SAFETY DATA SHEET

UNIVERSAL BLUE GASKET & JOINTING COMPOUND

1. IDENTIFICATION OF SUBSTANCE/AND OF THE COMPANY/UNDERTAKING

PRODUCT NAME UNIVERSAL BLUE GASKET & JOINTING COMPOUND

PART NUMBER 865135

SUPPLIER HYLOMAR LIMITED

HYLO HOUSE, CALE LANE, NEW SPRINGS
WIGAN, GREATER MANCHESTER
WN2 1JT
TELEPHONE +44 (0)1942 617000

E MAIL [email protected]

2. HAZARDS IDENTIFICATION

2.1. Classification of the substance or mixture

The mixture has been assessed and/or tested for its physical, health and environmental hazards and the following classification
applies.

Classification according to Directive 67/548/EEC or 1999/45/EC as amended

Classification Carc. Cat. 3;R40, Xn;R22-48/20, Xi;R36/38
The full text for all R-phrases is displayed in section 16.

Classification according to Regulation (EC) No 1272/2008 as amended

Health hazards

Acute toxicity, oral Category 4 H302 - Harmful if swallowed.

Skin corrosion/irritation Category 2 H315 - Causes skin irritation.
Serious eye damage/eye irritation Category 2 H319 - Causes serious eye irritation.

Carcinogenicity Category 2 H351 - Suspected of causing cancer.

Specific target organ toxicity - repeated Category 2 (Central nervous system) H373 - May cause damage to
exposure through prolonged or repeated
organs (Central nervous system)
exposure.
HAZARD SUMMARY

Physical hazards Not classified for physical hazards.

Health hazards Harmful if swallowed. Irritating to eyes and skin. Limited evidence of a carcinogenic effect.
Harmful: danger of serious damage to health by prolonged exposure through inhalation.

Environmental hazards Not classified for hazards to the environment.

Specific hazards Prolonged exposure may cause chronic effects.

Main symptoms Symptoms include itching, burning, redness, and tearing of eyes. Itching, redness, burning of
skin. Vapours may cause drowsiness and dizziness.

2.2. Label elements

Label according to Regulation (EC) No. 1272/2008 as amended

Contains: Dichlormethane
 UNIVERSAL BLUE GASKET & JOINTING COMPOUND

Signal word Danger

Hazard statements H302 - Harmful if swallowed.
H315 - Causes skin irritation.
H319 - Causes serious eye irritation.
H351 - Suspected of causing cancer.
H373 - May cause damage to organs (Central nervous system) through prolonged or repeated
exposure.
Precautionary statements
Prevention P201 - Obtain special instructions before use.
P202 - Do not handle until all safety precautions have been read and understood.
P260 - Do not breathe mist or vapour.
P264 - Wash thoroughly after handling.
P280 - Wear protective gloves/eye protection/face protection.
Response P301 + P312 - IF SWALLOWED: Call a POISON CENTRE or doctor/physician if you feel unwell.
P330 - Rinse mouth.
P302 + P352 - IF ON SKIN: Wash with plenty of soap and water.
P332 + P313 - If skin irritation occurs: Get medical advice/attention.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P337 + P313 - If eye irritation persists: Get medical advice/attention.
P362 - Take off contaminated clothing and wash before reuse.
Storage P405 - Store locked up.
Disposal P501 - Dispose of contents/container in accordance with local/regional/national/international
regulations.
Supplemental label information Not applicable.
2.3. Other hazards Not assigned.

3. COMPOSITION/INFORMATION ON INGREDIENTS
3.2. Mixtures
General information
Chemical name % CAS-No. / EC No. REACH Registration No. INDEX No. Notes

Dichlormethane 25-65 75-09-2 - 602-004-00-3

200-838-9
Classification: DSD: Carc. Cat. 3;R40, Xn;R22-48/20, Xi;R36/38
CLP: Acute Tox. 4;H302, Skin Irrit. 2;H315, Eye Irrit. 2;H319, Carc. 2;H351, STOT RE 2;H373

#: This substance has workplace exposure limit(s).

CLP: Regulation No. 1272/2008.
DSD: Directive 67/548/EEC.
Composition comments The full text for all R- and H-phrases is displayed in section 16. All concentrations are in percent by
weight unless ingredient is a gas. Gas concentrations are in percent by volume.

4. FIRST AID MEASURES

General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves.
4.1. Description of first aid measures
Inhalation Move into fresh air and keep at rest. If not breathing, give artificial respiration or give oxygen by
trained personnel. Get medical attention if any discomfort continues.
Skin contact Take off immediately all contaminated clothing. Wash skin thoroughly with soap and water. If
irritation develops and persists, get medical attention.
Eye contact Immediately rinse eyes with water. Remove any contact lenses, and continue flushing eyes with
running water for at least 15 minutes. Hold eyelids apart to ensure rinsing of the entire surface of
the eye and lids with water. Get immediate medical attention.
Ingestion Rinse mouth thoroughly. Do not induce vomiting. If vomiting occurs, keep head low so that
stomach content doesn't get into the lungs. Drink a few glasses of water or milk. Get medical
attention immediately.
 UNIVERSAL BLUE GASKET & JOINTING COMPOUND
Symptoms include itching, burning, redness, and tearing of eyes. Itching, redness, burning of skin.
Vapours may cause drowsiness and dizziness.
Provide general supportive measures and treat symptomatically.

5. FIREFIGHTING MEASURES

5.1. Extinguishing media The product is not flammable.

Suitable extinguishing Water spray, foam, dry powder or carbon dioxide.
media
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media
5.2. Special hazards arising By heating and fire, toxic vapours/gases may be formed. Solvent vapours may form explosive
from the substance or mixture mixtures with air.
5.3. Advice for firefighters
Special protective Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
equipment for firefighters Selection of respiratory protection for firefighting: follow the general fire precautions indicated in
the workplace.
Special fire fighting Cool containers exposed to heat with water spray and remove container, if no risk is involved.
procedures Prevent runoff from fire control or dilution from entering streams, sewers or drinking water supply.

6. ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures
For non-emergency Keep upwind. Ventilate closed spaces before entering them. Avoid inhalation of vapours/spray and
personnel contact with skin and eyes. Do not touch damaged containers or spilled material unless wearing
appropriate protective clothing.
For emergency responders Keep unnecessary personnel away. Wear protective clothing as described in Section 8 of this
safety data sheet.
6.2. Environmental precautions Prevent further leakage or spillage if safe to do so. Do not discharge into drains, water courses or
onto the ground.
6.3. Methods and material for Eliminate all ignition sources. Ventilate the area. Wipe up with absorbent material (e.g. cloth,
containment and cleaning up fleece). Transfer to a container for disposal. Following product recovery, flush area with water.
6.4. Reference to other For personal protection, see section 8 of the SDS. For waste disposal, see section 13 of the SDS.
sections
7. HANDLING AND STORAGE
7.1. Precautions for safe Keep away from sources of ignition - No smoking. Use only outdoors or in a well-ventilated area.
handling Avoid inhalation of vapours/spray and contact with skin and eyes. Wear protective clothing as
described in Section 8 of this safety data sheet. Avoid prolonged exposure. Wash thoroughly after
handling. Wash contaminated clothing before reuse. Observe good industrial hygiene practices.
Avoid release to the environment.
7.2. Conditions for safe Keep container tightly closed in a cool, well-ventilated place. Keep away from heat, spark, open
storage, including any flames and other sources of ignition. Store away from incompatible materials. Store in closed
incompatibilities original container at temperatures between 5°C and 25°C.
7.3. Specific end use(s) Non-Setting and Non-Hardening Gasketing Compound.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters

Occupational exposure limits Dichlormethane
UK. EH40 Workplace Exposure Limits (WELs)
Components Type Value
Dichlormethane (CAS STEL 1060 mg/m3
75-09-2)
300 ppm
TWA 350 mg/m3
100 ppm
 UNIVERSAL BLUE GASKET & JOINTING COMPOUND

Components Value Determinant Specimen Sampling time

Dichlormethane (CAS 30 ppm Carbon end-tidal *
75-09-2) monoxide breath

Recommended monitoring Follow standard monitoring procedures.

procedures
Derived no-effect level (DNEL) Not available.

Predicted no effect Not available.

concentrations (PNECs)

Exposure guidelines
UK EH40 WEL: Skin designation
Dichlormethane (CAS 75-09-2) Can be absorbed through the skin.
8.2. Exposure controls
Appropriate engineering Provide adequate ventilation. Observe Occupational Exposure Limits and minimise the risk of
controls inhalation of vapours.
Individual protection measures, such as personal protective equipment
General information Personal protective equipment should be chosen according to the CEN standards and in
discussion with the supplier of the personal protective equipment.
Eye/face protection If eye contact is likely, safety glasses with side shields or chemical type goggles should be worn.
Skin protection
- Hand protection Wear protective gloves. Polyvinyl alcohol gloves are recommended. Be aware that the liquid may
penetrate the gloves. Frequent change is advisable. Suitable gloves can be recommended by the
glove supplier.
- Other Normal work clothing (long sleeved shirts and long pants) is recommended.
Respiratory protection In case of inadequate ventilation or risk of inhalation of vapours, use suitable respiratory
equipment with gas filter (type A2). If engineering controls do not maintain airborne concentrations
below recommended exposure limits (where applicable) or to an acceptable level (in countries
where exposure limits have not been established), an approved respirator must be worn.
Thermal hazards Not applicable.
Hygiene measures Always observe good personal hygiene measures, such as washing after handling the material
and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants.
Environmental exposure Environmental manager must be informed of all major releases.
controls
9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance Blue thixotropic gel.

Physical state Liquid.
Form Thixotropic gel.
Colour Blue.
Odour Sweet.
Odour threshold Not available.
pH Not applicable.
Melting point/freezing point Not available.
Initial boiling point and boiling Not applicable.
range
Flash point Not applicable.
Evaporation rate Not applicable.
Flammability (solid, gas) Not applicable.
Upper/lower flammability or explosive limits
Flammability limit - lower Not applicable.
(%)
Flammability limit - upper Not applicable.
(%)
Vapour pressure 47 kPa (20 °C)
Vapour density 2.93 (Air = 1) (20 °C)
Relative density 1.32 (20 °C)
Solubility(ies) Slightly miscible.
Partition coefficient Log Pow: 1.25 - 1.30 (measured)
(n-octanol/water)
Auto-ignition temperature 600 °C (1112 °F)
Decomposition temperature Not available.
Viscosity Not applicable.
Explosive properties Not available.
Oxidizing properties Not available.
9.2. Other information
Explosive limit Not available.
VOC (Weight %) 25 - 65 % (Hylomar Test Method 1.1A Determination of Volatile Matter)

10. STABILITY AND REACTIVITY

10.1. Reactivity The product is stable and non reactive under normal conditions of use, storage and transport.
10.2. Chemical stability Material is stable under normal conditions.
10.3. Possibility of hazardous No dangerous reaction known under conditions of normal use.
reactions
10.4. Conditions to avoid Heat, sparks, flames, elevated temperatures.
10.5. Incompatible materials Strong oxidising agents. Alkali metals.
10.6. Hazardous Phosgene. Hydrogen chloride. Carbon monoxide. Carbon dioxide.
decomposition products
11. TOXICOLOGICAL INFORMATION
General information Occupational exposure to the substance or mixture may cause adverse effects.
Information on likely routes of exposure
Ingestion Harmful if swallowed. Ingestion may cause irritation and malaise.
Inhalation Vapours may cause drowsiness and dizziness.
Skin contact Causes skin irritation. May be absorbed through the skin.
Eye contact Causes serious eye irritation.
Symptoms Symptoms include itching, burning, redness, and tearing of eyes. Itching, redness, burning of
skin. Vapours may cause drowsiness and dizziness.
11.1. Information on toxicological effects

Acute toxicity Harmful if swallowed.

Product Species Test results
Universal Blue - Light, Medium & Heavy Grades (CAS Mixture)
Acute
Dermal
LD50 Rat > 2000 mg/kg
Inhalation
LC50 Rat 15000 ppm
Oral
LD50 Rat 1410 - 2524 mg/kg
Components Species Test results
Dichlormethane (CAS 75-09-2)
Acute
Inhalation
LC50 Guinea pig 40.2 mg/l, 6 Hours
Mouse 56.23 mg/l, 7 Hours
51.5 mg/l, 2 Hours
49.1 mg/l, 6 Hours
Rat 2000 mg/l, 15 Minutes
 UNIVERSAL BLUE GASKET & JOINTING COMPOUND

LD50 Mouse 16000 mg/l, 7 Hours

Oral
LD50 Rat 1600 mg/kg
Other
LD50 Mouse 437 mg/kg
Skin corrosion/irritation Causes skin irritation.
Serious eye damage/eye Causes serious eye irritation.
irritation
Respiratory sensitisation Not classified.
Skin sensitisation Not classified.
Germ cell mutagenicity Positive in vitro, but negative in vivo assays.
Carcinogenicity Suspected of causing cancer.
IARC Monographs. Overall Evaluation of Carcinogenicity
Dichlormethane (CAS 75-09-2) 2B Possibly carcinogenic to humans.
Reproductive toxicity Not classified.
Specific target organ toxicity - Not classified.
single exposure
Specific target organ toxicity - May cause damage to organs through prolonged or repeated exposure: Central nervous system.
repeated exposure Liver. Kidneys.
Aspiration hazard Not classified.
Mixture versus substance Not available.
information
Other information Symptoms may be delayed. Severe overexposure may cause cardiac sensitisation and result in
irregular rhythm.
12. ECOLOGICAL INFORMATION

12.1. Toxicity The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Product Species Test results
Universal Blue - Light, Medium & Heavy Grades (CAS Mixture)
LC50 Salmo garidneri 5.5 mg/l, 96 hours
Aquatic
Algae EC50 Algae > 662 mg/l, 48 hours
Crustacea EC50 Daphnia magna 135 - 2270 mg/l, 48 hours
Fish LC50 Guppy (Poecilia reticulata) 295 mg/l, 14 days
NOEC Pimephales promelas 357 mg/l, 8 days
Components Species Test results
Dichlormethane (CAS 75-09-2)
Aquatic
Crustacea EC50 Water flea (Daphnia magna) 1250 mg/l, 48 hours
Fish LC50 Fathead minnow (Pimephales promelas) 140.8 - 277.8 mg/l, 96 hours
12.2. Persistence and The product is not readily biodegradable. BOD: 5 - 25% / 28 days. The product is intrinsically
degradability biodegradable. Degradation = 100% / 28 days.
12.3. Bioaccumulative potential Potential to bioaccumulate is low. BCF (Cyprinus carpio): 6.4 - 40, 42 days at 0.025 ppm. Log
Pow: 1.25 - 1.30 (measured).
Partition coefficient Log Pow: 1.25 - 1.30 (measured)
n-octanol/water (log Kow)
Dichlormethane (CAS 75-09-2) 1.25
Bioconcentration factor (BCF) Not available.
12.4. Mobility in soil Not available.
Mobility in general The product is slightly soluble in water.
 UNIVERSAL BLUE GASKET & JOINTING COMPOUND

Other adverse effects The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
An environmental hazard cannot be excluded in the event of unprofessional handling or disposal.

13. DISPOSAL CONSIDERATIONS

13.1. Waste treatment methods
Residual waste Do not discharge into rivers, lakes, mountains, etc. because the product may affect the
environment.
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.
EU waste code The Waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Disposal methods/information Do not discharge into drains, water courses or onto the ground. Collect and reclaim or dispose in
sealed containers at licensed waste disposal site. Dispose of contents/container in accordance
with local/regional/national/international regulations.
Special precautions Dispose of in accordance with local regulations.
14. TRANSPORT INFORMATION
ADR
14.1. UN number UN2810
14.2. UN proper shipping Toxic liquid, organic, n.o.s. (Dichlormethane)
name
14.3. Transport hazard 6.1
class(es)
Subsidiary class(es) -
14.4. Packing group III
14.5. Environmental hazards No
Tunnel restriction code E
Labels required 6.1
14.6. Special precautions Read safety instructions, SDS and emergency procedures before handling.
for user
RID
14.1. UN number UN2810
14.2. UN proper shipping Toxic liquid, organic, n.o.s. (Dichlormethane)
name
14.3. Transport hazard 6.1
class(es)
Subsidiary class(es) -
14.4. Packing group III
14.5. Environmental hazards No
Labels required 6.1
14.6. Special precautions Read safety instructions, SDS and emergency procedures before handling.
for user
ADN
14.1. UN number UN2810
14.2. UN proper shipping Toxic liquid, organic, n.o.s. (Dichlormethane)
name
14.3. Transport hazard 6.1
class(es)
Subsidiary class(es) -
14.4. Packing group III
14.5. Environmental hazards No
Labels required 6.1
14.6. Special precautions Read safety instructions, SDS and emergency procedures before handling.
for user
IATA
14.1. UN number UN2810
14.2. UN proper shipping Toxic liquid, organic, n.o.s. (Dichlormethane)
name
14.3. Transport hazard 6.1
class(es)
Subsidiary class(es) -
14.4. Packing group III
 UNIVERSAL BLUE GASKET & JOINTING COMPOUND
14.5. Environmental hazards No
Labels required 6.1
ERG code 6L
14.6. Special precautions Read safety instructions, MSDS and emergency procedures before handling.
for user
IMDG
14.1. UN number UN2810
14.2. UN proper shipping Toxic liquid, organic, n.o.s. (Dichlormethane)
name
14.3. Transport hazard 6.1
class(es)
Subsidiary class(es) -
14.4. Packing group III
14.5. Environmental hazards
Marine pollutant No
Labels required 6.1
EmS F-A, S-A
14.6. Special precautions Read safety instructions, MSDS and emergency procedures before handling.
for user
14.7. Transport in bulk Not applicable.
according to Annex II of
MARPOL 73/78 and the IBC
Code
15. REGULATORY INFORMATION
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulations
Regulation (EC) No. 1005/2009 on substances that deplete the ozone layer, Annex I
Not listed.
Regulation (EC) No. 1005/2009 on substances that deplete the ozone layer, Annex II
Not listed.
Regulation (EC) No. 850/2004 On persistent organic pollutants, Annex I as amended
Not listed.
Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex I, part 1 as amended
Not listed.
Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex I, part 2 as amended
Not listed.
Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex I, part 3 as amended
Not listed.
Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex V as amended
Not listed.
Regulation (EC) No. 166/2006 Annex II Pollutant Release and Transfer Registry
Dichlormethane (CAS 75-09-2)
Regulation (EC) No. 1907/2006, REACH Article 59(1) Candidate List as currently published by ECHA
Not listed.
Authorisations
Regulation (EC) No. 1907/2006, REACH Annex XIV Substances subject to authorisation, as amended
Not listed.
Restrictions on use
Regulation (EC) No. 1907/2006, REACH Annex XVII Substances subject to restriction on marketing and use as amended
Dichlormethane (CAS 75-09-2)
Directive 2004/37/EC: on the protection of workers from the risks related to exposure to carcinogens and mutagens at
work
Not regulated.
Directive 92/85/EEC: on the safety and health of pregnant workers and workers who have recently given birth or are
breastfeeding
Dichlormethane (CAS 75-09-2)
Other EU regulations
Directive 96/82/EC (Seveso II) on the control of major-accident hazards involving dangerous substances
Not regulated.
 UNIVERSAL BLUE GASKET & JOINTING COMPOUND

Dichlormethane (CAS 75-09-2)

Other regulations The product is classified and labelled in accordance with EC directives or respective national laws.
This Safety Data Sheet complies with the requirements of Regulation (EC) No 1907/2006.
National regulations Young people under 18 years old are not allow to work with this product according to the EU
Directive 94/33/EC on the protection of young people at work.
15.2. Chemical safety No Chemical Safety Assessment has been carried out.
assessment

16. OTHER INFORMATION

List of abbreviations CLP: Regulation No. 1272/2008.
DNEL: Derived No-Effect Level.
PNEC: Predicted No-Effect Concentration.
References Not available.
Information on evaluation The mixture is classified based on test data for physical hazards. The classification for health and
method leading to the environmental hazards is derived by a combination of calculation methods and test data, if
classification of mixture available. For details, refer to Sections 9, 11 and 12.
Full text of any statements or R22 Harmful if swallowed.
R-phrases and H-statements R36/38 Irritating to eyes and skin.
under Sections 2 to 15 R40 Limited evidence of a carcinogenic effect.
R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation.
H302 Harmful if swallowed.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H351 Suspected of causing cancer.
Training information Follow training instructions when handling this material.
Disclaimer The information in the sheet was written based on the best knowledge and experience currently
available.