Msds Konturplast White

MATERIAL SAFETY DATA SHEET
prepared in accordance with Commission Regulation (EU) 2015/830 amending

Regulation (EC) No 1907/2006 (REACH) Page
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Edition Date of issue Update
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SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
1.1. Product identifier

Trade name: Masa chemoutwardzalna KONTURPLAST BIAŁY
1.2. Relevant identified uses of the substance or mixture and uses advised against:
1.2.1. Relevant identified uses
Professional use. Two compound cold plastic. Used for horizontal road markings.
1.2.2. Uses advised against

Other then mentioned in section 1.2.1.
1.3. Details of the supplier of the safety data sheet:

KONTUR Sp. z o. o.
Address: Kolonia Komarno 32, 21-543 Konstantynów, Poland
Tel. +48 (83) 341 43 54
Fax. +48 (83) 341 54 89
e-mail: [email protected]
1.4. Emergency telephone number:

+48 83 341 43 54 (active at 8:00 – 16:00 h)
SECTION 2: HAZARDS IDENTIFICATION
2.1. Classification of the mixture:
Under the Regulation (WE) no 1272/2008
Flam. Liq. 2 – Flammable liquids, Hazard Category 2; with assigned phrase stating the type of hazard
H225 Highly flammable liquid and vapour
Skin Irrit. 2 – Skin corrosion/irritation, Hazard Category 2; with assigned phrase stating the type of hazard
H315 Causes skin irritation
Skin Sens. 1 – Skin sensitisation, Hazard Category 1 with assigned phrase stating the type of hazard:
H317 May cause an allergic skin reaction
STOT SE 3 – Specific target organ toxicity – Single exposure, Hazard Category 3, Respiratory tract irritation;
with assigned phrase stating the type of hazard
H335 May cause respiratory irritation
Aquatic Chronic 3 – Hazardous to the aquatic environment, CHRONIC, Hazard Category 3 with assigned
phrase H stating the type of hazard
H412 Harmful to aquatic life with long lasting effects
Health hazard: product classified as hazardous to health, see section 11

Environmental Hazards: product is classified as hazardous to environment, harmful to aquatic life with long
lasting effects
Physical/Chemical hazards: product classified as hazardous, highly flammable liquid. Product vapours form
flammable/explosive mixtures with air.
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2.2. Label elements
Under the Regulation (WE) no 1272/2008
Pictograms:
GHS 02 GHS 07
Signal Word: Danger
Hazard statements:
Precautionary Statement:
General:
-
Prevention:
P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking
P2601 Avoid breathing mist/vapours/spray
P273 Avoid release to the environment
P280 Wear protective gloves/protective clothing/eye protection/face protection
Response:
P304 + P340 IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
P333 + P313 If skin irritation or rash occurs: Get medical advice/attention
Storage:
-
Disposal:
P501 Dispose of contents/container in accordance with local/regional/national/international regulation
Hazardous Ingredients: methyl methacrylate CAS no 80-62-6, 2-ethylhexyl acrylate CAS no 103-11-7, 2,2'-
ethylenedioxydiethyl dimethacrylate CAS no 109-16-0
2.3. Other hazards:

The mixture doesn’t meet the criteria for PBT or vPvB in accordance with Annex XIII of REACH Regulation.
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.1. Substances
Not applicable
3.2. Mixtures
The product is classified as mixture. It contains: hazardous ingredients listed below, fillers (quartz*, glass
microspheres, calcium carbonate*, titanium dioxide*),additives not classified as hazardous or at
concentration below applicable concentrations or specific concentration limits.
The classification of hazardous substance contained in the product are given in Table 3.1 of Annex VI to the
Regulation of the European Parliament and Council Regulation (EC) No 1272/2008 including its amends,
REACH data, the manufacturer and available literature data.
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No CAS No EC Index number REACH number Chemical name Quantity Hazard category H phrases
01-2119452498- methyl 4 – 10 % Flam. Liq. 2, Skin Irrit. 2, H225, 315, 317,
80-62-6 201-297-1 607-035-00-6
28-XXXX methacrylate*,** w/w Skin Sens. 1, STOT SE 3 335
01-2119453158- 2-ethylhexyl 4 – 10 % Skin Irrit. 2, Skin Sens. 1,
103-11-7 203-080-7 607-107-00-7 H315, 317, 335
37-XXXX acrylate*,** w/w STOT SE 3
2,2'-ethylenedioxy-
01-2119969287-
109-16-0 203-652-6 not assigned diethyl < 1 % w/w Skin Sens. 1 H317
21-XXXX
dimethacrylate***
01-2119565113- 2,6-di-tert-butyl-p- Aquatic Acute 1, Aquatic
128-37-0 204-881-4 not assigned ≤ 0,6 % w/w H400, 410
46-XXXX cresol*** Chronic 1
14808-60-7 238-878-4 not assigned - quartz**** < 0,4 % w/w STOT RE 1 H372
Acute Tox. 3 (oral), Acute
01-2119937766- N,N-dimethyl-p- Tox. 3 (derm), Acute Tox. 3 H301, 311, 331,
99-97-8 202-805-4 612-056-00-9 ≤ 0,2 % w/w
23-XXXX toluidine** (inh), STOT RE 2, Aquatic 373, 412
Chronic 3
01-2119519269- alkanes, C14-17, < 0,19 % Lact., Aquatic Acute 1, H362, 400, 410,
85535-85-9 287-477-0 602-095-00-X
33-XXXX chloro** w/w Aquatic Chronic 1 EUH 066
01-2119472430- N-methyl-2- < 0,15 % Skin Irrit. 2, Eye Irrit. 2, H315, 319, 335,
872-50-4 212-828-1 606-021-00-7
46-XXXX pyrrolidone*,** w/w Repr. 1B, STOT SE 3 360D
M-factor for environment hazardous substances (CAS no 128-37-0)

Acute hazard: M = 1
Chronic hazard: M = 1
M-factor for environment hazardous substances (CAS no 85535-85-9)

Acute hazard: M = 100
Chronic hazard: M = 10
* Substance for which there are Community workplace exposure limits

** Hazard classification of substances is consistent with the Table 3.1 of Annex VI to the Regulation of the
European Parliament and Council Regulation (EC) No 1272/2008
*** Hazard classification of substances is consistent with the REACH data
**** - Hazard classification of substances is consistent with the producer data
For the wording of the listed H phrases and hazard category refer to section 16.
SECTION 4: FIRST AID MEASURES
4.1. Description of first aid measures

General recommendations
In case of indisposition or labour injury immediately call a professional health service. Show the pictograms
and H phrases from the label or safety data sheet to a doctor. Inform the doctor on provided first aid. Do not
evoke vomiting in any case. If the affected person vomits, turn him/her on side (position of the head on its
side) in order to prevent suffocating with vomits.
Remove contaminated/soaked clothing and shoes immediately. ATTENTION: Take off contaminated/soaked
clothing to a safe place away from sources of ignition and heat.
Protection of first aid responders

Do not take any action that would create a risk to the rescuer unless suitable training.
Contamination of the skin

Remove contaminated clothing. Contaminated areas of the skin wash thoroughly water with soap. Do not
use solvents. In case of irritation or rash consult a doctor.
Contamination of the eye

Flush contaminated eyes with wide-open eyelids a continuous stream of water for about 15 minutes. In the
case of persistent irritation consult an ophthalmologist.
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Inhalation
If exposure, move victim to fresh air. Keep warm and quiet. Consult with doctor. Conscious person placed in
a rest half seated, ensure calm and warm, unconscious person lay in the recovery position.
Ingestion
Rinse mouth thoroughly with water. Do not induce vomiting. In case of occurrence of natural retches, hold
the victim bent forward. Contact with doctor immediately and show product label.
4.2. Most important symptoms and effects, both acute and delayed
Acute symptoms – irritation of the skin and eyes, with higher concentrations may have impaired balance
and coordination, the state similar to being drunk with arousal, followed by sleepiness.
Delayed symptoms – skin sensitizing for sensible persons
Effects of exposure – no data
4.3. Indication of any immediate medical attention and special treatment needed
Note to Physician: No specific antidote, treat symptomatically.
SECTION 5: FIREFIGHTING MEASURES
5.1. Extinguishing media

Suitable extinguishing agents: CO2, powders and foam, water spray, sand for small fires
Extinguishing media which must not be used for safety reasons: a strong jet of water – risk of fire spreading
and environment contamination
5.2. Special hazards arising from the mixture

The combustion of the product may produce carbon oxides, hydrocarbons, other harmful gases and fumes.
Avoid inhalation of combustion products, may pose a threat to health.
5.3. Advice for fire-fighters: strictly apply the breathing apparatus and protective clothing for fire fighting or
during clean-up work immediately after a fire in an enclosed or poorly ventilated areas.
General: inform about the fire, call the appropriate emergency services. Remove from the endangered area
unauthorized persons, not involved in extinguishing the fire, order evacuation if necessary.
Additional notes: vapours of product form explosive mixtures with air. Vapours are heavier than air,
accumulate at the surface of the earth and lower parts of the rooms. Tanks and packaging which are not
covered by the fire, exposed to fire or high temperature should be cooled by water from a safe distance (risk
of explosion), and if possible removed from the hazardous area. Fire residues and contaminated waters
dispose in according to applicable regulations. Do not introduce contaminated waters into drain.
SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions, protective equipment and emergency procedures

Use personal protective equipment, especially respiratory protection in case of vapour/fumes/aerosols of
product. Avoid direct contact with releasing product. Avoid breathing vapours.
Inform about the accident, call the appropriate emergency services (e.g. Fire Brigade, Police). Remove from
the hazardous area all persons not taking part in the emergency, order evacuation if necessary.
Remove all ignition sources – extinguish open flame, do not smoke, do not use sparking tools and devices,
eliminate hot surfaces and other sources of heat. Apply precaution measures preventing from electrostatic
discharges.
For emergency responders: read the information in Section 8
- Avoid formation and inhalation of product vapors and aerosols during removal
- use well-fitting and fitting safety goggles, protective gloves and protective clothing
6.2. Environmental precautions

Do not allow to enter drains, groundwater, soil and open water courses. Spilled product protect against
spreading using dams or barriers. In case of water contamination inform local authorities.
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6.3. Methods and material for containment and cleaning up

In case of container leakage, spillage of the product, protect the source of leak, pour the product into an
empty container or place damaged container in an emergency one. Limit the spread of spill by the
embankment of land, large quantities of liquid pump out. Small amounts of spilled liquid soak up with non-
flammable, absorbent material (sand, diatomite, universal binders, etc.) gather in closed container for
disposal and utilized. Perform clean-up work with adequate ventilation.
6.4. Reference to other sections

Personal protective equipment – section 8
Waste disposal – section 13
SECTION 7: HANDLING AND STORAGE
7.1. Precautions for safe handling

Avoid directly contact with product, vapour inhalation, contamination of unprotected skin, eyes. Ensure
adequate ventilation/exhaust in the workplace, prevent the formation of harmful concentrations of vapour in
the air, work in well ventilated areas. Store unused containers tightly closed. Observe good personal hygiene
and wear protective clothing in accordance with information set out in section 8.
Observe the basic rules of hygiene: do not eat, drink or smoke in the workplace. Contaminated clothing
should be immediately replaced with a clean one. Do not allow the product to be spilled, especially on large
body surfaces. Always wash your hands with soap and water after finishing work.
Persons who have contact with the product should be trained in the physical and chemical properties of the
product and the hazards.
Special measures for protection against fire and explosion:

Prevent formation of flammable /explosive concentrations of vapour in the air, eliminate sources of ignition -
don't use open flames, don't smoke, don't use sparking tools and fabrics susceptible to electrification; protect
tanks from heat, install explosion-proof electrical equipment.
At the place of use and storage, ensure easy access to extinguishing agents and emergency equipment (in
the event of fire, spillage, leakage, etc.).
Industrial hygiene
 ensure good ventilation (overall and local exhausted ventilation),
 ensure place for eyes and skin rinsing,
 wash hands with soap and water before eating, smoking and after work,
 immediately remove contaminated clothing,
 use general caution while working with chemical substances.
7.2. Conditions for safe storage, including any incompatibilities
Store only in certified, properly labelled, sealed containers in warehouse of flammable liquids, equipped with
ventilation and explosion-proof electrical installation. Protect packaging from heat, direct sun. At the
warehouse observe prohibition of smoking, using open flames and sparking tools. Protect packaging from
risk of mechanical damage. Recommended storage temperature: 0 – 25°C (lower or higher temperatures
can influence on product’s quality). Do not storage with foodstuff.
WARNING: Residues of the product (liquid, vapours) can remain in empty non-cleaned containers; they can
create fire/explosion hazard. Be careful. Non-cleaned containers can not be heated; cut; drilled; polished;
welded; or such actions can not be taken in the neighbourhood.
7.3. Specific end use(s)

See section 1.2.1
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SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Control parameters

Occupational Exposure Limit Value (Poland):
3 3
Hazardous Ingredients No CAS LTEL mg/m STEL, mg/m
Methyl methacrylate 80-62-6 100 300
2-ethylhexyl acrylate* 103-11-7 35 70
Calcium carbonate – inhaled fraction 471-34-1 10 -
Titanium dioxide – inhaled fraction 13463-67-7 10 -
Quartz, crystallite – inhaled fraction 14808-60-7 0,1 -
N-methyl-2-pyrrolidone* 872-50-4 40 80
* - absorption of substances through the skin may be as important as when inhaled
Allowable concentration of hazardous ingredient in biological material:

Not determined
DNEL, PNEC value:

Not determined for product
DNEL for workers

Acute exposition Long-term exposition
Component Route
Local effects Systemic effects Local effects Systemic effects
Methyl Oral - - - -
2 2
methacrylate Dermal 1,5 mg/cm - 1,5 mg/cm 13,7 mg/kg b.w./day
CAS 80-62-6 Inhalation - - 208 mg/m3 208 mg/m3
2-ethylhexyl Oral - - - -
2
acrylate Dermal 0,242 mg/cm - - -
CAS 103-11-7 Inhalation - - - 37,5 mg/m3
DNEL for consumers

Acute exposition Long-term exposition
Component Route
Local effects Systemic effects Local effects Systemic effects
Methyl Oral - - - -
methacrylate Dermal 1,5 mg/cm2 - 1,5 mg/cm2 8,2 mg/kg b.w./day
CAS 80-62-6 Inhalation - - 104 mg/m3 74,3 mg/m3
2-ethylhexyl Oral - - - -
acrylate Dermal 0,242 mg/cm2 - - -
CAS 103-11-7 Inhalation - - - 4,5 mg/m3
PNEC
aqua freshwater 0,94 mg/dm3
aqua marine water 0,94 mg/dm3
Methyl methacrylate
STP 10 mg/dm3
CAS 80-62-6
sediment freshwater 5,74 mg/kg sediment d.w.
soil 1,47 mg/kg soil d.w.
aqua freshwater 2,72 µg/dm3
aqua marine water 0,272 µg/dm3
2-ethylhexyl acrylate STP 2,3 mg/dm3
CAS 103-11-7 sediment freshwater 0,126 mg/kg sediment d.w.
sediment marine water 12,6 µg/kg sediment d.w.
soil 1 mg/kg soil d.w.
8.2. Exposure controls

Technical exposure controls:
Use engineering controls to reduce air contamination to permissible exposure level.
Explosion-proof general and local exhaust ventilation.
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Personal protection:
a) Respiratory protection – is not necessary under normal conditions with sufficient ventilation, required
during exposure to high concentrations of vapours. Wear mask or respirator completed with the filter type A.
Use autonomous or stationary isolating equipment in the event of oxygen deficiency (levels below 17% vol.)
or when the product concentration exceeds 1% vol.
b) Hand protection – wear protective gloves made of: butyl rubber, neoprene, nitrile rubber,
polyvinylchloride, thickness min. 0,4 – 0,7mm. The Breakthrough Time > 480 min. Material of gloves must be
resistant to the product. As the product is a mixture of several substances, the resistance of material of
gloves can not be calculated in advance and therefore has to be checked before use. From the
manufacturer's advice should be obtained information about the time of the penetration of substances and
such time must be respected. The Breakthrough Time indicated by the manufacturer must exceed the period
during which the product is being used. It is recommended to change gloves and replace them immediately if
you notice any signs of wear, damage (rupture, perforation) or changes in appearance (colour, flexibility,
shape).
c) Eye protection – required safety glasses in a sealed cover (goggles) or full face protection
d) Skin protection – wear protective clothing with coated fabric (e.g. Viton), antistatic, protective footwear
(eg neoprene). For explosive hazard areas use antistatic clothing, gloves and shoes.
e) Thermal hazards – not applicable
EN standards for personal protective equipment

EN 140:1998/AC:1999 Respiratory protective devices – Half masks and quarter masks – Requirements,
testing, marking
EN 143:2000/A1:2006 EN 143:2000 Respiratory protective devices – Particle filters – Requirements, testing,
marking
EN 149:2001+A1:2009 Respiratory protective devices – Filtering half masks to protect against particles -
Requirements, testing, marking
EN 420:2003+A1:2009 Protective gloves - General requirements and test methods
EN 374-1: 2003 Protective gloves against chemicals and microorganisms – Part 1: Terminology and
performance requirements
EN 374-2: 2003 Protective gloves against chemicals and microorganisms – Part 2: Determination of
resistance to penetration 3.
EN 374-3: 2003 Protective gloves against chemicals and microorganisms – Part 3: Determination of
resistance to permeation by chemicals
EN 166:2001 Personal eye-protection – Specifications
EN 172:1994 / A2:2001 Personal eye protection – Sunglare filters for industrial use
EN ISO 4007:2012 Personal protective equipment – Eye and face protection – Vocabulary
EN ISO 13688:2013 Protective clothing – General requirements
EN 14605:2005+A1:2009 Protective clothing against liquid chemicals – performance requirements for
clothing with liquid-tight (Type 3) or spray-tight (Type 4) connections, including items providing protection to
parts of the body only (Types PB [3] and PB [4])
EN ISO 20345:2011 Personal protective equipment – Safety footwear
When the concentration of hazardous substances is fixed and known, the selection of personal protective
equipment should be made taking into account the concentration of the substance present in a given
workplace, exposure time, the activities performed by the employee and the recommendations given by the
manufacturer of personal protective equipment. In an emergency situation or where the concentration in the
workplace is not known, use personal protection isolating body (tight suit completed with isolating respiratory
protective equipment.)
Applied personal protective equipment must meet the requirements contained in the Directive 89/686/WE
(with later changes). Procedures monitoring concentrations of hazardous compounds in the air and air
quality in the workplace - if they are available and appropriate for given workplace - in accordance with the
relevant local or European Standards, taking into account the conditions prevailing in the place of exposure
and appropriate measurement methodology adapted to the conditions of work.
Environmental exposure controls:

Do not allow to enter large amounts of product into ground water, sewage, waste water or soil.
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SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on basic physical and chemical properties

Form: liquid, resin contained dispersed fillers, white colour
Odour: characteristic
Odour threshold: not determined
pH: doesn't concern
Melting point/freezing point: not determined
Initial boiling point and boiling range: not determined
Flash point: < -21°C
Evaporation rate: not determined
Flammability: highly flammable
Upper/lower flammability or explosive limits: not determined
Vapour pressure: not determined
Vapour density: > 1 (air = 1)
3
Density: 1,84 – 1,95 g/cm
Solubility in water: no data
Partition coefficient: n-octanol/water: not determined
Auto-ignition temperature: not determined
Decomposition temperature: not determined
Kinematic viscosity (40°C): not determined
Oxidising properties: no data
Explosive properties: vapours form explosive mixtures with air
9.2. Other information no data
SECTION 10: STABILITY AND REACTIVITY
10.1. Reactivity
The product is chemically stable, reacts with oxidizers. Can polymerize.
10.2. Chemical stability

Stable under normal conditions (see Section 7 - storage conditions)
10.3. Possibility of hazardous reactions

Doesn't concern
10.4 Conditions to avoid

Open flame, other ignition sources, direct sunlight, and high temperature.
10.5. Incompatible materials

Strong oxidizers
10.6 Hazardous decomposition products

Under normal conditions of use are not known.
SECTION 11: TOXICOLOGICAL INFORMATION
11.1. Information on toxicological effects:

Acute toxicity:
Acute Oral Toxicity LD50: no data for product
Acute Dermal Toxicity LD50: no data for product
Acute Inhalation Toxicity LC50: no data for product
Classification of acute toxicity of product was made by calculation method acc. to Annex I point 3.1.3.6
Acute toxicity of hazardous components:
Acute Oral Toxicity LD50 (rat): 980 mg/kg (regarding N,N-dimethyl-p-toluidine)
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Acute Oral Toxicity LD50 (mouse): 250 mg/kg (regarding N,N-dimethyl-p-toluidine)

Acute Dermal Toxicity LD50 (rabbit): 935 mg/kg (regarding N,N-dimethyl-p-toluidine)
3
Acute Inhalation Toxicity LC50 (rat): 1,4 mg/dm /6h (regarding N,N-dimethyl-p-toluidine)
ATE value (calculated) after swallowing > 2000 mg/kg – product isn’t classified as acute toxicity (swallowing)
hazardous
ATE value (calculated) after skin contact > 2000 mg/kg – product isn’t classified as acute toxicity (skin
contact) hazardous
3
ATE value (calculated) after inhalation > 20 mg/dm /4h (vapour) – product isn’t classified as acute toxicity
(inhaled) hazardous
Skin corrosion/irritation: product classified as irritant (hazard category 2)
Serious eye damage/irritation: data not significant for classification, contact with eyes can cause temporary
irritation
Respiratory or skin sensitisation: product classified as skin sensitizer. Contains allergens: methyl
methacrylate, 2-ethylhexyl acrylate, 2,2'-ethylenedioxydiethyl dimethacrylate
Germ cell mutagenicity: hazardous ingredients of the product aren’t mentioned on the list of mutagenic
substances
Carcinogenicity: data not significant for classification, product contains crystalline quartz which is classified
by IARC as carcinogenic for human (group 1)
Reproductive toxicity: product isn’t classified as reproductive toxicity hazardous. Product contains
hazardous ingredient – N-methyl-2-pyrrolidone at concentrations below classification limit (< 0,3 % w/w)
STOT-single exposure: product classifies as hazardous – respiratory tract irritation (hazard category 3),
inhalation of high concentrations of vapours may cause drowsiness and dizziness.
STOT-repeated exposure: data not significant for classification
Aspiration hazard: data not significant for classification
SECTION 12: ECOLOGICAL INFORMATION
12.1. Toxicity
No data for product
Toxicity for hazardous components:
Methyl methacrylate:
3
Acute toxicity for fish (Lepomis macrochirus) LC50 (96h): 191 mg/dm
3
Acute toxicity for fish (Oncorhynchus mykiss) LC50 (96h): > 79 mg/dm
3
Acute toxicity for crustacea (Daphnia magna): EC50 (48h): 69 mg/dm
3
Acute toxicity for algae: IC50 (72h): 0,8 mg/dm
Alkanes, C14-17, chloro:
3
Acute toxicity for crustacea (Daphnia magna): EC50 (48h): 0,066 mg/dm
3
Chronic toxicity for crustacea (Daphnia magna) NOEC: 0,01 mg/dm
3
Acute toxicity for algae EC50 (96h): > 3,2 mg/dm
12.2. Persistence and degradability

The product is very slowly biodegradable
12.3. Bioaccumulative potential

No data for product
12.4. Mobility in soil

No data for product
12.5. Results of PBT and vPvB assessment:

Data not significant for classification
12.6. Other adverse effects

Product is classified as hazardous to the aquatic environment, harmful to aquatic life with long lasting effects.
In the form of trade is a threat to the environment. Take care that the product has not penetrated into the soil,
drinking water sources, water tanks etc.
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SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods:

Dispose of waste in accordance with all Federal, State and Local regulations.
Waste of product: communicate with the manufacturer of the product on the possibility of processing
waste. If it's not possible, deliver it to utilization in plants permitted to waste collection, transport, waste
recovery and disposal. Do not empty into drains. Recovery or disposal of waste product should be made in
accordance with applicable regulations. Suggested waste code:
08 04 09* - waste adhesives and sealants containing organic solvents or other dangerous substances
Disposing of the packaging: it is prohibited to burn them on the ground. Act like with waste of product.
Reusable packaging after cleaning can be further used if necessary.
Waste code: 15 01 10* - packaging containing residues of or contaminated by dangerous substances
SECTION 14: TRANSPORT INFORMATION
14.1. UN number: 1263

14.2. UN proper shipping name: Paint
14.3. Transport hazard class: 3
14.4. Packing group: II
14.5. Environmental hazards: no
14.6. Special precautions for user: see section 7.1.
Overland transport ADR
Classification code: F1
Warning label: 3
Hazard Identification: 33
Packing instruction: P001
Code of movement restriction through underpass: D/E
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code: no data
SECTION 15: REGULATORY INFORMATION
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
- Regulation (EC) No 1907/2006 of the European Parliament and of the Council from 18.12.2006 concerning
the Registration, Evaluation, Authorization and Restriction from Chemicals (REACH) with amends
- Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on
classification, labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006
- Commission Regulation (EU) 2015/830 of 28 May 2015 amending Regulation (EC) No 1907/2006 of the
European Parliament and the Council concerning the Registration, Evaluation, Authorisation and Restriction
of Chemicals (REACH)
- Commission Regulation (EC) No 790/2009 of 10 August 2009 amending, for the purposes of its adaptation
to technical and scientific progress, Regulation (EC) No 1272/2008 of the European Parliament and of the
Council on classification, labelling and packaging of substances and mixtures
- Commission Regulation (EU) No 286/2011 of 10 March 2011 amending, for the purposes of its adaptation
- Commission Regulation (EU) No 618/2012 of 10 July 2012 amending, for the purposes of its adaptation to
technical and scientific progress, Regulation (EC) No 1272/2008 of the European Parliament and of the
- Commission Regulation (EU) No 487/2013 of 8 May 2013 amending, for the purposes of its adaptation to
- Commission Regulation (EU) No 944/2013 of 2 October 2013 amending, for the purposes of its adaptation
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- Commission Regulation (EU) No 605/2014 of 5 June 2014 amending, for the purposes of introducing
hazard and precautionary statements in the Croatian language and its adaptation to technical and scientific
progress, Regulation (EC) No 1272/2008 of the European Parliament and of the Council on classification,
labelling and packaging of substances and mixtures
- Commission Regulation (EU) 2015/1221 of 24 July 2015 amending, for the purposes of its adaptation to
- Commission Regulation (EU) 2016/918 of 19 May 2016 amending, for the purposes of its adaptation to
- Commission Regulation (EU) 2016/1179 of 19 July 2016 amending, for the purposes of its adaptation to
- Commission Regulation (EU) 2017/776 of 4 May 2017 amending, for the purposes of its adaptation to
- European agreement concerning international road transport of dangerous products (ADR)
Federal, State and Local regulations.
ANNEX XVII REACH Restrictions on the manufacture, marketing and use of certain dangerous substances,
mixtures and articles:
Restriction in 1. Shall not be used in:

terms of point 3: -ornamental objects, intended to produce light or colour effects by means of different phases, for example in
ornamental lamps and ashtrays,
-tricks and jokes,
-games for one or more participants, or any object intended to be used as such, even with ornamental aspects.
2. Without prejudice to paragraph 1, substances and preparations which:
-present an aspiration hazard and are labelled with R65, and
-can be used as fuel in decorative lamps, and
-are placed on the market in packaging of a capacity of 15 litres or less, shall not contain a colouring agent, unless
required for fiscal reasons, or perfume or both.
3. Without prejudice to the implementation of other Community provisions relating to the classification, packaging
and labelling of dangerous substances and preparations, the packaging of substances and preparations covered
by paragraph 2, where intended for use in lamps, must be marked legibly and indelibly as follows: “Keep lamps
filled with this liquid out of the reach of children”.
Restriction in 1 Shall not be used on their own or in the form of preparations in aerosol generators that are placed on the market
terms of point 40: for the general public for entertainment and decorative purposes such as the following:
-metallic glitter intended mainly for decoration,
-artificial snow and frost,
-“whoopee” cushions,
-silly string aerosols,
-imitation excrement,
-horn for parties,
-decorative flakes and foams,
-artificial cobwebs,
-stink bombs,
-etc.
2. Without prejudice to the application of other Community provisions on the classification, packaging and labelling
of dangerous substances, the following words must appear legibly and indelibly on the packaging of aerosol
generators referred to above: “For professional users only”.
3. By way of derogation, paragraphs 1 and 2 shall not apply to the aerosol generators referred to in Article 9a of
Council Directive 75/324/EEC of 20 May 1975 on the approximation of the laws of the Member States relating to
aerosol dispensers (4).
4. The articles referred to in paragraphs 1 and 2 shall not be placed on the market unless they conform to the
requirements indicated.
15.2. Chemical safety assessment

Chemical safety assessment was not made for the product
SECTION 16. OTHER INFORMATION
Explanation of symbols and hazards phrases referring hazardous substances contained in product:
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01 08.02.2019 -
Flam. Liq. 2 Flammable liquids, Hazard Category 2

Acute Tox. 3 (oral) Acute Toxicity oral Hazard Category 3
Acute Tox. 3 (derm) Acute Toxicity dermal Hazard Category 3
Acute Tox. 3 (inh) Acute Toxicity inhalation Hazard Category 3
Skin Irrit. 2 Skin corrosion/irritation, Hazard Category 2
Skin Sens. 1B Sensitisation – Skin, Hazard Category 1B
Repr. 1B Reproductive toxicity, Hazard Category 1B
Lact. Reproductive toxicity, Additional category, Effects on or via lactation
STOT SE 3 Specific target organ toxicity – Single exposure, Hazard Category 3
STOT RE 1 Specific target organ toxicity – Repeated exposure, Hazard Category 1
STOT RE 2 Specific target organ toxicity – Repeated exposure, Hazard Category 2
Aquatic Acute 1 Hazardous to the aquatic environment ACUTE Hazard Category 1
Aquatic Chronic 1 Hazardous to the aquatic environment CHRONIC, Hazard Category 1

H301 Toxic if swallowed
H311 Toxic in contact with skin
H331 Toxic if inhaled
H360D May damage the unborn child
H362 May cause harm to breast-fed children
H372 Causes damage to organs through prolonged or repeated exposure
H373 May cause damage to organs through prolonged or repeated exposure
H400 Very toxic to aquatic life
H410 Very toxic to aquatic life with long lasting effects
H411 Toxic to aquatic life with long lasting effects
EUH066 Repeated exposure may cause skin dryness or cracking
Explanation of abbreviations and acronyms used in the MSDS:

CAS – Chemical Abstracts Service
STEL – short term exposure limits maximum of a substance harmful to health in the workplace
LTEL – long term exposure limits maximum of a substance harmful to health in the workplace
LEL – lower explosive limit
UEL – upper explosive limit
PBT – persistence, bioaccumulation potential and toxicity
vPvB – very high durability and very Bioaccumulative
LD50 – lethal dose 50%
LC50 – lethal concentration 50%
UN number – identification number of the material (the number of UN, UN number)
ADR – European Agreement concerning the international carriage of dangerous goods by road
MSDS was prepared in accordance with Commission Regulation (EU) 2015/830 of 28 May 2015 amending
Regulation (EC) No 1907/2006 of the European Parliament and the Council concerning the Registration,
Evaluation, Authorisation and Restriction of Chemicals (REACH)
Classification of product was made based on physical-chemical properties and content of hazardous
components, according to the Regulation (EC) No 1272/2008.
Training: persons, who work with this product should be trained respecting to properties and way of use this
product. Use appropriately according to producer data.
Source of data: this MSDS was prepared based on MSDS of ingredients, data of product, our knowledge and
experience according to actual legislation.
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01 08.02.2019 -
ECHA European Chemicals Agency, http://echa.europa.eu/
Recommendation and restriction of use: Use according to label. Additional safety information available at
producer.
Disclaimer: information given is designed only as a guide for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered as a warranty or quality specification. End
user is responsible for inappropriate use of information enclosed in MSDS or inappropriate use of product.
Distribution of MSDS: MSDS is delivered for demand of purchasing, who use product in professional
services.

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MATERIAL SAFETY DATA SHEET

prepared in accordance with Commission Regulation (EU) 2015/830 amending

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1. Product identifier

1.2.2. Uses advised against

1.3. Details of the supplier of the safety data sheet:

1.4. Emergency telephone number:

SECTION 2: HAZARDS IDENTIFICATION

2.1. Classification of the mixture:

Under the Regulation (WE) no 1272/2008

Health hazard: product classified as hazardous to health, see section 11

2.2. Label elements

Under the Regulation (WE) no 1272/2008

Signal Word: Danger

2.3. Other hazards:

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

M-factor for environment hazardous substances (CAS no 128-37-0)

M-factor for environment hazardous substances (CAS no 85535-85-9)

* Substance for which there are Community workplace exposure limits

SECTION 4: FIRST AID MEASURES

4.1. Description of first aid measures

Protection of first aid responders

Contamination of the skin

Contamination of the eye

SECTION 5: FIREFIGHTING MEASURES

5.1. Extinguishing media

5.2. Special hazards arising from the mixture

SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures

6.2. Environmental precautions

6.3. Methods and material for containment and cleaning up

6.4. Reference to other sections

SECTION 7: HANDLING AND STORAGE

7.1. Precautions for safe handling

Special measures for protection against fire and explosion:

7.3. Specific end use(s)

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters

* - absorption of substances through the skin may be as important as when inhaled

Allowable concentration of hazardous ingredient in biological material:

DNEL, PNEC value:

DNEL for workers

DNEL for consumers

8.2. Exposure controls

EN standards for personal protective equipment

Environmental exposure controls:

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

9.2. Other information no data

SECTION 10: STABILITY AND REACTIVITY

10.2. Chemical stability

10.3. Possibility of hazardous reactions

10.4 Conditions to avoid

10.5. Incompatible materials

10.6 Hazardous decomposition products

SECTION 11: TOXICOLOGICAL INFORMATION

11.1. Information on toxicological effects:

Acute Oral Toxicity LD50 (mouse): 250 mg/kg (regarding N,N-dimethyl-p-toluidine)

SECTION 12: ECOLOGICAL INFORMATION