.27 C Q.28 C Q.29 B Q.30 A
Q.31 D Q.32 B Q.33 D Q.34 ACD Q.35 AC
Q.36 BD Q.37 BD Q.38 AC
Q.39 D Q.40 (A) Q , (B) R, (C) P, S Q.41 (A) Q; (B) P; (C) S; (D) R
Q.42 (A) P,R,S (B) P,Q (C) Q,T (D) S
Q.43 B Q.44 A Q.45 B Q.46 B Q.47 D
Q.48 B Q.49 B Q.50 A Q.51 B Q.52 C
Q.53 D