Safety Data Sheet: Dimethylaminopropylamine (DMAPA)
Safety Data Sheet: Dimethylaminopropylamine (DMAPA)
Safety Data Sheet: Dimethylaminopropylamine (DMAPA)
Dimethylaminopropylamine (DMAPA)
Revision date : 2006/04/24 Page: 1/7
Version: 1.0 (30076701/MDS_GEN_US/EN)
2. Composition/information on ingredients
CAS Number Content (W/W) Chemical name
109-55-7 80.0 - 100.0 % 3-aminopropyldimethylamine
124-40-3 1.0 - 5.0 % dimethylamine
3. Hazard identification
Emergency overview
DANGER: CORROSIVE. FLAMMABLE LIQUID. Corrosive to the skin, eyes and respiratory system.
RISK OF SERIOUS DAMAGE TO EYES.
CAUSES SEVERE BURNS.
HARMFUL IF SWALLOWED.
HARMFUL IF INHALED.
HARMFUL IF ABSORBED THROUGH SKIN.
INGESTION MAY CAUSE GASTRIC DISTURBANCES.
Danger of skin sensitization on repeated contact.
Avoid contact with the skin, eyes and clothing.
Avoid inhalation of mists/vapours.
Use with local exhaust ventilation.
Wear NIOSH-certified chemical goggles.
Wear full face shield if splashing hazard exists.
Wear chemical resistant protective gloves.
Wear protective clothing.
Eye wash fountains and safety showers must be easily accessible.
4. First-aid measures
General advice:
Remove contaminated clothing.
If inhaled:
Remove the affected individual into fresh air and keep the person calm. Assist in breathing if necessary.
Immediate medical attention required.
If on skin:
Wash affected areas thoroughly with soap and water. Remove contaminated clothing. Wash soiled clothing
immediately. Immediate medical attention required.
If in eyes:
In case of contact with the eyes, rinse immediately for at least 15 minutes with plenty of water. Immediate
medical attention required.
If swallowed:
Do not induce vomiting. Rinse mouth and then drink plenty of water. Never induce vomiting or give anything
by mouth if the victim is unconscious or having convulsions. Immediate medical attention required.
5. Fire-fighting measures
Flash point: -5.2 °C
Autoignition: approx. 220 °C (DIN 51794)
Lower explosion limit: 2.3 %(V)
Upper explosion limit: 12.4 %(V)
Further information:
Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems.
Environmental precautions:
Substance/product is RCRA hazardous due to its properties.
Cleanup:
Spills should be contained, solidified, and placed in suitable containers for disposal.
Safety data sheet
Dimethylaminopropylamine (DMAPA)
Revision date : 2006/04/24 Page: 3/7
Version: 1.0 (30076701/MDS_GEN_US/EN)
Storage
General advice:
Avoid extreme heat. Avoid all sources of ignition: heat, sparks, open flame. Keep away from sources of
ignition - No smoking.
Storage incompatibility:
General: Segregate from acids and acid forming substances.
Hand protection:
Chemical resistant protective gloves, Consult with glove manufacturer for testing data.
Eye protection:
Tightly fitting safety goggles (chemical goggles). Wear face shield if splashing hazard exists.
Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. head protection, apron,
protective boots, chemical-protection suit.
Substances to avoid:
strong acids
Hazardous reactions:
Strong exothermic reaction with acids.
The product is chemically stable.
Reacts with oxidizing agents.
Corrosion to metals:
Corrosive effect on metals.
Oral:
LD50/rat: approx. 1,640 mg/kg
Moderately toxic.
LD50/rat:
Moderately toxic.
Inhalation:
Dermal:
Skin irritation:
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Eye irritation :
rabbit: Corrosive.
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Safety data sheet
Dimethylaminopropylamine (DMAPA)
Revision date : 2006/04/24 Page: 5/7
Version: 1.0 (30076701/MDS_GEN_US/EN)
Sensitization:
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Chronic toxicity
Experiences in humans:
Information on: 3-aminopropyldimethylamine
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Other information:
Together with nitrosating agents (f. i. nitrites, nitrogen oxides) nitrosamines may be formed under certain
conditions. Nitrosamines showed a carcinogenic effect in animal experiment.
Container disposal:
Empty containers with less than 1 inch of residue may be landfilled at a licensed facility. Recommend
crushing, puncturing or other means to prevent unauthorized use of used containers. If containers are not
empty, they must be disposed of in a RCRA-licensed facility.
RCRA: D001
Land transport
USDOT
Proper shipping name: FLAMMABLE LIQUID, TOXIC, CORROSIVE, N.O.S. (contains 3-
AMINOPROPYLDIMETHYLAMINE)
Hazard class: 3
ID-number: UN 3286
Packing group: II
Sea transport
IMDG
Proper shipping name: FLAMMABLE LIQUID, TOXIC, CORROSIVE, N.O.S. (contains 3-
AMINOPROPYLDIMETHYLAMINE, , , )
Hazard class: 3
ID-number: UN 3286
Packing group: II
Marine pollutant: NO
Air transport
IATA/ICAO
Proper shipping name: FLAMMABLE LIQUID, TOXIC, CORROSIVE, N.O.S. contains (3-
AMINOPROPYLDIMETHYLAMINE, , )
Hazard class: 3
ID-number: UN 3286
Packing group: II
Registration status:
TSCA, US released / listed
OSHA hazard category: Flammable Liquid, Toxic - dermal, Acute target organ effects reported,
Corrosive to skin and/or eyes, Toxic - inhalation, Toxic - oral, Sensitizer, OSHA PEL established
State regulations
State RTK
HMIS uses a numbering scale ranging from 0 to 4 to indicate the degree of hazard. A value of zero means that the
substance possesses essentially no hazard; a rating of four indicates high hazard.
IMPORTANT: WHILE THE DESCRIPTIONS, DESIGNS, DATA AND INFORMATION CONTAINED HEREIN
ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE , IT IS PROVIDED FOR YOUR
GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE,
WE RECOMMEND THAT YOU MAKE TESTS TO DETERMINE THE SUITABILITY OF A PRODUCT FOR
YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER
EXPRESSED OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A
PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR
INFORMATION SET FORTH, OR THAT THE PRODUCTS, DESIGNS, DATA OR INFORMATION MAY BE
USED WITHOUT INFRINGING THE INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASE
SHALL THE DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE CONSIDERED A
PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, YOU EXPRESSLY UNDERSTAND AND
AGREE THAT THE DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION FURNISHED BY BASF
HEREUNDER ARE GIVEN GRATIS AND BASF ASSUMES NO OBLIGATION OR LIABILITY FOR THE
DESCRIPTION, DESIGNS, DATA AND INFORMATION GIVEN OR RESULTS OBTAINED, ALL SUCH
BEING GIVEN AND ACCEPTED AT YOUR RISK.
END OF DATA SHEET