Safety Data Sheet: Date Prepared: 3/16/2015 SDS No: N-444
Safety Data Sheet: Date Prepared: 3/16/2015 SDS No: N-444
WORKING COPY
PRODUCT DESCRIPTION: Low VOC Roller and Blanket Wash for Sheetfed and Web Presses
PRODUCT CODE: N-444
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
Health:
Acute Toxicity (Oral), Category 5
Skin Irritation, Category 3
Eye Irritation, Category 2B
Respiratory Tract Irritation, Category 3
Physical:
Flammable Liquids, Category 4
GHS LABEL
Flammable Liquid and Vapor
Exclamation
mark
SIGNAL WORD: WARNING
HAZARD STATEMENTS
H227: Combustible liquid.
H303: May be harmful if swallowed.
H316: Causes mild skin irritation.
H320: Causes eye irritation.
H335: May cause respiratory irritation.
PRECAUTIONARY STATEMENTS
Prevention:
P210: Keep away from heat, sparks, open flames and hot surfaces. – No smoking.
P233: Keep container tightly closed.
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P241: Use explosion-proof electrical equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P261: Avoid breathing fumes, mist or vapors.
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear protective gloves and eye protection.
Response:
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P303+P361+P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with
water/shower.
P304+P340: IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing.
P370+P378: In case of fire: Use dry chemical for extinction.
Storage:
P403+P235: Store in a well-ventilated place. Keep cool.
P233: Keep container tightly closed.
Disposal:
P501: Dispose of contents and container in accordance with local regulations.
EMERGENCY OVERVIEW
PHYSICAL APPEARANCE: White emulsion liquid with solvent odor.
IMMEDIATE CONCERNS: Can cause eye, skin or respiratory tract irritation. Can cause severe lung damage and may be fatal if
swallowed. May cause CNS depression. Combustible. Vapors are heavier than air and may travel across the ground and
reach remote ignition sources causing a flashback fire. During emergencies, wear equipment to protect eyes, skin and
respiratory tract. Dike or absort spills to keep material and run-off from entering sewers, drains or waterways.
POTENTIAL HEALTH EFFECTS
EYES: Contact may cause eye irritation.
SKIN: Prolonged or repeated contact with liquid can cause defatting and drying of the skin, and can lead to irritation and/or
dermatitis.
SKIN ABSORPTION: May be harmful if absrobed through skin.
INGESTION: May cause nausea, vomitting, diarrhea; possible chemical pneumonitis if aspirated into lungs.
INHALATION: Irritating to the respiratory tract. May cause headache, dizziness, anesthetic effects (CNS depression). Breathing
high concentrations in an enclosed space or by intentional abuse can cause irregular heartbeats , which can cause death.
MEDICAL CONDITIONS AGGRAVATED: Significant chronic esposure may aggravate existing eye, skin, respiratory system, liver,
kidney, and CNS conditions.
EYES: Immediately flush eyes with plenty of water. If irritation persists, seek medical attention.
SKIN: Remove contaminated clothing; launder before re-use. Wash skin with soap and water. If irritation develops or persists,
seek medical attention.
INGESTION: Seek immediate medical advice. Do NOT induce vomiting, do NOT drink water.
INHALATION: Remove person to fresh air. If breathing becomes difficult, seek medical attention.
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5. FIRE FIGHTING MEASURES
FLAMMABLE CLASS: Category 4 - Combustible Liquid
EXTINGUISHING MEDIA: Foam, dry chemical; use water spray to cool exposed surfaces. Evacuate area and fight fire from a safe
distance if fire is contained in a small area; otherwise, call the local fire department. Fire media runoff may damage the
environment. Dike and collect media used to fight fire.
OTHER CONSIDERATIONS: Vapors are heavier than air and may accumulate in low or inadequately ventilated areas. Vapors
may travel along the ground to be ignited at locations distant from the handling site. Flashback or flame to the handling site may
occur.
HAZARDOUS DECOMPOSITION PRODUCTS: Fire may produce hazardous fumes.
EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
Supplier OEL
Chemical Name ppm mg/m 3
Aromatic Hydrocarbon TWA 17 100
ENGINEERING CONTROLS: Good, general ventilation should be sufficient for most operations. Ten or more room air changes
per hour containing a minimum of 15% fresh air is recommended.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety glasses.
SKIN: Gloves impervious to the hazardous ingredients.
RESPIRATORY: If used under normal operating conditions and with adequate ventilation, respiratory equipment is not required.
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pH: NA = Not Applicable
FLASH POINT AND METHOD: ~ (145°F) CC
FLAMMABLE LIMITS: Not established
AUTOIGNITION TEMPERATURE: Not Established
VAPOR PRESSURE: 1.56 mmHg at 20°C
VAPOR DENSITY: Not Established
BOILING POINT: (212°F) to (550°F)
FREEZING POINT: Not Established
SOLUBILITY IN WATER: Emulsifies
EVAPORATION RATE: Not Established
DENSITY: Not Established
SPECIFIC GRAVITY: 0.82 to 0.87 at (77°F)
Notes: Water = 1.00
VISCOSITY: Not Established
(VOC): 3.500 lbs/gal USEPA Method 24
COEFF. OIL/WATER: Not Established
HAZARDOUS POLYMERIZATION: No
STABILITY: Chemically stable
CONDITIONS TO AVOID: High temperatures, localized heat sources (i.e.: drum or band heaters), oxidizing conditions, freezing
conditions, direct sunlight, ultraviolet radiation, inert gas blanketing, strong oxidizers, strong reducers, free radical initiators, inert
gases, oxygen scavengers.
HAZARDOUS DECOMPOSITION PRODUCTS: Includes, but not limited to smoke, fumes, oxides of nitrogen, and oxides of
carbon.
INCOMPATIBLE MATERIALS: Stong oxidizers, acids, and/or bases.
ACUTE
INHALATION
Chemical Name ORAL LD50 DERMAL LD50
LC50
Solvent Naphtha (petroleum), Medium Aliphatic 25000 > 4000 > 700
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)
313 REPORTABLE INGREDIENTS: This product does not contain any ingredients subject to the reporting requirements of
SARA Title III Section 313 at or above reporting thresholds, unless listed below.
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA STATUS: All components of this product are registered on the TSCA inventory.
CANADA
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM): Class D2B Toxic Material
WHMIS CLASS: Class B Combustible Material
DOMESTIC SUBSTANCE LIST (INVENTORY): All components of this product are registered on the DSL inventory.
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HMIS RATING NFPA CODES
HEALTH * 1
2
FLAMMABILITY 2
1 0
PHYSICAL HAZARD 0
PERSONAL PROTECTION B
MANUFACTURER DISCLAIMER:
The specific chemical identities of some ingredients in this mixture are considered proprietary information and trade secrets. As
such they are witheld in accordance with CFR 1910.1200(i) of Title 29.
We believe the statements, technical information and recommendations contained herein are reliable, but they are given without
warranty or guarantee of any kind. Some information may be based on indirect test data.
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