Fomtec AFFF 6% A Page 1 of 8

SAFETY DATA SHEET

Fomtec AFFF 6% A
SECTION 1: Identification of the substance/mixture and of the
company/undertaking
Date issued 12.11.2012
Revision date 30.10.2013
1.1. Product identifier
Product name Fomtec AFFF 6% A
Article no. 10-6004-XX
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/preparation Appliance protection.
1.3. Details of the supplier of the safety data sheet
Company name Dafo Fomtec AB
Office address Garnisonsg. 47 A, Helsingborg
Postal address Box 683
Postcode S-13526
City Tyresö
Country Sweden
Tel + 46 850640500
E-mail [email protected]
Website http://www.fomtec.com/
1.4. Emergency telephone number
Emergency telephone National Poisons Information Service London:+44 20 7771 5394

SECTION 2: Hazards identification

2.1. Classification of substance or mixture
Substance / mixture hazardous Not regarded as a health or environmental hazard under current legislation.
properties
2.2. Label elements
Precautionary statements P264 Wash thoroughly after handling. P280 Wear protective gloves/protective
clothing/eye protection/face protection. P305 + P351 + P338 IF IN EYES:
Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. P337 + P313 If eye irritation
persists: Get medical advice/attention.
2.3. Other hazards

SECTION 3: Composition/information on ingredients

3.2. Mixtures
Substance Identification Classification Contents
Monopropylene glycol CAS no.: 57-55-6 2-6%
EC no.: 200-338-0
IUPAC name: Propane-1,2-diol
Sodium Alkyl Sulfate CAS no.: 90583-25-8 Xi; R38,R41 1-4%
EC no.: 292242 Skin Irrit. 2;H315
Eye Irrit. 2;H318

Revision date 30.10.2013

Fomtec AFFF 6% A Page 2 of 8
Diethylene glycol monobutyl ether CAS no.: 112-34-5 Xi; R36 5 - 10 %
EC no.: 203-961-6 Eye Irrit. 2; H319
Index no.: 603-096-00-8
Synonyms: 2-(2-Butoxyethoxy)
ethanol
Column headings CAS no. = Chemical Abstracts Service; EU (Einecs or Elincs number) =
European inventory of Existing Commercial Chemical Substances; Ingredient
name = Name as specified in the substance list (substances that are not
included in the substance list must be translated, if possible). Contents given
in; %, %wt/wt, %vol/wt, %vol/vol, mg/m3, ppb, ppm, weight%, vol%
HH/HF/HE T+ = Very toxic, T = Toxic, C = Corrosive, Xn = Harmful, Xi = Irritating, E
= Explosive, O = Oxidizing, F+ = Extremly flammable, F = Very flammable,
N = Environmental hazard

SECTION 4: First aid measures

4.1. Description of first aid measures
General Provide rest, warmth and fresh air. Get medical attention if any discomfort
continues.
Inhalation Fresh air and rest. Get medical attention if any discomfort continues.
Skin contact Remove contaminated clothing and launder thoroughly before re-use. Wash
skin thoroughly with soap and water for several minutes. Get medical attention
if any discomfort continues.
Eye contact Immediately rinse with water for several minutes. Make sure to remove any
contact lenses from the eyes before rinsing.
Ingestion Immediately rinse mouth and drink plenty of water. Keep person under
observation. If person becomes uncomfortable seek hospital and bring these
instructions.
Recommended personal protective No recommendation given.
equipment for first aid responders
4.2. Most important symptoms and effects, both acute and delayed
Information for health personnel Get medical attention if any discomfort continues.
4.3. Indication of any immediate medical attention and special treatment needed
Medical monitoring for delayed No recommendation given.
effects
Separate first aid equipment No recommendation given.

SECTION 5: Firefighting measures

5.1. Extinguishing media
5.2. Special hazards arising from the substance or mixture
5.3. Advice for firefighters
Fire fighting procedures Protective equipment for fire-fighters:

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
Personal protection measures Avoid contact with skin and eyes. Do not breathe vapour. For personal
protection, see section 8.
6.2. Environmental precautions
Environmental precautionary Prevent discharge of larger quantity to drain. Avoid discharge to the aquatic
measures environment.
6.3. Methods and material for containment and cleaning up
Cleaning method Absorb with sand or other inert absorbent. Flush area clean with lots of

Revision date 30.10.2013

Fomtec AFFF 6% A Page 3 of 8
water. Be aware of potential for surfaces to become slippery. For waste
disposal, see section 13.
6.4. Reference to other sections

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Handling Avoid contact with skin and eyes. Avoid inhalation of vapours. Wash hands
before breaks and before smoking, eating or drinking. Wash hands and
contaminated areas with water and soap after finished work. Container must
be kept tightly closed.
7.2. Conditions for safe storage, including any incompatibilities
Storage Store at moderate temperatures in dry, well ventilated area. Keep containers
tightly closed. Protect against direct sunlight.
7.3. Specific end use(s)

SECTION 8: Exposure controls/personal protection

8.1. Control parameters
Occupational Exposure limit values
Substance Identification Value TWA Year
Monopropylene glycol CAS no.: 57-55-6 8-hour TWA: 150 ppm
EC no.: 200-338-0 WEL

Sodium Alkyl Sulfate CAS no.: 90583-25-8

EC no.: 292242
Diethylene glycol monobutyl ether CAS no.: 112-34-5 8-hour TWA: 10 ppm 2011
EC no.: 203-961-6 8-hour TWA: 67,5 mg/m3
Index no.: 603-096-00-8 15 min.: 15 ppm
Synonyms: 2-(2-Butoxyethoxy) 15 min.: 101,2 mg/m3
ethanol
Substance Monopropylene glycol
Recommended type of equipment No recommendation given.
Suitable gloves type Nitrile gloves are recommended.
Eye protection If risk of splashing, wear safety goggles or face shield.
DNEL / PNEC from substances
Substance Monopropylene glycol
DNEL Group: Consumer
Exposure route: Inhalation
Exposure frequency: Long term (repeated)
Type of effect: Systemic effect
Value: 50 mg/m3
DNEL Group: Worker
Exposure route: Inhalation
Exposure frequency: Long term (repeated)
Type of effect: Local effect
Value: 10 mg/m3
DNEL Group: Worker
Exposure route: Inhalation
Exposure frequency: Long term (repeated)
Type of effect: Systemic effect
Value: 168 mg/m3
PNEC Exposure route: Soil
Value: 50 mg/kg soil dw

Revision date 30.10.2013

Fomtec AFFF 6% A Page 4 of 8
PNEC Exposure route: Water
Value: 183 mg/l
Remarks: Intermittent realeases water
PNEC Exposure route: Water
Value: 26 mg/l
Remarks: Marine water
PNEC Exposure route: Water
Value: 260 mg/l
Remarks: Fresh water
Substance Sodium Alkyl Sulfate
DNEL Group: Consumer
Exposure route: Dermal
Exposure frequency: Long term (repeated)
Type of effect: Systemic effect
Value: 2440 mg/kg bw7day
DNEL Group: Consumer
Exposure route: Inhalation
Exposure frequency: Long term (repeated)
Type of effect: Systemic effect
Value: 85 mg/m3
DNEL Group: Consumer
Exposure route: Oral
Exposure frequency: Long term (repeated)
Type of effect: Systemic effect
Value: 24 mg/kg bw/day
DNEL Group: Worker
Exposure route: Dermal
Exposure frequency: Long term (repeated)
Type of effect: Systemic effect
Value: 4060 mg/kg bw/day
DNEL Group: Worker
Exposure route: Inhalation
Exposure frequency: Long term (repeated)
Type of effect: Systemic effect
Value: 285 mg/m3
PNEC Exposure route: Water
Critical Component: Fresh water
Value: 0,112 mg/l
PNEC Exposure route: Water
Critical Component: Marine water
Value: 0,0112 mg/l
PNEC Exposure route: Sediment
Critical Component: Fresh water
Value: 1,25 mg/l
PNEC Exposure route: Sediment
Critical Component: marine water
Value: 0,125 mg/l
PNEC Exposure route: Sewage treatment plant STP
Value: 1,35 mg/l
PNEC Exposure route: Soil
Value: 0,185 mg/l
8.2. Exposure controls
Respiratory protection
Respiratory protection Under normal conditions of use respiration protection should not be required.
Hand protection
Revision date 30.10.2013
Fomtec AFFF 6% A Page 5 of 8
Hand protection Protective gloves must be used if there is a risk of direct contact or splash.
Suitable gloves type Rubber or plastic.
Eye / face protection
Eye protection Use approved safety goggles or face shield.
Skin protection
Skin protection (except hands) Use protective clothing, which covers arms and legs.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state Clear, yellowish liquid.
Colour Yellowish.
Odour Slight odour.
pH (as supplied) Value: 6,5-8,5
Freezing point Value: ~ -1 °C
Specific gravity Value: ~ 1,005 g/ml
Solubility description Completely soluble in water.
Viscosity Value: 20 mPas
Method of testing: Brookfield DV
9.2. Other information

SECTION 10: Stability and reactivity

10.1. Reactivity
Reactivity There are no known conditions that are likely to result in a hazardous
situation.
10.2. Chemical stability
Stability Stable under the prescribed storage conditions.
10.3. Possibility of hazardous reactions
Possibility of hazardous reactions None.
10.4. Conditions to avoid
Conditions to avoid Earth metals such as sodium, potassium and barium.
10.5. Incompatible materials
Materials to avoid Alkali earth metals.
10.6. Hazardous decomposition products
Hazardous decomposition products Thermal decomposition or combustion may liberate carbon oxides and other
toxic gases or vapours.

SECTION 11: Toxicological information

11.1. Information on toxicological effects
Toxicological data for substances
Substance Monopropylene glycol
LD50 oral Value: ~ 22000 mg/kg
Animal test species: Rat
LD50 dermal Value: > 2000 mg/kg
Animal test species: Rabbit
Substance Sodium Alkyl Sulfate
LD50 oral Value: > 2000 mg/kg
LD50 dermal Value: > 2000 mg/kg
Animal test species: Rat
Potential acute effects
Revision date 30.10.2013
Fomtec AFFF 6% A Page 6 of 8
Skin contact Liquid may irritate skin.
Eye contact Spray and vapour in the eyes may cause irritation and smarting.
Delayed effects / repeated exposure
Sensitisation No known chronic or acute health risks.
Carcinogenic, Mutagenic or Reprotoxic
Carcinogenicity No known chronic or acute health risks.
Mutagenicity No known chronic or acute health risks.
Reproductive toxicity No known chronic or acute health risks.

SECTION 12: Ecological information

12.1. Toxicity
Acute aquatic, fish Value: > 1700 mg/l
Fish, species: Rainbow Trout
Duration: 96 h
Acute aquatic, Daphnia Value: > 6000 mg/l
Daphnia, species: Daphnia Magna
Duration: 24 h
Aquatic, comments On basis of test data.
Toxicological data for substances
Substance Monopropylene glycol
Acute aquatic, fish Value: > 40613 mg/l
Species: not specified
Duration: 96hrs
Acute aquatic, algae Value: 19000 mg/l
Species: not specified
Acute aquatic, Daphnia Value: > 18340 mg/l
Species: Daphnia Magna
Duration: 48 hrs
Biodegradability Value: > 80 %
Test period: 28 days
Method of testing: OECD 301F
Substance Sodium Alkyl Sulfate
Acute aquatic, fish Value: ~ 110 mg/l
Method of testing: DIN 38412 T15
Species: Leuciscus Idus
Duration: 48 h
Acute aquatic, algae Value: > 100 mg/l
Species: Pseudokirchn. Subcapitata
Duration: 48 h
Acute aquatic, Daphnia Value: ~ 240 mg/l
Method of testing: DIN 38412 T11
Species: Daphnia Magna
Duration: 48 h
Persistence and degradability The product is easily biodegradable.
Biodegradability Value: ~ 60 %
Test period: 10 days
Chemical oxygen demand (COD) Value: 698 mg/l
Method of testing: DIN 38408 H41
Biological oxygen demand (BOD) Value: 494 mg/l
Test period: 5 days
Method of testing: EN 1899-1
12.2. Persistence and degradability
Biodegradability Value: ~ 92 %

Revision date 30.10.2013

Fomtec AFFF 6% A Page 7 of 8
Test period: 28 days
Persistence and degradability The product is expected to be biodegradable.
12.3. Bioaccumulative potential
Bioaccumulative potential Bioaccumulation: Is not expected to be bioaccumulable.
12.4. Mobility in soil
Mobility The product contains substances, which are water soluble and may spread in
water systems.
12.5. Results of PBT and vPvB assessment
PBT assessment results Not Classified as PBT/vPvB by current EU criteria.
12.6. Other adverse effects

SECTION 13: Disposal considerations

13.1. Waste treatment methods
Specify the appropriate methods of Dispose of waste and residues in accordance with local authority
disposal requirements.
Relevant waste regulation Directive 2008/98/EC of the European Parliament and of the Council of 19
November 2008 on waste and repealing certain Directives (Text with EEA
relevance).
EWC waste code EWC: 160305 organic wastes containing dangerous substances

SECTION 14: Transport information

14.1. UN number
Comments Not applicable. No information required.
14.2. UN proper shipping name
Comment Not applicable. No information required.
14.3. Transport hazard class(es)
Comment Not applicable. No information required.
14.4. Packing group
Comment Not applicable. No information required.
14.5. Environmental hazards
Comment Not applicable. No information required.
14.6. Special precautions for user
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Additional information.
Additional information. The product is not covered by international regulation on the transport of
dangerous goods (IMDG, IATA, ADR/RID).

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the
substance or mixture
EEC-directive COMMISSION REGULATION (EU) No 453/2010 of 20 May 2010 amending
Regulation (EC) No 1907/2006 of the European Parliament and of the Council
on the Registration, Evaluation, Authorisation and Restriction of Chemicals
(REACH). Methods of evaluating information (Art. 9 Regulation (EC) No
1272/2008): Dangerous Preparations Directive 1999/45/EC. Commission
Directive 2006/15/EC of 7 February 2006 establishing a second list of
indicative occupational exposure limit values in implementation of Council
Directive 98/24/EC and amending Directives 91/322/EEC and 2000/39/EC.

Revision date 30.10.2013

Fomtec AFFF 6% A Page 8 of 8
Legislation and regulations Directive 2008/68/EC of the European Parliament and of the Council of 24
September 2008 on the inland transport of dangerous goods (Text with EEA
relevance).
15.2. Chemical safety assessment
Chemical safety assessment Yes
performed

SECTION 16: Other information

List of relevant R-phrases (under R38 Irritating to skin.
headings 2 and 3). R36 Irritating to eyes.
R41 Risk of serious damage to eyes.
List of relevant H-phrases (Section H318 Causes Serious eye damage.
2 and 3). H319 Causes serious eye irritation.
H315 Causes skin irritation.
Responsible for safety data sheet Dafo Fomtec AB

Revision date 30.10.2013