Hoja de Seguridad OXYVINYLS - MTR - ANSI - EN
Hoja de Seguridad OXYVINYLS - MTR - ANSI - EN
Hoja de Seguridad OXYVINYLS - MTR - ANSI - EN
M40722 -
ANSI-North America Subformat ANSI EN
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Trade Name: OxyVinylsÒ 155, 155F, 185, 185F, 190F, 195, 195F, 200, 200F, 216, 216A, 216S,
220, 220F, 225, 225A, 225P, 226, 226F, 240, 240F, 240TH, 255, 255F, 280, 310,
355, 450F, 500, 500F
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OSHA REGULATORY STATUS: This material is considered hazardous by the OSHA Hazard Communication
Standard (29 CFR 1910.1200).
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EMERGENCY OVERVIEW:
Color: White
Physical State: Solid
Appearance: Powder, Granular
Odor: Odorless
MAJOR HEALTH HAZARDS: MAY CAUSE DAMAGE TO RESPIRATORY SYSTEM THROUGH PROLONGED OR
REPEATED EXPOSURE. MAY BE IRRITATING TO EYES. POLYVINYL CHLORIDE CONTAINS VINYL CHLORIDE.
VINYL CHLORIDE IS A CANCER-SUSPECT AGENT. THIS PRODUCT CONTAINS VINYL CHLORIDE MONOMER
(VCM) AT CONCENTRATIONS OF 10 PPM OR LESS (<0.001%).
PHYSICAL HAZARDS: Use methods to minimize generation of dust. PVC dust is capable of propagating a
secondary dust explosion.
PRECAUTIONARY STATEMENTS: Do not breathe dust. Avoid contact with skin, eyes and clothing. Keep container
tightly closed and properly labeled. Wash thoroughly after handling. Use only with adequate ventilation.
ADDITIONAL HAZARD INFORMATION: Fumes produced in processing may irritate respiratory tract, skin, and
eyes. This material causes mild mechanical irritation to skin and eyes. Good hygiene and safety practices should be
used when handling and working with this material. Good hygiene practices include but are not limited to: wearing
suitable gloves and/or eye protection; washing hands and affected skin immediately after handling, before breaks, and
at the end of the workday; regularly cleaning work area and clothing; etc.
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GHS CLASSIFICATION:
GHS: TARGET ORGAN TOXICITY (REPEATED Category 2 - May cause damage to lungs and respiratory
EXPOSURE): system through prolonged or repeated exposure
GHS: CARCINOGENICITY: Not classified as a carcinogen per GHS criteria
This product is not classified as a carcinogen by NTP,
IARC or OSHA
This material does not contain vinyl chloride monomer
(VCM) at high enough levels to classify it as a carcinogen
UNKNOWN ACUTE TOXICITY: Not applicable. This product was tested as a whole. This information only pertains to
untested mixtures.
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INHALATION: If adverse effects occur, such as irritation, remove to uncontaminated area. Get medical attention if
you feel unwell.
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SKIN CONTACT: Wash contaminated areas with water. If irritation persists, get medical advice/attention.
EYE CONTACT: If in eyes, rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. If irritation occurs, get medical advice/attention.
INGESTION: No expected effect. If large amounts are ingested, GET MEDICAL ATTENTION.
Delayed Symptoms/Effects:
- Inhalation of high levels of respirable PVC particles has been associated with pulmonary fibrosis, a PVC
pneumoconiosis, in several studies. Laboratory findings included small opacities on chest x-ray and impairment of
lung function (restriction or reversible airway obstruction)
- Occupational asthma has been reported
- Respirable particles are less than 10 microns in size. Particles associated with suspension polymerization are
typically greater than 10 microns in size
- This product contains less than 10 ppm of vinyl chloride monomer (VCM)
Medical Conditions Aggravated by Exposure: Respiratory conditions including asthma and other breathing
disorders.
Protection of First-Aiders: Do not breathe dust. Avoid contact with skin and eyes. Use personal protective
equipment. Refer to Section 8 for specific personal protective equipment recommendations. At minimum, treating
personnel should utilize PPE sufficient for prevention of bloodborne pathogen transmission.
Notes to Physician: This material causes mild mechanical irritation to skin and eyes. Removing the material via
irrigation is usually sufficient.
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Fire Hazard: Slight fire hazard. Although unlikely, dust/air mixtures may pose a limited risk of explosion under certain
conditions (see Section 7).
Explosive properties: Minimize dust formation. PVC dust is capable of propagating a secondary dust explosion.
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Fire Fighting: Move container from fire area if it can be done without risk. Avoid inhalation of material or combustion
by-products. Wear NIOSH approved positive-pressure self-contained breathing apparatus operated in pressure
demand mode. Cool extinguished material to prevent decomposition.
Hazardous Combustion Products: Phosgene, Hydrogen chloride, Oxides of carbon, Small amounts of benzene
and aromatic and aliphatic hydrocarbons
Sensitivity to Static Discharge: Electrostatic charges may build up during handling. Ground equipment.
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Personal Precautions:
Keep unnecessary people away, isolate hazard area and deny entry. Eliminate all sources of ignition. Ground
equipment. Do not breathe dust. Avoid contact with skin and eyes. Wear appropriate personal protective equipment
recommended in Section 8, Exposure Controls / Personal Protection, of the SDS.
Environmental Precautions:
Keep out of water supplies and sewers. Releases should be reported, if required, to appropriate regulatory agencies.
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Component OSHA Final PEL OSHA Final PEL OSHA Final PELCeiling
TWA STEL
Particles Not Otherwise Regulated 15 mg/m3 (Total) ----- -----
(PNOR) 5 mg/m3 (Respirable)
00-00-001
Vinyl chloride 1 ppm 5 ppm -----
75-01-4
OEL: Occupational Exposure Limit; OSHA: United States Occupational Safety and Health Administration;
PEL: Permissible Exposure Limit; TWA: Time Weighted Average; STEL: Short Term Exposure Limit
- The American Conference of Governmental Industrial Hygienists (ACGIH) is a voluntary organization of professional industrial
hygiene personnel in government or educational institutions in the United States. The ACGIH develops and publishes
recommended occupational exposure limits each year called Threshold Limit Values (TLVs) for hundreds of chemicals, physical
agents, and biological exposure indices.
Additional Advice:
1. The fabrication processes for the final product may involve coating, calendering, and molding. To assess the
health hazards associated with exposure to compounded PVC dusts, it may be necessary to have information on the
ingredients used in the compounding of the resin
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ENGINEERING CONTROLS: Provide local exhaust ventilation where dust or vapors may be generated. Ensure
compliance with applicable exposure limits.
Eye Protection: Use good hygiene practices when handling this material. Safety glasses with side-shields or
goggles are recommended when there is a potential for eye contact.
Skin and Body Protection: As a good hygiene practice, wear protective clothing to minimize skin contact such
as standard industrial work clothes, coveralls, safety footwear.
Hand Protection: As a good hygiene practice, wear appropriate chemical resistant gloves. Consult a glove
supplier for assistance in selecting an appropriate chemical resistant glove.
Respiratory Protection: A NIOSH approved respirator with N95 (dust, fume, mist) cartridges may be permissible
under certain circumstances where airborne concentrations are expected to exceed exposure limits, or when
symptoms have been observed that are indicative of overexposure. The added protection of a full face-piece
respirator is required when visible dusty conditions are encountered and eye irritation may occur. A respiratory
protection program that meets 29 CFR 1910.134 must be followed whenever workplace conditions warrant use of
a respirator.
HYGIENE MEASURES: Handle in accordance with good industrial hygiene and safety practices. Good hygiene
practices include but are not limited to: wearing suitable gloves and/or eye protection; washing hands and affected
skin immediately after handling, before breaks, and at the end of the workday; regularly cleaning work area and
clothing; etc.
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Possibility of Hazardous Reactions: Avoid heat, flames, sparks and other sources of ignition.
Hazardous Decomposition Products: Hydrochloric acid, Carbon oxides, Small amounts of benzene and aromatic
and aliphatic hydrocarbons, phosgene
Hazardous Polymerization: PVC is a stable polymer and will not further polymerize. This material will not
depolymerize to form VCM.
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TOXICITY DATA:
PRODUCT TOXICITY DATA: OXYVINYLSÒ PVC HOMOPOLYMER SUSPENSION RESIN (PRIME GRADES)
LD50 Oral: LD50 Dermal: LC50 Inhalation:
No data available No data available No data available
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Eye contact: Eye exposure may cause mild irritation of the eye lids and conjunctiva. May cause
eye irritation from the mechanical action of lodged particles.
Skin contact: This material is unlikely to cause chemical skin irritation. Skin irritation may occur
due to mechanical action. Exposing skin to powder or fine particulate may cause
slight redness, irritation.
Inhalation: No known effects. Inhalation of powder or fine particulates may cause irritation,
cough.
Ingestion: No known effects. This material is practically non-toxic by the oral route.
Chronic Effects: Chronic exposure to the respirable fraction (particles less than 10 microns in size)
of PVC particles, may produce pulmonary fibrosis. Particle sizes associated with
suspension polymerization are typically greater than 10 microns in size. Product
contains residual amounts of VCM, concentrations are less than 10
ppm(<0.001%).
ACUTE TOXICITY:
Vinyl chloride monomer (VCM) is NOT likely to be present at levels that would produce an acute biological effect
when used in a well ventilated area. Acute biological effects of VCM include CNS and respiratory depression.
CHRONIC TOXICITY:
The available evidence from experimental animals and from humans indicates that pure PVC is not metabolized in
mammals. Several studies have described pulmonary fibrosis from inhalation of high levels of respirable PVC
particles. PVC resin particles generated by suspension polymerization are generally large enough in diameter that
the majority are not considered respirable. Vinyl chloride monomer (VCM) is NOT likely to be present at levels that
would produce a chronic biological effect when used in a well ventilated area. Chronic biological effects of VCM
include damage to the liver, which causes angiosarcoma of the liver (a rare form of liver cancer in humans),
Raynaud's syndrome, and acroosteolysis (bone loss in finger tips). Long latent period may exist between exposure
and symptom onset.
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GHS: CARCINOGENICITY:
Not classified as a carcinogen per GHS criteria. This product is not classified as a carcinogen by NTP, IARC or
OSHA. This material does not contain vinyl chloride monomer (VCM) at high enough levels to classify it as a
carcinogen.
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ECOTOXICITY DATA:
Aquatic Toxicity:
No data available
This material is believed to be practically non-toxic to aquatic life
BIODEGRADATION: PVC will not biodegrade. Vinyl chloride may degrade under anaerobic conditions.
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Container Management:
Dispose of container in accordance with applicable local, regional, national, and/or international regulations. Container
rinsate must be disposed of in compliance with applicable regulations.
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LAND TRANSPORT
U.S. DOT 49 CFR 172.101:
Status: Not Regulated.
CANADIAN TRANSPORTATION OF DANGEROUS GOODS:
Status: Not Regulated.
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U.S. REGULATIONS
DEPARTMENT OF HOMELAND SECURITY (DHS)- Chemical Facility Anti-Terrorism Standards (6 CFR 27):
No components in this material are regulated under DHS
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CHLORIDE IS A CANCER SUSPECT AGENT. [NOTE: Although the OSHA Vinyl Chloride Standard requires this
specific language for containers of PVC resins, vinyl chloride is classified by IARC and NTP as a known human
carcinogen].
Canadian Chemical Inventory: All components of this product are listed on either the DSL or the NDSL.
STATE REGULATIONS
Component California California California Massachusetts New Jersey Right New Jersey
Proposition 65 Proposition 65 Proposition 65 Right to Know to Know Special Health
Cancer CRT List - Male CRT List - Female Hazardous Hazardous Hazards
WARNING: reproductive reproductive Substance List Substance List Substance List
toxin: toxin:
Ethene, chloro-, Not Listed ----- ----- ----- 3622 -----
homopolymer
(PolyVinyl Chloride)
9002-86-2
Vinyl chloride Not Listed ----- ----- Listed 2001 carcinogen;
75-01-4 flammable -
fourth degree;
mutagen
Component New Jersey - Pennsylvania Right Pennsylvania Right Pennsylvania Right Rhode Island Right
Environmental to Know Hazardous to Know Special to Know to Know Hazardous
Hazardous Substance List Hazardous Environmental Substance List
Substance List Substances Hazard List
Vinyl chloride Listed Present Present Not Listed
75-01-4
CANADIAN REGULATIONS
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the SDS contains all the information required by the Controlled Products Regulations
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IMPORTANT:
The information presented herein, while not guaranteed, was prepared by technical personnel and is true and
accurate to the best of our knowledge. NO WARRANTY OF MERCHANTABILITY OR OF FITNESS FOR A
PARTICULAR PURPOSE, OR WARRANTY OR GUARANTY OF ANY OTHER KIND, EXPRESSED OR IMPLIED, IS
MADE REGARDING PERFORMANCE, SAFETY, SUITABILITY, STABILITY OR OTHERWISE. This information is
not intended to be all-inclusive as to the manner and conditions of use, handling, storage, disposal and other factors
that may involve other or additional legal, environmental, safety or performance considerations, and OxyChem
assumes no liability whatsoever for the use of or reliance upon this information. While our technical personnel will be
happy to respond to questions, safe handling and use of the product remains the responsibility of the customer. No
suggestions for use are intended as, and nothing herein shall be construed as, a recommendation to infringe any
existing patents or to violate any Federal, State, local or foreign laws
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OSHA Standard 29 CFR 1910.1200 requires that information be provided to employees regarding the hazards of
chemicals by means of a hazard communication program including labeling, safety data sheets, training and access
to written records. We request that you, and it is your legal duty to, make all information in this Safety Data Sheet
available to your employees
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