Dendrites

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Dendrites

This month’s subject is not a rock, mineral, or fossil but rather a branching, tree or
fern like structure of interconnected crystals. Anyone who spends much time rock
hunting in the Bighorn Basin or elsewhere in Wyoming or Montana probably will find
a “moss agate”. These agates/chalcedonies have delicate branching inclusions that
resemble plants. The branching structures are called dendrites. They are not organic
(ie plants/moss) but rather small mineral crystals. In fact, dendrites are fairly
common. Besides being inclusions in some minerals such as cryptocrystalline quartz
(ie agate and chalcedony), dendrites of iron and manganese hydroxides can form on
surfaces such as bedding planes and joints in limestone, granite, rhyolite, shale and
other rocks. Dendrites also frequently develop during the crystallization of native
metals such as copper, silver, and gold. Snowflakes show a dendritic pattern. The
frost on your car windshields on very cold morning are ice crystals that display a
dendritic pattern.

Dendrites form when there is rapid crystallization and limited availability of the
elements needed to form the mineral. Chemists refer to these conditions as
disequilibrium. An example of this is frost on your windshield. When the moisture is
limited, water forms quickly into small flowers of frost. However if more moisture is
made available the crystals grow into a solid sheet of ice and the dendritic pattern is
no longer visible. No matter what the mineral is, the dendrites form according to
that mineral’s crystalline structure. Dendrites of snow and ice take on a hexagonal
form while the dendrites of native silver and copper display right angles typical of
their cubic (isometric) crystal shape.

The dendrites in agates, chalcedony, and other varieties of cryptocrystalline quartz


are usually manganese hydroxides or oxides. These types of dendrites are also
found in opal and crystalline quartz. In the past, geologists and others referred to
the mineral making up many of these dendrites as pyrolusite (a manganese oxide).
However, infra-red spectroscopy, X-ray diffraction and other modern analytical
methods show these inclusions to be more likely other manganese oxides and
hydroxides, like romanechite, birnessite, hollandite, todorokite, coronadite, and
cryptomelane. Currently, there are no known manganese dendrites in the world
which contain pyrolusite.
See photos below

Greg Jones 2/22/2022


Dendritic Frost formed on a windshield in Cody on cold morning, Feb 17,
2022. Photo by Greg L. Jones

A dendritic snowflake displays its hexagonal crystal shape. No matter


what the mineral is, the dendrites form according to that mineral’s
crystalline structure. Photo by danna § curious tangles. Used under limited license (CC BY-NC-ND
2.0)

Greg Jones 2/22/2022


This Dendritic crystalline native silver is
from the Mohawk Mine in the
Precambrian (1.05-1.06 GA) of
Michigan. It is on Display at Seaman
Mineral Museum, Michigan
Technological University in Houghton,
Michigan. Photo by James St. John Used under
limited license Attribution 2.0 Generic (CC BY 2.0)

Caption
Gold dendrites with quartz on display at the Carnegie
Museum of Natural History, Pittsburgh, Pennsylvania
Photo by James St. John Used under limited license Attribution 2.0 Generic (CC BY 2.0)

Greg Jones 2/22/2022


This Dendritic native copper from the
White Pine Mine in the Precambrian of
Michigan is on display at the Seaman
Mineral Museum, Michigan
Technological University in Houghton,
Michigan. Photo by James St. John Used under
limited license Attribution 2.0 Generic (CC BY 2.0)

Greg Jones 2/22/2022


Manganese hydroxide dendrites that have grown on a limestone
surface. Photo by Anders Sandberg
Used under limited license Attribution 2.0 Generic (CC BY 2.0)

Manganese dendrites in opal from Africa.


Photo by Greg L. Jones

Greg Jones 2/22/2022


A slice of Montana agate ready to be worked on the
wheel. Many rockhounds call this dendritic agate,
“moss” agate. Photo by Stephanie Melbraaten

The finished Montana Agate cab from slab above. Photo by Stephanie Melbraaten

Greg Jones 2/22/2022


Dendritic agate from Madagascar, Africa. Photo by Greg L. Jones

Greg Jones 2/22/2022


Dig Deeper (For more information)

https://www.mindat.org/min-26645.html
https://en.wikipedia.org/wiki/Dendrite_(crystal)
https://www.phase-trans.msm.cam.ac.uk/dendrites.html
https://minds.wisconsin.edu/bitstream/handle/1793/34662/Dendrites.pdf?
sequence=1

Greg Jones 2/22/2022


Greg Jones 2/22/2022
Greg Jones 2/22/2022

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