JEE Main 2022 July Session 2 Shift-2 (DT 26-07-2022) Chemistry
JEE Main 2022 July Session 2 Shift-2 (DT 26-07-2022) Chemistry
JEE Main 2022 July Session 2 Shift-2 (DT 26-07-2022) Chemistry
2022
COMPUTER BASED TEST (CBT)
Memory Based Questions & Solutions
Date: 26 July, 2022 (SHIFT-2) | TIME : (3.00 p.m. to 6.00 p.m)
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SUBJECT: CHEMISTRY
PART : CHEMISTRY
1. For the reaction at 27°C
H2F2(g) H2(g) + F2(g)
U = –59.6 KJ/mole, then value of H is –X KJ/mole. The value of X is:
[Report your answer to nearest integer]
Ans. (57)
Sol. H = U + ngRT
1×8.314×300
= –59.6 +
1000
= –59.6 + 2.49
= –57.11 KJ/mole
3. Which of the following metal have low melting point and it is closer to metalloid in periodic table
(1) Al (2) Ga (3) In (4) Tl
Ans. (2)
Sol. 13th group MP
B 2453 K
A 933 K
Ga 303 K
In 430 K
T 576 K
Ga have low meting point and it is closer to metalloid in periodic table.
4. 10 gram gaseous mixture of H2 and He at 6 bar pressure have volume 0.0125 m 3 at 300 k temperature.
Find weight of Helium in mixture (in gram).
Ans. (8)
Sol. PV = nRT
[6 × 0.0125 × 103 ] = ntotal × 0.082 × 300
ntotal = 3 mole
WH2 WHe
3
2 4
2 WH2 + WHe = 12 ……………(1)
WH2 + WHe = 10 ……………(2)
On solving
WH2 = 2 & WHe = 8
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| JEE MAIN-2022 | DATE : 26-07-2022 (SHIFT-2) | PAPER-1 | MEMORY BASED | CHEMISTRY
5. A solute 'X' dissolve in a solvent at molality 1m then elevation in boiling point is 3°C while at molality 2m,
k
depression in freezing point is 6°C, then ratio of b is 1 : X, then value of X is _________________
kf
Ans. (1)
Sol. Tb kb m
Tf k f m
3 kb 1
6 kf 2
kb 1
kf 1
So, X=1
6. In the following reaction sequence.
PCl3 + C2H5OH A
A + PCl3 B
How many non-ionisable H atom are present in B.
Ans. (2)
Sol. 3C2H5OH + PCl3 3C2H5Cl + H3PO3
H3PO3 + PCl3 H4P2O5
Pyrophosphorous acid
8. We have to prepare a buffer solution of NH3 and NH4Cl which have pH = 8.26. For this initially we have
1 litre 0.2 M ammonia solution, then how much amount of NH 4Cl in gram is added for this [pkb = 4.74 &
GMM of NH4Cl = 53.5 g]
Ans. (107)
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| JEE MAIN-2022 | DATE : 26-07-2022 (SHIFT-2) | PAPER-1 | MEMORY BASED | CHEMISTRY
9. A compound AB2 dissociate with half-life 200 sec and half-life is independent of concentration of AB2,
find time taken for 80% dissociation of AB2.
(1) 467 sec (2) 100 sec (3) 326 sec (4) 587 sec
Ans. (1)
Sol. As is independent an initial concentration so reaction is 1st order.
2
2.303 100
t= log
k 100 %
2.303 100
t= 200 log
0.693 20
2.303 200
= log5
0.693
= 664.65 ×0.7 = 466.66 ≈ 467 sec
10. Find correct order of covalent character in
CaF2, CaCl2, CaBr2, CaI2
(a) (b) (c) (d)
(1) a < b < c < d (2) b < c < a < d (3) c < c < b < a (4) d < c < a < b
Ans. (1)
Sol. As per Fazan rule as the size of anion increases covalent character increase.
So order of covalent character is
CaF2 < CaCl2 < CaBr2 < CaI2
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| JEE MAIN-2022 | DATE : 26-07-2022 (SHIFT-2) | PAPER-1 | MEMORY BASED | CHEMISTRY
14. Assertion : Finely divided gold particles are red in colour as concentration increase colour changes from
purple to blue and finally Golden.
Reason: The colour particle depends on wave length of light scattered.
(1) Assertion is true, Reason is true and Reason is correct explanation of Assertion
(2) Assertion is true, Reason is true and Reason is not correct explanation of Assertion.
(3) Assertion is true and Reason is false
(4) Assertion is false and Reason is true
Ans. (1)
Sol. The colour of colloidal solution depends on the wavelength of light scattered by the dispersed particles.
The wavelength of light further depends on the size and nature of the particles. The colour of colloidal
solution also changes with the manner in which the observer receives the light. For example, a mixture
of milk and water appears blue when viewed by the reflected light and red when viewed by the
transmitted light. Finest gold sol is red in colour; as the size of particles increases, it appears purple,
then blue and finally golden
15. Assertion : Phenolphthalein is a pH dependent indicator which is colourless in acidic medium and
change its colour to pink in basic medium.
Reason: Phenolphthalein is weak acid that does not dissociate in basic medium.
(1) Assertion is true, Reason is true and Reason is correct explanation of Assertion
(2) Assertion is true, Reason is true and Reason is not correct explanation of Assertion.
(3) Assertion is true and Reason is false
(4) Assertion is false and Reason is true
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| JEE MAIN-2022 | DATE : 26-07-2022 (SHIFT-2) | PAPER-1 | MEMORY BASED | CHEMISTRY
Ans. (3)
Sol. HPh ⇋ H+ + Ph–
Colourless Pink colour
(acidic medium) (Basic medium)
16. 10 ml of CuSO4 solution is treated with excess of KI solution, thus the liberated I2 required 20 ml, 0.02 M
hypo solution find the molarity of CuSO4 solution using following reactions.
2Cu2+ + 4I– Cu2I2 + I2
I2 + 2S2O3 2– 2I– + S4O62–
Then molarity of CuSO4 solution is ________× 10–2M
Ans. (4)
Sol. Mili eq. of Cu2+ = mili eq. of I2 = mili eq. of Hypo
1[M×10] = 1[0.02×20]
M = 4×10–2
O
CH2–CN DIBAL-H
17. EtO–C–CH2–CH2–
H2O
O
O O
CH2–C–H CH2–CN
H–C–CH2–CH2– H–C–CH2–CH2–
(1) (2)
O
O O
CH2–C=NH CH2–C–H
(3) EtO–C–CH2–CH2– (4) EtO–C–CH2–CH2–
Ans. (1)
O
O O
CH2–CN CH2–C–H
EtO–C–CH2–CH2–
DIBAL-H H–C–CH2–CH2–
Sol.
H2O
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| JEE MAIN-2022 | DATE : 26-07-2022 (SHIFT-2) | PAPER-1 | MEMORY BASED | CHEMISTRY
NO2 OH
NH2 I
(1) HNO2 , KI, Fe/H+, HNO2, Warm water (2) KI, HNO2, Fe/H+, HNO2, Warm water
(3) Fe/H+, HNO2 , KI, HNO2, Warm water (4) HNO2, Fe/H+, KI, Warm water, HNO2
Ans. (1)
NO2 NO2 OH
1. HNO2 1. Fe/H+
2. KI 2. HNO2,
Sol. 3. Warm Water
NH2 I I
Ans. (1)
Sol.
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| JEE MAIN-2022 | DATE : 26-07-2022 (SHIFT-2) | PAPER-1 | MEMORY BASED | CHEMISTRY
23. Ethylmagnesium bromide with methanol gives 2.24 ml gas at STP. Weight of the gas in mg.
Ans. (3)
Sol. C2H5MgBr + CH3OH C2H6(g) + CH3OMgBr
Volume of ethane = 2.24 ml
2.24 2.24
Mole of ethane = =
22400 2.24 10 4
2.24 30
Weight of ethane = = 3 10-3 gm = 3 mg
2.24 104
Sol.
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