Ink V451-D Videojet: Safety Data Sheet
Ink V451-D Videojet: Safety Data Sheet
Ink V451-D Videojet: Safety Data Sheet
Videojet®
Ink
V451-D
Page : 1 / 11
Version : UK ENGLISH
Version number : 2
Date of issue/ Date of revision : 4/9/2021
Date of previous issue : 9/27/2018 (1.00)
1.2 Relevant identified uses of the substance or mixture and uses advised against
Material uses : Industrial applications: Ink for use in a continuous ink jet process.
Videojet Technologies Europe B.V., P.O. Box 1, Strijkviertel 39, 3454 DeMeern, The Netherlands
Tel: +31 30 6 693 000 Fax: +31 30 6 693 060
Videojet Technologies U.K.,Ltd., 4 & 5 Ermine Centre Lancaster Way, Huntingdon, Cambs, PE29 6XX, United
Kingdom
Tel: 0870 240 5542 Fax: 0870 242 2835
Ingredients of unknown : 7.5 percent of the mixture consists of component(s) of unknown acute oral toxicity
toxicity 7.5 percent of the mixture consists of component(s) of unknown acute dermal
toxicity
16.1 percent of the mixture consists of component(s) of unknown acute inhalation
toxicity
Ingredients of unknown : Contains 16.1% of components with unknown hazards to the aquatic environment
ecotoxicity
Danger. Highly flammable liquid and vapour. Toxic if swallowed, in contact with skin or if inhaled. Causes damage
to organs. Do not breathe vapour. Wear protective gloves. Wear protective clothing. Keep away from heat, hot
surfaces, sparks, open flames and other ignition sources. No smoking. IF SWALLOWED: Immediately call a
POISON CENTER or physician. IF exposed: Call a POISON CENTER or physician. Keep container tightly closed.
Store in a well-ventilated place.
Hazardous ingredients : methanol (CAS 67-56-1, EC 200-659-6).
Type
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit
[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII
[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII
[5] Substance of equivalent concern
[6] Additional disclosure due to company policy
Occupational exposure limits, if available, are listed in Section 8.
See Section 16 for the full text of the H statements declared above.
Ingestion : Get medical attention immediately. Call a poison center or physician. Wash out
mouth with water. Remove dentures if any. Remove victim to fresh air and keep at
rest in a position comfortable for breathing. If material has been swallowed and the
exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should
be kept low so that vomit does not enter the lungs. Never give anything by mouth to
an unconscious person. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as a
collar, tie, belt or waistband.
4.2 Most important symptoms and effects, both acute and delayed
Potential acute health effects
Eye contact : No known significant effects or critical hazards.
Inhalation : Toxic if inhaled. Causes damage to organs following a single exposure if inhaled.
Skin contact : Toxic in contact with skin. Causes damage to organs following a single exposure in
contact with skin.
Ingestion : Toxic if swallowed. Causes damage to organs following a single exposure if
swallowed.
Over-exposure signs/symptoms
Eye contact : No specific data.
Inhalation : No specific data.
Skin contact : No specific data.
Ingestion : No specific data.
4.3 Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
6.2 Environmental : Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains
precautions and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Store in accordance with local regulations. Store in a segregated and approved area. Store in original container
protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section
10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidising materials. Keep
container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed
and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid
environmental contamination. See Section 10 for incompatible materials before handling or use.
Recommended monitoring : If this product contains ingredients with exposure limits, personal, workplace
procedures atmosphere or biological monitoring may be required to determine the effectiveness
of the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to monitoring standards, such as
the following: European Standard EN 689 (Workplace atmospheres - Guidance for
the assessment of exposure by inhalation to chemical agents for comparison with
limit values and measurement strategy) European Standard EN 14042 (Workplace
atmospheres - Guide for the application and use of procedures for the assessment
of exposure to chemical and biological agents) European Standard EN 482
(Workplace atmospheres - General requirements for the performance of procedures
for the measurement of chemical agents) Reference to national guidance
documents for methods for the determination of hazardous substances will also be
required.
DNELs/DMELs
Product/ingredient name Type Exposure Value Population Effects
1) methanol DNEL Short term Dermal 8 mg/kg bw/day General population Systemic
2) DNEL Long term Dermal 8 mg/kg bw/day General population Systemic
3) DNEL Short term Dermal 40 mg/kg bw/ Workers Systemic
day
4) DNEL Long term Dermal 40 mg/kg bw/ Workers Systemic
day
5) DNEL Short term Inhalation 50 mg/m³ General population Local
6) DNEL Long term Inhalation 50 mg/m³ General population Local
7) DNEL Short term Inhalation 50 mg/m³ General population Systemic
8) DNEL Long term Inhalation 50 mg/m³ General population Systemic
9) DNEL Short term Inhalation 260 mg/m³ Workers Local
10) DNEL Long term Inhalation 260 mg/m³ Workers Local
11) DNEL Short term Inhalation 260 mg/m³ Workers Systemic
12) DNEL Long term Inhalation 260 mg/m³ Workers Systemic
PNECs
Product/ingredient name Compartment Detail Value Method Detail
1) methanol Fresh water 20.8 mg/l Assessment Factors
Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust
controls ventilation or other engineering controls to keep worker exposure to airborne
contaminants below any recommended or statutory limits. The engineering controls
also need to keep gas, vapour or dust concentrations below any lower explosive
limits. Use explosion-proof ventilation equipment.
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and
safety showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn,
unless the assessment indicates a higher degree of protection: safety glasses with
side-shields.
Hand protection : Recommended: EN374 A
May be used (Short term exposure): Latex gloves. Nitrile gloves. Use gloves only
once. Gloves should be replaced regularly and if there is any sign of damage to the
glove material. The user must check that the final choice of type of glove selected
for handling this product is the most appropriate and takes into account the
particular conditions of use, as included in the user's risk assessment.
Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Recommended (EN14387): organic vapour filter (Type AX)
Additional information: In situations where misting or flying may occur, use
appropriate certified respirators. Use a properly fitted, particulate filter respirator
complying with an approved standard if a risk assessment indicates this is
necessary.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable levels.
Irritation/Corrosion
Conclusion/Summary
Skin : Not classified. No known significant effects or critical hazards.
V451-D UK ENGLISH Version: 2 Page: 8/11
Aspiration hazard
Conclusion/Summary : Not classified. No known significant effects or critical hazards.
Potential chronic health effects, Other
Conclusion/Summary : No known significant effects or critical hazards.
14.2 UN proper Printing Ink Printing Ink Printing Ink Printing Ink
shipping name
Additional information Special provisions 640 (C) Special provisions 640 (C) - -
Tunnel code (D/E)
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its
subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination
of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with
caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.