1.

IDENTIFICATION OF THE MATERIAL AND SUPPLIER

Product name: RAJAPAC L-8212
Factory PT. Rajawali Bukit Mas
Address: Jalan Raya Sukatenang, Sukaringin, Kec. Sukawangi, Bekasi
Emergency Telephone Number: 021 - 82657617
Generic Description: Coagulant
Physical Form: Liquid
Color: Clear Yellow to Brownish
NFPA Profile: Health 2 Flammability 0 Instability/Reactivity 0

2. HAZARDS IDENTIFICATION
Classified as a Dangerous Good according to NZS 5433:2012 Transport of Dangerous Goods on Land. Classified as
hazardous according to criteria in the HS (Minimum Degrees of Hazard) Regulations 2001. SIGNAL WORD: WARNING

Subclasses:
Subclass 6.1 Category D - Substances which are acutely toxic. Subclass
6.3 Category A - Substances that are irritating to the skin. Subclass 6.4
Category A - Substances that are irritating to the eye. Subclass 8.1
Category A - Substances that are corrosive to metals.
Subclass 9.1 Category B - Substances that are ecotoxic in the aquatic environment. Subclass 9.3 Category C - Substances
that are harmful to terrestrial vertebrates.

Approval Number: HSR005743

Hazard Statement(s):
H290 May be corrosive to metals. H302
Harmful if swallowed.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H411 Toxic to aquatic life with long lasting effects.
H433 Harmful to terrestrial vertebrates.

Precautionary Statement(s):

Prevention:
P102 Keep out of reach of children.
P234 Keep only in original container.
P264 Wash hands thoroughly after handling.
P270 Do not eat, drink or smoke when using this product. P273
Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P330
Rinse mouth.
P302+P352 IF ON SKIN: Wash with plenty of soap and water. P332+P313
If skin irritation occurs: Get medical advice/attention. P362 Take off
contaminated clothing before re-use.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/attention.
P321 Specific treatment (see First Aid Measures on the Safety Data Sheet). P390 Absorb
spillage to prevent material damage.
P391 Collect spillage.

Storage:
P406 Store in corrosive resistant container with a resistant inner liner.

Disposal:
P501 In case of a substance that is in compliance with a HSNO approval other than a Part 6A (Group Standards) approval, a
label must provide a description of one or more appropriate and achievable methods for the disposal of a substance in
accordance with the Hazardous Substances (Disposal) Regulations 2001. This may also include any method of disposal that
must be avoided.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Components CAS Number Proportion Hazard Codes

Aluminum Oxide (Al2O3) 39290-78-3 Min. 12.00% H315 H318
Non-hazardous component(s) - to 100%

4. FIRST AID MEASURES

Inhalation:
Remove victim from area of exposure - avoid becoming a casualty. Remove contaminated clothing and loosen remaining
clothing. Allow patient to assume most comfortable position and keep warm. Keep at rest until fully recovered. For all but the
most minor symptoms arrange for patient to be seen by a doctor as soon as possible, either on site or at the nearest hospital.

Skin Contact:
If skin or hair contact occurs, immediately remove any contaminated clothing and wash skin and hair thoroughly with
running water. If swelling, redness, blistering or irritation occurs seek medical assistance.

Eye Contact:
If in eyes, hold eyelids apart and flush the eye continuously with running water. Continue flushing until advised to stop by a
Poisons Information Centre or a doctor, or for at least 15 minutes.

Ingestion:
Rinse mouth with water. If swallowed, do NOT induce vomiting. Give a glass of water. Seek immediate medical assistance.

Indication of immediate medical attention and special treatment needed:

Treat symptomatically. Material is acidic.

5. FIRE FIGHTING MEASURES

Suitable Extinguishing Media: Not combustible, however, if material is involved in a fire use: Extinguishing media appropriate
to surrounding fire conditions.

Hazchem or Emergency Action Code: 2X

Specific hazards arising from the substance or mixture: Non-combustible material.

Special protective equipment and precautions for fire-fighters: Decomposes on heating emitting toxic fumes, including those
of oxides of sulfur and oxides of aluminum. Fire fighters to wear self-contained breathing apparatus and suitable protective
clothing if risk of exposure to products of decomposition.
6. ACCIDENTAL RELEASE MEASURES
Emergency procedures/Environmental precautions: Clear area of all unprotected personnel. If contamination of sewers or
waterways has occurred advise local emergency services.

Personal precautions/Protective equipment/Methods and materials for containment and cleaning up:
Slippery when spilt. Avoid accidents, clean up immediately. Wear protective equipment to prevent skin and eye contact.
Contain - prevent run off into drains and waterways. Use absorbent (soil, sand or other inert material). Neutralize with lime
or soda ash. Collect and seal in properly labelled containers or drums for disposal.

7. HANDLING AND STORAGE

Precautions for safe handling: Avoid skin and eye contact and breathing in vapor, mists and aerosols. Conditions for safe
storage, including any incompatibilities: Store in a cool, dry, well-ventilated place. Store away from incompatible
materials described in Section 10. Keep containers closed when not in use - check regularly for leaks.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Workplace Exposure Standards: No value assigned for this specific material by the New Zealand Workplace Health &
Safety Authority. However, Workplace Exposure Standard(s) for constituent(s)Aluminum, as Al: Soluble salts WES-TWA
5 mg/m3As published by the New Zealand Workplace Health & Safety Authority.

WES - TWA (Workplace Exposure Standard - Time Weighted Average) - The eight-hour, time-weighted average exposure
standard is designed to protect the worker from the effects of long-term exposure.

These Workplace Exposure Standards are guides to be used in the control of occupational health hazards. All atmospheric
contamination should be kept to as low a level as is workable. These workplace exposure standards should not be used as
fine dividing lines between safe and dangerous concentrations of chemicals. They are not a measure of relative toxicity.

Appropriate engineering controls:

Ensure ventilation is adequate and that air concentrations of components are controlled below quoted Workplace Exposure
Standards. Keep containers closed when not in use.
If in the handling and application of this material, safe exposure levels could be exceeded, the use of engineering
controls such as local exhaust ventilation must be considered and the results documented. If achieving safe exposure levels
does not require engineering controls, then a detailed and documented risk assessment using the relevant Personal Protective
Equipment (PPE) (refer to PPE section below) as a basis must be carried out to determine the minimum PPE requirements.

Individual protection measures, such as Personal Protective Equipment (PPE):

The selection of PPE is dependent on a detailed risk assessment. The risk assessment should consider the work situation,
the physical form of the chemical, the handling methods, and environmental factors.

OVERALLS, SAFETY SHOES, CHEMICAL GOGGLES, GLOVES.

Wear overalls, chemical goggles and impervious gloves. Always wash hands before smoking, eating, drinking or using the
toilet. Wash contaminated clothing and other protective equipment before storage or re-use.

If determined by a risk assessment an inhalation risk exists, wear a suitable mist respirator meeting the requirements of
AS/NZS 1715 and AS/NZS 171.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state: Liquid
Color: Clear Yellow to Brownish
Odor: Negligible
Solubility: Miscible with water.
Specific Gravity: Min.1.180 @ 27°C
Al2O3 (%) Min. 12.00 %
Relative Vapor Density (air=1): Not available
Vapor Pressure (20 °C): Not available
Flash Point (°C): Not applicable
Flammability Limits (%): Not applicable
Autoignition Temperature (°C): Not available
pH: 3.5– 5.0
Viscosity: Not available

10. STABILITY AND REACTIVITY

Reactivity: Reacts with metals

Chemical stability: Stable under normal ambient and anticipated storage and handling conditions of temperature and pressure.

Possibility of hazardous reactions: Corrosive to some metals. Corrosive to aluminum. Corrosive to mild steel. Hazardous
polymerization will not occur.

Conditions to avoid: Incompatible materials: Avoid contact with alkalis.

Incompatible materials: Incompatible with alkalis. Incompatible with some metals and other materials (see
'Hazardous Reactions').
Hazardous decomposition products: Oxides of sulfur. Oxides of aluminum.

11. TOXICOLOGICAL INFORMATION

No adverse health effects expected if the product is handled in accordance with this Safety Data Sheet and the product
label. Symptoms or effects that may arise if the product is mishandled and overexposure occurs are: Ingestion: Swallowing
can result in nausea, vomiting, diarrhea, and gastrointestinal irritation. May cause burns to mouth and throat. Eye contact:
An eye irritant.

Skin contact: Contact with skin will result in irritation.

Inhalation: Breathing in mists or aerosols may produce respiratory irritation. Acute

toxicity: No LD50 data available for the product.

Chronic effects: No information available for the product.

12. ECOLOGICAL INFORMATION

Ecotoxicity: Avoid contaminating waterways.
Aquatic toxicity: Toxic to aquatic organisms.
96hr LC50 (static) (Salvelinus fontinalis): 3.6 mg/L
Terrestrial toxicity: Harmful to terrestrial vertebrates.

13. DISPOSAL CONSIDERATIONS

Disposal methods:

Refer to local government authority for disposal recommendations. Dispose of contents/container in accordance with
local/regional/national/international regulations.

14. TRANSPORT INFORMATION

UN No: 3264
Transport Hazard Class: 8 Corrosive

Packing Group: III

Proper Shipping Name or Technical Name: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (CONTAINS
ALUMINIUM COMPOUND)
Hazchem or Emergency Action Code: 2X

Marine Transport
Classified as Dangerous Goods by transport by sea; DANGEROUS GOODS. Transport
Hazard Class: 8 Corrosive
Packing Group: III
Proper Shipping Name or Technical Name: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (CONTAINS
ALUMINIUM COMPOUND)
Hazchem or Emergency Action Code: 2X

15. REGULATORY INFORMATION

Classified as hazardous according to criteria in the HS (Minimum Degrees of Hazard) Regulations 2001. Subclasses:

Subclass 6.1 Category D - Substances which are acutely toxic. Subclass

6.3 Category A - Substances that are irritating to the skin. Subclass 6.4
Category A - Substances that are irritating to the eye. Subclass 8.1
Category A - Substances that are corrosive to metals.
Subclass 9.1 Category B - Substances that are ecotoxic in the aquatic environment. Subclass 9.3 Category C - Substances
that are harmful to terrestrial vertebrates.

Approval Number: HSR005743

Hazard Statement(s):

H290 May be corrosive to metals. H302

Harmful if swallowed.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H411 Toxic to aquatic life with long lasting effects. H433 Harmful to terrestrial vertebrates.
16. OTHER INFORMATION
(1) `Registry of Toxic Effects of Chemical Substances'. Ed. D. Sweet, US Dept. of Health & Human Services: Cincinnati, 10/
2012.

Reason(s) for Issue:

Revised Primary SDS Updated
Formulation
Change to Transport Information
This SDS summarizes to our best knowledge at the date of issue, the chemical health and safety hazards of the material and
general guidance on how to safely handle the material in the workplace.