Mole & Eqt. Concept (Assignment - 5)

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Q1: In the reaction 2Na2S2O3 + I2 → Na2S4O6 + 2 NaI, the equivalent weight of Na2S2O3

(mol. wt. = M) is equal to


(A) M

(B) M/2

(C) M/3

(D) M/4
Q1: In the reaction 2Na2S2O3 + I2 → Na2S4O6 + 2 NaI, the equivalent weight of Na2S2O3
(mol. wt. = M) is equal to
(A) M

(B) M/2

(C) M/3

(D) M/4

Solution:

Q2: 74.5 g of a metallic chloride contain 35.5 g of chlorine. The equivalent weight of the
metal is
(A) 19.5

(B) 35.5

(C) 39.0

(D) 78.0
Q2: 74.5 g of a metallic chloride contain 35.5 g of chlorine. The equivalent weight of the
metal is
(A) 19.5

(B) 35.5

(C) 39.0

(D) 78.0

Solution:

wt. of metallic chloride


wt. of chlorine = 35.5
wt. of metal
Equivalent weight of metal

Q3: The equivalent weight of an element is 4. Its chloride has a V.D 59.25. Then the
valency of the element is
(A) 4

(B) 3

(C) 2

(D) 1
Q3: The equivalent weight of an element is 4. Its chloride has a V.D 59.25. Then the
valency of the element is
(A) 4

(B) 3

(C) 2

(D) 1

Solution:

Valency of the element =3.


Q4: The oxide of a metal has 32% oxygen. Its equivalent weight would be
(A) 34

(B) 32

(C) 17

(D) 8
Q4: The oxide of a metal has 32% oxygen. Its equivalent weight would be
(A) 34

(B) 32

(C) 17

(D) 8

Solution:

Let weight of metal oxide = 100gm


Weight of oxygen = 32gm
weight of metal
Equivalent weight of oxide .
Q5: 1.520 g of the hydroxide of a metal on ignition gave 0.995 gm of oxide. The
equivalent weight of metal is
(A) 1.520

(B) 0.995

(C) 19.00

(D) 9.00
Q5: 1.520 g of the hydroxide of a metal on ignition gave 0.995 gm of oxide. The
equivalent weight of metal is
(A) 1.520

(B) 0.995

(C) 19.00

(D) 9.00

Solution:

or

Q6: One gram of hydrogen is found to combine with 80g of bromine one gram of calcium
valency = 2 combines with 4g of bromine the equivalent weight of calcium is
(A) 10

(B) 20

(C) 40

(D) 80
Q6: One gram of hydrogen is found to combine with 80g of bromine one gram of calcium
valency = 2 combines with 4g of bromine the equivalent weight of calcium is
(A) 10

(B) 20

(C) 40

(D) 80

Solution:

One gram of hydrogen combines with 80gm of bromine.


So, equivalent weight of bromine = 80gm
4gm of bromine combines with 1gm of Ca
80gm of bromine combines with = .
Q7: Ca(OH)2 + H3PO4 → CaHPO4 + 2H2O the equivalent weight of H3PO4 in the above
reaction is
(A) 21

(B) 27

(C) 38

(D) 49
Q7: Ca(OH)2 + H3PO4 → CaHPO4 + 2H2O the equivalent weight of H3PO4 in the above
reaction is
(A) 21

(B) 27

(C) 38

(D) 49

Solution:

The equivalent weight of


mole wt of = 3 + 31 + 64 = 98

Q8: A compound contains atoms of three elements in A, B and C. If the oxidation number
of A is +2, B is +5 and that of C is –2, the possible formula of the compound is
(A) A3(BC4)2

(B) A3(B4C)2

(C) ABC2

(D) A2(BC3)2
Q8: A compound contains atoms of three elements in A, B and C. If the oxidation number
of A is +2, B is +5 and that of C is –2, the possible formula of the compound is
(A) A3(BC4)2

(B) A3(B4C)2

(C) ABC2

(D) A2(BC3)2

Solution:

.
Q9: In the following reaction, which choice has value twice that of the equivalent mass of
the oxidising agent
SO2 + H2O → 3S + H2O
(A) 64

(B) 32

(C) 16

(D) 48
Q9: In the following reaction, which choice has value twice that of the equivalent mass of
the oxidising agent
SO2 + H2O → 3S + H2O
(A) 64

(B) 32

(C) 16

(D) 48

Solution:

; Twice

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