11-06-22 - Inc - Sr.iit - Star Co-Sc (Model-B) - Jee Adv - 2018 (P-I) - Wat-49 - QP

SEC: INC.
SR_*CO-SC Date: 11-06-22

Time: 3 Hrs Max. Marks: 180
11-06-22_INC.SR.IIT_STAR CO-SC (MODEL-B)_JEE ADV_WAT-49_SYLLABUS
PHYSICS: PRESENT WEEK (80%): Kirchoff's laws & Circuit problems for
finding equivalent resistance, Wheatstone bridge, Conversion of
galvanometer into ammeter and voltmeter, Meter bridge
PREVIOUS WEEK (20%): Current Electricity: Electric current
density drift velocity mobility, Ohm's law ohmic non-ohmic
conductors, resistance, resistivity and conductivity, colour coding of
resistors, series and parallel combination of resistors, Temperature
dependence of resistance & resistivity, Internal resistance of a cell,
emf and terminal potential difference combination of resistors in
series, parallel, Heating effect of current (fuse, bulb etc..)
(EXCLUDING: circuit problems for finding equivalent resistance),
CHEMISTRY: PRESENT WEEK (80%): Aryl halides: preparation using EAS,
Sandmayer reaction, Mechanism of SNAr reactions (Exclude:
Benzyne mechanism & cine substitution) and EAS Reactions
chlorobenzene, Fittig, Wurtz-Fittig reactions
Grignard reagent: Preparation and properties of Grignard reagent
PREVIOUS WEEK (20%): Alkyl halides: Preparation and Reactions
of alkyl halides, Mechanism of Nucleophilic Substitution reactions
(SN1, SN2 ), Mechanism of Nucleophilic Substitution reactions (SNi
and NGP), Polyhalogen compounds NCERT(Exclude haloform
reaction)
MATHEMATICS: PRESENT WEEK (80%): Leibnitz Rule, Definite integrals,
Inequation, Approximation, Definite integrals - Reduction formula
PREVIOUS WEEK (20%): Definite Integration: Definite Integration,
Fundamental theorem of integral calculus, Properties of Definite
integrals, Limit as a sum
Narayana IIT Academy 11-06-22_INC.SR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-49_Q’P
Time: 3:00Hour’s IMPORTANT INSTRUCTIONS Max Marks: 180
PHYSICS:
+Ve - Ve
Section Question Type No.of Qs Total marks
Marks Marks
Questions with Multiple Correct Choice
Sec – I(Q.N : 1 – 6) +4 -2 6 24
(partial marking scheme) (+1,0)
Questions with Numerical Value Type
Sec – II(Q.N : 7 – 14) +3 0 8 24
(e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐127.30)
Questions with Comprehension Type
Sec – III(Q.N : 15-18) +3 -1 4 12
(2 Comprehensions – 2 +2 = 4Q)
Total 18 60
CHEMISTRY:
+Ve - Ve
Marks Marks
Sec – I(Q.N :19 – 24) +4 -2 6 24
Sec – II(Q.N : 25 –32) +3 0 8 24
(e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐127.30)
Sec – III(Q.N : 33-36) +3 -1 4 12
Total 18 60
MATHEMATICS:
+Ve - Ve
Marks Marks
Sec – I(Q.N:37 – 42) +4 -2 6 24
Sec – II(Q.N :43–50) +3 0 8 24
(e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐127.30)
Sec –III(Q.N : 51-54) +3 -1 4 12
Total 18 60
Jr.IIT_*CO SC Page No: 2

PHYSICS MAX.MARKS: 60
SECTION- I
(Maximum Marks : 24)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which
are correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
1. A battery of emf E and internal resistance r is connected across a resistance R.
Resistance R can be adjusted to any value greater than to equal to zero. A graph is
plotted between the current passing through the resistance (I) and potential difference
(V) across it. Select the correct alternatives
A) Internal resistance of the battery is 5

B) E.m.f. of the battery is 10V
C) Maximum current which can be taken from the battery is 2A.
D) V  l graph can never be a straight lines as shown in figure.
2. Consider a conductor of variable cross section in which current is flowing from cross
section ‘1’ to ‘2’. Then
A) current passing through both cross section is the same

B) current through ‘1’ is less than that through ‘2’
C) Drift velocity of electrons at ‘1’ is less than that at ‘2’
D) Drift velocity is same at both the cross sections

3. In the network shown in figure, points A,B and C are at potentials of 70V, 0 and 10 V,
respectively. Then
A) Point D is at a potential of 40V

B) The currents in the sections AD, DB, DC are in the ratio 3:2:1
C) The currents in the sections AD, DB, DC are in the ratio 1:2:3
D) The network draws a total power of 200 W
4. Two circuits (as shown in figure) are called Circuit A and Circuit B. The equivalent
resistance of Circuit A is x that of Circuit B is y between 1 and 2
A) y  x B) y   
3 1 R C) xy  2 R 2 D) y  x  2 R
5. In the circuit shown in figure, reading of ammeter will
A) Increase if S1 is closed B) Decrease if S1 is closed

C)Increase if S2 is closed D) Decrease if S2 is closed

6. A micrometer has a resistance of 100 and a full scale range of 50 A. It can be
used as a voltmeter of a higher range ammeter provided a resistance is added to it.
Pick the correct range and resistance combination(s)
A) 50 V range with 10k  resistance in series
B) 10 V range with 200k  resistance in series
C) 5 mA range with 1 resistance in parallel
D) 10 mA range with 1k  resistance in parallel
SECTION - II
This section contains EIGHT (08) questions. The answer to each question is a NUMERICAL VALUE
For each question, enter the correct numerical value (in decimal notation, truncated/rounded off to the
second decimal place; e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) designated to enter the answer.
Full Marks: +3 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
7. The potential difference VA  VB for the circuit shown in the figure is   22 / x V . Find
the value of x
8. Find the potential difference (in V) between points A and B shown in the circuit
9. A galvanometer with a coil resistance of 100 shows a full-scale deflection when a

current of 1mA is passed through it. What is value of the resistance which cane
convert this galvanometer into an ammeter showing a full-scale deflection for a
current 10A?

10. A resistance of 2 is connected across on gap of meter-bridge (the length of the wire
is 100 cm) and an unknown resistance, greater than 2 , is connected across the other
gap. When these resistance are interchanged, the balance point shifts by 20 cm.
neglecting any corrections, the unknown resistance is __________ 
11. Nine wires each of resistance r  5  are connected to make a prism as shown in the
figure. Find the equivalent resistance of the arrangement across AB  in  
12. Two circular rings of identical radii and resistance of 36 each are placed in such a
way that they cross each other’s center C1 and C2 as shown in the figure. Conducting
joints are made at intersection points A and B of the rings. An ideal cell of emf 20 V is
connected across A and B. Find the power delivered by the cell  in102W 
13. A battery of internal resistance 4 is connected to the network of resistance as

shown. In order that the maximum power can be delivered to the network, the value of
R in  should be_____
14. Find current in 2 resistor________.

SECTION – III
(COMPREHENSIN TYPE)
This section contains 2Paragraphs. Based on each paragraph, there are 2 questions. Each question has 4
options (A), (B), (C) and (D) for its answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases
Paragraph for Question Nos. 15 to 16:
A resistor circuit is constructed such that twelve resistors are arranged to form a cube
as shown in the figure. Each resistor has a resistance of 2 . The potential difference
of 30 V is applied across two of the opposing points as shown
15. The points having the same potential are

(i) B,D,E (ii) C,F,H (iii) C,E
A) Only (i) is correct B) (i), (ii) and (iii) are correct
C) Only (ii) is correct D) (i) and (ii) both are correct
16. If we replace resistors between A and B and resistors between G and H by wires of
zero resistance, then the points having the same potential are:
(i) D,E,C,F (ii) A, B (iii) G, H
A) Only (i) is correct B) Only (ii) is correct
C) Only (iii) is correct D) (i), (ii) and (iii) are correct
All bulbs consume same power. The resistance of bulb 1 is 36 . Answer the
following questions:
17. What is the resistance of bulb 3?

A) 4 B) 9 C)12  D)18 
18. What is the voltage output of the battery if the power of each bulb is 4W?
A) 12 V B) 16 V C) 24 V D) None of these

CHEMISTRY MAX.MARKS: 60
SECTION- I
option.
19. Correct statement is
A) Nucleophilicity of  SH is greater then  OH in dimethyl formamide
B) Hydrazine is a better nucleophile than NH 3
C) Phenoxide ion is more basic than acetate ion
D) NH 3 is a better nucleophile than H 2 N  BH 2
20. In which of the following cases, the configuration of chiral C is retained in product ?
Et Et
  i  TsCl
OH  OH 
i Na
* *  ii  CH3ONa
H  ii  CH3  Br H
A) D B) D
C2 H 5
*

 
H OH i SOCl /
2 N
 ii  CH O Na 3
C) D
C2 H 5
*  3

 ii  CH 2 N2 
OH i BF
H
D) D

21. When 20 g of a compound  A M .F .  C4 H10O4  reacts with excess of CH 3 MgBr ,14.6 L of
CH 4 is obtained at STP. What is structural formula of (A)?
CH 2  OH
CH 2OH
 CH  OH 2 HO  CH 2  C  CH 2OH
CH 2  OH OH
A) B)
HO CH 2OH
HO OH
OH
C) HO OH D) HO
22. Comment on optical activity of the products of the following reaction :
A) They form a racemic mixture B) They are diastereomers

C) They are meso forms D) They are optically inactive
23. In which of the following reactions tertiary alcohol will be obtained as a product?
O
MgBr  excess   H  C  Cl  
H

A)
O
PhMgBr  excess   CH3  C  Cl  

H

B)
O O
CH3 MgBr  excess   CH3  C  O  C  CH3  

H

C)
O
CH3mgBr  excess   Cl  C  O  Et  
H

D)
24. Select the correct order of reactivity towards Grignard reagent for nucleophilic attack
O O
A) R  C  R  R  C  H
Cl  CH 2  C  H  CH 3CH 2  C  H
O O
B)
O O
H 3C  C  O NO2  H 3C  C  O
C)
O O
R  C  OR  R  C  NR2
D)
SECTION - II
25. Magnesium carbide on hydrolysis gives a product which on heating with Na followed
by treatment with ethyl chloride gives another product (A). (A) on catalytic reduction
gives (B). Calculate the number of monochlorinated product (s) of compound (B).
26. Find the S % of Electrophilic Carbon In SN2 Transition State ?
27. How many millilitres of ethene would be produced when 2.62g of vinyl magnesium
bromide is treated with 224 ml of ethyne at STP ?

28.
Find the number of moles of alc. KOH consumed in the above reaction
29. When (S)-2-chloropentane reacts with NaOH in 75 per cent EtOH and 25 per cent
acetone follows rate law:
Rate  2.35  10 5 .OH   5.30 106
Then, calculate percentage of S N 1 product when concentrationof OH   1.5 molar.If
percentage of S N 1 product =X, then calculate value of Y if: Y  X  5
30. The number of equivalents of Grignard reagent (x) used in following is _________
31. The number of stereoisomers of the product possible in the following reaction is ____.

Cl
NO2
32. Which of the following is more reactive towards S N Ar than
F I
Cl
NO2
NO2 NO2
A) B) C)
Cl Cl
Cl O2 N
NO2 NO2
NO2 NO2 NO2

D) E) F)
SECTION – III
(COMPREHENSIN TYPE)
Aryl and vinyl halides are less reactive towards nucleophilic substitution reaction .
Chlorobenzene itself and other aryl halides having electron -donating substituents
undergonucleophilic substitution reactions by benzyne mechanism while aryl halides
having electron -withdrawing substituents at O- and p- Based on the given passage
reply the following question
33. In the reaction of p-chlorotoluene with KNH 2 in liq NH 3 .the major product is -
A)o-toluidine B)m-toluidine C) p-toluidine D) p-chloroaniline

OCH 3
NaNH 2 / liq NH 3
A.
34. In the reaction Cl The major product is –

OCH 3
OCH 3 OCH 3 OCH 3
NH 2
NH 2 Cl
NH
A) 2
B) C) D)
Grignard reagent is usually prepared by
R  X  Mg 
Et O
 RMgX
2
Grignard reagent
Ar  X  Mg 
Et2 O
 ArMgX Grignard reagent
Grignard reagent acts as a strong base. Grignard reagent carry out nucleophilic attack
in absence of acidic hydrogen .Grignard reagent from complex with its ether solvent .
Complex formation with molecule of ether is an important factor in the formation and
stability of Grignard reagent
35. What is the correct order of reactivity of halides with magnesium ?
A) R  Cl  R  Br  R  I B) R  Br  R  Cl  R  I
C) R  I  R  Br  R  Cl D) R  I  R  Br  R  Cl
36. Which of the following reactants give primary alcohol as a major product when reacts
with RMgX followed by acidification ?
O
(i) CH 2  CH 2
(iii) CH 2  CH  CH 3
(ii) H C  H
O
O
(vi)
(iv) CH 3  C  H (v) O
O
A) i,ii,v B) i,ii,v,vi c) ii,iv,vi d) v,iv,iii,vi

MATHEMATICS MAX.MARKS: 60
SECTION- I
option.

2
37. If I   log  sin 2x  dx then
0
 
2 2
A) I   log sin x  dx B) I   log cos x  dx

0 0

2

C) I   log cos 2x  dx D) I   log 2
0
2
 2
38. If Im   cos m x sin m x dx where m  N  0 then
0
1 1 1 1
A) Im  Im1  B) Im  Im1 
2 2m 2 2m
1  2 3 4 m  22 23 2m 
C) Im  m 2  2  2  2  ......  2   1
D) Im  m1 2    ......  
2  2 3 4 m  2 2 3 m
 

sin nx
39. If In   dx; n=0, 1, 2….
 1   x
 sin x
10 10
A) In  In2 B) I
m 0
2m1  10 C) I
m 0
2m 0 D) In  In1
1 1
40. Let f  x  is a real valued function defined by : f  x   x 2  x 2  t  f  t  dt  x3  f  t  dt then
1 1
which of the following hold  s  good ?

1
10 30
A)  t  f  t  dt  B) f 1  f  1 
1
11 11
1 1
20
C)  t  f  t  dt   f  t  dt D) f 1  f  1 
1 1
11

 /4
Let I n    tan x  dx and let J n   1 I 2 n for n  0,1, 2 then which of the following hold
n n
41.
0
 s  good ?
 1 for
n
1
A) I n  I n 2  B) J n  J n 1  n 1
n 1 2n  1
1
un
C) If u  tan x then I n   du D) lim Jn  0
0
1  u 2 n 
e2
Inx
42. Let A   dx. Identity which of the following statement(s) is(are) correct?
1 x
 1 
A) A  2  e  
1
B) A   e  1  2  
 e  e
2
C) A   t et dt D) 3  A  5
0
SECTION - II
1|x|, |x| 1
 
43. Let f  x    
 and g  x   f  x 1  f x  1 x  R, , then the value of


 0, |x|  1


2011
 g  x  dx is equal to
2011

x2 k
44. If  7
dx 
15
, then k  _____
0 1  x 2  2
1 100 1 101 I 
45. I1   1  x 50  dx, I2   1  x 50  dx then  1   _______
 I2 
0 0
(Here [.] denotes G.I.F))

x2
46. Let F  x    f t dt . If F  x   x 2 1  x  then f 4  ____

0
x
47. Let g be a differentiable function satisfying   x  t  1g  t  dt  x 4  x 2 for all x  0 . The
0
1
12
value of  g ` x   g  x   10 dx
0
is equal to:

1 4
48. If f  x   x3  3x  4 then the value of  f  x dx   f 1  x  dx equals:
1 0
49. The value of lim

1  2 1 2
 ....  n 2 13  23  ....  n3 14  24  ....  n 4 
is equal to:
15  25  ....  n5 
n  2
k
x /2
sin 2 nx 100
50. Let Vn   2
sin x
dx. If 
r 1
Vr 
2
, where k  N , then k is equal to:
SECTION – III
(COMPREHENSIN TYPE)
x
Let g : R  R be a differentiable function which satisfies g  x   1   g  t  dt and

0
g ` 0   1.
1
 

51. The value of definite integral    g  rx  dx is equal to:
3  r 1 
A) In 1  e  e 1
 B) In 1  e  e 1 2
 C) In 1  e  e 2  D) 1  e 1  e 2 
52. Number of solution of the equation g   x   g  x  is equal to :
A) 0 B) 1 C) 2 D) 3
Let y  g  x  be a function of the graph of broken line connected by points  2, 0  ,  0,3
x
and  2, 4  in the x  y plane. Also f  x    g  t   t dt , x   2, 2 and h  x  is the inverse
2
of f  x  .
53. The value of f ` 0  is:
1
A) 3 B) -3 C) D) does not exist
3
The value of h    h`  is:

31 31
54.
 4  4
17 7 9 13
A) B) C) D)
5 5 5 5

11-06-22 - Inc - Sr.iit - Star Co-Sc (Model-B) - Jee Adv - 2018 (P-I) - Wat-49 - QP

Uploaded by

Copyright:

Available Formats

11-06-22 - Inc - Sr.iit - Star Co-Sc (Model-B) - Jee Adv - 2018 (P-I) - Wat-49 - QP

Uploaded by

Document Information

Original Title

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

11-06-22 - Inc - Sr.iit - Star Co-Sc (Model-B) - Jee Adv - 2018 (P-I) - Wat-49 - QP

Uploaded by

Copyright:

Available Formats

SEC: INC.

SR_*CO-SC Date: 11-06-22

Jr.IIT_*CO SC Page No: 2

A) Internal resistance of the battery is 5

A) current passing through both cross section is the same

Jr.IIT_*CO SC Page No: 3

A) Point D is at a potential of 40V

5. In the circuit shown in figure, reading of ammeter will

A) Increase if S1 is closed B) Decrease if S1 is closed

Jr.IIT_*CO SC Page No: 4

9. A galvanometer with a coil resistance of 100 shows a full-scale deflection when a

Jr.IIT_*CO SC Page No: 5

13. A battery of internal resistance 4 is connected to the network of resistance as

14. Find current in 2 resistor________.

Jr.IIT_*CO SC Page No: 6

15. The points having the same potential are

17. What is the resistance of bulb 3?

Jr.IIT_*CO SC Page No: 7

A) Nucleophilicity of  SH is greater then  OH in dimethyl formamide

B) Hydrazine is a better nucleophile than NH 3

C) Phenoxide ion is more basic than acetate ion

D) NH 3 is a better nucleophile than H 2 N  BH 2

Jr.IIT_*CO SC Page No: 8

A) They form a racemic mixture B) They are diastereomers

PhMgBr  excess   CH3  C  Cl  

CH3 MgBr  excess   CH3  C  O  C  CH3  

26. Find the S % of Electrophilic Carbon In SN2 Transition State ?

bromide is treated with 224 ml of ethyne at STP ?

Jr.IIT_*CO SC Page No: 10

Rate  2.35  10 5 .OH   5.30 106

Then, calculate percentage of S N 1 product when concentrationof OH   1.5 molar.If

percentage of S N 1 product =X, then calculate value of Y if: Y  X  5

Jr.IIT_*CO SC Page No: 11

NO2 NO2 NO2

undergonucleophilic substitution reactions by benzyne mechanism while aryl halides

having electron -withdrawing substituents at O- and p- Based on the given passage

reply the following question

A)o-toluidine B)m-toluidine C) p-toluidine D) p-chloroaniline

Jr.IIT_*CO SC Page No: 12

34. In the reaction Cl The major product is –

OCH 3 OCH 3 OCH 3

A) i,ii,v B) i,ii,v,vi c) ii,iv,vi d) v,iv,iii,vi

Jr.IIT_*CO SC Page No: 13

A) I   log sin x  dx B) I   log cos x  dx

which of the following hold  s  good ?

Jr.IIT_*CO SC Page No: 14

(Here [.] denotes G.I.F))

46. Let F  x    f t dt . If F  x   x 2 1  x  then f 4  ____

Jr.IIT_*CO SC Page No: 15

49. The value of lim

Let g : R  R be a differentiable function which satisfies g  x   1   g  t  dt and

The value of h    h`  is:

Jr.IIT_*CO SC Page No: 16

You might also like