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FBF FPF: Inorganic Chemistry QUIZ # 03 Time: 10 Min

This document contains an inorganic chemistry quiz with multiple choice and matching questions testing knowledge of topics including: 1. Back bonding and its effects on bond angles, strengths, and hybridization in molecules like PF3, BF3, N(SiH3)3, and OCl2. 2. Hybridization, bond angles, and characteristics of molecules such as AsH3, SbH3, XeO4, SO32-, BF2Cl, and CFClBrI. 3. The role of back bonding in properties including acidity, planarity, bond lengths, and stability in systems like B3N3H6, BF3, BCl3, SiH3

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424 views

FBF FPF: Inorganic Chemistry QUIZ # 03 Time: 10 Min

This document contains an inorganic chemistry quiz with multiple choice and matching questions testing knowledge of topics including: 1. Back bonding and its effects on bond angles, strengths, and hybridization in molecules like PF3, BF3, N(SiH3)3, and OCl2. 2. Hybridization, bond angles, and characteristics of molecules such as AsH3, SbH3, XeO4, SO32-, BF2Cl, and CFClBrI. 3. The role of back bonding in properties including acidity, planarity, bond lengths, and stability in systems like B3N3H6, BF3, BCl3, SiH3

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honey1002
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© © All Rights Reserved
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Download as PDF, TXT or read online on Scribd
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TM

Path to success KOTA (RAJASTHAN)

INORGANIC CHEMISTRY QUIZ # 03 TIME : 10 MIN.

SECTION–I (i) : (Maximum Marks : 27)


 This section contains NINE questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four option(s) is correct.
 For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
 Marking scheme :
+3 If only the bubble(s) corresponding to all the correct option(s) is (are) darkened
0 If none of the bubbles is darkened
–1 In all other cases
1. In which of the following cases the increase in bond angle is not due to back bonding.
 angle in CH OCH .
(A) COC 
(B) SiNSi angle in N(SiH3)3.
3 3

 angle in BF .
(C) FBF  angle in PF .
(D) FPF
3 3
2. Which of the following molecule has large extent of back bonding :-
(A) O(SiH3)2 (B) OCl2
(C) Both has same extent of back bonding (D) None of these
3. Choose the incorrect statement from the following-
(A) Bond angles are not affected in BF3 due to back bonding
(B) Bond angles are affected in PF3 due to back bonding
(C) Bond angles are not affected in B(OMe)3 due to back bonding
(D) None of these
4. There is no hybridisation of the central atom in AsH3 because :-
(A) As is of 3rd period element
(B) The energy gap between 3s and 3p orbital is large enough
(C) The energy gap between 3s and 3p orbital is sufficiently less
(D) The energy gap between 4s and 4p orbital is large enough
5. In which of the following cases, the strength of back bonding is maximum :-
(A) PF3 (B) BF3 (C) (H3Si)3N (D) (SiH3)2O
6. If the %- s-character in one Sb-H bond in SbH3 is 1.0%. What is % p-character is the orbital occupied
by its lone pair -
(A) 99.0 (B) 97 (C) 90 (D) None
7. In which of the following cases, the direction of back bonding is from central atom to surrounding
atom.
(A) PCl3 (B) PF3 (C) OCl2 (D) :CCl2

INORGANIC CHEM. / QUIZ # 03 E-1 / 4


TM

Path to success KOTA (RAJASTHAN )

8. Choose the correct statement regarding bond angle :-


 in F CO < HCH
(A) FCF  in H2CO 
(B) BrPBr  in PF
in PBr3 < FPF
2 3


(C) FSF(eq) 
 FSF(ax) in SF4  angles in IF are identical
(D) All FIF 5

9. Which of the following molecule has minimum % s-character in it's hybrid orbital for the underline d
atom :
(A) XeO4 (B) XeO2F4 (C) H3PO4 (D) H2CCH–CH3
SECTION–I (ii) : (Maximum Marks : 12)
 This section contains THREE questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these
four option(s) is (are) correct.
 For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
 Marking scheme :
+4 If only the bubble(s) corresponding to all the correct option(s) is (are) darkened
0 In all other cases
10. Which of the following correct order of bond angle is / are -
(A) SCl2 > OCl2 (B) OCl2 > OF2 (C) AsF3 > AsH3 (D) BF3 > H3O+
11. Which of following the molecule (s) has/have back bonding -
(A) N(SiH3)3 (B) BF3 (C) OCl2 (D) BF4–
12. Select the correct statements :
(A) When lone pair of surrounding atom is involved in back bonding then bond angle does not change
any where
(B) When lone pair of central atom is involved in back bonding then bond angle does not change
(C) In B3N3H6 all B – N bond lengths are equal and these are shorter than the single B – N covalent
bonds due to delocalisation of  e¯
(D) BF3, BCl3 are gaseous BBr3 liquid and BI3 solid because when size increases instantaneous
dipole-induced dipole interaction increases
SECTION–I(iii) : (Maximum Marks : 9)
 This section contains ONE paragraphs.
 Based on each paragraph, there will be THREE questions
 Each question has FOUR options (A), (B), (C) and (D) ONLY ONE of these four option(s) is correct.
 For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
 Marking scheme :
+3 If only the bubble(s) corresponding to all the correct option(s) is(are) darkened
0 In all other cases
Pagragraph for Q.No. 13 to 15
Back bonding may change the angle, bond strength and even if state of hybridisation also of a molecule.
13. If back bonding does not occur in N(SiH3)3, then what will be the hybridisation of N and Si-atoms.
(A) sp2, sp3 (B) sp2, sp2 (C) sp3, sp2 (D) sp3, sp3

Inorganic / Quiz # 03 E-2/4


TM

Path to success KOTA (RAJASTHAN )

14. In which of the following phenomenon on the back bonding has no role
(A) Higher acidic character of SiH3OH compared to C2H5OH
(B) Planarity of B3N3H6
(C) Bond angle changes in B(OCH3)3
(D) None of these
15. Back–bonding plays a central role in the following phenomena :
(A) B–X bond length is lower in BF3 as compared to BCl3
(B) Stronger acidic strength of (CH3)3SiOH as compared to (CH3)3COH
(C) Less lewis basic strength of (SiH3)3N as compared to (CH3)3N

(D) Less stability of Si=Si as compared to C=C

SECTION–II : (Maximum Marks : 8)


 This section contains ONE questions.
 Each question contains two columns, Column-I and Column-II.
 Column-I has four entries (A), (B), (C) and (D)
 Column-II has five entries (P), (Q), (R), (S) and (T)
 Match the entries in Column-I with the entries in column-II.
 One or more entries in Column-I may match with one or more entries in Column-II.
 The ORS contains a 4 × 5 matrix whose layout will be similar to the one shown below :
(A) (P) (Q) (R) (S) (T)

(B) (P) (Q) (R) (S) (T)

(C) (P) (Q) (R) (S) (T)

(D) (P) (Q) (R) (S) (T)


 For each entry in column-I, darken the bubbles of all the matching entries. For example, if entry (A)
in Column-I matches with entries (Q), (R) and (T), then darken these three bubbles in the ORS. Similarly,
for entries (B), (C) and (D).
 Marking scheme :
For each entry in Column-I
+2 If only the bubble(s) corresponding to all the correct match(es) is (are) darkened
0 In all other cases

1. Match the column


Column-I Column-II
(Molecules/Species) (Characteristics which is/are not correct for the
given molecule/species in column-I)
(A) CFClBrI (P) All possible bond angles are identical
(B) XeF4 (Q) Specie/ molecule is planar
(C) SO32– (R) Specie/ molecule is non-polar
(D) BF2Cl (S) Specie/ molecule is non-planar
(T) All possible bond angles are different

Inorganic / Quiz # 03 E-3/4


TM

Path to success KOTA (RAJASTHAN )

SECTION–IV : (Maximum Marks : 16)


 This section contains FOUR questions.
 The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive
 For each question, darken the bubble corresponding to the correct integer in the ORS
 Marking scheme :
+4 If only the bubble(s) corresponding to all the correct option(s) is (are) darkened
0 If none of the bubbles is darkened
–1 In all other cases
1. The number of molecules is / are linear shape with respect to underlined atom :
CH3NCS, SiH3NCS, GeH3NCS, C3O2, (CH3)2O, (SiH3)2O
2. The number of species which consists of sp3d hybridised central atom for the underlined atoms with
in the following species / molecules is / are :

XeF4 , ICl2 , XeO2F2 , PCl4 , PCl6 , SF4, SOF4, XeOF4
3. The number of molecules is / are pyramidal shape :
XeO3, NCl3, ClF3, P(SiH3)3, N(SiH3)3
4. Find number of molecule(s) has / have 3p – 2p back bonding.
OCl2 :CCl2 BCl3 CCl3

Inorganic / Quiz # 03 E-4/4

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