GLASS/WINDOW CLEANER SPRAY

Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878 Date
first issue: 01/08/2012 Review date: 14/10/2020 Supersedes version of: 22/10/2019 Version: 11.0

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier
Product form : Mixture
Product name : GLASS/WINDOW CLEANER SPRAY
Product code : 2W04579
Type of product : Cleaning agent,Solvents
Product group : Mixture
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified uses
Industrial/Professional use spec : Industrial
For professional use only
Use of the substance/mixture : Cleaning/washing agents and additives

1.2.2. Uses advised against

No additional information available
1.3. Details of the supplier of the safety data sheet
Manufacturer Supplier
VOW EUROPE LTD Christeyns NV
1ST FLOOR Afrikalaan 182
1 EUROPA DRIVE 9000 GENT - Belgium
SHEFFIELD, S9 1XT T +32 (0)9/ 223 38 71 - F +32 (0)9/ 233 03 44
T: 0844 980 8000 [email protected] - www.christeyns.com
WWW.VOWEUROPE.COM
1.4. Emergency telephone number
Country Official advisory body Address Emergency number Comment
Ireland National Poisons Information Centre PO Box 1297 +353 1 809 2566
Beaumont Hospital Beaumont Road (Healthcare professionals-
9 Dublin 24/7)
+353 1 809 2166 (public,
8am - 10pm, 7/7)
United Kingdom National Poisons Information Service Dudley Road 0344 892 0111
(Birmingham Centre) B18 7QH Birmingham
City Hospital

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Not classified

Adverse physicochemical, human health and environmental effects

No additional information available
2.2. Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Precautionary statements (CLP) : P102 - Keep out of reach of children.
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
EUH-statements : EUH210 - Safety data sheet available on request.
EUH208 - Contains Mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7]
and 2-methyl-2H -isothiazol-3-one [EC no. 220-239-6] (3:1). May produce an allergic
reaction.
2.3. Other hazards
This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII

SECTION 3: Composition/information on ingredients

3.1. Substances
Not applicable

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GLASS/WINDOW CLEANER SPRAY
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878

3.2. Mixtures
Name Product identifier % Classification according to
Regulation (EC) No.
1272/2008 [CLP]
2-butoxyethanol; ethyleneglycol monobutyl ether; (CAS-no) 111-76-2 5 – 10 Acute Tox. 4 (Oral), H302
butyl cellosolve (Einecs nr) 203-905-0 (ATE=1300 mg/kg bodyweight)
substance with national workplace exposure limit(s) (EG annex nr) 603-014-00-0 Acute Tox. 4 (Dermal), H312
(GB); substance with a Community workplace (ATE=1100 mg/kg bodyweight)
exposure limit Acute Tox. 4
(Inhalation:dust,mist), H332
(ATE=1.5 mg/l/4h)
Skin Irrit. 2, H315
Eye Irrit. 2, H319
Ethanol (CAS-no) 64-17-5 3–5 Flam. Liq. 2, H225
substance with national workplace exposure limit(s) (Einecs nr) 200-578-6
(GB) (EG annex nr) 603-002-00-5
Isopropanol (CAS-no) 67-63-0 1–3 Flam. Liq. 2, H225
substance with national workplace exposure limit(s) (Einecs nr) 200-661-7 Eye Irrit. 2, H319
(GB) (EG annex nr) 603-117-00-0 STOT SE 3, H336
(REACH-no) 01-2119457558-25
Mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC (CAS-no) 55965-84-9 < 0.1 Acute Tox. 2 (Inhalation), H330
no. 247-500-7] and 2-methyl-2H -isothiazol-3-one [EC (Einecs nr) 611-341-5 Acute Tox. 2 (Dermal), H310
no. 220-239-6] (3:1) (EG annex nr) 613-167-00-5 (ATE=78 mg/kg bodyweight)
(REACH-no) 01-2120764691-48 Acute Tox. 3 (Oral), H301
(ATE=64 mg/kg bodyweight)
Skin Corr. 1C, H314
Eye Dam. 1, H318
Skin Sens. 1A, H317
Aquatic Acute 1, H400 (M=100)
Aquatic Chronic 1, H410 (M=100)

Specific concentration limits:

Name Product identifier Specific concentration limits
Mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC (CAS-no) 55965-84-9 ( 0.0015 ≤C ≤ 100) Skin Sens. 1A, H317
no. 247-500-7] and 2-methyl-2H -isothiazol-3-one [EC (Einecs nr) 611-341-5 ( 0.06 ≤C < 0.6) Eye Irrit. 2, H319
no. 220-239-6] (3:1) (EG annex nr) 613-167-00-5 ( 0.06 ≤C < 0.6) Skin Irrit. 2, H315
(REACH-no) 01-2120764691-48 ( 0.6 ≤C ≤ 100) Eye Dam. 1, H318
( 0.6 ≤C ≤ 100) Skin Corr. 1C, H314
Full text of H-statements: see section 16

SECTION 4: First aid measures

4.1. Description of first aid measures
General advice : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical
advice (show the label where possible).
Inhalation : Allow affected person to breathe fresh air. Allow the victim to rest.
Skin contact : Remove affected clothing and wash all exposed skin area with mild soap and water,
followed by warm water rinse.
Eye contact : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness
persists.
Ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.
4.2. Most important symptoms and effects, both acute and delayed
Acute effects skin : mild skin irritation.
Acute effects eyes : May cause eye irritation. Redness.
Acute effects oral route : May cause irritation to the digestive tract.
4.3. Indication of any immediate medical attention and special treatment needed
No additional information available

SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing media : Water.
5.2. Special hazards arising from the substance or mixture
Hazardous decomposition products in case of fire : Toxic fumes may be released. Carbon dioxide. Carbon monoxide.

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GLASS/WINDOW CLEANER SPRAY
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878

5.3. Advice for firefighters

Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire fighting water from entering the environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.

6.1.2. For emergency responders

Protective equipment : Equip cleanup crew with proper protection.
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible.
Collect spillage. Store away from other materials.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection.

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or
smoking and when leaving work. Provide good ventilation in process area to prevent
formation of vapour.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Heat
sources. Keep container tightly closed.
Incompatible materials : Sources of ignition. Direct sunlight.
Packaging materials : polyethylene. stainless steel.
7.3. Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection

8.1. Control parameters
8.1.1 National occupational exposure and biological limit values
2-butoxyethanol; ethyleneglycol monobutyl ether; butyl cellosolve (111-76-2)
EU - Indicative Occupational Exposure Limit (IOEL)
Local name 2-Butoxyethanol
IOEL TWA 98 mg/m³
IOEL TWA [ppm] 20 ppm
IOEL STEL 246 mg/m³
IOEL STEL [ppm] 50 ppm
Notes Skin
United Kingdom - Occupational Exposure Limits
Local name 2-Butoxyethanol
WEL TWA (OEL TWA) [1] 123 mg/m³
WEL TWA (OEL TWA) [2] 25 ppm
WEL STEL (OEL STEL) 246 mg/m³
WEL STEL (OEL STEL) [ppm] 50 ppm
Remark (WEL) Sk (Can be absorbed through the skin. The assigned substances are those for which there
are concerns that dermal absorption will lead to systemic toxicity), BMGV (Biological
monitoring guidance values are listed in Table 2)

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GLASS/WINDOW CLEANER SPRAY
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878

Isopropanol (67-63-0)
United Kingdom - Occupational Exposure Limits
Local name Propan-2-ol
WEL TWA (OEL TWA) [1] 999 mg/m³
WEL TWA (OEL TWA) [2] 400 ppm
WEL STEL (OEL STEL) 1250 mg/m³
WEL STEL (OEL STEL) [ppm] 500 ppm
Regulatory reference EH40/2005 (Fourth edition, 2020). HSE

Ethanol (64-17-5)
United Kingdom - Occupational Exposure Limits
Local name Ethanol
WEL TWA (OEL TWA) [1] 1920 mg/m³
WEL TWA (OEL TWA) [2] 1000 ppm

8.1.2. Recommended monitoring procedures

No additional information available

8.1.3. Air contaminants formed

No additional information available

8.1.4. DNEL and PNEC

No additional information available

8.1.5. Control banding

No additional information available
8.2. Exposure controls
8.2.1. Appropriate engineering controls
No additional information available

8.2.2. Personal protection equipment

Personal protective equipment:
Avoid all unnecessary exposure.

8.2.2.1. Eye and face protection

No additional information available

8.2.2.2. Skin protection

No additional information available

8.2.2.3. Respiratory protection

Respiratory protection:
Not required

8.2.2.4. Thermal hazards

No additional information available

8.2.3. Environmental exposure controls

Other information:
Do not eat, drink or smoke during use.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state : Liquid
Colour : Blue.
Physical state/form : Liquid.
Odour : Characteristic.

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Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878

Odour threshold : Not available

Melting point/range : -1 °C
Freezing point : Not available
Boiling point/Boiling range : 99 °C
Flammability : Non flammable.
Explosive limits : Not available
Lower explosive limit (LEL) : Not available
Upper explosive limit (UEL) : Not available
Flash point : 53 °C Not sustained combustibility
Autoignition temperature : Not available
Decomposition temperature : Not available
pH :7
Viscosity, kinematic : Not available
Solubility : soluble in water.
Partition coefficient n-octanol/water (Log Kow) : Not available
Vapour pressure : Not available
Vapour pressure at 50 °C : Not available
Density : Not available
Relative density : 0.987
Relative vapour density at 20 °C : Not available
Particle size : Not applicable
Particle size distribution : Not applicable
Particle shape : Not applicable
Particle aspect ratio : Not applicable
Particle aggregation state : Not applicable
Particle agglomeration state : Not applicable
Particle specific surface area : Not applicable
Particle dustiness : Not applicable
9.2. Other information
9.2.1. Information with regard to physical hazard classes
Not sustained combustibility : Yes

9.2.2. Other safety characteristics

VOC content : 96 g/l

SECTION 10: Stability and reactivity

10.1. Reactivity
Stable under normal conditions.
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
No dangerous reactions known under normal conditions of use.
10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures.
10.5. Incompatible materials
No additional information available
10.6. Hazardous decomposition products
fume. Carbon dioxide. Carbon monoxide.

SECTION 11: Toxicological information

11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008
Acute toxicity (oral) : Not classified
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Not classified

2-butoxyethanol; ethyleneglycol monobutyl ether; butyl cellosolve (111-76-2)

LD50 oral rat 1300 mg/kg
LC50 Inhalation - Rat (Vapours) 2 mg/l/4h

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GLASS/WINDOW CLEANER SPRAY
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878

Ethanol (64-17-5)
LD50 oral rat > 2000 mg/kg
LD50 dermal rabbit > 2000 mg/kg

Mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H -isothiazol-3-one [EC no. 220-239-
6] (3:1) (55965-84-9)
LD50 oral rat 64 mg/kg
LD50 dermal rat 87.12 mg/kg
LD50 dermal rabbit 78 mg/kg
LC50 Inhalation - Rat 0.33 mg/l/4h
LC50 Inhalation - Rat (Dust/Mist) 0.33 mg/l/4h

Skin corrosion/irritation : Not classified

pH: 7
Additional information : Based on available data, the classification criteria are not met
Serious eye damage/irritation : Not classified
pH: 7
Additional information : Based on available data, the classification criteria are not met
Respiratory or skin sensitisation : Not classified
Additional information : Based on available data, the classification criteria are not met
Germ cell mutagenicity : Not classified
Additional information : Based on available data, the classification criteria are not met
Carcinogenicity : Not classified
Additional information : Based on available data, the classification criteria are not met

Reproductive toxicity : Not classified

Additional information : Based on available data, the classification criteria are not met

STOT-single exposure : Not classified

Additional information : Based on available data, the classification criteria are not met

Isopropanol (67-63-0)
STOT-single exposure May cause drowsiness or dizziness.

STOT-repeated exposure : Not classified

Additional information : Based on available data, the classification criteria are not met

Aspiration hazard : Not classified

Additional information : Based on available data, the classification criteria are not met
11.2. Information on other hazards
11.2.1. Endocrine disrupting properties

11.2.2 Other information

Potential adverse human health effects and : Based on available data, the classification criteria are not met
symptoms

SECTION 12: Ecological information

12.1. Toxicity
Hazardous to the aquatic environment, short-term : Not classified
(acute)
Hazardous to the aquatic environment, long-term : Not classified
(chronic)

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Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878

2-butoxyethanol; ethyleneglycol monobutyl ether; butyl cellosolve (111-76-2)

LC50 - Fish [1] 1474 mg/l
EC50 - Crustacea [1] 1550 mg/l
ErC50 other aquatic plants 1840 mg/l
NOEC chronic crustacea 100 mg/l

Ethanol (64-17-5)
LC50 - Fish [1] > 100 mg/l
EC50 - Crustacea [1] > 100 mg/l
ErC50 algae > 100 mg/l

Mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H -isothiazol-3-one [EC no. 220-239-
6] (3:1) (55965-84-9)
LC50 - Fish [1] 0.19 mg/l Rainbow trout
LC50 - Fish [2] zonnebaars
EC50 - Crustacea [1] 0.16 mg/l
EC50 - Other aquatic organisms [1] 0.126 mg/l waterflea
EC50 - Other aquatic organisms [2] 0.003 mg/l
EC50 72h - Algae [1] 0.027 mg/l
ErC50 algae 0.003 mg/l Skeletonema costatum
ErC50 other aquatic plants 0.018 mg/l selenastrum capricornutum
NOEC chronic fish 0.05 mg/l
NOEC chronic crustacea 0.1 mg/l
NOEC chronic algae 0.0014 mg/l
12.2. Persistence and degradability
BRITE
Persistence and degradability Biodegradable.

2-butoxyethanol; ethyleneglycol monobutyl ether; butyl cellosolve (111-76-2)

Biodegradation 90.4 %

Mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H -isothiazol-3-one [EC no. 220-239-
6] (3:1) (55965-84-9)
Persistence and degradability t1/2 anaëroob = 0,2d. t 1/2 aëroob = 0,38 - 1,3d. 2-methyl-2H-isothiazool-3-on: t1/2
aëroob = 0,38 - 1,4d.
12.3. Bioaccumulative potential
BRITE
Bioaccumulative potential No bioaccumulation.

2-butoxyethanol; ethyleneglycol monobutyl ether; butyl cellosolve (111-76-2)

Bioconcentration factor (BCF REACH) < 100
Partition coefficient n-octanol/water (Log Kow) ≈ 0.8

Mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H -isothiazol-3-one [EC no. 220-239-
6] (3:1) (55965-84-9)
Log Pow 0.4
12.4. Mobility in soil
No additional information available

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GLASS/WINDOW CLEANER SPRAY
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878

12.5. Results of PBT and vPvB assessment

BRITE
This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII
12.6. Endocrine disrupting properties
No additional information available
12.7. Other adverse effects
Additional information : Avoid release to the environment.

SECTION 13: Disposal considerations

13.1. Waste treatment methods
Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations.
Waste / unused products : Avoid release to the environment.

SECTION 14: Transport information

In accordance with ADR / IMDG / IATA
ADR IMDG IATA

14.1. UN number or ID number

Not regulated Not regulated Not regulated

14.2. UN proper shipping name

Not regulated Not regulated Not regulated

14.3. Transport hazard class(es)

Not regulated Not regulated Not regulated

14.4. Packing group

Not regulated Not regulated Not regulated

14.5. Environmental hazards

Not regulated Not regulated Not regulated
No supplementary information available
14.6. Special precautions for user
Overland transport
Not regulated
Transport by sea
Not regulated
Air transport
Not regulated
14.7. Maritime transport in bulk according to IMO instruments
Not applicable

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations
Contains no REACH substances with Annex XVII restrictions
Contains no substance on the REACH candidate list
Contains no REACH Annex XIV substances
Contains no substance subject to Regulation (EU) No 649/2012 of the European Parliament and of the Council of 4 July 2012 concerning the export
and import of hazardous chemicals.
Contains no substance subject to Regulation (EU) No 2019/1021 of the European Parliament and of the Council of 20 June 2019 on persistent
organic pollutants

VOC content : 96 g/l

15.1.2. National regulations

No additional information available

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Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2020/878

15.2. Chemical safety assessment

No chemical safety assessment has been carried out for the substance or the mixture by the supplier
No chemical safety assessment has been carried out

SECTION 16: Other information

Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16
December 2008 on classification, labelling and packaging of substances and mixtures, amending and
repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006.
Other information : None.

Full text of H- and EUH-statements:

Acute Tox. 2 (Dermal) Acute toxicity (dermal), Category 2
Acute Tox. 2 (Inhalation) Acute toxicity (inhal.), Category 2
Acute Tox. 3 (Oral) Acute toxicity (oral), Category 3
Acute Tox. 4 (Dermal) Acute toxicity (dermal), Category 4
Acute Tox. 4 (Inhalation:dust,mist) Acute toxicity (inhalation:dust,mist) Category 4
Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4
Aquatic Acute 1 Hazardous to the aquatic environment — Acute Hazard, Category 1
Aquatic Chronic 1 Hazardous to the aquatic environment — Chronic Hazard, Category 1
Eye Dam. 1 Serious eye damage/eye irritation, Category 1
Eye Irrit. 2 Serious eye damage/eye irritation, Category 2
Flam. Liq. 2 Flammable liquids, Category 2
Skin Corr. 1C Skin corrosion/irritation, Category 1, Sub-Category 1C
Skin Irrit. 2 Skin corrosion/irritation, Category 2
Skin Sens. 1A Skin sensitisation, category 1A
STOT SE 3 Specific target organ toxicity — Single exposure, Category 3, Narcosis
H225 Highly flammable liquid and vapour.
H301 Toxic if swallowed.
H302 Harmful if swallowed.
H310 Fatal in contact with skin.
H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H330 Fatal if inhaled.
H332 Harmful if inhaled.
H336 May cause drowsiness or dizziness.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
EUH208 Contains Mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H -
isothiazol-3-one [EC no. 220-239-6] (3:1). May produce an allergic reaction.
EUH210 Safety data sheet available on request.
Safety Data Sheet (SDS), EU
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental
requirements only. It should not therefore be construed as guaranteeing any specific property of the product.

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