12th Sprint Reloaded-Solutions

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Concentration Terms
Mass % Vol %

Mole Fraction
w1 = mass of V1 = Vol. of
solvent solvent
w2 = mass of V2 = Vol. of
solute solute
Concentration Terms
Molarity Molality

PPM Dilution Equation


Henry’s Law Formula
P = Partial pressure of gas
P = KH x x = mole fraction(Solubility)
KH = Henry’s constant

Raoult’s Law Formula

PA = Vapour pressure of A in
the solution
PAo = Vapour pressure of pure
Solvent A
XA= mole fraction of A
Colligative Properties
Relative Lowering of
Vapour Pressure Elevation in Boiling Point

Depression in Freezing Point Osmotic Pressure


Let’s solve

Most
Important
Questions
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Let’s solve

Most
Important
Questions
Very Short Answers (VSA)
1.

000(AI 2016)000

Answer
P = KH x
● Solubility is inversely proportional to Henry’s constant

● Hence, gas (B) being less soluble,would have a higher KH value.


Very Short Answers (VSA)
2. The number of moles of NaCl in 3 litres of 3M
solution is

Answer
Very Short Answers (VSA)
3. Define Raoult’s law.

000(AI 2014 C)000

Answer
“It states that for a solution of volatile liquids, the vapour pressure of each
component is directly proportional to its mole fraction present in solution”
Very Short Answers (VSA)
4. State the condition resulting in reverse osmosis.
000(AI 2007)000

Answer
Reverse osmosis occurs when a pressure
larger than the osmotic pressure is applied
to the solution side.
Very Short Answers (VSA)
5. Write mathematical form of Raoult’s law of
relative lowering of vapour pressure
000(Board 2012)000

Answer
Short Answers (SA-I)
6.

000(AI 2013)000
Short Answers (SA-I)
Answer
Short Answers (SA-I)

7. Explain why a solution of chloroform and acetone


shows negative deviation from Raoult’s law.
000(Delhi 2011 C)000
Short Answers (SA-I)
Answer

● Chloroform molecule forms H-bonding with acetone molecule.

● This leads to the decrease in vapour pressure and resulting in


negative deviation
Short Answers (SA-I)
8. The vapour pressure of water is 12.3 kPa at 300 K.
Calculate vapour pressure of 1 molal solution of a
solute in it.
000(CBSE 2012)000
Short Answers (SA-I)
Answer
Short Answers (SA-II)
9.

0(AI 2013, 2008)000


Short Answers (SA-II)
Answer
Short Answers (SA-II)
10.

000(Delhi 2013)000
Short Answers (SA-II)
Answer
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