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    Exam 4 Sample Problems

    Uploaded by

    TJ Smith
    CHM 231

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd

    Exam 4 Sample Problems

    Uploaded by

    TJ Smith
    26 views2 pages
    CHM 231

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    © © All Rights Reserved

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    PDF, TXT or read online from Scribd

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    CHM 231

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    26 views2 pages

    Exam 4 Sample Problems

    Uploaded by

    TJ Smith
    CHM 231

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 2

    Campus CHM 231, Exam 4 – Sample Problems

    Dr. Spurgeon
    __________________________________________________________________________________________

    1. The following names are incorrect (they do not follow the IUPAC rules). Provide a structural formula that fits the incorrect name
    and then rename the structure correctly, using the IUPAC rules.

    a. (2E)-Hexen-5-one b. 4-Bromo-1-cyclohexen-5-one

    Name _____________________________ Name _____________________________

    2. Show the mechanism for the following formation of a hemiacetal (R2C(OH)OR) – a key functional group in the cyclization of sugars:

    O O OH

    cat. H A
    HO H (acid)

    3. Complete the following reaction schemes by providing the necessary product, starting material, and/or reagents in the boxes
    provided. Be sure to note any regio- and/or stereocontrol in the reaction. Also, answer any related questions.

    Jones
    a. Reagent
    OH

    O
    Ag2O
    b.
    NH4OH
    OH H H2O

    Br 1. COOH

    c. 2.

    3.
    4. Match the structure with functional group/description
    O

    O Na Polypeptide
    O

    Triglyceride (fat/oil)
    O

    H 2N O O

    H H
    N N
    H 2N N OH
    H

    O O
    Soap
    OH

    O
    Wax
    O O

    O O

    5. Circle the amino acid(s) below that have basic side chain(s).

    O O O

    H 2N CH C OH H 2N CH C OH H 2N CH C OH

    CH CH3 CH2 CH2

    CH3 C O

    NH2
    HN

    O O
    O
    H 2N CH C OH H 2N CH C OH
    H 2N CH C OH
    CH2 CH2
    CH2
    C O CH2
    SH
    OH CH2

    CH2

    NH2

    6. Pick any three (3) of the amino acids above and draw them as Fischer Projections in their naturally occurring stereochemistry.

    7. Know your reactions!!

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