Material Safety Data Sheet

Sulfuric acid 98%

Section 1 - Chemical Product and Company Identification

MSDS Name: Sulfuric acid 98%

Synonyms: Hydrogen sulfate; Oil of vitriol; Vitriol brown oil; Mattling acid; Battery
acid; Sulphuric acid; Electrolyte acid; Dihydrogen sulfate; Spirit of sulfur; Chamber
acid.
Company Identification:
ANKIT RAJ ORGANO CHEMICALS LTD
201.TRIMURTI ARCADE,L B S MARG,
GHATKOPAR ( WEST),MUMBAI.400 086.INDIA
For information, call: 91-22 2511 5113

Section 2 - Composition, Information on Ingredients

CAS# Chemical Name Percent EINECS/ELINCS

7664-93-9 Sulfuric acid 90-98 231-639-5

Section 3 - Hazards Identification

EMERGENCY OVERVIEW

Appearance: clear colorless to yellow liquid.

Danger! Causes eye and skin burns. Causes digestive and respiratory tract burns.
May be fatal if mist inhaled. Strong inorganic acid mists containing sulfuric acid may
cause cancer. Concentrated sulfuric acid reacts violently with water and many other
substances under certain conditions. May cause lung damage. Hygroscopic (absorbs
moisture from the air). Corrosive to metal.
Target Organs: Lungs, teeth, eyes, skin.

Potential Health Effects

Eye: Causes severe eye burns. May cause irreversible eye injury. May cause
blindness. May cause permanent corneal opacification. The severity of injury depends
on the concentration of the solution and the duration of exposure.
Skin: Causes skin burns. The severity of injury depends on the concentration of the
solution and the duration of exposure.
Ingestion: May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns.
Inhalation: May cause irritation of the respiratory tract with burning pain in the
nose and throat, coughing, wheezing, shortness of breath and pulmonary edema.
Causes chemical burns to the respiratory tract. Inhalation may be fatal as a result of
spasm, inflammation, edema of the larynx and bronchi, chemical pneumonitis and
pulmonary edema. Because its vapor pressure is negligible, it exists in the air only as
a mist or spray. Exposure may impair lung function and cause mucostasis (reduced
mucous clearance).
Chronic: Prolonged or repeated skin contact may cause dermatitis. Prolonged or
repeated inhalation may cause nosebleeds, nasal congestion, erosion of the teeth,
perforation of the nasal septum, chest pain and bronchitis. Prolonged or repeated
eye contact may cause conjunctivitis. Effects may be delayed. Workers chronically
exposed to sulfuric acid mists may show various lesions of the skin,
tracheobronchitis, stomatitis, conjunctivitis, or gastritis. Occupational exposure to
strong inorganic acid mists containing sulfuric acid is carcinogenic to humans.

Section 4 - First Aid Measures

Eyes: In case of contact, immediately flush eyes with plenty of water for a t least 15
minutes. Get medical aid immediately.
Skin: In case of contact, immediately flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Get medical aid
immediately. Wash clothing before reuse.
Ingestion: If swallowed, do NOT induce vomiting. Get medical aid immediately. If
victim is fully conscious, give a cupful of water. Never give anything by mouth to an
unconscious person.
Inhalation: POISON material. If inhaled, get medical aid immediately. Remove
victim to fresh air. If not breathing, give artificial respiration. If breathing is difficult,
give oxygen.
Notes to Physician: Monitor arterial blood gases, chest x-ray, and pulmonary
function tests if respiratory tract irritation or respiratory depression is evident. Treat
dermal irritation or burns with standard topical therapy. Effects may be delayed. Do
NOT use sodium bicarbonate in an attempt to neutralize the acid.

Section 5 - Fire Fighting Measures

General Information: As in any fire, wear a self-contained breathing apparatus in

pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Use water spray to keep fire-exposed containers cool. Substance is noncombustible.
Contact with water can cause violent liberation of heat and splattering of the
material. Contact with metals may evolve flammable hydrogen gas. Runoff from fire
control or dilution water may cause pollution. Approach fire from upwind to avoid
hazardous vapors and toxic decomposition products. Strong dehydrating agent,
which may cause ignition of finely divided materials on contact. Oxides of sulfur may
be produced in fire.
Extinguishing Media: Use extinguishing media most appropriate for the
surrounding fire. Do NOT get water inside containers. If water is used, care should
be taken, since it can generate heat and cause spattering if applied directly to
sulfuric acid.
Flash Point: Not applicable.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: 3; Flammability: 0; Instability: 2; Special
Hazard: -W-

Section 6 - Accidental Release Measures

General Information: Use proper personal protective equipment as indicated in

Section 8.
Spills/Leaks: Avoid runoff into storm sewers and ditches which lead to waterways.
Clean up spills immediately, observing precautions in the Protective Equipment
section. Carefully scoop up and place into appropriate disposal container. Provide
ventilation. Do not get water inside containers. Cover with dry earth, dry sand, or
other non-combustible material followed with plastic sheet to minimize spreading and
contact with water.

Section 7 - Handling and Storage

Handling: Wash thoroughly after handling. Remove contaminated clothing and wash
before reuse. Do not allow water to get into the container because of violent
reaction. Do not get in eyes, on skin, or on clothing. Keep container tightly closed.
Discard contaminated shoes. Use only with adequate ventilation. Do not breathe
spray or mist. Do not use with metal spatula or other metal items. Inform laundry
personnel of contaminant's hazards.
Storage: Do not store near combustible materials. Keep container closed when not
in use. Store in a cool, dry, well-ventilated area away from incompatible substances.
Do not store near alkaline substances. Store protected from moisture. Ideally,
sulfuric acid should be stored in isolation from all other chemicals in an approved
acid or corrosives safety cabinet.

Section 8 - Exposure Controls, Personal Protection

Engineering Controls: Facilities storing or utilizing this material should be equipped

with an eyewash facility and a safety shower. Use adequate general or local exhaust
ventilation to keep airborne concentrations below the permissible exposure limits.
Use a corrosion-resistant ventilation system.
Exposure Limits

Chemical Name ACGIH NIOSH OSHA - Final PELs

0.2 mg/m3 TWA 1 mg/m3 TWA 15
Sulfuric acid 1 mg/m3 TWA
(thoracic fraction) mg/m3 IDLH

OSHA Vacated PELs: Sulfuric acid: 1 mg/m3 TWA

Personal Protective Equipment
Eyes: Wear chemical splash goggles and face shield.
Skin: Wear neoprene gloves, apron, and/or clothing. Viton gloves are recommended.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or
European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149
approved respirator if exposure limits are exceeded or if irritation or other symptoms
are experienced.

Section 9 - Physical and Chemical Properties

Physical State: Liquid

Appearance: oily - clear colorless to yellow
Odor: odorless
pH: 0.3 (1N solution)
Vapor Pressure: < 0.001 mm Hg @ 20 deg C
Vapor Density: 3.38 (air=1)
Evaporation Rate:Slower than ether.
Viscosity: 21 mPas @ 25 C
Boiling Point: 290 - 338 deg C
Freezing/Melting Point:10 deg C
Decomposition Temperature:340 deg C
Solubility: Soluble with much heat
Specific Gravity/Density:1.84
Molecular Formula:H2SO4
Molecular Weight:98.07

Section 10 - Stability and Reactivity

Chemical Stability: Sulfuric acid reacts vigorously, violently or explosively with

many organic and inorganic chemicals and with water.
Conditions to Avoid: Excess heat, exposure to moist air or water, Note: Use great
caution in mixing with water due to heat evolution that causes explosive spattering.
Always add the acid to water, never the reverse..
Incompatibilities with Other Materials: Metals, oxidizing agents, reducing
agents, bases, acrylonitrile, chlorates, finely powdered metals, nitrates, perchlorates,
permanganates, epichlorohydrin, aniline, carbides, fulminates, picrates, organic
materials, flammable liquids.
Hazardous Decomposition Products: Oxides of sulfur.
Hazardous Polymerization: Has not been reported.

Section 11 - Toxicological Information

RTECS#:
CAS# 7664-93-9: WS5600000
LD50/LC50:
CAS# 7664-93-9:
Draize test, rabbit, eye: 250 ug Severe;
Inhalation, mouse: LC50 = 320 mg/m3/2H;
Inhalation, mouse: LC50 = 320 mg/m3;
Inhalation, rat: LC50 = 510 mg/m3/2H;
Inhalation, rat: LC50 = 510 mg/m3;
Oral, rat: LD50 = 2140 mg/kg;
.

Carcinogenicity:
CAS# 7664-93-9:

• ACGIH: A2 - Suspected Human Carcinogen (contained in strong inorganic

acid mists)
• California: carcinogen, initial date 3/14/03 (listed as Strong inorganic acid
mists containing sulfuric acid).
• NTP: Known carcinogen (listed as Strong inorganic acid mists containing s).
• IARC: Group 1 carcinogen

Epidemiology: Workers exposed to industrial sulfuric acid mist showed a statistical

increase in laryngeal cancer. This suggests a possible relationship between
carcinogenesis and inhalation of sulfuric acid mist.
Teratogenicity: Sulfuric acid was not teratogenic in mice and rabbits, but was
slightly embryotoxic in rabbits (a minor, rare skeletal variation). The animals were
exposed to 5 and 20 mg/m3 for 7 hr/day throughout pregnancy. Slight maternal
toxicity was present at the highest dose in both species.
Reproductive Effects: No information found
Mutagenicity: There are no mutagenicity studies specifically of sulfuric acid.
However, there are established effects of reduced pH in mutagenicity testing, as
would be caused by sulfuric acid. These effects are an artifact of low pH and are not
necessarily due to biological effects of sulfuric acid itself.
Neurotoxicity: No information found
Other Studies:

Section 12 - Ecological Information

Ecotoxicity: Fish: Bluegill/Sunfish: 49 mg/L; 48Hr; TLm (tap water @ 20C)

Fish: Bluegill/Sunfish: 24.5 ppm; 48Hr; TLm (fresh water)

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is

classified as a hazardous waste. US EPA guidelines for the classification
determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must
consult state and local hazardous waste regulations to ensure complete and accurate
classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

US DOT Canada TDG

Shipping Name: SULFURIC ACID SULFURIC ACID
Hazard Class: 8 8
UN Number: UN1830 UN1830
Packing Group: II II

Section 15 - Regulatory Information

US FEDERAL

TSCA
CAS# 7664-93-9 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
 None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
CAS# 7664-93-9: 1000 lb final RQ; 454 kg final RQ
SARA Section 302 Extremely Hazardous Substances
CAS# 7664-93-9: 1000 lb TPQ
SARA Codes
CAS # 7664-93-9: immediate, delayed, reactive.
Section 313
This material contains Sulfuric acid (CAS# 7664-93-9, 90-98%),which is subject
to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 7664-93-9 is listed as a Hazardous Substance under the CWA.
None of the chemicals in this product are listed as Priority Pollutants under the
CWA.
None of the chemicals in this product are listed as Toxic Pollutants under the
CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 7664-93-9 can be found on the following state right to know lists:
California, New Jersey, Pennsylvania, Minnesota, Massachusetts.

California Prop 65
The following statement(s) is(are) made in order to comply with the
California Safe Drinking Water Act:
WARNING: This product contains Sulfuric acid, listed as `Strong inorganic acid mists
contain', a chemical known to the state of California to cause cancer.
California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
C
Risk Phrases:
R 35 Causes severe burns.

Safety Phrases:
S 26 In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
S 30 Never add water to this product.
S 45 In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).

WGK (Water Danger/Protection)

CAS# 7664-93-9: 2
 Section 16 - Additional Information

MSDS Creation Date: 01/01/2008

The information above is believed to be accurate and represents the best information currently available to us.
However, we make no warranty of merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users should make their own investigations to
determine the suitability of the information for their particular purposes. In no event shall Industrial Solvents be
liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental,
consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of
such damages.

Disclaimer:
****************************************************************** ***************
The information contained herein in good faith but makes no representation as to its
comprehensiveness or accuracy. A properly trained person using this product intends this
document only as a guide to the appropriate precautionary handling of the material. Individuals
receiving the information must exercise their independent judgment in determining its
appropriateness for a particular purpose.

We, Make No Representations Or Warranties, Either Express Or Implied, Including Without

Limitation Any Warranties Of Merchantability, Fitness For A Particular Purpose With Respect To
The Information Set Forth Herein Or The Product To Which The Information Refers. Accordingly,
We Will Not Be Responsible For Damages Resulting From Use Of or Reliance upon This Information.
****************************************************************** ***************
Prepared by: ANKITRAJ EXPOTRADE PVT. LTD.
101 TRIMURTI ARCADE, LBS MARG, GHATKOPAR WEST, MUMBAI 400086, MAHARASHTRA, INDIA.
Phone No: +91 22 25167004/ 25167005
Fax No: +91 22 25148486
E-mail Address: [email protected] / [email protected]