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Selected Question for Revision | Physical Chemistry-II
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VMC | Chemistry 1 Physical Chemistry-II | JEE-2022

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11. Consider the bcc unit cells of the solids 1 and 2 with the position
of atoms as shown below. The radius of atom B is twice that of
atom A. The unit cell edge length is 50% more in solid 2 than in 1.
What is the approximate packing efficiency in solid 2?
(A) 65% (B) 45%

(C) 90% (D) 75%
12. Consider an ionic solid MX with NaCl structure. Construct a new structure (Z) whose unit cell is constructed from
the unit cell of MX following the sequential instructions given below. Neglect the charge balance.
(i) Remove all the anions (X) except the central one
(ii) Replace all the face centered cations (M) by anions (X)
(iii) Remove all the corner cations (M)
(iv) Replace the central anion (X) with cation (M)
 number of anions 
The value of   in Z is ________.
 number of cations 
13

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18. Increasing amount of solid HgI 2 is added to 1L of an aqueous solution containing 0.1 mol KI. Which of the
following graphs does represent the variation of freezing point of the resulting with the amount of HgI 2 added ?
(A) (B) (C) (D)

19. Freezing point of 0.2 M KCN solution is –0.7°C. On adding 0.1 mole of Hg(CN)2 to one litre of the 0.2 M KCN
solution, the freezing point of the solution becomes –0.53°C due to the reaction
Hg(CN) 2  mCN   Hg(CN) m
m
 2 . What is the value of m assuming molality = molarity?
20. A graph of vapour pressure and temperature for three different liquids X, Y and Z is shown below:
The following inferences are made:

(A) X has higher intermolecular interactions compared to Y.
(B) X has lower intermolecular interactions compared to Y.
(C) Z has lower intermolecular interactions compared to Y.
The correct inference(s) is are :
(A) A and C (B) A (C) B (D) C

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*21. For a solution formed by mixing liquids L and M, the vapour pressure of L plotted against the mole fraction of M in
solution is shown in the following figure. Here  L and  M represent mole fractions of L and M, respectively, in
the solution. The correct statement(s) applicable to this system is(are)
(A) The point Z represents vapour pressure of pure liquid M and Raoult’s law of
obeyed from x L  0 to x L  1
(B) The point Z represents vapour pressure of pure liquid L and Raoult’s law is
obeyed when x L  1
(C) The point Z represents vapour pressure of pure liquid M and Raoult’s law is
obeyed when x L  0
(D) Attractive intermolecular interactions between L-L in pure liquid L and
M-M in pure liquid M are stronger than those between L-M when mixed in
solution
22. The plot given below shows P – T curves (where P is the pressure and T is the temperature) for two solvents X and
Y and isomolal solutions of NaCl in these solvents. NaCl completely dissociates in both the solvents.
On addition of equal number of moles of a non-volatile solute S in equal amount (in kg) of these solvents, the
elevation of boiling point of solvent X is three times that of solvent Y. Solute S is known to undergo dimerization in
these solvents. If the degree of dimerization is 0.7 in solvent Y, the degree of dimerization in solvent X is _______.
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32. Consider the given plots for a reaction obeying Arrhenius equation (0C  T  300C) : (k and E a are rate
constant and activation energy, respectively)
Choose the correct option:
(A) Both I and II are correct
(B) I is wrong but II is right
(C) I is right but II is wrong
(D) Both I and II are wrong
33. Two reactions (i) A  products (ii) B  products, follows first order kinetics. The rate of the reaction (i) is doubled
when the temperature is raised from 300 K to 310 K. The half- life for this reaction at 310 K is 30 min. At the same
temperature B decomposes twice as fast as A. If the energy of activation for the reaction (ii) is half that of reaction
(i), calculate the rate constant of the reaction (ii) at 300 K.
34. In a bimolecular reaction, the steric factor P was experimentally determined to be 4.5. The correct option(s) among
the following is(are)
(A) Experimentally determined value of frequency factor is higher than that predicted by Arrhenius equation
(B) The value of frequency factor predicted by Arrhenius equation is higher than that determined
experimentally
(C) The activation energy of the reaction is unaffected by the value of the steric factor
(D) Since P  4.5 , the reaction will not proceed unless an effective catalyst is used
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49. Which of the following is not correct?

(A) Aqueous solution of NaCl is an electrolyte
(B) The units of electrochemical equivalent are g-coulomb
(C) In the Nernst equation, n represents the number of electrons transferred in the reaction
(D) Standard reduction potential of hydrogen electrode is zero volts
50. In the electrolysis of acidulated water, it is desired to obtain 1.12 cc of hydrogen per second under STP condition.
The current to be passed is:
(A) 1.93 A (B) 9.65 A (C) 19.3 A (D) 0.965 A
51. The disperse phase in colloidal iron (III) hydroxide and colloidal gold is positively and negatively charged,
respectively, which of the following statements is NOT correct?
(A) Magnesium chloride solution coagulates, the gold sol more readily than the iron (III) hydroxide sol
(B) Sodium sulphate solution causes coagulation in both sols
(C) Mixing the sols has no effect
(D) Coagulation in both sols can be brought about by electrophoresis
52. Which of the following statements is incorrect regarding physisorptions?
(A) It occurs because of vander Waal’s forces
(B) More easily liquefiable gases are adsorbed readily
(C) Under high pressure it results into multi molecular layer on adsorbent surface
(D) Enthalpy of adsorption ( Hadsorption ) is low and positive
53. 3 g of activated charcoal was added to 50 mL of acetic acid solution (0.06N) in a flask. After an hour it was filtered
and the strength of the filtrate was found to be 0.042 N. the amount of acetic acid adsorbed (per gram of charcoal)
is:
(A) 18 mg (B) 36 mg (C) 42 mg (D) 54 mg

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54. Given Gas H2 CH 4 CO2 SO 2

Critical 33 190 304 630
Temperature/K
On the basis of data given above, predict which of the following gases shows least adsorption on a definite amount
of charcoal ?
(A) CO2 (B) H2 (C) CH 4 (D) SO 2
55. 10 mL of 1 mM surfactant solution forms a monolayer covering 0.24 cm 2 on a polar substrate. If the polar head is
approximated as a cube, what is its edge length?
(A) 1.0 pm (B) 0.1 nm (C) 2.0 nm (D) 2.0 pm
3
56. 0.27 g of a long chain fatty acid was dissolved in 100cm of hexane. 10 mL of this solution was added dropwise
to the surface of water in a round watch glass. Hexane evaporates and a monolayer is formed. The distance from
edge to centre of the watch glass is 10 cm. What is the height of the monolayer?
[Density of fatty acid  0.9g cm 3 ,   3 ]
(A) 104 m (B) 102 m (C) 106 m (D) 108 m
*57. When O 2 is adsorbed on a metallic surface, electron transfer occurs from the metal to O 2 . The TRUE statement(s)
regarding this adsorption is (are):
(A) O 2 is physisorbed (B) Heat is released
(C) Occupancy of *2p of O 2 is increased (D) Bond length of O 2 is increased
58. The qualitative sketches I, II and III given below show the variation of surface tension with molar concentration of
three different aqueous solutions of KCl, CH3OH and CH3 (CH 2 )11 OSO3 Na  at room temperature. The
correct assignment of the sketches is:
(A) I : KCl II : CH3OH III : CH3 (CH 2 )11 OSO3 Na 

(B) I : CH3 (CH 2 )11 OSO3 Na  II : CH3OH III : KCl
(C) I : KCl II : CH3 (CH 2 )11 OSO3 Na  III : CH3OH
(D) I : CH3OH II : KCl III : CH3 (CH 2 )11 OSO3 Na 
*59. The correct statement(s) about surface properties is(are):
(A) Cloud is an emulsion type of colloid in which liquid is dispersed phase and gas is dispersion medium
(B) Adsorption is accompanied by decrease in enthalpy and decrease in entropy of the system
(C) The critical temperatures of ethane and nitrogen are 563 K and 126 K, respectively. The adsorption of
ethane will be more than that of nitrogen on same amount of activated charcoal at a given temperature
(D) Brownian motion of colloidal particles does not depend on the size of the particles but depends on
viscosity of the solution
60. Molar conductivity (  m ) of aqueous solution of sodium stearate, which behaves as a strong electrolyte, is recorded
at varying concentrations (c) of sodium stearate. Which one of the following plots provides the correct
representation of micelle formation in the solution?
(Critical micelle concentration (CMC) is marked with an arrow in the figures)
(A) (B) (C) (D)

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VMC | Chemistry 1 Physical Chemistry-II | JEE-2022

(A) 65% (B) 45%

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(A) (B) (C) (D)

The following inferences are made:

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49. Which of the following is not correct?

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54. Given Gas H2 CH 4 CO2 SO 2

(A) I : KCl II : CH3OH III : CH3 (CH 2 )11 OSO3 Na 

(A) (B) (C) (D)

VMC | Chemistry 8 Physical Chemistry-II | JEE-2022

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