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SPOTCHECK ® SKL-SP2 - aerosol

Safety Data Sheet


Prepared according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

Date of issue: 10/31/2018 Revision date: 10/31/2018 Version: 1.0

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING


1.1. PRODUCT IDENTIFIER
Product form : Mixture
Product name : SPOTCHECK ® SKL-SP2 - aerosol
Vaporizer : Aerosol

1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED AGAINST
1.2.1. Relevant identified uses
Main use category : Industrial use
Use of the substance/mixture : Non-Destructive Testing.
1.2.2. Uses advised against
No additional information available
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET
Manufacturer
Magnaflux® (A Division of ITW Ltd)
Faraday Road, South Dorcan Industrial Estate
SN3 5HE Swindon - UK
T +44 (0)1793 524566 - F +44 (0)1793 490459
[email protected] - www.eu.magnaflux.com
1.4. EMERGENCY TELEPHONE NUMBER
Emergency number : DURING OFFICE HOURS, CALL T: +44 (0)1793 524566 (English only) [Office hours (GMT)
Monday - Thursday 8am - 5pm, Friday 8am - 4pm];
OUT OF OFFICE HOURS, CALL T: +44(0)203 394 9866

SECTION 2: HAZARDS IDENTIFICATION


2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Aerosol 1 H222;H229
Skin Sens. 1 H317
Asp. Tox. 1 H304
Full text of hazard classes and H-statements : see section 16

Adverse physicochemical, human health and environmental effects


No additional information available

2.2. LABEL ELEMENTS


Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayExtra classification(s) to display
Hazard pictograms (CLP) :

GHS02 GHS07 GHS08


Signal word (CLP) : Danger
Hazardous ingredients : Hydrocarbons, C12-C15, n-alkanes, isoalkanes, cyclics, < 2% aromatics ; 2-Naphthalenol, 1-[2-
[2-ethyl-4-[2-(2-ethylphenyl)diazenyl]phenyl]diazenyl]-, ar-heptyl derivs
Hazard statements (CLP) : H222 - Extremely flammable aerosol.
H229 - Pressurised container: May burst if heated.
H304 - May be fatal if swallowed and enters airways.
H317 - May cause an allergic skin reaction.
Precautionary statements (CLP) : P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P211 - Do not spray on an open flame or other ignition source.
P251 - Do not pierce or burn, even after use.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310+P331 - IF SWALLOWED: Immediately call a POISON CENTER/doctor. Do NOT
induce vomiting.
P410+P412 - Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.
EUH-statements : EUH066 - Repeated exposure may cause skin dryness or cracking.

10/31/2018 EN (English) 1/7


SPOTCHECK ® SKL-SP2 - aerosol
Safety Data Sheet
Prepared according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

Unknown acute toxicity (CLP) - SDS : 48.35% of the mixture consists of ingredient(s) of unknown acute toxicity (Oral)
88.35% of the mixture consists of ingredient(s) of unknown acute toxicity (Dermal)
56.32% of the mixture consists of ingredient(s) of unknown acute toxicity (Inhalation (Gas))
Unknown hazards to the aquatic environment : Contains 86.37 % of components with unknown hazards to the aquatic environment
(CLP)
2.3. OTHER HAZARDS
No additional information available

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS


3.1. SUBSTANCES
Not applicable

3.2. MIXTURES

Name Product identifier % Classification according to


Regulation (EC) No.
1272/2008 [CLP]
Hydrocarbons, C12-C15, n-alkanes, isoalkanes, cyclics, < 2% (CAS-No.) 869062-45-3 30 - 60 Asp. Tox. 1, H304
aromatics (EC-No.) 920-107-4
1,2-Benzenedicarboxylic acid, di-C8-10-branched alkyl esters, (CAS-No.) 68515-48-0 5 - 10 Aquatic Acute 1, H400
C9-rich (EC-No.) 271-090-9
2-Naphthalenol, 1-[2-[2-ethyl-4-[2-(2- (CAS-No.) 1401000-07-4 1-5 Skin Sens. 1, H317
ethylphenyl)diazenyl]phenyl]diazenyl]-, ar-heptyl derivs (EC-No.) 825-706-3 Aquatic Chronic 4, H413

Full text of H-statements: see section 16

SECTION 4: FIRST AID MEASURES


4.1. DESCRIPTION OF FIRST AID MEASURES
First-aid measures after inhalation : If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for
breathing. Get medical advice/attention if you feel unwell.
First-aid measures after skin contact : IF ON SKIN: Wash with plenty of water. Take off contaminated clothing and wash it before
reuse. If skin irritation or rash occurs: Get medical advice/attention.
First-aid measures after eye contact : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
First-aid measures after ingestion : IF SWALLOWED: Immediately call a POISON CENTER/doctor. Do NOT induce vomiting.
Never give anything by mouth to an unconscious person.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED
Symptoms/effects after inhalation : May cause irritation to the respiratory tract.
Symptoms/effects after skin contact : May cause skin irritation. Repeated exposure may cause skin dryness or cracking. May cause
an allergic skin reaction.
Symptoms/effects after eye contact : May cause eye irritation. Symptoms may include discomfort or pain, excess blinking and tear
production, with possible redness and swelling.
Symptoms/effects after ingestion : May be fatal if swallowed and enters airways. May be harmful if swallowed. May cause
gastrointestinal irritation, nausea, vomiting and diarrhea. May result in aspiration into the lungs,
causing chemical pneumonia.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED
Symptoms may be delayed. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

SECTION 5: FIREFIGHTING MEASURES


5.1. EXTINGUISHING MEDIA
Suitable extinguishing media : Carbon dioxide (CO2), dry chemical powder, foam. Water spray or fog.
Unsuitable extinguishing media : Do not use water jet.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE
Fire hazard : Extremely flammable aerosol. Products of combustion may include, and are not limited to:
oxides of carbon, oxides of nitrogen. Irritating fumes.
Explosion hazard : Heat may build pressure, rupturing closed containers, spreading fire and increasing risk of
burns and injuries.
5.3. ADVICE FOR FIREFIGHTERS
Firefighting instructions : DO NOT fight fire when fire reaches explosives. Evacuate area.
Protection during firefighting : Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory
protection (SCBA). Cool closed containers exposed to fire with water spray.

10/31/2018 EN (English) 2/7


SPOTCHECK ® SKL-SP2 - aerosol
Safety Data Sheet
Prepared according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

SECTION 6: ACCIDENTAL RELEASE MEASURES


6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES
General measures : Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to
unnecessary and unprotected personnel. Elominate every possible source of ignition. Use only
non-sparking tools. Use special care to avoid static electric charges.
6.1.1. For non-emergency personnel
No additional information available
6.1.2. For emergency responders
No additional information available
6.2. ENVIRONMENTAL PRECAUTIONS
Prevent entry to sewers and public waters.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP
For containment : Stop leak without risks if possible. Move containers from spill area. Use only non-sparking
tools. Use explosion-proof equipment. Absorb and/or contain spill with inert material (sand,
vermiculite or other appropriate material), then place in suitable container. Do not flush into
surface water or sewer system. Wear recommended personal protective equipment.
Methods for cleaning up : Sweep or shovel spills into appropriate container for disposal. Provide ventilation.
6.4. REFERENCE TO OTHER SECTIONS
For further information refer to section 8: "Exposure controls/personal protection".

SECTION 7: HANDLING AND STORAGE


7.1. PRECAUTIONS FOR SAFE HANDLING
Additional hazards when processed : Do not pierce or burn, even after use. Keep away from sources of ignition - No smoking.
Hazardous waste due to potential risk of explosion.
Precautions for safe handling : Avoid contact with skin and eyes. Ensure adequate ventilation. Do not swallow. Handle and
open container with care. When using do not eat, drink or smoke. Do not spray on an open
flame or other ignition source. Use non-sparking tools. Use explosion-proof equipment. Take
precautionary measures against static discharge.
Hygiene measures : Wash contaminated clothing before reuse. Always wash hands after handling the product.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES
Technical measures : Proper grounding procedures to avoid static electricity should be followed.
Storage conditions : Keep out of the reach of children. Store tightly closed in a dry and cool place. Keep away from
ignition sources. Keep out of direct sunlight. Do not expose to temperatures exceeding 50 °C/
122 °F. Keep in fireproof place.
Storage temperature : 10 - 30 °C
7.3. SPECIFIC END USE(S)
Not available.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION


8.1. CONTROL PARAMETERS
No additional information available

8.2. EXPOSURE CONTROLS


Appropriate engineering controls:
Ensure good ventilation of the work station.

Hand protection:
Chemical resistant gloves (according to European standard NF EN 374 or equivalent)

Eye protection:
Safety glasses or goggles are recommended when using product.

Skin and body protection:


Wear suitable protective clothing

Respiratory protection:
In case of insufficient ventilation, wear suitable respiratory equipment. Respirator selection must be based on known or anticipated exposure levels,
the hazards of the product and the safe working limits of the selected respirator.

10/31/2018 EN (English) 3/7


SPOTCHECK ® SKL-SP2 - aerosol
Safety Data Sheet
Prepared according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

Environmental exposure controls:


Avoid release to the environment.
Other information:
Handle in accordance with good industrial hygiene and safety procedures. Do not eat, drink or smoke when using this product.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES


9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES
Physical state : Liquid
Appearance : Red Aerosol
Colour : Red
Odour : Mild hydrocarbon
Odour threshold : No data available
pH : Neutral
Relative evaporation rate (butylacetate=1) : < 0.1
Melting point : No data available
Freezing point : No data available
Boiling point : 230 °C
Flash point : -40 °C (aerosol propellant)
Auto-ignition temperature : > 200 °C
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : < 0.5 mm Hg (@ 38°C)
Relative vapour density at 20 °C : >1
Relative density : 0.85 g/cm3
Solubility : Negligible.
Partition coefficient n-octanol/water : 3.9 - 6 (distillates (petroleum), hydrotreated light naphthenic)
Viscosity, kinematic : 3.3 mm²/s (@ 20°C)
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : Non oxidizing.
Lower explosive limit (LEL) : 1 vol %
Upper explosive limit (UEL) : 6 vol %
9.2. OTHER INFORMATION
No additional information available

SECTION 10: STABILITY AND REACTIVITY


10.1. REACTIVITY
No dangerous reactions known under normal conditions of use.
10.2. CHEMICAL STABILITY
Extremely flammable aerosol. Extreme risk of explosion by shock, friction, fire or other sources of ignition. Contents under pressure. Container may
explode if heated. Do not puncture. Do not burn.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS
No dangerous reactions known under normal conditions of use.
10.4. CONDITIONS TO AVOID
Heat. Incompatible materials. Sources of ignition. Direct sunlight.
10.5. INCOMPATIBLE MATERIALS
Strong oxidizing agents. Acids. Strong alkalis.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS
May include, and are not limited to: oxides of carbon, oxides of nitrogen. Irritating fumes.

SECTION 11: TOXICOLOGICAL INFORMATION


11.1. INFORMATION ON TOXICOLOGICAL EFFECTS
Acute toxicity (oral) : Not classified.
Acute toxicity (dermal) : Not classified.
Acute toxicity (inhalation) : Not classified.

10/31/2018 EN (English) 4/7


SPOTCHECK ® SKL-SP2 - aerosol
Safety Data Sheet
Prepared according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

1,2-Benzenedicarboxylic acid, di-C8-10-branched alkyl esters, C9-rich (68515-48-0)


LD50 oral rat > 10000 mg/kg
LD50 dermal rabbit > 3160 mg/kg
Unknown acute toxicity (CLP) - SDS : 48.35% of the mixture consists of ingredient(s) of unknown acute toxicity (Oral)
88.35% of the mixture consists of ingredient(s) of unknown acute toxicity (Dermal)
56.32% of the mixture consists of ingredient(s) of unknown acute toxicity (Inhalation (Gas))
Skin corrosion/irritation : Not classified.
Additional information : Based on available data, the classification criteria are not met. Repeated exposure may cause
skin dryness or cracking.
Serious eye damage/irritation : Not classified.
Additional information : Based on available data, the classification criteria are not met.
Respiratory or skin sensitisation : May cause an allergic skin reaction.
Germ cell mutagenicity : Not classified.
Additional information : Based on available data, the classification criteria are not met.
Carcinogenicity : Not classified.
Additional information : Based on available data, the classification criteria are not met.
Reproductive toxicity : Not classified.
Additional information : Based on available data, the classification criteria are not met.

STOT-single exposure : Not classified.


Additional information : Based on available data, the classification criteria are not met.
STOT-repeated exposure : Not classified.
Additional information : Based on available data, the classification criteria are not met.
Aspiration hazard : May be fatal if swallowed and enters airways.
SPOTCHECK ® SKL-SP2 - aerosol
Vaporizer Aerosol
Viscosity, kinematic 3.3 mm²/s (@ 20°C)

Other information : Likely routes of exposure: ingestion, inhalation, skin and eye.

SECTION 12: ECOLOGICAL INFORMATION


12.1. TOXICITY
Ecology - general : May cause long-term adverse effects in the aquatic environment.
Unknown hazards to the aquatic environment : Contains 86.37 % of components with unknown hazards to the aquatic environment
(CLP)
Acute aquatic toxicity : Not classified.
Chronic aquatic toxicity : Not classified.

1,2-Benzenedicarboxylic acid, di-C8-10-branched alkyl esters, C9-rich (68515-48-0)


LC50 fish 1 0.42 mg/l (Exposure time: 96 h - Species: Ictalurus punctatus [flow-through])
LC50 fish 2 > 0.16 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [flow-through])
EC50 Daphnia 1 > 0.086 mg/l (Exposure time: 48 h - Species: Daphnia magna)
EC50 96h algae (1) > 2.8 mg/l (Species: Pseudokirchneriella subcapitata)

12.2. PERSISTENCE AND DEGRADABILITY


SPOTCHECK ® SKL-SP2 - aerosol
Persistence and degradability Not established.

12.3. BIOACCUMULATIVE POTENTIAL


SPOTCHECK ® SKL-SP2 - aerosol
Bioaccumulative potential Not established.

12.4. MOBILITY IN SOIL


No additional information available
12.5. RESULTS OF PBT AND VPVB ASSESSMENT
No additional information available

12.6. OTHER ADVERSE EFFECTS


Additional information : No other effects known

10/31/2018 EN (English) 5/7


SPOTCHECK ® SKL-SP2 - aerosol
Safety Data Sheet
Prepared according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

SECTION 13: DISPOSAL CONSIDERATIONS


13.1. WASTE TREATMENT METHODS
Product/Packaging disposal recommendations : This material must be disposed of in accordance with all local, state, provincial, and federal
regulations. Container under pressure. Do not drill or burn even after use.

SECTION 14: TRANSPORT INFORMATION


In accordance with ADR / IATA / IMDG

14.1. UN NUMBER
UN-No. (ADR) : 1950
UN-No. (IMDG) : 1950
UN-No. (IATA) : 1950
14.2. UN PROPER SHIPPING NAME
Proper Shipping Name (ADR) : AEROSOLS, flammable.
Proper Shipping Name (IMDG) : AEROSOLS, flammable.
Proper Shipping Name (IATA) : AEROSOLS, flammable.
14.3. TRANSPORT HAZARD CLASS(ES)
ADR
Transport hazard class(es) (ADR) : 2.1
Danger labels (ADR) :
IMDG
Transport hazard class(es) (IMDG) : 2.1
IATA
Transport hazard class(es) (IATA) : 2.1
14.4. PACKING GROUP
Packing group (ADR) : Not applicable
Packing group (IMDG) : Not applicable
Packing group (IATA) : Not applicable
14.5. ENVIRONMENTAL HAZARDS
Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available.
14.6. SPECIAL PRECAUTIONS FOR USER
Special transport precautions : Do not handle until all safety precautions have been read and understood.
14.7. TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL AND THE IBC CODE
IBC code : Not applicable.

SECTION 15: REGULATORY INFORMATION


15.1. SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR THE SUBSTANCE OR MIXTURE
15.1.1. EU-Regulations

Contains no REACH substances with Annex XVII restrictions


Contains no REACH candidate substance.
Contains no REACH Annex XIV substances

15.1.2. National regulations


National regulations (Germany):
Wassergefahrdungklasse (water hazard class): WGK 1 – Low hazard to waters
TechnischeAnleitungLuft (TA-Luft): Class 5.2.5 Organic substances, except dusts.

15.2. CHEMICAL SAFETY ASSESSMENT


No chemical safety assessment has been carried out

SECTION 16: OTHER INFORMATION


Indication of changes:
None.

10/31/2018 EN (English) 6/7


SPOTCHECK ® SKL-SP2 - aerosol
Safety Data Sheet
Prepared according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE
COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and
mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending
Regulation (EC) No 1907/2006.
Other information : None.
Prepared by : Nexreg Compliance Inc.
www.Nexreg.com
Full text of H- and EUH-statements:
Aerosol 1 Aerosol, Category 1
Aquatic Acute 1 Hazardous to the aquatic environment — Acute Hazard, Category 1
Aquatic Chronic 4 Hazardous to the aquatic environment — Chronic Hazard, Category 4
Asp. Tox. 1 Aspiration hazard, Category 1
Skin Sens. 1 Skin sensitisation, Category 1
H222 Extremely flammable aerosol.
H229 Pressurised container: May burst if heated.
H304 May be fatal if swallowed and enters airways.
H317 May cause an allergic skin reaction.
H400 Very toxic to aquatic life.
H413 May cause long lasting harmful effects to aquatic life.
EUH066 Repeated exposure may cause skin dryness or cracking.
Classification and procedure used to derive the classification for mixtures according to Regulation (EC) 1272/2008 [CLP]:
Aerosol 1 H222;H229 Expert judgment
Skin Sens. 1 H317 Calculation method
Asp. Tox. 1 H304 Calculation method

SDS EU (REACH Annex II)_NEXREG_NEW_Magnaflux

Disclaimer: We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information
contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. It is the user’s responsibility to satisfy
oneself as to the suitability and completeness of this information for the user’s own particular use.

10/31/2018 EN (English) 7/7

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