0% found this document useful (0 votes)
56 views167 pages

Fluidization Engineering: Lecture 09: Calculation of Gas Pumping Power Consumption in Fluidized Bed

The document discusses how to calculate the power consumption of a blower used to pump gas through a fluidized bed. It provides the equations to calculate the ideal shaft work required to compress the gas from an initial to final pressure. It notes that the actual shaft work required is greater than the ideal due to frictional losses. The document gives equations to calculate the actual shaft work using the compressor efficiency and discusses typical efficiency values for different compressor types.

Uploaded by

shubham
Copyright
© © All Rights Reserved
Available Formats
Download as PDF, TXT or read online on Scribd
Download as pdf or txt
0% found this document useful (0 votes)
56 views167 pages

Fluidization Engineering: Lecture 09: Calculation of Gas Pumping Power Consumption in Fluidized Bed

The document discusses how to calculate the power consumption of a blower used to pump gas through a fluidized bed. It provides the equations to calculate the ideal shaft work required to compress the gas from an initial to final pressure. It notes that the actual shaft work required is greater than the ideal due to frictional losses. The document gives equations to calculate the actual shaft work using the compressor efficiency and discusses typical efficiency values for different compressor types.

Uploaded by

shubham
Copyright
© © All Rights Reserved
Available Formats
Download as PDF, TXT or read online on Scribd
Download as pdf or txt
Download as pdf or txt
You are on page 1/ 167

G

I IT
,
on er
si d
is m
m ju
Fluidization Engineering

er Ma
rp K
rio S
t p rof
ou P
Lecture 09: Calculation of gas pumping power consumption in

ith @
w ght
fluidized bed

i
r m yr
fo p
y co
By
an er
in d
it un

Dr. Subrata K. Majumder


e is
us nt

Chemical Engineering Department, IIT Guwahati


ot e
nn um

Contact: [email protected]
ca cc
u do
Yo is
Th
Th
Yo is
u do
ca cc
nn um
ot e
us nt
e is
it un
in d
an er
y co
fo p
r m yr
i
w ght
ith @
ou P
in the fluidized bed

t p rof
rio S
rp K
er Ma
m ju
is m
How to calculate the power

si d
on er
consumption to pump the gas

, I IT
What to learn in this lecture

G
G
,I IT
on er
si d
is m
Power consumption of the blower

m ju
er Ma
rp K
• Power consumption is a significant cost factor in any process

rio S
t p rof
using fluidized beds

ou P
• Occasionally it can be so high that it cancels the advantages of

ith @
w ght
fluidization operation.

i
r m yr
• Therefore, roughly estimate the power requirement in the early

fo p
design stages—before making a detailed design or deciding to
pilot plant. y co
an er
in d

• Since the distributor contribute a considerable fraction of


it un

pressure drop across a fluid bed, it is always important to


e is

estimate the power consumption of the blower that drives the


us nt
ot e

gas through the bed


nn um
ca cc
u do
Yo is
Th
G
, I IT
on er
si d
Power consumption of the blower

is m
m ju
er Ma
• Consider a stream of gas to be compressed from an initial

rp K
pressure P1 to higher pressure P2 to pump it through the

rio S
entire fluid bed system. Then

t p rof
ou P
ith @
w ght
i
r m yr
fo p
y co
As per thermodynamics, for adiabatic reversible
an er
operations with negligible kinetic and potential energy
in d
it un

effects, the ideal shaft work to compress each kilogram of


e is

gas is given by
us nt
ot e
nn um
ca cc
u do
Yo is
Th
G
, I IT
on er
si d
If an ideal gas behaviour is assumed

is m
m ju
er Ma
rp K
rio S
t p rof
the ideal pumping requirement then becomes

ou P
ith @
w ght
i
r m yr
fo p
y co
an er
in d
it un
e is

where v is the volumetric flow rate of gas (in m3/s)


us nt
ot e
nn um

Cp, Cv are the specific heat capacity of gas at constant


ca cc

pressure and volume respectively


u do
Yo is
Th
G
I IT
,
on er
Adiabatic reversible compression of a gas from pl to p2 cause to

si d
is m
increase in its temperature. From thermodynamics one can

m ju
er Ma
calculate the temperature at p2 as

rp K
rio S
t p rof
ou P
ith @
w ght
i
r m yr
fo p
y co
where γ = ratio specific heats of gas  1.67, 1.40, and 1.33 for
an er
in d

monatomic, diatomic, and triatomic gases, respectively.


it un
e is
us nt

However for real operations with its frictional losses, the actual
ot e
nn um

shaft work required is always greater than the ideal.


ca cc
u do
Yo is
Th
G
I IT
,
on er
si d
is m
For real operations with its frictional losses, the actual

m ju
er Ma
shaft work can be represented by

rp K
rio S
t p rof
ou P
ith @
w ght
Where  is the compressor efficiency which is roughly

i
r m yr
given by
fo p
y co
an er
 = 0.55 – 0.75 for a turbo-blower
in d
it un

 = 0.6 – 0.8 for a roots blower


e is

 = 0.8 – 0.9 for an axial blower or a two-stage


us nt
ot e

reciprocating compressor
nn um
ca cc
u do
Yo is
Th
G
I IT
,
on er
si d
is m
m ju
The actual temperature of gas leaving a well-

er Ma
insulated (adiabatic), but not 100% efficient

rp K
compressor, is then

rio S
t p rof
ou P
ith @
w ght
i
r m yr
fo p
y co
an er
in d
it un

This temperature is higher than the ideal


e is
us nt
ot e
nn um
ca cc
u do
Yo is
Th
G
, I IT
on er
si d
• Example:

is m
m ju
er Ma
Determine the compressor power to pass reactant gas

rp K
rio S
into the plenum of the fluid bed system. Also calculate

t p rof
the temperature rise due to heat of compression. The

ou P
ith @
system parameters are

w ght
i
r m yr
Gas enters the compressor at

fo p
Pgrid distributor = 6 kPa
Pbed y co
= 15 kPa
T1 = 20 oC,
P1 = 101 kPa,
an er
in d

Pcyclone+filters+others = 12 kPa The volumetric flowrate of fluid is 10 m3/s


it un

Pexit of filters = 350 kPa The efficiency of compressor is 85% and


e is

the ratio of the specific heat ratio is 1.4


us nt
ot e
nn um
ca cc
u do
Yo is
Th
Th
Yo is
u do
ca cc
nn um
ot e
Solution

us nt
e is
it un
in d
an er
y co
fo p
r m yr
i
w ght
ith @
ou P
t p rof
rio S
rp K
er Ma
m ju
is m
si d
on er
, I IT
G
Th
Yo is
u do
ca cc
nn um
ot e
us nt
e is
it un
in d
an er
y co
fo p
r m yr
i
w ght
ith @
ou P
t p rof
rio S
rp K
er Ma
m ju
is m
si d
on er
, I IT
G
Th
Yo is
u do
ca cc
nn um
ot e
Example

us nt
e is
it un
in d
an er
y co
fo p
r m yr
i
w ght
ith @
ou P
t p rof
rio S
rp K
er Ma
m ju
is m
si d
on er
, I IT
G
Th
Yo is
u do
ca cc
nn um
ot e
us nt
Solution

e is
it un
in d
an er
y co
fo p
r m yr
i
w ght
ith @
ou P
t p rof
rio S
rp K
er Ma
m ju
is m
si d
on er
,
Contd.. next page

I IT
G
Th
Yo is
u do
ca cc
nn um
ot e
us nt
e is
it un
in d
an er
y co
fo p
r m yr
i
w ght
ith @
ou P
t p rof
rio S
rp K
er Ma
m ju
is m
si d
on er
, I IT
G
Contd.. next page
Th
Yo is
u do
ca cc
nn um
ot e
us nt
e is
it un
in d
an er
y co
fo p
r m yr
i
w ght
ith @
ou P
t p rof
rio S
rp K
er Ma
m ju
is m
si d
on er
, I IT
G
Th
Yo is
u do
ca cc
nn um
ot e
us nt
e is
it un
in d
an er
y co
fo p
r m yr
i
Exercise Problem

w ght

Answer: (i) 882.04 kW, (iii) 655.72 kW


ith @
ou P
t p rof
rio S
rp K
er Ma
m ju
is m
si d
on er
, I IT
G
Th
Yo is
u do
ca cc
nn um
ot e
us nt
e is
it un
in d
an er
y co
fo p
r m yr
i
w ght
ith @
ou P
Thank You

t p rof
rio S
rp K
er Ma
m ju
is m
si d
on er
, I IT
G
G
I IT
,
on er
si d
is m
m ju
er Ma
Fluidization Engineering

rp K
rio S
t p rof
ou P
ith @
Lecture 10: Bubbling Fluidization-Part 1: Bubble

w ght
Characteristics

i
r m yr
fo p
y co
an er
By
in d
it un

Dr. Subrata K. Majumder


e is

Chemical Engineering Department, IIT Guwahati


us nt
ot e
nn um

Contact: [email protected]
ca cc
u do
Yo is
Th
G
, I IT
on er
si d
Learning about bubbling fluidized bed

is m
m ju
er Ma
rp K
• What are the basic characteristic feature of bubbling fluidized bed?

rio S
• How bubbles are formed?

t p rof
ou P
• What is the maximum stable size of the bubble?

ith @
w ght
• How to estimate the bubble size?

i
r m yr
• How bubble rise velocity is related to bubble size or fluidized bed diameter?

fo p
y co
• Is there any model to represent the bubble size?
an er
• How bubbles are interacting to each other?
in d
it un

• How slug is formed? And what are the characteristic feature of slugging?
e is

• How does entrainment of particle happen in bubbling fluidized bed?


us nt
ot e

• How bubble size affect the mixing of phases in the bed?


nn um

• More..........
ca cc
u do
Yo is
Th
G
I IT
,
on er
si d
is m
m ju
Bubbling Fluidized Bed

er Ma
rp K
rio S
Emulsion phase

t p rof
• This type of fluidization is called

ou P
aggregative fluidization Bubble phase

ith @
• Under this conditions, the bed

w ght
appears to be divided into two-

i
r m yr
phases, the bubble phase and the

fo p
emulsion phase.
y co
• The bubbles appear to be very
an er
in d

similar to gs bubbles formed in a


it un

liquid and hey behave in a similar


e is

manner.
us nt

• The bubbles coalescence as they rise


ot e
nn um

through the bed


ca cc
u do
Yo is
Th
G
, I IT
on er
si d
Bubble formation

is m
m ju
er Ma
rp K
rio S
• Bubble formation in a fluidized bed is very similar to that in

t p rof
an inviscid liquid.

ou P
• At a very low gas flow rate, the frequency and size of the

ith @
bubbles formed are primarily governed by a balance

w ght
between the surface tension of the fluid and the buoyancy
force of the bubble.

i
r m yr
fo p
• The inertia of the fluid moved by the rising bubbles becomes
y co
more important than the surface tension at higher gas rates.
an er
• At still higher gas rates, the momentum of gas issuing from
in d

the orifice can manifest as a jet before breakup into bubbles.


it un

• The gas bubble size, shape, formation, rising velocity, and


e is

coalescence, breakup in the fluidized beds have quantitative


us nt

similarity with those of gas bubbles in liquids


ot e
nn um
ca cc
u do
Yo is
Th
G
I IT
• If the number of orifices per unit area is Nor [cm-2] and all the gas in

,
on er
excess of umf forms bubbles of equal size, the volumetric flow rate of

si d
gas from each of the orifices, vor, can be found from the expression
Bubble formation from porous plate

is m
m ju
er Ma
rp K
• For a low enough flow rate so that the initial bubbles from adjacent

rio S
orifices

t p rof
ou P
ith @
w ght
• Combining these above equations

i
r m yr
fo p
At low gas flowrate
y co
an er
• If lor is the spacing between adjacent holes of gas distributor
in d
it un
e is

At high flowrate
us nt
ot e
nn um
ca cc
u do
Yo is
Th
G
, I IT
on er
Bubble formation from gas jet

si d
is m
m ju
• The gas issuing from an orifice might be in the form of bubbles, a

er Ma
pulsating jet (a periodic jet), or a permanent flamelike jet, depending
on the relative properties of the gas, the bed material, and the

rp K
operating conditions

rio S
t p rof
• When the gas velocity is low, the bed material is dense, and the
particle size is small, the gas jet issuing from the orifice or the nozzle

ou P
ith @
tends to be truncated into bubbles right at the orifice, a phenomenon
very similar to that observed when gas is injected into a liquid

w ght
medium.

i
r m yr
• Markhevka et al. (1971) observed a jet in a fluidized bed located close

fo p
to the wall formed elongated cavities, which were periodically
y co
truncated to become bubbles at the orifice depending on the jet
an er
penetration length.
in d
it un

• In 1993, Roach proposed a critical Froude number, (Fr)c, as a


demarcation for jetting and bubbling. For systems above the critical
e is

Froude number, bubbles are formed; below it, jets are present. The
us nt

critical Froude number is expressed as follows:


ot e
nn um
ca cc
u do
Yo is
Th
G
, I IT
on er
si d
Bubble size

is m
m ju
er Ma
• Using the analogy of bubble formation in an inviscid liquid, Davidson and

rp K
Harrison (1963) derived equations for both the bubble frequency and the

rio S
bubble size (volume), assuming there is no gas leakage from the bubble to

t p rof
the emulsion phase

ou P
ith @
Applicable at high gas flowrate

w ght
Bubble volume G = gas flowrate

i
r m yr
fo p
• At high gas flow rates where the bubble sizes are independent of the
y co
bed viscosity, the inviscid liquid theory can predict the bubble sizes
an er
satisfactorily.
in d
it un
e is

• At low gas flow rates where the viscosity effects are quite pronounced,
us nt

the inviscid liquid theory underestimates the bubble sizes. In this case,
ot e
nn um

the following equation by Davidson and Schuler (1960) should be used


ca cc

Bubble volume Applicable at low gas flowrate


u do

G = gas flowrate
Yo is
Th
G
I IT
,
on er
Bubble size

si d
is m
m ju
er Ma
rp K
By capturing
image

rio S
by suitable camera

t p rof
Spherical

ou P
ith @
bubble

w ght
VBi

i
r m yr
fo p
With the same volume of
y co
equivalent spherical bubble of diameter db
an er
in d
it un
e is

ith bubble
us nt
ot e
nn um

Volume to surface mean


ca cc

bubble diameter or Souter –mean bubble diameter


u do
Yo is
Th
G
I IT
Effect of gas flowrate on bubble

,
on er
si d
is m
size

m ju
er Ma
rp K
rio S
t p rof
ou P
ith @
w ght
i
r m yr
fo p
y co
an er
in d
it un
e is
us nt
ot e
nn um
ca cc

Size of bubbles at different levels in beds of Geldart A and Β particles; from


u do

Kunii and Levenspiel (1991)


Yo is
Th
G
, I IT
on er
Effect of pressure on bubble size

si d
is m
m ju
er Ma
At higher pressure bubbles shrink drastically in small particle (Geldart A)

rp K
beds but hardly at all in larger particle (Geldart B ) beds.

rio S
t p rof
ou P
ith @
w ght
i
r m yr
fo p
y co
an er
in d
it un
e is
us nt
ot e
nn um

Effect of pressure on bubble size in beds of Geldart A and Β solids


(adapted from Weimer and Quarderer, 1985)
ca cc
u do

from Kunii and Levenspiel (1991)


Yo is
Th
Th
Yo is
u do
ca cc
nn um
ot e
us nt
e is
it un
in d
an er
y co
fo p
r m yr
i
w ght
ith @
ou P
t p rof
rio S
rp K
er Ma
m ju
is m
si d
on er
, I IT
G
Effect of group of particle on bubble size

from Kunii and Levenspiel (1991)


Th
Yo is
u do
ca cc
nn um
ot e
us nt
e is
it un
in d
an er
y co
fo p
r m yr
i
w ght
ith @
ou P
t p rof
rio S
rp K
er Ma
m ju
is m
si d
on er
, I IT
G
Effect of distributor on bubble size

from Kunii and Levenspiel (1991)


G
, I IT
on er
Bubble Size Correlations

si d
is m
m ju
er Ma
rp K
For Geldart Β and D solids, the bubble size db at any height z in the bed as

rio S
per Mori and Wen (1975) correlation

t p rof
ou P
ith @
w ght
Porous distributor

i
r m yr
fo p
y co
an er
where
in d

db0 is the initial bubble size formed near the bottom of the bed,
it un

dbm is the limiting (maximum) size of bubble expected in a very deep bed.
e is
us nt
ot e
nn um
ca cc
u do
Yo is
Th
G
, I IT
on er
Bubble Size Correlations

si d
is m
m ju
er Ma
rp K
Werther (1978) correlation

rio S
t p rof
ou P
ith @
w ght
i
r m yr
Porous distributor

fo p
y co
an er
in d
it un
e is
us nt
ot e
nn um

Similar way, from experimental data the correlation can be developed to


predict the bubble axially with other type of distributor
ca cc
u do
Yo is
Th
G
, I IT
on er
Initial bubble size formed from jet

si d
is m
m ju
er Ma
• When the momentum of the jets dissipates, bubbles are formed at the end

rp K
of the jets. The initial bubble size was studied by Basov et al. (1969) and

rio S
Merry (1975).

t p rof
• They suggested the equations

ou P
ith @
w ght
Or

i
r m yr
fo p
y co
an er
in d

The inlet jet velocity should be calculated from the equation


it un
e is

ug, can be calculated based on the crosssectional area of


us nt

the jet nozzle and the volumetric jet flow rate.


ot e
nn um

The solid particle velocity, us, can be calculated


ca cc

assuming the gas/solid slip velocity to be the terminal


u do

velocity of a single particle of the average size


Yo is
Th
G
, I IT
on er
Bubble Frequency

si d
is m
m ju
er Ma
• Nguyen and Leung (1972) performed experiments in a 2-D bed with a

rp K
fluidizing velocity of 1.2 times the minimum fluidizing velocity and found

rio S
that the bubble frequency is better approximated by the following equation

t p rof
ou P
ith @
Bubble frequency

w ght
i
r m yr
fo p
• According to Kunii and Levenspiel: consider pairs and chains of bubbles
y co
issuing from an orifice in a bed that is otherwise at minimum fluidizing
an er
conditions. At higher orifice flows, the bubble frequency just above the
in d

orifice should be
it un
e is

G is in cm3/s
us nt

g =981 cm/s2
ot e
nn um
ca cc
u do

For G = 200-2000 cm3/s , this equation gives fn = 19 - 12 s-1


Yo is
Th
Th
Yo is
u do
ca cc
nn um
ot e
us nt
e is
it un
in d
an er
y co
fo p
r m yr
i
w ght
ith @
ou P
t p rof
rio S
rp K
flow rates; from Kunii and Levenspiel (1991).

er Ma
m ju
is m
si d
on er
, I IT
G
Frequency of bubbles passing a point in a fluidized bed at various gas
G
, I IT
on er
Bubble Rise Velocity

si d
is m
m ju
er Ma
Single Bubble Rise Velocity in Liquids

rp K
rio S
• In a liquid of small viscosity, the rate of rise of large bubbles depends

t p rof
primarily on inertial forces and surface tension.

ou P
ith @
• The shape of the bubble will adjust itself to maintain the pressure inside the

w ght
bubble constant.

i
r m yr
• An approximate solution by Dumitrescu (1943) for a long bubble in a tube

fo p
gives
y co
an er
in d
it un
e is

 Davies and Taylor (1950) also provided a solution with a slightly different
us nt

empirical constant.
ot e
nn um

For single bubble


ca cc
u do

where dbe is the diameter of the sphere having the same volume as the bubble
Yo is
Th
G
I IT
,
on er
si d
is m
Important notes

m ju
er Ma
rp K
rio S
t p rof
ou P
• The wall effect predominates when equivalent bubble

ith @
diameter dbe is more than 1/3 of the bed diameter

w ght
i
• The wall effect becomes negligible only when dbe is less

r m yr
fo p
than 0.1 of the bed diameter
y co
an er
• The regime where the wall effect is dominant is generally
in d

called the slugging regime


it un
e is
us nt
ot e
nn um
ca cc
u do
Yo is
Th
G
, I IT
on er
si d
Absolute Bubble rise velocity in a stream of bubbles

is m
m ju
er Ma
• In the case of a stream of bubbles in a vertical tube generated continuously by

rp K
blowing air in at the bottom, the absolute upward rising velocity of each bubble

rio S
is greater than the velocity of a similar size single bubble rising in a stagnant

t p rof
liquid.

ou P
ith @
• By making a simple material balance, it is possible to derive the absolute bubble

w ght
velocity as

i
r m yr
Constant = 1.0 for uniform velocity

fo p
y co
an er
Nicklin et al. (1962) found experimentally that the absolute bubble velocity is
in d
it un
e is
us nt
ot e
nn um

The factor 1.2 stems from the fact that the peak velocity at the middle of the tube is
about 1.2 times the average velocity, owing to the nonuniform velocity profile. The
ca cc

bubbles evidently rise relative to the fastest moving liquid in the middle of the tube.
u do
Yo is
Th
G
, I IT
on er
si d
is m
Absolute bubble rise velocity in a swarm of bubbles

m ju
er Ma
rp K
rio S
• For a swarm of bubbles, the same concept applies:

t p rof
ou P
ith @
(A)

w ght
i
r m yr
From the continuity of gas flow it can be derived that

fo p
y co (B)
an er
in d
it un
e is

where H is the liquid height when gas velocity is u, and H0 is the liquid height when
us nt
ot e

gas velocity is zero. ubr from experimentally observable quantities.


nn um
ca cc

Equations (A) and (B) can be applied to a bubbling gas–solid fluidized bed by
u do

replacing u with u - umf, assuming that the two-phase theory applies.


Yo is
Th
G
, I IT
on er
Single bubble rise velocity in gas-solid fluidized bed

si d
is m
m ju
• The rising velocity of a single bubble in a quiescent bed has been found

er Ma
experimentally to be

rp K
rio S
t p rof
ou P
ith @
w ght
This compares with the experimental value of Davis and Taylor (1950) for
bubbles in liquids as

i
r m yr
fo p
y co
an er
in d
it un

Wall effects retard the rise of bubbles when dbe/dbed > 0.125.
e is
us nt
ot e
nn um
ca cc
u do

For dbe/dbed > 0.6, the bed should be considered not to be bubbling, but slugging
Yo is
Th
G
, I IT
on er
Bubbles in gas–solid fluidized beds usually are spherical-capped with the included angle

si d
equal to 120. The bubbles in air–water systems have an angle of 100

is m
m ju
er Ma
A spherical-cap bubble with an included angle, , as shown in Fig., has a
volume

rp K
rio S
t p rof
ou P
ith @
If the equation for bubble rise velocity is written in a general form,

w ght
it can be expressed as

i
r m yr
fo p
y co
an er
in d

Schematic of
it un

Combining above these two equations we have spherical-cap bubble


e is
us nt

When the bubbles are large enough to


ot e
nn um

exceed approximately 25% of the


column diameter, the bubble velocity is
ca cc

affected by the presence of the vessel


u do

wall.
If C = 0.71, the included bubble angle is 120
Yo is
Th
G
, I IT
on er
si d
Absolute bubble rise velocity in a swarm of bubbles

is m
m ju
in bubbling beds

er Ma
rp K
rio S
t p rof
ou P
In order to come up with an equation for bubble rise velocity that covers

ith @
the whole range of particle sizes from Geldart A to D and that accounts for the

w ght
vessel size, Werther (1978) proposed the equation

i
r m yr
fo p
y co
an er
in d
it un

where ψ is the fraction of visible bubbles, and  is a factor that accounts for the
deviation of bed bubbles from single rising bubbles.
e is
us nt
ot e
nn um

dbed = dt
ca cc
u do

ψ changed with height z in the bed. Thus, up to z/dbed  1, approximately  = 0.8, 0.65, and
0.26 for Geldart A, B, and D particles.
Yo is
Th
G
, I IT
on er
si d
is m
If Beds with Internals

m ju
er Ma
rp K
rio S
• Hydraulic diameter of the bed

t p rof
ou P
ith @
w ght
i
r m yr
fo p
y co
an er
in d
it un
e is

For all calculations for different parameters will be based on the


us nt

hydraulic diameter instead of normal diameter of the bed


ot e
nn um
ca cc
u do
Yo is
Th
Th
Yo is
u do
ca cc
nn um
ot e
us nt
e is
it un
in d
an er
y co
fo p
r m yr
i
w ght
ith @
ou P
t p rof
Thank You

rio S
rp K
er Ma
m ju
is m
si d
on er
, I IT
G
G
I IT
,
on er
si d
is m
m ju
er Ma
Fluidization Engineering

rp K
rio S
t p rof
ou P
ith @
Lecture 11: Bubbling Fluidization-Part 2: Bubble

w ght
i
Characteristics

r m yr
fo p
y co
an er
By
in d
it un

Dr. Subrata K. Majumder


e is
us nt

Chemical Engineering Department, IIT Guwahati


ot e
nn um

Contact: [email protected]
ca cc
u do
Yo is
Th
G
I IT
,
on er
si d
is m
Growth of Bubbles in Fluidized Beds

m ju
er Ma
rp K
rio S
• The bubbles in fluidized beds grow in size due primarily to three

t p rof
ou P
factors:

ith @
• The effective hydrostatic pressure decreases toward the top of

w ght
the fluidized bed

i
r m yr
fo p
• Bubbles coalesce in the vertical direction with the trailing
y co
bubble catching up the leading bubble, and
an er
in d

• Bubbles coalesce in the horizontal direction with the


it un

neighboring bubbles
e is
us nt

• The effect of the hydrostatic pressure is usually small


ot e
nn um

• The bubbles grow in size owing largely to coalescence


ca cc
u do
Yo is
Th
G
I IT
,
on er
si d
Galdert Model

is m
m ju
er Ma
rp K
rio S
• Geldart (1972) found that the fluidization behavior of

t p rof
Group B powders was independent of both of the mean

ou P
ith @
particle size and of particle size distribution.

w ght
• In particular, the mean bubble size was found to depend

i
r m yr
only on the type of the distributor, the distance above the
fo p
y co
distributor plate, and the excess gas velocity above that
an er
required at the minimum fluidization condition, u - umf.
in d
it un

Mathematically, it can be expressed as


e is
us nt
ot e
nn um
ca cc
u do
Yo is
Th
G
I IT
,
on er
Galdert Model

si d
is m
m ju
For Porous Plate distributor

er Ma
rp K
rio S
t p rof
Experimentally, it has been found that for the porous

ou P
ith @
plates, the following equation applies

w ght
i
r m yr
fo p
y co
an er
in d

Applicable for porous plate of 1 hole per 10 cm2 of bed


it un
e is

area.
us nt
ot e
nn um
ca cc
u do
Yo is
Th
Th

used
Yo is
u do
ca cc
nn um
ot e
us nt
e is
it un
in d
an er
y co
fo p
r m yr
i
w ght
ith @
ou P
t p rof
For Orifice Plate distributor

rio S
rp K
er Ma
m ju
is m
si d
on er
, I IT
G
For orifice plates, the following equation can be
Galdert Model
G
I IT
,
on er
si d
is m
m ju
Mori and Wen Model

er Ma
rp K
rio S
t p rof
Mori and Wen (1975) assumed that all gas

ou P
above the minimum fluidizing velocity went

ith @
w ght
to form a single train of bubbles rising along

i
the center line of the bed and calculated the

r m yr
fo p
diameter of bubble with bed height h as
y co
an er
in d
it un
e is
us nt
ot e
nn um
ca cc
u do
Yo is
Th
G
I IT
,
on er
si d
is m
m ju
er Ma
• According to Mori and Wen (1975)

rp K
model, the maximum bubble size

rio S
depends on only relative velocity of gas

t p rof
to the minimum fluidization velocity and

ou P
ith @
the cross sectional area of the bed

w ght
i
r m yr
fo p
y co
an er
in d
it un

where Abed is the area of


e is

the bed and Nor is the


us nt

total number of orifices.


ot e
nn um
ca cc
u do
Yo is
Th
G
I IT
,
on er
si d
is m
Initial Bubble size (Mori and Wen, 1975 Model)

m ju
er Ma
rp K
rio S
For perforated plates, the initial

t p rof
ou P
bubble diameter dbo is expressed as

ith @
w ght
i
r m yr
fo p
y co
an er
in d
it un
e is
us nt

where Abed is the area of


ot e

the bed and Nor is the


nn um

total number of orifices.


ca cc
u do
Yo is
Th
G
I IT
,
on er
For porous plates:

si d
is m
m ju
er Ma
The following expression should be used

rp K
to estimate the initial bubble sizes.

rio S
t p rof
ou P
ith @
w ght
i
r m yr
fo p
y co
The validity of the above equations has been tested within
an er
in d

the ranges of the following parameters


it un
e is
us nt
ot e
nn um
ca cc
u do
Yo is
Th
G
I IT
,
on er
Rowe model

si d
is m
m ju
er Ma
• Rowe (1976) suggested the following equation to estimate the

rp K
rio S
bubble size in a fluidized bed:

t p rof
ou P
ith @
w ght
i
r m yr
fo p
y co
an er
• Here ho is an empirical constant and is a characteristics of the
in d
it un

distributor plate.
e is

ho = 0 for a porous plate


us nt
ot e
nn um

> 1 m for large tuyeres


ca cc
u do
Yo is
Th
G
I IT
,
on er
Darton et al. model

si d
is m
m ju
er Ma
rp K
• Darton et al. (1977) assumed that the

rio S
bubbles are lined up as close together

t p rof
as possible, as shown in Fig. They also

ou P
ith @
defined a so-called ‘‘catchment area’’

w ght
for each particular bubble track. The

i
r m yr
bubble frequency can then be
fo p
y co
calculated by ub/2Rb with the bubble
an er
velocity
in d
it un
e is
us nt
ot e
nn um
ca cc
u do
Yo is
Th
Th
Yo is
u do
ca cc
nn um
ot e
us nt
e is
it un
in d
the two phase theory.

an er
y co
fo p
r m yr
i
w ght
ith @
ou P
• The bubble flow in each track can
be calculated as follows assuming

t p rof
rio S
rp K
er Ma
m ju
Darton et al. model (cont.)

is m
si d
on er
, I IT
G
G
I IT
,
on er
Darton et al. model (cont.)

si d
is m
m ju
er Ma
rp K
If the bubbles are hemispheres, the volume of each

rio S
individual bubble can be calculated by the equation

t p rof
ou P
ith @
w ght
i
r m yr
fo p
y co
an er
in d

Then, after substitution


it un

Acatch = Catchment area;


e is
us nt

The catchment area is


ot e
nn um

defined as the area of


distributor plate per hole
ca cc
u do
Yo is
Th
G
I IT
,
on er
si d
is m
Darton et al. model (cont.)

m ju
er Ma
rp K
rio S
t p rof
When two bubbles of equal volume

ou P
ith @
from the nth stage coalesce to form a

w ght
bubble of the (n+1)th stage, you can

i
r m yr
have

fo p
y co
an er
in d
it un
e is
us nt
ot e
nn um
ca cc
u do
Yo is
Th
G
I IT
,
on er
Darton et al. model (cont.)

si d
is m
m ju
er Ma
rp K
If you further assume that the height of each bubble

rio S
coalescence stage is proportional to the diameter of the

t p rof
catchment area, you can get

ou P
ith @
w ght
i
 = 1.17.

r m yr
fo p
y co
an er
where dc is the diameter of a circular catchment area for
in d
it un

each bubble stream and hn is height of nth stage.


e is
us nt
ot e
nn um
ca cc
u do
Yo is
Th
Th
Yo is
Since
u do
ca cc
nn um
ot e
us nt
e is
it un
in d
an er
y co
fo p
r m yr
i
w ght
ith @
ou P
t p rof
rio S
rp K
er Ma
m ju
With the initial bubble diameter, one can get

is m
si d
on er
,
Darton et al. model (cont.)

I IT
G
G
I IT
,
Darton et al. model (cont.)

on er
si d
is m
m ju
er Ma
The total bed height can thus be expressed as

rp K
rio S
t p rof
ou P
ith @
 = 1.17.

w ght
i
r m yr
fo p
y co
an er
If the bubbles grow to the size of the vessel diameter, the
in d
it un

bed becomes a slugging bed. From this analysis, this occurs


e is

at the following conditions


us nt
ot e
nn um
ca cc
u do
Yo is
Th
G
, I IT
on er
Zenz (1977) model

si d
is m
m ju
er Ma
Zenz (1977) assumed the bubble growth in the fluidized

rp K
rio S
bed resembles the well-known Fibonacci series (Zenz,

t p rof
1978) and proposed the following equation for bubble

ou P
growth.

ith @
w ght
i
r m yr
fo p
y co
an er
in d
it un
e is
us nt
ot e
nn um
ca cc

n is 1, 2, 3, 5, 8, 13,......... A Fibonacci Series


u do

Bubble growth by Fibonacci series


Yo is
Th
G
I IT
,
on er
si d
Choi et al. (1998) Model

is m
m ju
er Ma
rp K
rio S
 For the model, it made use of the simplified collision theory to

t p rof
account for the coalescing frequency of the bubble with

ou P
ith @
assumptions that

w ght
the bubble moves upward,

i
r m yr
fo p
the time-averaged instantaneous bubble movement at a point
y co
of bed cross section is regular, and
an er
in d
it un

the bubble speed, Vb, as constant. And hence, average bubble-


e is

rising velocity, ub, is related as half of Vb.


us nt
ot e

Bubble coalescence was considered to occur on a pair of


nn um

bubbles at a time.
ca cc
u do
Yo is
Th
G
I IT
,
on er
si d
is m
Choi et al. Model (cont.)

m ju
er Ma
rp K
rio S
The coalescing frequency per unit volume Fcv is

t p rof
expressed as

ou P
ith @
w ght
i
r m yr
fo p
y co
an er
in d
it un
e is
us nt
ot e
nn um

where db and n are the spherical bubble diameter and the


ca cc

number of bubbles per unit volume, respectively.


u do
Yo is
Th
G
I IT
,
on er
si d
is m
Choi et al. Model (cont.)

m ju
er Ma
rp K
rio S
When the number of bubbles is assumed to increase by 1 (one)

t p rof
at a breakup of a bubble, the total splitting frequency per unit

ou P
ith @
volume Fs can be written as

w ght
i
r m yr
fo p
y co
an er
in d
it un
e is
us nt

in which fs* is the average splitting frequency of an original


ot e
nn um

single bubble.
ca cc
u do
Yo is
Th
G
I IT
,
on er
si d
is m
m ju
er Ma
Choi et al. Model (cont.)

rp K
rio S
t p rof
ou P
ith @
The variation of the number flow rate Nf of bubbles across the

w ght
bed cross section with respect to height h above the distributor

i
r m yr
is
fo p
y co
an er
in d
it un
e is
us nt
ot e
nn um

with an initial condition that Nf = Nfo at h = 0


ca cc
u do
Yo is
Th
G
I IT
,
on er
Choi et al. Model (cont.)

si d
is m
m ju
er Ma
When umb = umf and volumetric bubble flux qb = (u - umf),

rp K
rio S
t p rof
the number flow rate Nf of bubbles across the bed cross section

ou P
ith @
and bubble voidage b are estimated from the following relations,

w ght
respectively:

i
r m yr
fo p
y co
an er
in d
it un
e is
us nt

where  is a coefficient.
ot e

For coarse particles, the minimum


nn um

bubbling velocity equals umf, but


ca cc

for fine particles it is much larger


u do

than umf.
Yo is
Th
Th
Yo is
u do
ca cc
nn um
ot e
us nt
e is
it un
in d
an er
y co
fo p
r m yr
i
w ght
ith @
ou P
t p rof
rio S
rp K
er Ma
m ju
is m
si d
on er
, I IT
G
G
, I IT
on er
si d
Choi et al. Model (cont.)

is m
m ju
er Ma
rp K
Since ub = Vb/2 the variation of bubble diameter db

rio S
t p rof
with respect to height h is

ou P
ith @
w ght
i
r m yr
fo p
y co
an er
in d
it un

with an initial condition that db = dbo at h = 0.


e is
us nt
ot e

Glicksman et al. (1987) considered the mean coalescence rate while assuming the
nn um

bubbles were in a random spatial distribution like that of the present Choi et al.
ca cc

(1998) Model.
u do
Yo is
Th
G
I IT
,
on er
si d
is m
m ju
Choi et al. Model (cont.)

er Ma
rp K
rio S
If the coalescence frequencies = breakup frequencies,

t p rof
ou P
ith @
the bubble diameter becomes the equilibrium bubble diameter that is

w ght
i
r m yr
fo p
y co
an er
in d

the equilibrium bubble diameter increases linearly with the ratio


it un

of volumetric bubble flux qb to the splitting frequency of a bubble


e is
us nt
ot e
nn um
ca cc
u do
Yo is
Th
G
, I IT
on er
Choi et al. Model (cont.)

si d
is m
m ju
er Ma
Substituting the above equation of equlibrium condition, and with the initial
boundary condition, the variation of bubble diameter db with respect to height h

rp K
can be expressed as

rio S
t p rof
ou P
ith @
w ght
i
r m yr
fo p
Where
y co
an er
in d
it un
e is
us nt
ot e

Miwa et al.
nn um

(1972)
ca cc
u do

For perforated plate distributor For porous plate distributor


Yo is
Th
Th
Yo is
u do
ca cc
nn um
ot e
us nt
e is
it un
in d
an er
y co
fo p
r m yr
i
w ght
ith @
ou P
t p rof
rio S
rp K
er Ma
m ju
is m
si d
et al. (1998)

on er
, I IT
G
How bubble size is changing

fluid velocity is shown by Choi


with height of fluidized bed and
G
, I IT
on er
si d
Bubble growth from Mutiple Entry Nozzles

is m
m ju
er Ma
rp K
Bubble growth from mutiple entry nozzles was studied by Yates et al. (1995)

rio S
t p rof
for a Group A powder by means of x-rays. The simple correlation expressed
here was found to correlate the data well:

ou P
ith @
w ght
i
ls = the orifice separation distance

r m yr
fo p
y co hc = the average height above the
an er
orifice at which coalescence completes
in d
it un
e is

The volume of the bubble void and its associated gas shell following
us nt
ot e

coalescence can be correlated as


nn um
ca cc
u do

Vb = the bubble volume


Yo is
Th
G
, I IT
on er
Pattern of bubble growth and

si d
is m
m ju
solid circulation

er Ma
rp K
rio S
• All the models for the growth of bubbles in fluidized Constant gas velocity, increasing bed height

t p rof
beds have assumed same type of ordered

ou P
ith @
progression and independent of solid movement in

w ght
the beds

i
• Whitehead (1979)pointed out that the pattern of

r m yr
fo p
bubble coalescence and solid circulation in large
y co
industrial fluidized beds depended on both the bed
an er
depth and the operating velocity
in d
it un

• Figure shows the patterns observed in large Constant bed height, increasing gas velocity
e is

fluidized beds of Group B powders with industrial-


us nt

type distributor plates (Whitehead and Young, 1967;


ot e

Whitehead et al., 1977)


nn um
ca cc
u do
Yo is
Th
Th
Yo is
u do
ca cc
nn um
ot e
us nt
e is
it un
in d
an er
y co
fo p
r m yr
i
w ght
ith @
ou P
Thank You

t p rof
rio S
rp K
er Ma
m ju
is m
si d
on er
, I IT
G
G
I IT
,
on er
si d
is m
Fluidization Engineering

m ju
er Ma
rp K
rio S
t p rof
Lecture 12: Bubbling Fluidization-Part 3: Bubble

ou P
ith @
coalescence in three-phase fluidization

w ght
i
r m yr
fo p
y co By
an er
in d

Dr. Subrata K. Majumder


it un
e is

Chemical Engineering Department, IIT Guwahati


us nt
ot e

Contact: [email protected]
nn um
ca cc
u do
Yo is
Th
G
I IT
,
on er
si d
is m
Coalescence

m ju
er Ma
rp K
rio S
• The coalescence of two bubbles in turbulent flow in

t p rof
three phase fluidized bed is usually considered to

ou P
occur in three steps.

ith @
• First, the bubbles collide,

w ght
• Second, the surface of the colliding bubbles

i
r m yr
flattens against each other

fo p
y co
• Third, trapping a small amount of liquid
an er
between colliding bubbles
in d
it un

• Since the collision of three or more bubbles at the


same time has a very small probability, only binary
e is

collision is normally considered in coalescence


us nt
ot e

models.
nn um
ca cc
u do
Yo is
Th
Th
Yo is
u do
ca cc
nn um
ot e

Colliding
us nt
e is
it un
in d
an er
y co
fo p
r m yr
i
w ght
ith @
Coalescence mechanism

ou P
surface
t p rof
v = velocity, rio S
Flattens the

rp K
er Ma
h = drainage height

m ju
is m
si d
on er
, I IT
G
G
I IT
,
on er
si d
is m
m ju
Film thining model of coalescence

er Ma
rp K
rio S
t p rof
• Coalescence may not result from each collision, and thus

ou P
coalescence efficiency was introduced by many investigators.

ith @
w ght
The most popular model for the coalescence efficiency is the

i
film-thinning model (e.g., Kirkpatrick and Lockett, 1974,

r m yr
fo p
Prince and Blanch, 1990, Luo, 1993).
y co
an er
in d
it un

• According to the model, when the bubbles approach faster,


e is

they tend to bounce back without coalescence due to the


us nt

limitation on the film drainage rate governed by the surface


ot e
nn um

tension.
ca cc
u do
Yo is
Th
G
I IT
,
on er
si d
is m
Film thining model of coalescence

m ju
er Ma
rp K
• Two bubbles will coalesce provided they remain in contact for

rio S
t p rof
a period of time sufficient for the liquid film between them to

ou P
thin out to the critical value necessary for rupture.

ith @
w ght
• The coalescence rate, Ω, for bubbles of size of di and dj, can be

i
r m yr
expressed as

fo p
y co
an er
in d
it un
e is
us nt
ot e
nn um

Where θij is the collision frequency and Pc is the


ca cc

coalescence efficiency.
u do
Yo is
Th
G
I IT
,
on er
Collision Frequency

si d
is m
m ju
er Ma
• Collision may occur due to a variety of mechanisms. One is the

rp K
random motion of bubbles due to turbulence. Saffman and Turner

rio S
t p rof
(1956) proposed a collision frequency model which only takes

ou P
turbulent collision into account

ith @
w ght
i
r m yr
fo p
y co
an er
in d

• where θij is the collision frequency between bubbles with diameter of di


it un

and dj.
e is
us nt

• ni and nj are the bubble number density (m-3),


ot e
nn um

• ε is local turbulent specific energy dissipation rate (m2s−3)


ca cc
u do
Yo is
Th
G
I IT
,
on er
si d
is m
m ju
er Ma
• In addition to turbulence, bubbles

rp K
rio S
of different sizes have different

t p rof
rise velocities that may lead to

ou P
ith @
collision

w ght
i
r m yr
fo p
• Also bubbles located in a region of
y co
relatively high liquid velocity may
an er
collide with bubbles in a slower
in d
it un

section of the velocity field


e is
us nt
ot e
nn um
ca cc
u do
Yo is
Th
G
, I IT
on er
si d
• Prince and Blanch (1990) proposed a collision frequency model based on the

is m
m ju
summation of the turbulent collision rate, buoyancy-driven collision rate

er Ma
and laminar shear collision rate as follows:

rp K
rio S
t p rof
ou P
ith @
w ght
i
r m yr
fo p
y co
an er
in d
it un
e is
us nt
ot e
nn um
ca cc
u do

ul is the liquid velocity, R is the radius of bubble


Yo is
Th
G
I IT
,
on er
si d
Lehr and Mewes (2001) model for collision

is m
m ju
er Ma
frequency

rp K
rio S
t p rof
• Lehr and Mewes (2001) suggested another

ou P
ith @
expression for collision frequency following

w ght
Prince and Blanch’s (1990) model which takes

i
r m yr
the turbulence and buoyancy driven induced
fo p
y co
collision into account:
an er
in d
it un
e is
us nt
ot e
nn um
ca cc
u do
Yo is
Th
G
I IT
,
on er
si d
Lehr and Mewes (2001) model for collision

is m
m ju
frequency

er Ma
rp K
rio S
• If a bubble enters another bubble’s wake

t p rof
ou P
(Figure), it will usually overtake the leading

ith @
bubble in an inline collision that may result in

w ght
coalescence.

i
r m yr
fo p
y co
• Although there are many observations of the
an er
wake effects, all of which showed that the wake
in d
it un

effect is very important for coalescence, the


e is

wake-induced collision models are rare.


us nt
ot e
nn um
ca cc
u do
Yo is
Th
G
I IT
,
on er
si d
is m
Collision frequency due to wake entrainment

m ju
er Ma
rp K
• Wu et al. (1998) defined the effective wake

rio S
t p rof
volume, in which the bubbles that follow may

ou P
collide with the leading one is:

ith @
w ght
= the projected bubble area  by the effective

i
r m yr
fo p
length, L, which is 5-7 times the bubble
y co
an er
diameter.
in d
it un
e is
us nt

• They assumed that the wake structure of the


ot e
nn um

leading bubble to be the same as that of a solid


ca cc

sphere
u do
Yo is
Th
G
I IT
,
on er
Collision frequency due to wake entrainment

si d
is m
m ju
er Ma
• Wu et al. (1998) presented the following collision frequency due to wake

rp K
entrainment (bubble of size d is the leading bubble):

rio S
t p rof
ou P
ith @
w ght
i
r m yr
fo p
y co
an er
in d

Lw
it un
e is
us nt
ot e
nn um
ca cc

Lw = length of wake
u do

g = gas holdup
Yo is
Th
G
I IT
,
on er
Some important points

si d
is m
m ju
er Ma
rp K
• Most authors use turbulence-induced collision only, partly

rio S
because the wake-induced collision, especially the wake-

t p rof
induced coalescence efficiency, is not well understood.

ou P
ith @
• As far as the order of magnitude is concerned, the wake

w ght
and turbulence induced collision are of the same order,

i
r m yr
while the laminar shear induced collision is less important.
fo p
y co
• The buoyancy-driven collision is an inline collision, and
an er
in d

when the leading bubble collides with the trailing bubble,


it un

the trailing bubble is in the wake of the leading bubble.


e is
us nt

• Hence, the velocity difference between the two bubbles


ot e
nn um

cannot be calculated by the free rising velocity difference


as suggested by Clift et al. (1978)
ca cc
u do
Yo is
Th
G
I IT
,
on er
si d
Some Important Points (contd.)

is m
m ju
er Ma
rp K
• In summary, in turbulent flow there are only two important

rio S
collision mechanisms: the wake entrainment and turbulence.

t p rof
ou P
• One can either assume that the wake-induced coalescence

ith @
efficiency is the same as the turbulence-induced coalescence

w ght
efficiency so that the summation of these two collision frequency

i
r m yr
can then be used to calculate the coalescence efficiency (Hibiki
fo p
and Ishii, 2000)y co
an er
in d

• or one can consider only the turbulence-induced collision as the


it un

existing coalescence efficiency models are based on turbulence


e is

induced coalescence (Luo, 1993).


us nt
ot e
nn um
ca cc
u do
Yo is
Th
G
I IT
,
on er
si d
is m
m ju
Coalescence Efficiency

er Ma
rp K
rio S
t p rof
• According to coalescence theory (Ross et al., 1978; Chesters,

ou P
1991), coalescence will more likely to occur upon a collision of

ith @
two bubbles if the contact time (interaction time), tI, exceeds

w ght
the coalescence time, tc, required for drainage of the liquid film

i
r m yr
between them to a critical rupture thickness
fo p
y co
• Coulaloglou and Tavlarides (1977) suggested the following
an er
in d

expression in liquid droplet coalescence rate investigation.


it un
e is
us nt
ot e
nn um
ca cc
u do
Yo is
Th
G
I IT
,
on er
Interaction and coalescence times

si d
is m
m ju
er Ma
• the interaction time, tI, is proportional to the characteristic

rp K
lifetime of an eddy of size equal to the sum of the sizes of the

rio S
approaching bubbles which can be estimated as

t p rof
ou P
ith @
w ght
i
r m yr
• the coalescence time, tc, can be estimated from the film
fo p
drainage modely co
an er
in d
it un
e is

Then the coalescence efficiency can be estimated as


us nt
ot e
nn um
ca cc
u do
Yo is
Th
Th
Yo is
u do
ca cc
nn um
ot e
us nt
e is
efficiency

it un
in d
an er
y co
fo p
r m yr
i
w ght
ith @
ou P
t p rof
rio S
rp K
er Ma
m ju
is m
si d
on er
, I IT
G
Different Models of bubble coalescence
G
I IT
,
on er
si d
is m
m ju
• As per experiments of Doubliez, 1991; Duineveld,

er Ma
1994 with individual bubbles show that small

rp K
rio S
bubbles and small approach velocities lead to

t p rof
higher coalescence efficiency

ou P
ith @
w ght
i
r m yr
• Thus, for two colliding bubbles with given
fo p
y co
diameters the coalescence efficiency depends on
an er
the relative velocity of approach.
in d
it un
e is
us nt

• This velocity depends on the angle at which the


ot e
nn um

two bubbles collide.


ca cc
u do
Yo is
Th
G
, I IT
on er
si d
is m
m ju
• Lehr and Mewes (2001) assume that the relative

er Ma
probability is equal for all steradians. Thus, the

rp K
coalescence efficiency can be written as:

rio S
t p rof
ou P
ith @
w ght
i
r m yr
fo p
y co
an er
in d
it un
e is
us nt

Wecrit = 0.06 Steradians:


ot e

the SI unit of solid angle, equal to the angle at


nn um

the centre of a sphere subtended by a part of


ca cc

the surface equal in area to the square of the


u do

radius.
Yo is
Th
G
I IT
,
on er
Super imposition of buoyancy driven and laminar shear collision

si d
is m
frequencies on turbulence induce collision frequency:

m ju
er Ma
rp K
• The buoyancy driven and laminar shear collision frequencies may be

rio S
superimposed on turbulence induce collision frequency (Prince and

t p rof
Blanch, 1990) because the bubble relative velocity can be

ou P
ith @
superimposed,

w ght
• So the turbulent induced coalescence efficiency model may not be

i
r m yr
fo p
applied to buoyancy driven and laminar shear collision events.
y co
• Still coelescence rate equation can be used as
an er
in d
it un

If
e is
us nt
ot e
nn um

then the coalescence rate, can be estimated as


uij is the bubble
ca cc

approach velocity
u do
Yo is
Th
G
I IT
,
on er
si d
is m
m ju
Ojima et al. (2015) Model for coalescence in

er Ma
slurry fluidized bed

rp K
rio S
t p rof
• The authors (Ojima et al., 2014a), therefore, measured the time,

ou P
ith @
tC, elapsed from bubble contact to the rupture of the liquid

w ght
film between two coalescing bubbles in a 2D column using

i
r m yr
hydrophilic particles of 100 μm in diameter to quantitatively

fo p
evaluate the effect of particle concentration on bubble
coalescence
y co
an er
in d
it un

• The tC decreased with increasing the volume concentration CS


of particles, i.e., bubble coalescence is enhanced with
e is
us nt

increasing CS.
ot e
nn um
ca cc
u do
Yo is
Th
G
I IT
,
on er
si d
Ojima et al. (2015) Model (cont.)

is m
m ju
er Ma
• First they have interpreted the coalescence of bubble in absence of

rp K
particle as shown in Figure which shows a typical bubble coalescence

rio S
t p rof
process between two bubbles in the absence of particles (CS=0). The origin

ou P
of the time in the figure was set at the instant of bubble coalescence. The

ith @
process can be divided into two phases:

w ght
i
r m yr
Approach phase where the trailing

fo p
y co bubble faster than the leading bubble
approaches the latter, and
an er
in d

Coalescence phase where the distance


it un

between contacting bubbles is kept


e is

almost constant before the liquid film


us nt

ruptures
ot e
nn um
ca cc
u do
Yo is
Th
G
, I IT
Ojima et al. (2015) Model (cont.)

on er
si d
is m
m ju
er Ma
• They also done the experiment with different conentration of particles and explained as:

rp K
• They stated that coalescing bubbles at CS= 0.20 as shown in Figure (a). compared with the

rio S
bubbles at CS=0, the coalescence phase is shorter at all dS. The decrease in dS also decreases

t p rof
the time duration of the coalescence phase, i.e., bubble coalescence is enhanced.

ou P
• The effect of dS, however, disappears at the higher concentration, CS = 0.40, as shown in

ith @
Figure (b). In this case, the bubbles coalesce immediately after the contact, so that dS has

w ght
little influence on coalescence.

i
r m yr
fo p
y co
an er
in d
it un
e is
us nt
ot e
nn um
ca cc
u do

(a) (b)
Yo is
Th
G
, I IT
on er
Ojima et al. (2015) Model (cont.)

si d
is m
m ju
• Figure (c) shows an example of the bubble coalescence processes of coalescing bubbles

er Ma
at CS=0.30 and dS=100 μm, where 0 s denotes the instant of film rupture. There are

rp K
particles in the film. The film thickness is about 300 μm and is almost uniform in the

rio S
recorded region before the film rupture (−3/12,500 s). The film then ruptures within the

t p rof
time duration of 1/12,500 s and the rupture front rapidly propagates. The bubble
coalescence processes at dS=60 and 150 μm are shown in Figure (d).

ou P
ith @
w ght
i
r m yr
fo p
y co
an er
in d
it un

(c) (d)
e is
us nt
ot e
nn um
ca cc
u do
Yo is
Th
G
, I IT
on er
si d
is m
Ojima et al. (2015) Model (cont.)

m ju
er Ma
rp K
• They reported that the final film thickness hf before the film rupture tended

rio S
to increase with increasing CS and with decreasing dS. The cause of this

t p rof
tendency can be understood as follows:

ou P
ith @
• since the order of the film thickness is a few times of dS, the liquid film

w ght
takes a porous-like structure due to the presence of particles. The liquid

i
r m yr
elements there are, therefore, to be very thin and fragile.

fo p
y co
• The particle number density increases with decreasing dS, and therefore,
an er
the decrease in dS makes the porous-like structure finer and more fragile.
in d
it un
e is

For two-phase flow


us nt
ot e
nn um

However this should be changed in presence of particle


ca cc
u do
Yo is
Th
G
, I IT
on er
si d
is m
m ju
Ojima et al. (2015) Model (cont.)

er Ma
rp K
rio S
• The enhancement of bubble coalescence due to the presence of

t p rof
particles can, therefore, be implemented into the model by

ou P
ith @
accounting for the particle effect on hf.

w ght
• For this, They introduced a particle-effect multiplier into the

i
r m yr
coalescence efficiency in the Prince–Blanch model as follows:
fo p
y co
an er
in d
it un
e is
us nt
ot e
nn um

Here must be one at CS=0 and =0 at CS=0.45 because of the immediate


coalescence after contact.
ca cc
u do
Yo is
Th
G
I IT
,
on er
si d
is m
m ju
Ojima et al. (2015) Model (cont.)

er Ma
rp K
rio S
t p rof
• They reported that for  can be evaluated within

ou P
ith @
a range 0<CS<0.45 using the linear interpolation,

w ght
i
r m yr
fo p
y co
an er
in d
it un
e is
us nt
ot e
nn um
ca cc
u do
Yo is
Th
G
I IT
,
on er
si d
is m
m ju
Ojima et al. (2015) Model (cont.)

er Ma
rp K
rio S
t p rof
• They haave suggested the following interpolation

ou P
ith @
function based on their interpolation data as

w ght
i
r m yr
fo p
y co
an er
in d
it un
e is
us nt
ot e
nn um
ca cc
u do
Yo is
Th
G
I IT
,
on er
si d
Ojima et al. (2015) Model (cont.)

is m
m ju
er Ma
rp K
From their model it was concluded that

rio S
t p rof
• The time required for bubble coalescence after bubble contact

ou P
decreases, in other words, bubble coalescence is enhanced with

ith @
decreasing the particle diameter.

w ght
i
• The particle-effect multiplier is of great use to take into account the

r m yr
fo p
effects of the particle concentration and diameter in multi-fluid
y co
simulations of three-phase fluidized bed.
an er
in d

• The interaction between the bubble interfaces and particles in the


it un

bubble coalescence process after bubble contact is a local


e is
us nt

phenomenon and rarely depends on the macroscopic behavior of the


ot e
nn um

interface.
ca cc
u do
Yo is
Th
Th
Yo is
u do
ca cc
nn um
ot e
us nt
e is
it un
in d
an er
y co
fo p
r m yr
i
w ght
ith @
ou P
Thank You

t p rof
rio S
rp K
er Ma
m ju
is m
si d
on er
, I IT
G
G
I IT
,
on er
si d
is m
m ju
er Ma
Fluidization Engineering

rp K
rio S
t p rof
ou P
Lecture 13: Bubbling Fluidization-Part 4: Bubble

ith @
w ght
breakup in three-phase fluidization

i
r m yr
fo p
y co By
an er
in d
it un

Dr. Subrata K. Majumder


e is

Chemical Engineering Department, IIT Guwahati


us nt
ot e
nn um

Contact: [email protected]
ca cc
u do
Yo is
Th
G
, I IT
on er
Bubble breakup

si d
is m
m ju
er Ma
rp K
• The bubbles in turbulent dispersion are not only exposed to a turbulent

rio S
field, but are also subject to both inertial and viscous forces.

t p rof
ou P
• Moreover, the gas-liquid interface is also subjected to instability due to the

ith @
difference in density and velocity of the gas and liquid phase

w ght
• The most important force in stabilizing the bubble is the surface tension

i
r m yr
fo p
• In addition, a centrifugal force, induced by internal circulation of the gas in
y co
a bubble, can suppress the disturbances at the gas-liquid interface and act
an er
as a stabilizing force
in d
it un

• On the other hand, such a centrifugal force can also disintegrate the bubble
e is

as it increases with an increase in bubble size. The bubble breaks up when


us nt

the centrifugal force exceeds the surface tension force, especially at high
ot e

pressures when gas density is high.


nn um
ca cc
u do
Yo is
Th
G
, I IT
on er
The fate of a bubble breakup

si d
is m
m ju
er Ma
• The fate of a bubble is determined by the breakup/

rp K
deformation force and the stabilization/restoration force

rio S
t p rof
(Table).

ou P
• If the bubbles are much larger than the microscale of

ith @
w ght
turbulence (Shinnar, 1961; Narsimhan et al., 1979), the viscous

i
force can be neglected.

r m yr
fo p
y co
Breakup/deformation force Stabilization/restoration force
an er
Turbulent stress/ eddy bombardment Surface tension
in d
it un

Inertial force Liquid acceleration along the bubble


e is

Viscous force surface


us nt
ot e

Kelvin-Helmholtz instability
nn um

Rayleigh-Taylor instability
ca cc
u do

Centrifugal force induced by gas internal circulation


Yo is
Th
G
, I IT
on er
si d
The fate of a bubble breakup

is m
m ju
er Ma
• Concerning the criterion for breakup, one can distinguish at

rp K
rio S
least five cases in the literature

t p rof
• (i) Turbulent kinetic energy of the bubble greater than a critical

ou P
ith @
value (Chatzi et al., 1989)

w ght
• (ii) Velocity fluctuation around the particle surface greater

i
r m yr
than a critical value (Alopaeus et al., 2002)

fo p
y co
• (iii) Turbulent kinetic energy of the hitting eddy greater than a
critical value (Martinez-Bazan et al., 1999)
an er
in d

• (iv) Inertial force of the hitting eddy greater than the interfacial
it un

force of the smallest daughter particle (Lehr et al., 2002)


e is
us nt

• (v)Combination of the criterion (c) and (d) (Zhao and Ge,


ot e

2007).
nn um
ca cc
u do
Yo is
Th
G
I IT
,
on er
si d
is m
The fate of a bubble breakup (cont.)

m ju
er Ma
rp K
rio S
t p rof
• Much of the published literature assumes that the

ou P
bubble break-up occurs through bubble interactions

ith @
w ght
with turbulent eddies

i
r m yr
• Only the eddies which are approximately equal to the
fo p
y co
size of the bubble can break the bubble, since larger
an er

eddies have the tendency to transport the bubble rather


in d
it un

than break it,


e is
us nt

• while very small eddies do not contain sufficient


ot e
nn um

energy to break the bubble.


ca cc
u do
Yo is
Th
G
I IT
,
on er
si d
The fate of a bubble breakup (cont.)

is m
m ju
er Ma
• For a complete bubble breakup model, the number of daughter

rp K
bubbles produced upon breakup of a parent bubble, the daughter

rio S
t p rof
bubble size probability density function (p.d.f.) and breakup rate

ou P
need to be provided

ith @
w ght
• In addition, when a bubble exceeds a critical value, the bubble

i
interface becomes unstable and breakup is likely to occur.

r m yr
fo p
Therefore, the bubble breakup can be related to the maximum
y co
attainable stable size (Kocamustafaogullari and Ishii, 1995)
an er
in d

• And hence a complete bubble breakup model, should also include


it un

the maximum stable bubble size (which gives a threshold below


e is
us nt

which a bubble will not be breakable in a given turbulent flow


ot e

field).
nn um
ca cc
u do
Yo is
Th
G
I IT
,
on er
si d
is m
m ju
The fate of a bubble breakup (cont.)

er Ma
rp K
rio S
t p rof
• In turbulent flow, bubble breakup is caused by fluctuating eddies

ou P
ith @
resulting in the pressure variation along the bubble surface.

w ght
• When a bubble size exceeds a critical value, at which the

i
r m yr
breakup/deformation mechanism and the stabilization/ restoration
fo p
y co
mechanism reach equilibrium, the bubble interface becomes
an er
unstable and break-up is likely to occur
in d
it un

• It is to be noted that the maximum stable bubble size is not equal to


e is

the maximum (possible) bubble size in a given system


us nt
ot e
nn um
ca cc
u do
Yo is
Th
G
I IT
,
on er
si d
is m
m ju
Maximum Stable Bubble Size

er Ma
rp K
rio S
t p rof
• Levich (1962) model: recognized the importance of

ou P
internal gas circulation, assumed the centrifugal force

ith @
w ght
to be equal to the dynamic pressure induced by the gas

i
r m yr
moving at the bubble rise velocity, ub, and proposed a
fo p
y co
simple expression to calculate the maximum stable
an er
bubble size:
in d
it un
e is
us nt
ot e
nn um
ca cc
u do
Yo is
Th
G
, I IT
on er
si d
Maximum Stable Bubble Size (cont.)

is m
m ju
er Ma
• Martínez-Bazán et al. (1999) model: Martínez-Bazán et

rp K
al. (1999), based on Kolmogorov’s concept, suggested

rio S
t p rof
the following maximum stable bubble size in turbulent

ou P
ith @
flows

w ght
i
r m yr
fo p
y co  = 8.2
an er
in d

 = the energy dissipation rate per


it un

unit mass of fluid mixture (m2s−3)


e is
us nt

In this model, only the dominant forces, turbulence stress and


ot e
nn um

surface tension, are considered


ca cc
u do
Yo is
Th
G
, I IT
on er
Energy dissipation rate is the rate of energy loss due to fluid flow from location (1) to

si d
is m
location (2). The rate of energy loss in a turbulent flow is given by

m ju
er Ma
rp K
rio S
t p rof
ou P
ith @
w ght
where
ρ = density of the fluid (kg/m3)

i
r m yr
P1 = pressur at upstream location (N/m2)

fo p
y co
P2 = pressur at downstream location (N/m2)
u1 = superficial velocity of the fluid at the upstream location (m/s)
an er
in d

u2 = superficial velocity of the fluid at the downstream location (m/s)


it un

z1,z2 = elevation of fluid relative to reference points upstream and


e is

downstream locations, (m)


us nt

h = energy dissipation from point (1) to point (2) (J/kg)


ot e
nn um

g = gravity acceleration constant (m/s2)


ca cc

Any conversion of mechanical energy into thermal energy is


u do

accounted for the energy dissipation term h.


Yo is
Th
G
I IT
,
on er
si d
is m
m ju
er Ma
rp K
• For estimation of energy dissipation rate in the turbulent

rio S
pipe flow, the well-known empirical relationship can be

t p rof
used

ou P
ith @
w ght
i
r m yr
fo p
y co
an er
in d
it un

where
e is

dc = column diameter (m)


us nt
ot e

f = Fanning friction factor


nn um

u = superficial velocity of continuous liquid (m/s)


ca cc
u do
Yo is
Th
G
, I IT
on er
si d
Energy dissipation rate in the flow passing through a restriction

is m
m ju
er Ma
rp K
• When fluid flows through a restriction, it experiences pressure

rio S
t p rof
drop. It is due to the energy dissipation that take place when

ou P
large velocity gradients are present in the flow

ith @
w ght
i
r m yr
fo p
y co
an er
in d
it un

where where
e is

E = energy dissipation rate (W) ρm = density of phase mixture (kg/m3)


us nt

ΔP = permanent pressure drop (N/m2) Vm,dis = mixture volume used for energy
ot e

Q = volumetric flow rate (m3/s) dissipation (m3)


nn um

tres = mean residence time of the mixture in


ca cc

the dissipation zone (seconds)


u do
Yo is
Th
G
, I IT
on er
si d
is m
Maximum Stable Bubble Size (Cont.)-Other

m ju
er Ma
models

rp K
rio S
t p rof
Luo et al. (1999) model: accounts for the internal

ou P
ith @
circulation of the gas in a bubble by using the force

w ght
balance between the centrifugal force and the surface

i
r m yr
fo p
tension force. y co
an er
in d
it un
e is
us nt
ot e
nn um

 = Surface tension (N/m); g = gravitational acceleration (m/s2)


ca cc
u do
Yo is
Th
G
I IT
,
on er
si d
is m
Maximum Stable Bubble Size (Cont.)-Other

m ju
er Ma
models

rp K
rio S
t p rof
• Lehr and Mewes (2001): suggested another

ou P
ith @
formula following the idea of Levich (1962) and

w ght
Luo and Svendsen (1996):

i
r m yr
fo p
y co
an er
in d
it un
e is
us nt
ot e
nn um
ca cc
u do
Yo is
Th
Th
Yo is
u do
ca cc
nn um
ot e
us nt
e is
it un
in d
an er
y co
fo p
r m yr
i
w ght
ith @
ou P
t p rof
rio S
rp K
er Ma
m ju
is m
Breakup rate or frequency

si d
on er
, I IT
G
G
, I IT
on er
si d
is m
Breakup Rate: Prince and Blanch (1990) Model

m ju
er Ma
• Based on the energy of the eddy and the surface tension force on

rp K
rio S
the bubble, Prince and Blanch (1990) proposed a model for

t p rof
breakup rate shown below:

ou P
ith @
w ght
The model is incomplete as it does not

i
r m yr
provide the daughter bubble size p.d.f.

fo p
y co
an er
in d
it un

Where
ne = eddy density of size de ,
e is

N(k) = number of eddies of wave number (k) per mass of fluid.


us nt

uci = critical velocity of an eddy necessary to break a bubble of


ot e
nn um

diameter di
ca cc

ute = turbulent velocity of an eddy of diameter de,


u do

θie = collision rate of bubbles with eddies of the appropriate size.


Yo is
Th
G
, I IT
on er
si d
Breakup Rate: Luo & Svendsen (1996) Model

is m
m ju
er Ma
• The kinetic energy carried by the turbulent eddies plays a dominant role in the

rp K
break-up process. The imbalance between the kinetic energy and the surface energy

rio S
is used to define the break-up rate

t p rof
ou P
• Luo & Svendsen (1996) developed a bubble breakup model as given as

ith @
w ght
i
r m yr
fo p
y co
an er
in d
it un
e is
us nt
ot e

Where v and v’ are the volume of bubble of two sizes,  = eddy size, lK = Kolmogorov
nn um

length scale
ca cc

 = kinematic viscosity
u do
Yo is
Th
G
I IT
,
on er
si d
is m
Daughter bubble size probability density

m ju
er Ma
function (p.d.f.)- Luo and Svendsen (1996) Model

rp K
rio S
t p rof
• Based on the theory of

ou P
isotropic turbulence, Luo and

ith @
Svendsen (1996) proposed a

w ght
breakup criteria in which the

i
r m yr
fo p
breakup probability is
y co
proportional to the difference
an er
between the energy carried by
in d
it un

the arriving eddies and the


e is

increase in surface energy due


us nt

to a breakup.
ot e
nn um

Luo and Svendsen’s (1996)


ca cc

breakup model illustration


u do
Yo is
Th
G
I IT
,
on er
si d
Daughter bubble size probability density function

is m
m ju
(p.d.f.)- Luo and Svendsen (1996) Model (contd.)

er Ma
rp K
rio S
• The bombarding frequency of the eddies of

t p rof
size λ on bubbles of size d can be expressed as

ou P
ith @
w ght
i
r m yr
fo p
y co
an er
in d

 is the local gas holdup


it un
e is

Luo and Svendsen’s (1996) model also


us nt
ot e

predicts that all the bubbles of size greater


nn um

Luo and Svendsen’s (1996)


than the turbulence inertial subrange tend to
ca cc

breakup model illustration


u do

breakup
Yo is
Th
G
I IT
,
on er
si d
The probability of breakup into bubble

is m
m ju
er Ma
• The probability of breakup into bubble with a given fraction of

rp K
fBV upon such bombarding was given as

rio S
t p rof
ou P
ith @
Here

w ght
i
r m yr
fo p
where y co
an er
v = the volume of the parent bubble of size d,
in d
it un

cf = ratio of increased surface area with respect to the surface


e is

area of parent bubble


us nt
ot e
nn um

As per isotropic
ca cc

turbulence theory
u do

Luo and Svendsen (1996)


Yo is
Th
G
I IT
,
on er
si d
Breakup rate: Martínez-Bazán et al.’s (1999)

is m
m ju
model

er Ma
rp K
rio S
• Proposed a

t p rof
phenomenological model

ou P
ith @
based on turbulence stress

w ght
and surface tension analysis

i
r m yr
for daughter bubbles

fo p
distribution y co
an er
• As the bubble residence time
in d
it un

within the breakup region is


e is

very short, neither buoyancy


us nt

effect nor the dynamics of


ot e
nn um

bubble oscillation play any


ca cc

role in breakup
u do

Kg = 0.25  = 8.2
Yo is
Th
G
, I IT
on er
si d
is m
Breakup rate: Martínez-Bazán et al.’s (1999)

m ju
er Ma
model (cont.)

rp K
rio S
• In this model, there are two distinct breakup regimes dependent on bubble

t p rof
size

ou P
ith @
• The breakup rate is zero for bubbles of size d  dmax

w ght
• The dreakup rate increases rapidly for bubbles larger than the maximum

i
r m yr
stable bubble size.

fo p
y co
• The breakup rate, after reaching, d = 1.63dmax , decreases with bubble size
an er
in d

• In the limit of very large bubbles, d/dmax >>1, the surface tension forces
it un

become very small and the breakup rate can be approximated by


e is
us nt
ot e
nn um
ca cc
u do
Yo is
Th
G
,I IT
on er
si d
Breakup rate: Martínez-Bazán et al.’s (1999)

is m
rm aju
model (cont.)

pe M
K
ri S
t p rof
Breakup rateor
• for small bubbles of size

ou P
ith @
smaller than, dmax but

w ght
comparable to the critical

i
r m yr
Breakup rate
diameter dbc, the breakup rate
fo p
dbc
can be written as: y co
an er
Bubble diameter
in d
it un
e is

Typical breakup rate with respect


us nt

to bubble diameter predicted by


ot e
nn um

Martínez-Bazán et al. (1999)


ca cc
u do
Yo is
Th
G
, I IT
on er
Dauaghter bubble distribution function Based on

si d
is m
Martínez-Bazán et al.’s (1999) model

m ju
er Ma
rp K
• Accroding to this model the possibility of splitting a fraction of bubbles of size from

rio S
the parent bubble of size is proportional to the difference in the turbulence stress

t p rof
acting between the two points separated by the distance and the confinement

ou P
pressure due to the surface tension of the parent bubble. This produces an inverted

ith @
U-shaped (∩-shaped) daughter bubble distribution function and can be expressed

w ght
as:

i
r m yr
fo p
y co
an er
in d
it un
e is
us nt
ot e
nn um
ca cc

 = 8.2
u do
Yo is
Th
G
, I IT
on er
si d
Bubble breakup rate: Lehr and Mewes (2001) Model

is m
m ju
er Ma
• Lehr and Mewes (2001) suggested another formula, following the idea

rp K
rio S
of Levich (1962) and Luo and Svendsen (1996), for bubble breakup rate

t p rof
of bubble size into bubbles of size vz and (v-vz):

ou P
ith @
w ght
i
r m yr
fo p
y co
an er
in d
it un
e is
us nt
ot e
nn um

Note: This equation is valid for bubbles larger than the maximum stable bubble.
ca cc

It does not need a predefined daughter bubble size distribution. The daughter bubble size
u do

distribution is a result that can be calculated directly from the model.


Yo is
Th
G
, I IT
The probability of breakup into bubble Lehr

on er
si d
is m
and Mewes (2001) Model

m ju
er Ma
• According to Lehr and Mewes (2001), the breakup probability

rp K
rio S
distribution can be expressed in terms of a normalized product of two

t p rof
functions related to the two breakup criteria:

ou P
ith @
w ght
For a given collision between bubbles of size di (or
volume vi ) and eddies of size j and energy level e(λj)

i
r m yr
fo p
y co Surface
an er
energy
in d
it un

criteria
e is
us nt
ot e

where
nn um

Energy di is parent bubble diameter


ca cc

density dk is daughter bubble


u do

criteria
diameter
Yo is
Th
Th
Yo is
u do
ca cc
nn um
ot e
us nt
e is
it un
in d
an er
y co
fo p
r m yr
i
w ght
ith @
ou P
t p rof
Thank You

rio S
rp K
er Ma
m ju
is m
si d
on er
, I IT
G
G
I IT
,
on er
si d
is m
m ju
er Ma
Fluidization Engineering

rp K
rio S
t p rof
Lecture 14: Entrainment Characteristics (Part 1)

ou P
ith @
w ght
i
r m yr
fo p
y coBy
an er
in d

Dr. Subrata K. Majumder


it un
e is

Chemical Engineering Department, IIT Guwahati


us nt
ot e

Contact: [email protected]
nn um
ca cc
u do
Yo is
Th
G
I IT
,
on er
si d
is m
What is Entrainment?

m ju
er Ma
rp K

Lean phase or free board


rio S
t p rof
• Definition: Entrainment means the flux of

ou P
ith @
solids carried out of the fluidized bed by

w ght
the gas in kg per unit cross-sectional area

TDH
i
r m yr
fo p
per second
y co
an er
Splash
in d

Dense
phase
it un

zone
• Denoted by Gs (kg/m2.s)
e is
us nt
ot e
nn um
ca cc
u do
Yo is
Th
G
I IT
,
on er
si d
is m
m ju
Importance to learn

er Ma
rp K
rio S
t p rof
• The entrainment rate has to be known for the design of

ou P
gas/solid separators like cyclones or filters.

ith @
w ght
• On the other hand, the loss of bed material that is related to

i
the entrainment may be important for the technical and also

r m yr
fo p
the economic success of a fluidized bed application.
y co
an er
• It characterizes the selective removal of particles of individual
in d
it un

size from the fluidized bed


e is
us nt
ot e
nn um
ca cc
u do
Yo is
Th
G
I IT
,
on er
si d
Important Terms and its Definitions

is m
m ju
er Ma
rp K
rio S
• A fluidization vessel usually has

t p rof
three zones:

ou P
ith @
w ght
• dense bubbling phase zone: the

i
r m yr
bulk density remains almost

fo p
constant y co
an er
• lean or dispersed phase zone: the
in d

bulk density of solid decreases with


it un

height
e is

• Splash zone: the demarcation


us nt

between bed and freeboard


ot e
nn um
ca cc
u do
Yo is
Th
G
, I IT
on er
si d
Important Terms and its Definitions

is m
m ju
er Ma
rp K
rio S
• Freeboard: The section of the vessel between the

t p rof
surface of the dense phase and the exit of the gas

ou P
ith @
stream. The bulk density of solids decreases with

w ght
height in the freeboard, increasing the freeboard
decreases the entrainment from the bed.

i
r m yr
fo p
y co
• Transport disengaging height (TDH): a freeboard
an er
in d

height above which bulk density does not change


it un

appreciably. When the gas stream exits above the


e is

transport disengaging height, or Hf > TDH, then


us nt

both the size distribution and entrainment rate are


ot e

close to constant.
nn um
ca cc
u do
Yo is
Th
G
I IT
,
on er
si d
is m
Important Terms and its Definitions

m ju
er Ma
rp K
rio S
• Saturation carrying capacity: of the gas

t p rof
stream represents the largest flux of solid

ou P
that can be entrained out of the vessel whose

ith @
w ght
exit is above the TDH. This depends on the

i
properties of the particles and on the flow

r m yr
fo p
conditions of the gas.
y co
an er
in d
it un

• Elutriation: the classifying effect of the


e is

fluidized bed entrainment. It characterizes


us nt

the selective removal of particles of


ot e
nn um

individual size from the fluidized bed.


ca cc
u do
Yo is
Th
G
I IT
,
on er
si d
Mechanism of entrainment

is m
m ju
er Ma
rp K
rio S
• Bubbles and slugs breaking at the surface

t p rof
of the bed that throw solids into the
freeboard.

ou P
ith @
• Since the bubbles' pressure is higher than

w ght
bed surface pressure, they "pop" on
reaching the surface, spraying solids

i
r m yr
from the bubble roofs into the freeboard.

fo p
y co
• Since bubbles with their wakes may rise
an er
very much faster than the surrounding
in d

medium, this wake material may be


it un

thrown as a clump into the freeboard.


e is

• Finally, when two bubbles coalesce just


us nt

as they break the surface of the bed, one


ot e

observes an especially energetic ejection


nn um

of wake solids from the trailing bubble


ca cc

into the freeboard.


u do
Yo is
Th
G
I IT
,
on er
si d
is m
m ju
er Ma
Entrainment Mechanism (contd.)

rp K
rio S
t p rof
• In bubbling beds, it is mainly the wake

ou P
ith @
material that is thrown into the freeboard,

w ght
whereas in slugging beds it is the roof solids

i
r m yr
that spray into the freeboard.
fo p
y co
• In liquid-solid beds there have no freeboard
an er
in d

solids because they fluidize smoothly with


it un

no bubbling action.
e is
us nt
ot e
nn um
ca cc
u do
Yo is
Th
G
, I IT
on er
si d
is m
Effect of dynamic variables

m ju
er Ma
rp K
• Gas velocity: It increases with the superficial gas

rio S
velocity. Both the ejection of particles from the

t p rof
dense bed into the freeboard and the transport

ou P
ith @
through the freeboard are affected by the

w ght
superficial velocity. In general, the elutriation rate
increases proportionally with the gas velocity to a

i
r m yr
power of 2 to 4.

fo p
y co
• Solid velocity: Solid velocity affect the entrainment
an er
due to the exchange of momentum between solids.
in d
it un

If there are wider particle size distribution, even


coarser particle will have higher settling velocity,
e is

due to the momentum exchange between particles,


us nt

Influence of pressure on the total


ot e

couarse particle may entrained while finer particle entrainment rates. dbed 0.3 m,
nn um

may be decllerated. sand, dp 70 m, (Chan and


ca cc

Knowlton, 1984)
u do
Yo is
Th
G
I IT
,
on er
si d
is m
Effect of system properties

m ju
er Ma
rp K
rio S
t p rof
• Viscosity: Effects of the changing viscosity

ou P
ith @
should not play any dominant role, since the

w ght
influence of the pressure on viscosity is small.

i
r m yr
fo p
y co
an er
• Density: Increase in bulk density of solid or the
in d
it un

increase in density of the gas used decrease the


e is

entrainment rate
us nt
ot e
nn um
ca cc
u do
Yo is
Th
G
I IT
,
on er
si d
Effect of particle characteristics

is m
m ju
er Ma
rp K
rio S
• Particle type: Particles belonging to the Geldart group A

t p rof
fluidized at high velocities, the ejection from the roof

ou P
ith @
predominates and hence entrainment, while for group B

w ght
particles fluidized with lower velocities, ejection from the

i
r m yr
wake is governing the process, hence lower entrainment

fo p
y co
(Davidson,1983).
an er
in d
it un

• Size of particles: at most only slightly affected, by changing


e is

the size of the coarse material.


us nt
ot e
nn um
ca cc
u do
Yo is
Th
G
I IT
,
on er
si d
is m
m ju
Effect of bubble characteristics

er Ma
rp K
rio S
t p rof
ou P
• Bubble size: Bubble size should have some effect, because it

ith @
w ght
determines the quantity of fines thrown into the freeboard to
be picked up by the flowing gas.

i
r m yr
fo p
y co
• Increase of the entrainment flux is due to the increase of
an er
bubble sizes with height
in d
it un

• The probability of bubbles to coalesce near the bed surface


e is

and increase the ejection force to entrainment of the particles.


us nt
ot e
nn um
ca cc
u do
Yo is
Th
G
, I IT
on er
si d
Effect of thermodynamic condition

is m
m ju
er Ma
rp K
• Pressure:

rio S
The entrainment flux increases with pressure. These

t p rof
effects may directly be related to the increasing

ou P
density of the gas and thus decrease in single particle

ith @
terminal velocity. An increase in pressure increases

w ght
entrainment enormously and changes the size

i
r m yr
distribution of solids by including more of the larger

fo p
y co
solids (Chan and Knowlton)
an er
in d
it un

• Temperature:
e is

There is no significant effect of temperature on Influence of pressure on the total


us nt

entrainment. However, a decrease of the elutriation entrainment rates. dbed = 0.3 m,


ot e
nn um

rate constant with increasing temperature in the range sand, dp = 70 m, (Chan and
between 270 and 670K for the fine FCC (Wouters and Knowlton, 1984)
ca cc

Geldart, 1998).
u do
Yo is
Th
G
, I IT
on er
si d
Effect of Bed Size

is m
m ju
er Ma
• Bed heights:

rp K
rio S
Increase of the entrainment fluxes with increasing bed height, the

t p rof
influence being more pronounced for the entrainment flux at the
bed surface and higher gas velocities. Particles are not moving

ou P
ith @
individually through the freeboard; they form clusters, which
allow slip velocities between gas and particles that are much

w ght
higher than the single particle’s terminal velocity. Such clusters

i
will form also with very fine particles and thus provide an

r m yr
explanation of why the entrainment is decreasing with increasing

fo p
y co
height even for fine particle systems (Geldart and Pope,1983; Kunii
and Levenspiel, 1989)
an er
in d

• Bed diameter:
it un

Entrainment is independent of size for units larger than 0.1 m in


e is

diameter. the entrainment in the larger unit to be higher than in


us nt

the smaller unit. The gas velocity is reduced by the square of the Effect of the bed height on the
ot e

ratio of bed diameter to freeboard diameter, which leads to a entrainment flux (a)above the TDH and (b)
nn um

significant reduction of the entrainment flux by increasing the


freeboard diameter. just above the bed surface. (dbed = 0.61 m,
ca cc

silica sand, dp = 61 m, Baron et al., 1990.)


u do
Yo is
Th
G
, I IT
on er
si d
Effect of Internals

is m
m ju
er Ma
• May increase the entrainment due to the increased gas velocity in the

rp K
rio S
freeboard (Tweedle et al., 1970), depending on the design of internals.

t p rof
• It may help to reduce the entrainment flow significantly.

ou P
ith @
• Reducing the size of bursting bubbles by stirrers or bed internals can

w ght
drastically lower entrainment.

i
r m yr
• Horizontal louvers close to the bed surface reduce entrainment about 33%

fo p
y co
(Martini et al., 1976) for large particle.
an er
• Horizontal tubes in the bed do not affect the rate of entrainment (George
in d

and Grace, 1981) for large particle.


it un

• Vertical internals cause an increase in entrainment (Kato et al., 1985)


e is
us nt

whereas for small particle do not significantly affect entrainment (Zhang


ot e

et al., 1982; Kato et al., 1985)


nn um
ca cc
u do
Yo is
Th
G
I IT
,
on er
si d
Estimation of TDH

is m
m ju
er Ma
• An important parameter for the design of a fluidized bed

rp K
rio S
vessel is the TDH. To reduce the carryover from a fluidized

t p rof
bed, the freeboard should have, wherever possible, a height of

ou P
at least the TDH

ith @
w ght
• There is only a gradual decay of the entrainment flux vs. the

i
r m yr
height at the level of TDH.

fo p
y co
• Based on experimental data different correlations were
an er
developed some of which important are given as follows:
in d
it un
e is
us nt
ot e
nn um
ca cc
u do
Yo is

Ref. Kunii & Levenspiel, 1991)


Th
G
I IT
,
on er
si d
is m
Entrainment Model: Lewis et al. Model

m ju
er Ma
rp K
rio S
• The density of solids or holdup present at various

t p rof
levels Zf as the freeboard height Hf is shown in Fig.

ou P
ith @
• Curve AGB represents the solids holdup when the

w ght
freeboard height is at Hf,A > TDH

i
r m yr
• Curves CD and EF are for freeboard heights Hf,C and

fo p
Hf,E , respectively, both below the TDH
y co
an er
• At complete reflux (curve AGB), the density of solids
in d

in the freeboard falls off exponentially from the value


it un

at the bed surface, or


e is
us nt
ot e
nn um
ca cc
u do
Yo is
Th
G
, I IT
on er
si d
Entrainment Model (Hf < TDH): Lewis et al. Model (contd.)

is m
m ju
er Ma
• At smaller Hf, below TDH (curves CD

rp K
and EF), the solid density is some

rio S
constant value less than at complete

t p rof
reflux, or

ou P
ith @
w ght
i
r m yr
fo p
y co
• The entrainment falls off exponentially as,
an er
in d
it un
e is
us nt
ot e
nn um

To discourage side reactions in the freeboard of a large-


ca cc

diameter turbulent bed reactor, to use a short freeboard


u do

is recommended.
Yo is
Th
G
I IT
,
on er
si d
Kunii and Levenspiel Model

is m
m ju
er Ma
rp K
rio S
• A simple flow model to represent the complex

t p rof
phenomena occurring in the freeboard.

ou P
ith @
w ght
i
r m yr
• Their model lumped velocities and other

fo p
quantities incorporated the main features of
y co
freeboard behavior, such as the ejection of
an er
in d

agglomerates of solids into the freeboard,


it un

followed by the upflow, downflow, and


e is

breakup of these agglomerates.


us nt
ot e
nn um
ca cc
u do
Yo is
Th
G
, I IT
Generalized version of Kunii and Levenspiel

on er
si d
is m
Model: Freeboard-Entrainment Model

m ju
er Ma
rp K
rio S
• Consider a freeboard above bubbling or turbulent fluidized

t p rof
bed with the following assumptions:

ou P
ith @
• Assumptions 1: Three distinct phases are present in the

w ght
freeboard.

i
r m yr
• Phase 1: Gas stream with completely dispersed solids.

fo p
The fines are carried upward and out of the bed at
y co
velocity u1 while the coarse material rains back into the
an er
bed.
in d
it un

• Phase 2: Agglomerates, coming from the bed, and moving


e is

upward at velocity u2 .
us nt

• Phase 3: Agglomerates and thin wall layers of particles


ot e
nn um

moving downward at velocity u3


ca cc
u do
Yo is
Th
G
I IT
,
on er
si d
Freeboard-Entrainment Model (contd.)

is m
m ju
er Ma
rp K
rio S
• Assumption 2: At any level in the freeboard

t p rof
the rate of removal of fines from the

ou P
ith @
agglomerates to form dispersed solid of phase

w ght
1 is proportional to the volume fraction (or

i
r m yr
solid density) of agglomerates at that level.

fo p
y co
• Assumption 3: Upward-moving agglomerates
an er
will eventually reverse direction and move
in d
it un

downward, the frequency of change from


e is

phase 2 to phase 3 being proportional to the


us nt

volume fraction of phase 2 at that level.


ot e
nn um
ca cc
u do
Yo is
Th
Th
Yo is
u do
ca cc
nn um
ot e
us nt
e is
it un
in d
an er
y co
fo p
r m yr
i
w ght
ith @
ou P
t p rof
rio S
rp K
er Ma
m ju
is m
si d
on er
, I IT
G
Th
Yo is
u do
ca cc
nn um
ot e
us nt
e is
it un
in d
an er
y co
fo p
r m yr
i
w ght
ith @
ou P
t p rof
rio S
rp K
er Ma
m ju
is m
si d
on er
, I IT
G
G
I IT
,
on er
si d
is m
• Now consider at any level Zf in the freeboard Mass flux [kg/m2.s]

m ju
er Ma
Gs1= the mass flux of phase 1

rp K
rio S
Gs2 = the mass flux of phase 2

t p rof
Gs3 = the mass flux of phase 3

ou P
ith @
1 = mass of phase 1 per unit volume of freeboard [kg/m3]

w ght
i
2 = mass of phase 2 per unit volume of freeboard [kg/m3]

r m yr
fo p
y co
3 = mass of phase 3 per unit volume of freeboard [kg/m3]
an er
• Then at steady state conditions the net upward flux of solids at any
in d
it un

level in the freeboard is given by


e is
us nt
ot e
nn um

(1)
ca cc
u do
Yo is
Th
G
, I IT
on er
• Also, the average (or bulk) density of solids at any level in the

si d
is m
bed is

m ju
er Ma
rp K
(2)

rio S
t p rof
ou P
ith @
• Let x be the fraction of fines in bed for which ut < u.

w ght
• Due to vigorous turbulence or mixing, the particles may inter-

i
r m yr
transfer the phase from each other like
fo p
y co
an er
in d
it un

Phase1 Rate coefficients for transfer:


e is
us nt

xK1 xK1 • xΚ1 for the transfer of fines from


ot e

phases 2 and 3 to 1, and


nn um

K2
ca cc

Phase 2 Phase 3 • K2 for the transfer from phase 2 to


u do

phase 3.
Yo is
Th
Th
Yo is
u do

For phase 2:
For phase 1:
ca cc
nn um
ot e
us nt
e is
it un
in d
an er
y co
fo p
r m yr
i
w ght
ith @
ou P
t p rof
Mass Balances at Level Zf

rio S
rp K
er Ma
m ju
is m
si d
on er
, I IT
G
(3)

(4)
G
, I IT
on er
si d
for phase 3:

is m
m ju
er Ma
rp K
rio S
t p rof
(5)

ou P
ith @
Since all solids that reach the freeboard height Hf leave the vessel, there

w ght
is no downflow there, so

i
r m yr
fo p
(6)
y co
an er
Only upflow agglomerates of solids projected into the freeboard from the
in d
it un

dense bed, So
e is
us nt

(7)
ot e
nn um

Solving equations (3 to 5), one can get expression for 1, 2,
ca cc

3 with these boundary conditions


u do
Yo is
Th
G
, I IT
on er
si d
With Eq. (1), the net flux of solids at any freeboard level and at the

is m
vessel outlet can then be expressed as

m ju
er Ma
rp K
rio S
(8)

t p rof
ou P
ith @
w ght
where Gs* is the flux of carryover from a very tall vessel fluidizing only

i
entrainable solids when Hf > TDH .

r m yr
fo p
y co (9)
an er
in d
it un
e is
us nt
ot e

(10)
nn um
ca cc
u do
Yo is
Th
G
I IT
,
Special case

on er
si d
is m
m ju
er Ma
• For a vigorously bubbling bed or a turbulent bed with

rp K
few fines

rio S
(11)

t p rof
ou P
ith @
w ght
• So, from equation (9) and (10) one can get

i
r m yr
(12)

fo p
y co
an er
in d
it un

• Therefore the equation (8) becomes


e is

(13)
us nt
ot e
nn um

These expressions provide a physical interpretation of the


ca cc
u do

parameters reported by Lewis et al.


Yo is
Th
Th
Yo is
u do
ca cc
nn um
ot e

Since always
us nt
e is
it un
in d
an er
y co
Special case

fo p
r m yr
i
w ght
ith @
ou P
t p rof
rio S
rp K
er Ma
m ju
is m
si d
on er
,
Since for

I IT
G
upward flux can be obtained by substituting the densities 1, 2 in equation

(15)
(14)
G
I IT
,
on er
si d
is m
• for fine particles, Lewis et al. found that product of decay

m ju
er Ma
coefficient is inversely proportional to the gas velocity in the
fluidized bed and depends on the particle size

rp K
rio S
• Walsh et al. found that the above statement is also holds for

t p rof
coarse particles.

ou P
ith @
w ght
i
r m yr
fo p
y co
an er
in d
it un
e is
us nt
ot e
nn um
ca cc
u do
Yo is
Th
G
I IT
,
on er
si d
Entrainment profile In terms of Density

is m
m ju
er Ma
• The entrainment profile can be expressed as density once one

rp K
solved for the densities (1, 2, 3) from the entrainment model

rio S
t p rof
for different phases as

ou P
ith @
w ght
i
r m yr
fo p
y co
an er
in d
it un
e is
us nt
ot e
nn um
ca cc
u do
Yo is
Th
G
I IT
,
on er
si d
Example

is m
m ju
er Ma
rp K
rio S
• Estimate the entrainment flux from a short free-board of a

t p rof
fluidized bed. Assume that the bed is operated at a certain

ou P
ith @
velocity of about 167.66 times of minimum fluidization

w ght
velocity for all particle to be entrainable.

i
r m yr
fo p
y co
an er
in d
it un
e is
us nt
ot e
nn um
ca cc
u do
Yo is
Th
G
, I IT
on er
Solution

si d
is m
m ju
Fig. 1

er Ma
u = 167.66*0.003 = 0.503 m/s

rp K
rio S
t p rof
ou P
ith @
From the figure (1)

w ght
i
r m yr
Gs* = 0.654

fo p
y co
Gsu0 = 5.0 kg/m2.s From the figure (2)
an er
Fig. 2
in d
it un

a = 1.66 as per
e is
us nt
ot e
nn um

Gs = 0.92 kg/m2.s as per


ca cc
u do

Gsu0: 1, 2, 5, 6; Gsud0: 3, 4
Yo is
Th
Th
Yo is
u do
ca cc
nn um
ot e
us nt
e is
it un
in d
an er
y co
fo p
r m yr
i
w ght
ith @
ou P
t p rof
Thank You

rio S
rp K
er Ma
m ju
is m
si d
on er
, I IT
G
Th
Yo is
u do
ca cc
nn um
ot e
us nt
e is
it un
in d
an er
y co
fo p
r m yr
i
w ght
ith @
ou P
t p rof
rio S
rp K
er Ma
m ju
is m
si d
on er
, I IT
G

You might also like