OUT GOING SR(MPC) Date: 06-06-2022

Time: 3 Hrs GTM-6 Max. Marks: 300

KEY SHEET
PHYSICS
1 C 2 A 3 C 4 B 5 A 6 B

7 A 8 A 9 D 10 D 11 C 12 C

13 B 14 C 15 A 16 A 17 C 18 A

19 A 20 C 21 3 22 4 23 400 24 5

25 200 26 25 27 1726 28 10 29 3 30 1

CHEMISTRY
31 D 32 A 33 B 34 C 35 A 36 D

37 C 38 B 39 B 40 D 41 D 42 C

43 A 44 C 45 C 46 C 47 A 48 C

49 D 50 C 51 1 52 68 53 336 54 6

55 5 56 2 57 8 58 1 59 1 60 1

MATHS
61 A 62 D 63 C 64 C 65 C 66 C

67 C 68 D 69 A 70 D 71 A 72 D

73 B 74 D 75 D 76 A 77 D 78 A

79 C 80 A 81 7 82 3 83 9 84 9

85 108 86 6 87 2 88 1 89 9 90 1
THE NARAYANA GROUP

SOLUTIONS
PHYSICS
1.   100 , r  100, X L  L  0.5  103  100  5  102 , and
1 1 1011
Xc    
C 0.1 1012 100 
Since XC is approximately infinite , so the phase angle between current and supplied voltage and the
nature of the circuit is  90o predominantly capacitive circuit

p2 K2 p 4 K1
2. p  2mK    2   2  p2  2 p
p1 K1 p K1
p p
The percentage change in its momentum 100   100  100%
p p
b c
3. Let Mass  t a b c    M 1 L0T 0   T a   LT     ML2T 1 
 a  b  c  0 c  1, and b  2c  0  b    2
 a  b  c  1  2  1
h h p2 h2
4. According to de-Broglie ‘s hypothesis    p  mv   K  
mv  2m 2m 2
hc 2m 2 2mc 2
Cut-off wavelength of emitted X-ray   hc  2 
K h h
5. Total surface energy before coalesce   i  2  4 R    8 R 2 ........  i 
2

Let new radius becomes r ,so according to conservation energy we can write
1
4 R 3 4 r 3
2   r  23 R
3 3
Total surface energy after coalesce
2
 f  4 r 2   2 3  4 R 2 ........  ii 
1
i 8 R 2
 2  2 3 :1
f
 2 3  4 R 2
6. | P || Q | x
 
let the angle between Pand Q is  so according to question , we can write
   
| P  Q | n | P  Q | P 2  Q 2  2 PQ cos   n  P 2  Q 2  2 PQ cos 
 X 2  X 2  2 X 2 cos   n  X 2  X 2  2 X 2 cos 
 n2 1 
   cos 1  2 
 n 1
7. let the distance travelled is x, so
 x
| vEg |  speed of escalator with respect to ground
t2

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THE NARAYANA GROUP
 x
| vBE |  speed of boy with respect to escalator
t1
 x x
| vBg |   speed of boy with respect to ground
t1 t2
The time taken by him to walk up on the moving escalator
x
t  
| v Bg |
x t1t2
t  
x x t1  t2

t1 t2
8. For minimum,

x   2n  1
2
The maximum possible path difference=distance between the sources=3m.
For no minimum

 3   6
2
V 330
f    55
 6
 If f  55 Hz, no minimum will occur.
9. Let the image distance from lens be y

1 1 1
 
y   24  x  9
1 1 1
 
 y x 9
1 1 2
 
x  24  x  9
24 x  x 2 9

24 2
2
x  24 x  108  0
X=6cm, 18cm

mv 2 l 2 lv 2
10. KT  and K R  
2 2 2R 2
According to question, we can write
1 lv 2 1 mv 2 mR 2
K R  KT     l   Solid cyinder
2 2R2 2 2 2
11. As we know that direction of propagation  p̂  of wave is given as

 
p̂  Eˆ  Bˆ  iˆ  kˆ   ˆj
12. Assuming Tension in metal wire suspended from roof varies linearly and 0 and T0
(developed due its own weight) are tensions are ends of wire of length  . So

Page 3
THE NARAYANA GROUP
T1    1    , and T2    2   
T1  1   T  T 
  2 1 1 2
T2  2   T2  T1
13. According to question, we can write
v t 1
dv c v2 c dx 2c 2
Power  Fv  c  mv  c   vdv   dt   tv  t
dt 0
m0 2 m dt m
 3
x d 1
2c 2c  t 2  2 2c  23   23 
t   x  t 
2
  dx  t dt  x   
0 m 0 m3 3 m   
2
14. According to ideal gas law we know that
PV  nRT
15. The current induced in the solenoid will produce a magnetic field to oppose the motion of the magnet
and hence P will be north to repel the magnet and correspondingly Q will be south.
16. As we know that  2   2  A2  X 2  for SHM , so
12   2  A2  X 12  ...............  i  , and  22   2  A2  X 22  .............  ii 
Subtracting equation (ii) from equation (i) , we have
2 12  22 X 22  X 12
12   22   2  X 22  X12    
  T  2
T X 22  X 12 12  22
18. Capacitor is proportional to the area of the plates. Since each side increases by 1%, area increases by
2%. Hence capacitance increases by 2%.

19. Let the true dip is  and apparent dip is   so

Bv tan  3
tan      tan   cos  tan 450 cos 300  1
BH cos  cos  2
 3
   tan 1  
 2 
20. Given   499 and  0  4  10 7 H / m
As we know that
 r  1    1  499  500  Relative permeability
Absolute permeability=   r 0  500  4  107  2  104 H / m
1
2 R  4 2 R 3  2
21. Time period of Satellite  T   
v  GM 
3
T 1.02 R  2
3 3 3
 T R  2  2
3
 1.02  2  1  0.02  2
T1
R2
T  3 
 2   1   0.02   T2  1  0.03  T1  T   0.03 T1
T1  2 
T
The percentage difference in the time periods of the two satellites=  100
T1
  0.03  100  3%
22. Let the work function of metal is  , so

Page 4
THE NARAYANA GROUP

hc
K1  3V0 e    ................. i 

hc
K 2  V0 e    .................  ii 

Doing (i)  3 X (ii) ,we have
hc 3hc hc
0=   2 
 2 4
hc
The threshold wavelength=  4

23. The quantity of heat conducted per second through the bottom rod making the ‘Y’ gets divided equally
at the junction of the three rods. If ‘θ’ is the temperature of the junction, we have KA(θ – 0)/L =
2KA(600 – θ)/L where K is the thermal conductivity, A is the area of cross section and L is the length
of the identical rods.
[Note that the L.H.S. is the quantity of heat conducted through the lower single rod making the ‘Y’
and the R.H.S. is the sum of the quantities of heat conducted through the upper two rods].
The above equation yields θ = 400°C

dN
24. R   N   N0e  t  n  R   n   N 0   t , so
dt
6 3 1
  tan    s  Slope of graph
40 20
0.693 0.693  20
 t1    4.62s
2  3
2 2
2 2  2   2   2 1200 
25.     2  
0  1800     600   2   
 60   60   60 10 
2 2 80  40
  60    20   2  4       400 rad
2  4
 400
Number of rotations=   200
2 2
V 0.75  0.70 0.05 1000
26. R    25
l  5  3 103 2

27. Since process is isothermal, so

V  4
W  nRT n  f   1 8.3  300  n    1 8.3  300  n  2 
 Vi  2
 W  1 8.3  300  0.6931  1725.82 J  17258  10 1 J
28. Here
Req  12 / /  6   4  4 / /  4    6 / /  12 
 12  6   4  4   6 12 
   
 18   8   18 
 4  2  4  10

29. For ascent

Page 5
THE NARAYANA GROUP
2 2
ta  
aascent g  sin    cos  
For descent
2 2
td  
adescent g  sin    cos  
According question , we can write
1 1  1  1 
ta  td    
2 sin    cos   4   sin    cos  
 sin    cos   4sin   4  cos   5 cos   3sin 
3 3 3
   tan   tan 300 
5 5 5
30.

2L 2
vavg   v
1 L 3

v ev
2eV 2 1
 V  6e  2e  2  4e  2  e 
e 1 3 2
CHEMISTRY
31. Mechanism path is free radical.

32. Given electronic configuration is for Ga and in 5th period diagonally situated element is Sn with
respect to Ga. Hence electronic configuration of Sn is  Kr  4d 10 5s 2 5 p 2 .
33.

Page 6
THE NARAYANA GROUP
34. Bakelite is cross linked polymer of formaldehyde and novolac. Novolac is linear polymer of phenol-
formaldehyde.
35. Calcinations is the decomposition in absence of air , ZnCO3 

 ZnO  CO 
while roasting is the oxidation process, 2ZnS  3O2  2ZnO  2 SO2 
36. High leaving tendency corresponds to high reactivity towards hydrolysis. Hence orderis.

37. In strong field of octahedral complex of Fe 2  , the electronic configuration is , Fe26

2
  Ar  3d 6 4 s 0
Number of unpaired electrons are zero in the presence of strong field ligand

Hence, spin only magnetic moment

 n  n  2   0 BM  n  0 
38. KI acts as a reducing agent for Cu 2   2Cu   4 Kl 
 Cu2l2  l2  4 K  
39. Enzymes are the form of proteins and highly specific regarding temperature and pH change. It also
lowers the activation energy for biochemical reaction.

40.

Product formed after EAS reaction (Coupling reaction)

41. NO2 gas reported to retard photosynthesis
42. Due to the larger acid dissociation constant (Ka) sulphuric acid acts as an acid and HNO3 acts as a
base.

43. In Cul , Cu  ha 3d 10 4s 0 ,  n  0 and   0 BM 

In Cu  NH 3  4  Cl2 , Cu  has 3d 9 4s 0  n  1 and   1.73BM 
InO2 & O2 only one electron is unpaired in anti bonding MO,
Hence  n=1and  =1.73BM 
44. In metamers, distribution of alkyl groups are changed with respect to polyvalent functional groups

Page 7
THE NARAYANA GROUP

45.

46. Due to the absence of acidic hydrogen in But – 2- yne, metallic sodium does not react with this.
47. In halide anion analysis AgNO3 added in carius method to detect halide anion.

48. Regarding industrial consumption of H2 manufacturing of NH3 is the largest applications

49.

50. Cl    101 M

CrO4   10 3 M

1  1.7 1010
for AgCl ppt ,  Ag   M
req 101
 Ag    1.7  10 9 M
req

1.9  1012
For Ag 2CrO4 ppt 2 ,  Ag   req  M
103
Page 8
THE NARAYANA GROUP
 Ag    4.3  105 M
req

Being lower concentration of [Ag+ ] in case of AgCl, it will precipitate first

51. Total wt=4gm=WNaOH  WNa2 CO3
Let us suppose moles are ‘ m ’ for each.
4 = 40m + 106 m
 4 
m    mole of NaOH and Na2 CO3 each.
 146 
4
 Mass of NaOH (x gm)=  40  1.095  1.0
146
AgNO3
0.15 gm (organic compounds)   AgBr  s 
52.
 0.2397 gm
 80 
Weight of Br in AgBr=   0.2397   0.102 gm
 188 
0.102 100
% Br in compound=  68%
0.15
H  G
53. From H  G  T S S 
T
 51.4   49.4   1 1 1 1
S    1000 JK mol  336 JK mol
 300 
h 6.63  1034
54. Here,  =  m
2  m  eV 2  1.6  1019  40000  9.1 1031
   0.614 1011 m
  6.14 1012 m [Nearest integer = 6]
55. Wt of Cl  in 100 ml  1.8  103 gm
1.8  103
Mol. of Cl in 100 ml   0.0507  103 mole
35.5
3
0.0507  10  1000
 Cl     5.07  104 M
100
i.e. 0.507 milli mole in one lit required in one hr.
Coagulation value = (milli mole / lit) required in one hr=0.507
= 1 ( Nearest integer)
strong 2
56. NiCl2  NaCN 
O . A.
  Ni  CN  6 

Complex has Ni 4+ and strong ligand, hence following are the metal ion electronic configuration.

Page 9
THE NARAYANA GROUP

Change of unpaired electron = 2

57. In fcc structure of diamond four C present in fcc lattice and other four C present in tetrahedral voids
where 50% of tetrahedral voids are occupied. Hence number of carbon atoms present per unit cell of
diamond is 8.

58. Total pressure of mixture =PTotal  X A  PAo  X B  PBo  90  0.6  15  0.4  60 mm

X B  PBo
Mole fraction of B in vapour phase,  XB  
PTotal
0.4 15
 X B   0.1  1101
60  0
59. PCl 5  g   PCl 3  g   Cl 2  g  (first order reaction)
2.303  50 
K log  
120  10 
2.303  log 5 2.303  0.6989
K    0.0134 min 1
120 min 120
Rate constant at 300K=1.34  10-2 min -1 [Nearest integer = 1.0]
60. 6OH   Cl    ClO3  3H 2O  6e
10
Mole of ClO3 or KClO3   0.08456 mol
122.6
1 mole of ClO3 or KClO3 produced by 6 faraday (F).
 08456 mole of ClO3 or KClO3 produced by  6  0.08156  F
l t
 6  0.8156
F
6  0.08156  96500
l A  1.311A  1A
10  60  60
MATHS
x-3 x-1 x-2
61. Equation of plane  r to line   and passes through the point
2 1 1
 2,3, 1 is 2  x  2   1 y  3  1 z  1  0
 2x  y  z  6  0 .............  i 
Hence point (1,2,2) satisfies equation (i)

1 1  cos   2i sin  2sin 2  2i sin 
62. z  2
2 2 2
1  cos   2i sin  1  cos     2i sin   1  cos    4sin 2 

2sin 2
2 1 1  1
 Re  z     cos 2 
  2 2    5 2 2
4sin 2  sin  4cos  2 1  3cos 2 
2 2 2  2


    2 sin x dx  1
2 0

Page 10
THE NARAYANA GROUP
3 1 4
63. 1 2 3  0  k  5
6 5 k
m n
64. 1  y  1  y 
The coefficient of y (a 1 ) = 1. nC 1  mC 1  1  n  m  10..........  i 
coefficient of y 2  a2   1. nC 2  mC 1. nC 1.  1. mC 2  10
n  n  1 m  m  1
 mn   10  m 2  n 2  2mn   n  m   20
2 2
2
  n  m    n  m   20  n  m  80
 3  15 5
 2  
1 5 1 5 1 15 1 5 1 8 12  tan 1 220
65. tan   sin  tan  tan  tan
9  12 8 12 15 5 21
1  1
 25  8 12
 220  220
 tan  tan 1 
 21  21
n 1 1 1
 5r  1 7
66. l   f    l   f  5 x  dx    5 x  1 dx 
r 0  n n 0 0 2
67. Let mid point of PQ is R(h,k)
4 2    1 4 2    1
 4 2  1 
h  2 and k  2
2 2
Eliminate α from above these two, we get
2(3x - y) 2 + (x - 3y) +2 = 0
3 f   2 
68. f  x   x3  3x2  x  f  1 .................. i 
2
3 f   2 
f   x   3x 2  6 x  .................  ii 
2
f   x   6 x  6
 f   2   12  6  6
f   1  6  6  0
Hence f(x) is local maxima at x = -1
and f(x) is local minima at x = 3
 from (i) local minimum value at x = 3 is f(3) = -27
69. Center of the smallest circle is A
Center of the largest circle is B
r1 | CP  CB | 3 2  3 and
r2 | CP  CB | 3 2  3
r1 3 2  3
  3 2 2
r2 3 2  3

7  10  11  15  a  b
70. 10   a  b  17.......................  i 
6

Page 11
THE NARAYANA GROUP
20 7 2  102  112  152  a 2  b 2
   102
3 6
a 2  b 2  145
solving (i) and (ii) we get a = 8, b = 9 or a = 9 , b = 8
|a-b|=1
y
71. A    2sin x  2
x
dy y
   2sin x  2.................. i 
dx x
 I .F  e
1/ x dx
 x from (i) (xy)=2  x sin xdx  2  xdx
xy  2   x cos x  sin x   x 2  c...................  ii 
  4 2
according to question, we get c=0  y    
2  
5x  3
72. f  x   y...........  i 
6x 
y3 x3
x  f 1  x   ..............  ii 
6y  5 6x  5
According to question, f  x   f 1  x   from (i) and (ii) we get  =5
x  1 y z 1
73.   ............  i 
a 1 a
x2 y z
  ............  ii 
3 1 3
b
Let A(-1,0,1) and B(-2,0,0)  direction ratios of AB =-1,0,-1
 lines are coplanar
a 1 a
3
 3 1  0  b  1 and a  R  0
b
1 0 1
  7 2  32  52 11
74. The projection of BAon BC  cos ABC  7 
27 3 2
75.  
 f  x   ln x  1  x 2  f   x    f  x 
Hence f(x) is an odd function.

2
 
Now g  t    cos  4 t  f  x   dx


2
 
2 2
Put t  0, g  0    cos  f  x   dx   cos  f  x   dx.............. i 
 
 
2 2

Page 12
THE NARAYANA GROUP
where cos(f(x)) is an even function .
Now again put t = 1,
 
2
  1 2
4  2 

g 1   cos   f  x   dx   cos  fx   sin  f  x   dx 

 
2 2
  
 2 2
 2
1   1
  cos  f  x   dx   sin  f  x   dx   2 0 cos  f  x   dx, where cos  f  x   is an even
2   
 2
 2 2

function and sin(f(x)) is an odd function.
1
 g 1   g  0  , from  i 
2
 g  0   2 g 1
76. Truth table
Hence according to option
(4) is most appropriate option
p q p →q
T T T
T F F
F T T
F F T
77. log 1 x  log 1 x  log 1 x  ............  log 1 x  504
92 93 94 9 22

 2 log 9 x  3log 9 x  4 log 9 x  .......  22 log 9 x  504

 log9 x  2 log 9 x  3log 9 x  4 log x  .........  22 log 9 x  log 9 x  504
 1  2  3  ......  22  log 9 x  log 9 x  504  x  81

78. l

2
  x    sin x dx............... i 
2

l

2
   x  sin x dx............... ii 
2

b b

by using property   f  x  dx   f  a  b  x  dx 
a a 

2
Adding (i) and (ii) we get 2l=   2  dx  2  l  

-
2
79. Let smallest angle is C = θ
Therefore angle A=900  
And angle B = 900
i.e. b > a > c
Here , a =2Rcos , b = 2R , c = 2Rsin
b2  a 2  c 2
according to question ,
1 1 1
2
 2 2
c a b

Page 13
THE NARAYANA GROUP

a 2b 2
 2
 a 2  b2
c
cos 2 
 2
 cos 2   1
sin 
 1  sin 2   sin 2   2  sin 2  
 sin 4   3sin 2   1  0
3 5
 sin 2  
2
5 1
 sin  
2
80.    
P A  B  P A  B  1 k,
P  A  B   P  A  C   1  2k ,

P  B  C   P  B  X   1  k , and
PA  B  C  k2
P  A  P  B   2 P  A  B   1  k ............  i 
P  B   P  C   2 P  B  C   1  k ............  ii 
P  A  P  C   2 P  A  B   1  2k ............  iii 
4k  3 2
Adding (i),(ii) and (iii) we get P  A  B  C   k
2
2
2k 2  4k  2  1 2  k  1  1 1
 P A  B  C    P  A  B  C 
2 2 2

an  2  an an
81. an 1  let p   n
2 n 1 8

a 16a a
 64 nn22  nn1 1  nn
8 8 8
  
a 16a a  a a   a 
 64 nn22   n n11   nn  64  p  1  22   16  p  1   p
n 1 8 n 1 8 n 1 8  8 8   8
 1 1  1
 64  p   2   16  p    p  64 p  8  1  16 p  2  p  47 p  7
 8 8   8
 x2   x2 x3 
 x 1  x   ...     x    .....    x 2 1  x 
2 2 3
82. lim   
3
  10
x0 x

For limit to exist     0.........  i  ,      0........ ii 
2
 
and     10
2 3
Solving (i),(ii) and (iii) we get   6,   6 and   9        3

Page 14
THE NARAYANA GROUP
2 2 2
83.  50   45   5
 1 11 
B  90o circum centre=O  , 
2 2 
 17 
Mid point of BC D  2, 
 2
9
Equation of OD is y=2x+ .This line passes through
2
 
 0, 2   9
 
84. Let equation of normal PQ is
3
y  tx  3t  t 3 and it is passing through
2
 3 
P  3,   t  1
 2
3  3
 Q  ,3   a  and b  3
2  2
2  a  b  9
 2 1 1 
85. A   1 2 1 | A | 4 | 3adj  2 A1  || 3.2 2 adj  A1  |
 
 1 1 2 
123 12 12 12
 
 123 | adj A1 | 123 | A1 |2 
| A |2

16
 108
 
86. | v1 || v2 | p 2  p  2  0  p  1, 2 we take only p = 2 (p > 0)
 
v2 .v2 4 33 6 32  3 2
 cos       tan      6
v1 v2 13 4 3 3 4 3 3
1 
cos  cos1  e  x  
2  dx put cos2  e  x  2sin 2 d   e x dx
87.  dy   x 2
e 1   e x 
2cos  sin 2 d
  dy    y  2sin   c  y  1,  0, c  1
1  cos2 
1  e x
y 2  1 at  , 0 , e  2
2
log   2 x  5  x  1  log  x  1 log  2 x  5  log  x  1
88.  4 0  3  0
log  x  1 log  2 x  5  log  x  1 log  2 x  5 
 x   1, 0    0,  
log  2 x  5 2
Put t   t   3  0  t 2  3t  2  0  t  1, 2
log  x  1 t
log  2 x  5  log  2x+5
 1  x  4(not possible) and  2 x  2
log  x  1 log  x  1
Hence only one solution is possible.

Page 15
THE NARAYANA GROUP
1 A A A A
89.  0  1  2  .......... 20
   1  2  ..........   20     1   2   20
Solving by partial fraction , we get
1 1 1
A13  , A14  and A15 
13!7! 14!6! 15!5!
1 1 1 1
 A14  A15    
14!6! 15!5! 14!5! 10
2 2 2
A  A15 3  A  A15   3   A14  A15 
 14    14      100   9
A13 10  A13   10   A13 
90. f  t   t 3  6t 2  9t  3
 f   t   3t 2  12t  9  3  t  1 t  3
 f   t   0  t  1,3
 f 1  1, f  3  3
 f  x , 0  x 1

g  x   1 , 1  x  3g  x  is continuous
4  x , 3 x  4

3  x  1 x  3 , 0  x  1

g  x    0 , 1 x  3
 1 , 3 x 4

Hence g(x) is not differentiable at only x = 3.

Page 16