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SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006
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SDS # : 30844
RUBIA TIR 6400 15W-40

Date of the previous version: 2015-06-24 Revision Date: 2015-10-27 Version 5.02

Section 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE

COMPANY/UNDERTAKING

1.1. Product identifier

Product name RUBIA TIR 6400 15W-40

Number 08Q
Substance/mixture Mixture

1.2. Relevant identified uses of the substance or mixture and uses advised against

Identified uses Motor oil.

1.3. Details of the supplier of the safety data sheet

Supplier TOTAL UK LIMITED

One Euston Square
40 Melton Street. London. NW1 2FD
UNITED KINGDOM
Tel: +44 (0)20 7339 8000
Fax: +44 (0)20 7339 8033

For further information, please contact:

Contact Point Specific Product Related Info: 01977 636200

E-mail Address [email protected]

1.4. Emergency telephone number

00 33 149 00 00 49 (24h/24, 7d/7)

TOTAL UK ltd: + 44 (0) 20 7339 8000
For Lubricants only: TOTAL Lubricants - +44 (0)1977 636200
For bitumen only: Total Bitumen -+44 (0) 17 7272 9302

UK: National Poisons Information Service (NPIS): NHS111 or a doctor

Section 2: HAZARDS IDENTIFICATION

2.1. Classification of the substance or mixture

REGULATION (EC) No 1272/2008 ***

For the full text of the H-Statements mentioned in this Section, see Section 2.2.***

Classification***
The product is not classified as dangerous according to Regulation (EC) No. 1272/2008***

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SDS # : 30844
RUBIA TIR 6400 15W-40
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2.2. Label elements

Labelled according to REGULATION (EC) No 1272/2008***

Hazard Statements
None***

Precautionary statements
None***

Supplemental Hazard Statements

EUH210 - Safety data sheet available on request***

Contains Calcium long chain alkarylsulphonate May produce an allergic reaction***

2.3. Other hazards

Physical-Chemical Properties Contaminated surfaces will be extremely slippery.***

Environmental properties Should not be released into the environment.***

Section 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.2. Mixture

Hazardous components
Chemical Name EC-No REACH CAS-No Weight % GHS Classification
Registration
Number
Polyolefin polyamine - no data available ^ <5 Aquatic Chronic 4 (H413)
succinimide, polyol***
Zinc alkyldithiophosphate*** 272-028-3 no data available 68649-42-3 <2.5 Eye Dam. 1 (H318)
Aquatic Chronic 2 (H411)

Calcium long chain - - 722503-69-7 <2.5 Aquatic Chronic 4 (H413)

alkarylsulphonate***
Calcium long chain - - 722503-69-7 <1 Skin Sens. 1 (H317)
alkarylsulphonate*** Aquatic Chronic 4 (H413)

Calcium long chain alkaryl - - 722503-68-6 <1 Aquatic Chronic 4 (H413)

sulfonate*** Skin Sens.1 (H317)

Additional information Product containing mineral oil with less than 3% DMSO extract as measured by IP 346.***

For the full text of the H-Statements mentioned in this Section, see Section 16.

Section 4: FIRST AID MEASURES

4.1. Description of first aid measures

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General advice IN CASE OF SERIOUS OR PERSISTENT CONDITIONS, CALL A DOCTOR OR
EMERGENCY MEDICAL CARE.***

Eye contact Rinse thoroughly with plenty of water, also under the eyelids.***

Skin contact Remove contaminated clothing and shoes. Wash off with soap and water. Wash
contaminated clothing before reuse. High pressure jets may cause skin damage. Take
victim immediately to hospital.***

Inhalation Move to fresh air.

Ingestion Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a
physician or poison control centre immediately.***

4.2. Most important symptoms and effects, both acute and delayed

Eye contact Not classified. The supplier of some components contained within this formulation has
indicated that the classification as irritant is not required. This product does not meet the EU
criteria for classification.***

Skin contact Not classified. Repeated or prolonged skin contact may cause allergic reactions with
susceptible persons.***

Inhalation Not classified. Inhalation of vapours in high concentration may cause irritation of respiratory
system.

Ingestion Not classified. Ingestion may cause gastrointestinal irritation, nausea, vomiting and
diarrhoea.

4.3. Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician Treat symptomatically.

Section 5: FIRE-FIGHTING MEASURES

5.1. Extinguishing media

Suitable extinguishing media Carbon dioxide (CO 2). ABC powder. Foam. Water spray or fog.

Unsuitable Extinguishing Media Do not use a solid water stream as it may scatter and spread fire.

5.2. Special hazards arising from the substance or mixture

Special hazard Incomplete combustion and thermolysis may produce gases of varying toxicity such as
carbon monoxide, carbon dioxide, various hydrocarbons, aldehydes and soot. These may
be highly dangerous if inhaled in confined spaces or at high concentration.

5.3. Precautions for fire-fighters

Special protective equipment for Wear self-contained breathing apparatus and protective suit.
fire-fighters

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Other information Cool containers / tanks with water spray. Fire residues and contaminated fire extinguishing
water must be disposed of in accordance with local regulations.

Section 6: ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures

General Information Do not touch or walk through spilled material. Contaminated surfaces will be extremely
slippery. Use personal protective equipment. Ensure adequate ventilation. Remove all
sources of ignition.

6.2. Environmental precautions

General Information Do not allow material to contaminate ground water system. Try to prevent the material from
entering drains or water courses. Local authorities should be advised if significant spillages
cannot be contained. See Section 12 for additional Ecological Information.

6.3. Methods and materials for containment and cleaning up

Methods for cleaning up Dam up. Contain spillage, and then collect with non-combustable absorbent material, (e.g.
sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according
to local / national regulations (see section 13). Keep in suitable, closed containers for
disposal.

6.4. Reference to other sections

Personal protective equipment See Section 8 for more detail.

Waste treatment See section 13.

Section 7: HANDLING AND STORAGE

7.1. Precautions for safe handling

Advice on safe handling When using, do not eat, drink or smoke. For personal protection see section 8. Use only in
well-ventilated areas. Do not breathe vapours or spray mist. Avoid contact with skin, eyes
and clothing.

Prevention of fire and explosion Take precautionary measures against static discharges: Ground/bond containers, tanks
and transfer/receiving equipment.

Hygiene measures Ensure the application of strict rules of hygiene by the personnel exposed to the risk of
contact with the product. Regular cleaning of equipment, work area and clothing is
recommended. Wash hands and face before breaks and immediately after handling the
product. Do not use abrasives, solvents or fuels. Do not dry hands with rags that have been
contaminated with product. Do not put product contaminated rags into workwear pockets.

7.2. Conditions for safe storage, including any incompatibilities

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Technical measures/Storage Keep away from food, drink and animal feedingstuffs. Keep in a bunded area. Keep
conditions container tightly closed. Preferably keep in the original container. Otherwise, reproduce all
the statutory information from the labels onto the new container. Do not remove the hazard
labels of the containers (even if they are empty). Design the installations in order to avoid
accidental emissions of product (due to seal breakage, for example) onto hot casings or
electrical contacts. Protect from frost, heat and sunlight. Protect from moisture.

Materials to avoid Strong oxidising agents.

7.3. Specific use(s)

Specific use(s) No information available.

Section 8: EXPOSURE CONTROLS / PERSONAL PROTECTION

8.1. Control parametres

Exposure limits Mineral oil mist:

USA: OSHA (PEL) TWA 5 mg/m3, NIOSH (REL) TWA 5 mg/m3, STEL 10 mg/m3, ACGIH
(TLV) TWA 5 mg/m3 (highly refined)

Legend See section 16

8.2. Exposure controls

Occupational Exposure Controls

Engineering measures Apply technical measures to comply with the occupational exposure limits. When working in
confined spaces (tanks, containers, etc.), ensure that there is a supply of air suitable for
breathing and wear the recommended equipment.

Personal protective equipment

General Information If the product is used in mixtures, it is recommended that you contact the appropriate
protective equipment suppliers. These recommendations apply to the product as supplied.

Respiratory protection When workers are facing concentrations above the exposure limit they must use
appropriate certified respirators. Respirator with combination filter for vapour/particulate (EN
14387). Type A/P2. The use of breathing apparatus must comply strictly with the
manufacturer's instructions and the regulations governing their choices and uses.

Eye protection Tightly fitting safety goggles. Safety glasses with side-shields.

Skin and body protection Wear suitable protective clothing. Protective shoes or boots. Long sleeved clothing.

Hand protection Hydrocarbon-proof gloves: Nitrile rubber, Fluorinated rubber. Please observe the
instructions regarding permeability and breakthrough time which are provided by the
supplier of the gloves. Also take into consideration the specific local conditions under which
the product is used, such as the danger of cuts, abrasion, and the contact time. If used in
solution, or mixed with other substances, and under conditions which differ from EN 374,
contact the supplier of the EC approved gloves.

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Environmental exposure controls

General Information The product should not be allowed to enter drains, water courses or the soil.

Section 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

Appearance Clear
Colour brown
Physical state @20°C Liquid
Odour characteristic***
Odour Threshold No information available

Property Values Remarks Method

pH Not applicable*** ***
Melting point/range No information available

Boiling point/boiling range No information available***

Flash point 232 °C Cleveland Open Cup (COC)

450 °F Cleveland Open Cup (COC)
Evapouration rate No information available
Flammability Limits in Air No information available
Upper *** No information available
Lower *** No information available
Vapour pressure No information available
Vapour density No information available
Relative density 0.889 @ 15 °C***
Density 889 kg/m3 @ 15 °C
Water solubility Insoluble
Solubility in other solvents Soluble in many common
organic solvents
logPow No information available***
Autoignition temperature No information available
Decomposition temperature No information available
Viscosity, kinematic 101 mm2/s @ 40 °C ISO 3104
14 mm2/s @ 100 °C ISO 3104
Explosive properties Not explosive
Oxidising properties Not applicable
Possibility of hazardous reactions No information available***

9.2. Other information

Freezing point No information available

Section 10: STABILITY AND REACTIVITY

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10.1. Reactivity

General Information No information available.

10.2. Chemical stability

Stability Stable under recommended storage conditions.

10.3. Possibility of hazardous reactions

Hazardous reactions None under normal processing.

10.4. Conditions to Avoid

Conditions to Avoid Heat (temperatures above flash point), sparks, ignition points, flames, static electricity.

10.5. Incompatible materials

Materials to avoid Strong oxidising agents.

10.6. Hazardous Decomposition Products

Hazardous Decomposition Products None under normal use.

Section 11: TOXICOLOGICAL INFORMATION

11.1. Information on toxicological effects

Acute toxicity Local effects Product Information

Skin contact . Not classified. Repeated or prolonged skin contact may cause allergic reactions with
susceptible persons.***

Eye contact . Not classified. The supplier of some components contained within this formulation has
indicated that the classification as irritant is not required. This product does not meet the EU
criteria for classification.***

Inhalation . Not classified. Inhalation of vapours in high concentration may cause irritation of
respiratory system.

Ingestion . Not classified. Ingestion may cause gastrointestinal irritation, nausea, vomiting and
diarrhoea.

Acute toxicity - Component Information

Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation

Zinc alkyldithiophosphate*** LD50 2900 mg/kg (Rat) LD50 > 2000 mg/kg (Rabbit)

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Sensitisation

Sensitisation Not classified as a sensitizer. Contains senitizer(s). May produce an allergic reaction.

Specific effects

Carcinogenicity This product is not classified carcinogenic. During use in engines, contamination of oil with
low levels of combustion products occurs. Used motor oils have been shown to cause skin
cancer in mice following repeated application and continuous exposure. Brief or intermittent
skin contact with used motor oil is not expected to have serious effects in humans if the oil
is thoroughly removed by washing with soap and water.
Mutagenicity This product is not classified as mutagenic.
Reproductive toxicity This product does not present any known or suspected reproductive hazards.

Repeated Dose Toxicity

Subchronic Toxicity No information available.

Target Organ Effects (STOT)

Target Organ Effects (STOT) No information available.

Other information

Other adverse effects Characteristic skin lesions (oil blisters) may develop following prolonged and repeated
exposures (contact with contaminated clothing).

Section 12: ECOLOGICAL INFORMATION

12.1. Toxicity

Not classified.

Acute aquatic toxicity - Product Information

No information available.

Acute aquatic toxicity - Component Information

.
Chemical Name Toxicity to algae Toxicity to daphnia and Toxicity to fish Toxicity to
other aquatic microorganisms
invertebrates.
Zinc alkyldithiophosphate*** EC50 (72h) 2.2 mg/l EC50 (48h) 1.2 mg/l LC50 (96h) 4.5 mg/l
68649-42-3 (Daphnia magna)

Chronic aquatic toxicity - Product Information

No information available.

Chronic aquatic toxicity - Component Information

.

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Chemical Name Toxicity to algae Toxicity to daphnia and Toxicity to fish Toxicity to
other aquatic microorganisms
invertebrates.
Zinc alkyldithiophosphate*** NOEC 1.0 mg/l NOEC (21d) 0.4 mg/l NOEC(28d) 1.8 mg/l
68649-42-3 (Daphnia magna)

Effects on terrestrial organisms

No information available.***

12.2. Persistence and Degradability

General Information
No information available.

12.3. Bioaccumulative potential

Product Information No information available.***

logPow No information available***

Component Information .
Chemical Name log Pow
Zinc alkyldithiophosphate*** - 68649-42-3 0.56
12.4. Mobility in soil

Soil Given its physical and chemical characteristics, the product generally shows low soil
mobility.***

Air Loss by evaporation is limited.***

Water Insoluble. The product spreads on the surface of the water.***

12.5. Results of PBT and vPvB assessment

PBT and vPvB assessment No information available.***

12.6. Other adverse effects

General Information No information available.***

Section 13: DISPOSAL CONSIDERATIONS

13.1. Waste treatment methods

Waste from residues / unused Dispose of in accordance with the European Directives on waste and hazardous waste.
products Dispose of in accordance with local regulations. Where possible recycling is preferred to
disposal or incineration. After use, this oil must be sent to a licensed waste oil facility.
Incorrect disposal of used oil poses a risk to the environment. Mixture with other waste
types such as solvents, brake- and cooling liquids is forbidden.

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Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or
disposal.

EWC Waste Disposal No The following Waste Codes are only suggestions:. 13 02 05. According to the European
Waste Catalogue, Waste Codes are not product specific, but application specific. Waste
codes should be assigned by the user based on the application for which the product was
used.

Section 14: TRANSPORT INFORMATION

ADR/RID not regulated

IMDG/IMO not regulated

ICAO/IATA not regulated

ADN not regulated

Section 15: REGULATORY INFORMATION

15.1. Safety, health and environmental regulations/legislation specific for the substance or
mixture

European Union

Further information

No information available

15.2. Chemical Safety Assessment

Chemical Safety Assessment No information available

15.3. National regulatory information

The United Kingdom

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Section 16: OTHER INFORMATION

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Full text of H-Statements referred to under sections 2 and 3

H318 - Causes serious eye damage
H411 - Toxic to aquatic life with long lasting effects
H413 - May cause long lasting harmful effects to aquatic life
H317 - May cause an allergic skin reaction***

Abbreviations, acronyms
UVCB = Substance of unknown or Variable composition, Complex reaction products or Biological material
OECD = Organization for Economic Co-operation and Development
bw = body weight
bw/day = body weight/day
GLP = Good Laboratory Practice
fw = fresh water
mw = marine water
or = occasional release
dw = dry weight
NIOSH = National Institute of Occupational Safety and Health
OSHA = Occupational Safety and Health Administration
ACGIH = American Conference of Governmental Industrial Hygienists
IARC = International Agency for Research of Cancer
DNEL = Derived No Effect Level
PNEC = Predicted No Effect Concentration
LD50 = 50% Lethal Dose - Chemical amount, given at once, which causes the death of 50% (one half) of a group of test animals
LC50 = 50% Lethal concentration - Concentration of a chemical in air or a chemical in water which causes the death of 50% (one
half) of a group of test animals
LL = Lethal Loading
NOEC = No Observed Effect Concentration
NOEL = No Observed Effect Level
NOAEL = No Observed Adverse Effect Level
EC x = Effect Concentration associated with x% response

Legend Section 8
TWA: Time Weight Average
STEL: Short Time Exposure Limit
+ Sensitiser * Skin designation
** Hazard Designation C: Carcinogen
M: Mutagen R: Toxic to reproduction

Revision Date: 2015-10-27

Revision Note *** Indicates updated section.

This safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006
_____________________________________________________________________________________________
This safety data sheet serves to complete but not to replace the technical product sheets. The information contained
herein is given in good faith and is accurate to the best of knowledge at the date indicated above.It is understood by the
user that any use of the product for purposes other than those for which it was designed entails potential risk.The
information given herein in no way dispenses the user from knowing and applying all provisions regulating his
activity.The user bears sole liability for the precautions required when using the product.The regulatory texts indicated
herein are intended to aid the user to fulfil his obligations. This list is not to be considered complete and exhaustive.It is
the user's responsibility to ensure that he is subject to no other obligations than those mentioned.

End of Safety Data Sheet

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