Organic DPT 1-14

D P T
DAILY PRACTICE TEST

TARGET IIT 2021
SRG/FL/KOHINOOR
ORGANIC CHEMISTRY DPT # 01 TIME : 15 Min.

Q. Count the number of primary, secondary, tertiary, quarternary carbon as well as hydrogen in given
compound :
S.No. Compound 1ºC 2ºC 3ºC 4ºC 1ºH 2ºH 3ºH IHD
CH3
1. CH3CH2CHCHCH2CH2CHCH3
CH2CH3
COOH
2. CH2–C–—CH2
OH OH OH
3. CH3
HO
CH3
CO2H
4.
Cl Br
H 3C OH
5.
H3C CH3
CH=CH–CHCH2CH3
6. CH3
7.
8.
9.
10.
O
CH2 CH2CH2CH3
11.
The IITian’s Hub I IIT/MEDICAL/FOUNDATION/OLYMPIAD

D P T
DAILY PRACTICE TEST
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ORGANIC CHEMISTRY DPT # 0 2 TIME : 15 Min.
SECTION–I : (i) One or more options correct Type

This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and
(D) out of which ONE or MORE are correct. 4(–2)
Paragraph for Q.No. 01 to 04
O O
C–NH2
NC Ph
O
H2 N OH
H O
Based on given molecule
1. Which functional group is present in above compound :
(A) Ketone (B) Carboxylic acid (C) Amine (D) Alcohol
2. Which functional group is not present in above compound :
(A) Ester (B) 2º amine (C) Alkyne (D) Amide
3. How many functional group is/are present in above compound :
(A) 5 (B) 6 (C) 7 (D) 8
4. Degree of unsaturation in above compound is :
(A) 7 (B) 9 (C) 12 (D) 13
5. Which of the following compound contain only 1 type of carbon atom
(A) (B) (C) (D)
CH3 CH3
6. and
CH3
Number of secondary carbon atoms present in the above compounds are respectively :
(A) 6, 4, 5 (B) 4, 5, 6 (C) 5, 4, 6 (D) 6, 2, 1

7. Number of 1º, 2º and 3º hydrogen in isocatane is :
(A) 9, 8, 1 (B) 12, 5, 1 (C) 15, 2, 1 (D) None of these

8. Which of the following compound contain only 2 types of carbon atom
N N
(A) (B) N N
N N
(C) (D)
9. Which of the following is 3º (tertiary alcohol)
OH OH
OH
(A) (B) (C) (D) None
10. Which of the following compound has phenol group ?
OH OH OH
(A) (B) (C) (D)
OH OH

D P T
DAILY PRACTICE TEST
TARGET IIT 2021
SRG/FL/KOHINOOR
1. Which of the following compound contain all 1º, 2º & 3º amine
N NH2
N N
(A) (B)
N N
N NH2
(C) (D) H2N NH NH2
N
H
OH O Cl
O–H
2.
O
Number of functional group in above compound is :

(A) 3 (B) 4 (C) 5 (D) 6
3. Which of the following is 1º amine ?
NH2 CH3
(A) (B) CH3–C–NH2 (C) CH3–NH2 (D) None
CH3
H3C O CH3
4. Present functional group is
H3C O CH3
(A) Ketone (B) Ester (C) Ether (D) Alcohol
5. Which of the following is not 3º amine ?

CH3
(A) CH3–N (B) CH3–NH–Et (C) CH3–NH–CH3 (D) CH3–NH2
CH3

O
H2N
OH
HO
O
H O NH2
6. Which functional group is present in above compound ?
(A) Ketone (B) Carboxylic acid (C) Amine (D) Alcohol
7. Which functional group is not present in above compound ?
(A) Ester (B) 2º Amine (C) Alkyne (D) Amide
8. Types of functional group is present in above compound
(A) 5 (B) 6 (C) 7 (D) 8
9. Degree of unsaturation in above compound is :
(A) 5 (B) 6 (C) 7 (D) 8
10. Which of the following is a 2º amine.
(A) CH3–CH2–CH–CH3 (B)

N
NH2
H
NH2 H
N
(C) (D)

D P T
DAILY PRACTICE TEST
TARGET IIT 2021
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1. Circle the functional group & also find out the degree of unsaturation :
O H H
N N
(i) O (ii) H O
N O
Me
OH
O
O
O Cl
(iii) (iv) H
H
O O O O
OH O
O
O
O OH O
O
N
(v) (vi)
O
NH2
O O O O NH2
H
COOH O Me
O
H OH OH O
(vii) (viii) (ix) (x) O O
H OH
COOH O
COOH Me
COOH H

D P T
DAILY PRACTICE TEST
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1. Compound having 1ºC : 2ºC : 3ºC = 1 : 1 : 1 is
(A) (B) (C) (D)
2. Total possible aldehyde of molecular formula C5H10O are (only structures) :
(A) 2 (B) 3 (C) 4 (D) 5
3. Compound having molecular formula C5H8O3. It may have functional group
O O O O O
(A) —C—O—C— (B) —C—H (C) —C— (D) —C—OH
4. Which is not a hydrocarbon.
OH
(A) (B) (C) (D)

O
5. A hydrocarbon alkane having molecular weight (198) & also contain only 1º & 4ºC then total number
of 1ºC is :
(A) 8 (B) 10 (C) 6 (D) 12

6. Number of carbon atom in longest chain during IUPAC nomenclature of following compound.
(A) 8 (B) 7 (C) 6 (D) 5

7. Correct IUPAC name of compound cyclobutyl cyclopropane is :
(A) Bicycloheptene (B) Cyclobutyl cyclobutene
(C) Dicyclobutyl propane (D) Cyclopropyl cyclobutane
8. In all compounds of IUPAC name P1-bromo-P2-chloro-P3-methyl but-P4-yne which is always correct
(Pi represent position of side chain & multiple bond according to IUPAC).
P4 1 P1 1 P1 1 P1 1
(A) P  3 (B) P  2 (C) P  3 (D) P  4
3 2 3 4

9. Isooctane can be obtained by joining
(A) Isopropyl & neo-pentyl (B) Isobutyl & Tertiary butyl
(C) neo-hexyl & Tertiary butyl (D) None is correct
10. How many compounds are possible having molecular formula C4H6 & having not any -bond.
(A) 1 (B) 0 (C) 2 (D) 4
11. IUPAC name of following compound :
(A) 1-cyclopropyl-1-heptyl cyclobutene (B) 1-cyclobutyl-1-cyclopropyl heptene

(C) 1-cyclobutyl-1-heptyl cyclopropene (D) 1-cyclobutyl-1-cyclopropyl hexane
12. Correct IUPAC name of compound
(A) 2,4-dimethyl cyclohexa-1,4-diene (B) 1,5-dimethyl cyclohexa-1,5-diene
(C) 1,3-dimethyl cyclohexa-1,3-diene (D) None of these
13. Correct statement reagarding smallest ketone is/are :
(A) Only 1ºC present (B) Only 1 DBE
(C) Only six 1ºH (D) Only 1 two degree carbon
14. Double bond equivalent in A is x & in B is y than (x-y) is -
(CH3CO)2N-ph
'A' 'B'
(A) 9 (B) 8 (C) 7 (D) 6
15.
(A) 1,2-dimethyl cyclobuta-1,3-diene (B) 1,3-dimethyl cyclobuta-1,3-diene
(C) 1,4-dimethyl cyclobuta-1,2-diene (D) 1,4-dimethyl cyclobuta-1,3-diene

D P T
DAILY PRACTICE TEST
TARGET IIT 2021
SRG/FL/KOHINOOR

1. Which of the following is not an example of vic-dihalide?
(A) Dichloromethane (B) 1,2-dichloroethane
(C) Ethylidene chloride (D) Allyl chloride
2. If any two hydrogen of C3H4 is replaced by phenyl substitutent than double bond equivalent of new
compound obtained is -
(A) 8 (B) 6 (C) 10 (D) 9
3. Correct IUPAC name of the given compound.
Cl
Br
O
(A) 5-bromo-2-chloro-1,4-epoxy cyclohexane (B) 2-bromo-5-chloro-1,4-epoxy cyclopentane
(C) 2-bromo-5-chloro-1,4-epoxy cyclohexane (D) 2-bromo-5-chloro-2,5-epoxy cyclohexane

O
O
(A) 5-ethyl-2-methyl cyclohexa-2,5-diene-1,4-dione (B) 2-ethyl-5-methyl cyclohexa-2,5-diene-1,4-dione
(C) 2-ethyl-5-methyl cyclohex-2,5-diene dione (D) 2-ethyl-5-ethyl cyclohexa-2,5-diene-1,4-dione
5. Correct IUPAC name of the given compound is :
O OH O
O
O
O O
(A) 2-Methanoyloxy-2-ethoxy carbonyl-3-oxo-butanoic acid
(B) 2-ethanoyloxy-2-methoxy carbonyl-3-oxo-butanoic acid
(C) 2-ethanoyloxy-2-methoxy carbonyl-3-oxo-butane carboxylic acid
(D) 2-ethanoyloxy-2-methoxy carbonyl-2-oxo-butanoic acid

COOH

Cl
Br
(A) 1-Bromo-2-chloro benzene-4-carboxylic acid
(B) 4-Bromo-1-carboxy-3-chloro-beneze
(C) 4-Bromo-3-chloro benzoic acid
(D) 1-Bromo-2-chloro-4-carboxy benzene
7. The correct IUPAC name for CH2=CHCH2NHCH3 is -
(A) Allymethylamine (B) 2-amino-4-pentene
(C) 4-aminopent1-1-ene (D) N-methylprop-2-en-1-amine
8. Which one of the following is/are homocyclic compound ?
COOH
(A) (B) (C) (D)
N
9. The structure of spiro [3,3] heptane is:
(A) (B) (C) (D)
10. Dicarboxylic acid having chiral centre is /are
(A) Tartic acid (B) Lactic acid (C) Malic acid (D) Citric acid
11. IUPAC name of m-cresol is__________.
(A) 3-methylphenol (B) 3-chlorophenol
(C) 3-methoxyphenol (D) benzene-1,3-diol

SECTION–II : Matrix-Match Type
This Section contains 1 question. Question has four statements (A, B, C and D) given in Column I
and five statements (P, Q, R, S and T) in Column II. Any given statement in Column I can have correct
matching with ONE or MORE statement(s) given in Column II. For example, if for a given question,
statement B matches with the statements given in Q and R, then for the particular question, against
statement B, darken the bubbles corresponding to Q and R in the ORS. 8(0)
1. Match the column -
Column - I Column-II
O O
(A) OMe (P) 2-(1-Methyl propyl) pent-3-enal
COOH
(B) (Q) 1-Cyclo hexyl prop-2-enol

CHO
OH
(C) (R) 3-Formyl benzoic acid
CHO
(D) (S) Methyl-3-oxo butanoate
(T) 3-Carboxy benzaldehyde
SECTION-IV : (Integer Value Correct Type)
This section contains 3 questions. The answer to each question is a single digit Integer, ranging from
0 to 9 (both inclusive) 4(–2)
1. Number of 3º carbon atoms in compound N-cyclobutyl-N-cyclo-propyl-3,4dimethyl hexan-2-amine
2. Number of possible organic compound with different structure & IUPAC name p1-bromo-p2-chloro
cyclohex-p3-enone for minimum value of p1 + p2 + p3 . Where pi indicates position of side chains &
functional groups.
Br
x
3. Find the value of (x + y) in a compound Cl where x & y represents position of
y
Br & Cl during IUPAC Nomenclature.

D P T
DAILY PRACTICE TEST
TARGET IIT 2021
SRG/FL/KOHINOOR

1. A compound of molecular formula C6H12O3 can have -
O
(A) Carboxylic acid -C-OH (B) Aldehyde –C
O H
O
(C) Ester C O (D) Anhydride –C–O–C
G O O
2. A compound C contain / ratio, 1 : 1 if G is -
G G
G
(A) CHO (B) CN (C) COOH (D) CCH

3. Double bond equivalent & total number of different functional group in given compound
CHO OH O
NC NH
NH
NC
O CH2OH
(A) 5, 6 (B) 6, 7 (C) 9, 8 (D) 9, 7

4. IUPAC name of compound
CH2-CH3
CH3-CH-CH-CH3
CH2-CH3
(A) 2, 3-diethyl butane (B) 2-ethyl-3-methyl pentane

(C) 3-methyl-2-ethyl pentane (D) 3,4-dimethyl hexane
5. Which of the following contains equal number of 1º, 2º & 3º carbon atoms.
(A) (B) (C) (D)

6. Which of the following represent different functional group.
(A) Me–CH2–NH2 , Me–NH–Me (B) Me–CH2–OH , Me–O–Me
O O
(C) Me–CH2–OH , Me2CH–OH (D) Me–C–NH2 , Me–C–NH–Me
7. IUPAC name of iso-octane is :
(A) 2, 4, 4-trimethyl pentane (B) 2, 2, 4-trimethyl pentane
(C) Isopropyl t-butyl methane (D) 2, 2-dimethyl-3-ehtyl butane
8. Which of the following is / are incorrect IUPAC names
(A) 1-Chloro-ethanone (B) 1-Methyl-1-Ethanol
(C) 1-Chloro-2-Propene (D) 3-Chloro-1-Propene
9. IUPAC name of compound is :
(A) 1-Ethoxy cyclohexa-1,3-diene (B) 1-Ethoxy cyclohexa-1,5-diene
(C) 2-Ethoxy cyclohexa-1,5-diene (D) 2-Ethoxy cyclohexa-1,3-diene
10. Which of the following is / are incorrect IUPAC names
(A) 2-Ethyl-3-methyl pentane (B) 1-amino butane-1-one
(C) 2-Methyl-3-ethyl pentane (D) 4-(1, 1-dimethyl ethyl)-2-methyl pentane
11. Which of the following is not correct about member of any homologous series :
(A) They have similar chemical properties (B) They have similar physical properties
(C) They differ by a –C2H5 or its multiple (D) They can not be represent by same general formula
1. Minimum value of (p1 + p2 + p3 + p4) where pi represents position of substituents & functional group
in IUPAC name p1-Bromo-p2-Chloro-pent-p3-en-p4-one. (p1 , p2 , p3 & p4 may or may not be same)-

D P T
DAILY PRACTICE TEST
TARGET IIT 2021
SRG/FL/KOHINOOR

1. How many functional groups are present in the following
CHO OMe
H 2N
CN
O CH2–OH
(A) 5 (B) 6 (C) 7 (D) 8

2. Double bond equivalent of the following is :
CN
CHO
O
(A) 9 (B) 10 (C) 11 (D) 12
3. Which of the following is/are homocyclic compound ?
NO2 COOH CH3

(A) (B) (C) (D)
N
4. What is the correct IUPAC name of the following :
CH3–CH=CH–CH–CH2–CH3
CN
(A) 4-Cyano hex-2-ene (B) Hex-4-ene-3-nitrile
(C) 2-Ethyl pent-3-ene nitrile (D) 2-(prop-1-enyl) butane nitrile
5. Which of the following is correct order of –I effect.
(A) –NO2 > –NH2 > –NHR -(B) –F > Cl > –Br > –I
   
(C)  N H3   N H2 Me   N HMe 2  N Me 3 (D) –CCH > –Ph > –CH=CH2
6. IUPAC name of compound is :
(A) 5-ethyl-3,3-dimethyl cyclohexene (B) 4-ethyl-5,5-dimethyl cyclohex-2-ene

(C) 3-ethyl-5,5-dimethyl cyclohex-6-ene (D) 6-ethyl-4,4-dimethyl cyclohexene
Paragraph for Q.07 to Q.09
OH NH2 CH3 CH3
N O N
(I) | (III) (IV) (V) | (VII) (VIII)
H H
(II) (VI)
7. Which of the following represent homocyclic compound :
(A) I, IV, VI (B) II, III, IV (C) I, VII, VIII (D) IV, V
8. Choose the correct option(s) :
(A) All compounds except V same degree of unsaturation
(B) V has common name aniline
(C) There are only three compounds which contains only 2º carbon
(D) Among all compounds there are four different functional groups are present
9. Which of the following is an isomer of CH3–CH2–CH=CH–CH2–CH3 :
(A) I (B) IV (C) VII (D) VIII

1. How many of the following have all type of carbon atoms i.e. (1º, 2º, 3º & 4º C-atoms)
(A) (B) (C) (D)
(E) (F) (G) (H)

CMe3
2. x = Number of carbon atoms in principal carbon chain

y = locant of methyl group
z = locant of C = C
CH3
|
CH3 – CH –CH=CH– CH–CH2–CH3
|
COOH
Fill your answer as sum of digits (excluding decimal places) till you get the single digit answer.

D P T
DAILY PRACTICE TEST
TARGET IIT 2021
SRG/FL/KOHINOOR

1. Which of the following IUPAC names indicates Homocyclic compound :
(A) Cyclohexane-1,2-dicarboxylic acid (B) Cyclohexane-1,2-Dicarboxylic anhydride
(C) Benzene carbonyl chloride (D) Cyclopent-3-en-1-ol
2. Which of the following IUPAC name is are incorrect :
(A) 1-Amino pentan-1-one (B) 2-Methyl pentan-5-ol
(C) 3-Carboxy pentane (D) 1-Bromo-3-chloro-4-iodo cyclohexane
3. Which of the following is/are incorrect IUPAC name :
(A) 3-Ethyl butane (B) 1-Methyl heptane
(C) 2,5-Diethyl hexane (D) 2,2,2-Trimethyl pentane
4. Which of the following has all 4 types of C-atoms i.e., 1º , 2º, 3º & 4º C-atoms
(A) (B) (C) Iso-octane (D) Neo-pentane
5. What is the correct IUPAC name of the following compound
HO
O
(A) 3,5-diethyl-2-methyl-4-propyloct-5-enoic acid
(B) 4,6-diethyl-7-methyl-5-propyloct-3-enoic acid
(C) 2-methyl-3,5-diethyl-4-propyloct-5-enoic acid
(D) 3,5-diethyl-2-methyl-4-propyloct-6-enoic acid
6. Which of the following is not a homocyclic compound
(A) Phenol (B) Aniline (C) Ethylene epoxide (D) Benzene
7. Which of the following compound have even number of degree of unsaturation ?
CN
O H3C–C=O
NH
OH
(A) (B) (C) (D) H3C–C  C—Ph
OH N
O COOH
O CH = O

O O
CH3O–C O–C–CH3
COOH
8. Double bond equivalent (DBE) of the given compound is :
(A) 2 (B) 3 (C) 4 (D) 5
9. Number of different types of functional groups in the given compound is :
(A) 2 (B) 3 (C) 4 (D) 5
10. Correct IUPAC name of compound is :
(A) 3-Carbonylmethoxy-5-Ethanoyl oxy cyclohexanoic acid
(B) 3-Ethanoyloxy-5-methoxy carbonyl cyclohexane carboxylic acid
(C) 5-Ethanoyloxy-3-methoxy carbonyl cyclohexanoic acid
(D) 3-Methoxy carbonyl-5-Ethanoyl oxy cyclohexane carbonyl acid
1. Number of carbon atoms in the principal carbon chain of the given compound is :
CH = O
CH3 – CH – CH — CH
OH CH
CH2
2. An open chain unbranched alkane, isolated from species of blue-green algae has a molecular weight
of 240. Identify the number of 1º carbons in it.

D P T
DAILY PRACTICE TEST
TARGET IIT 2021
SRG/FL/KOHINOOR
Type of Questions M.M., Min.

Single choice Objective (’–1’ negative marking) Q.1 to Q.4 (3 marks, 3 min.) [12, 12]
Multiple choice objective (’–1’ negative marking) Q.5 to Q.6 (4 marks, 4 min.) [8, 8]
Subjective Questions (’–1’ negative marking) Q.7 (4 marks, 5 min.) [4, 5]
Match the Following (no negative marking) Q.8 (8 marks, 10 min.) [8, 10]
1. Number of hydrogen atoms in the given compound is :
(A) 8 (B) 10 (C) 12 (D) 14

2. Ketene CH2 = C = O has
(A) Only sp2 carbon atom (B) Only sp carbon atom
(C) sp2 and sp carbon atoms (D) sp3, sp2 and sp carbon atoms
3. Which of the following is not an unsatrurated compound.
(A) CH3– CH = CH – CH3 (B) HC C–C CH
(C) CH3– CH2 – CH2 – (D) CH2 = CH – CH = CH2
4. Which of the following is homocyclic compound.
(A) (B) (C) (D)
5.* The alicyclic compound/s is / are
(A) (B) (C) (D)

O
6.* The correct options for a homologous series

(A) All members have same general formula
(B) All members have same chemical properties
(C) All members have same physical properties
(D) All members have same functional groups

7. How many secondary carbon atom are present in the compound ?
8. Match the following :
I Compounds II Class of compounds
(A) (p) Saturated compound
O
(B) (q) Heterocyclic compound
(C) (r) Unsaturated compound
(D) OH (s) Hydrocarbon

D P T
DAILY PRACTICE TEST
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SRG/FL/KOHINOOR

Multiple choice objective (’–1’ negative marking) Q.6 (4 marks, 4 min.) [4, 4]
Match the Following (no negative marking) Q. 8 (8 marks, 10 min.) [8, 10]
1. Number of sp2–sp sigma bonds in the given compound is :
(A) 1 (B) 2 (C) 3 (D) 4
2. How many tertiary carbon atom are present in the compound :
(A) 2 (B) 3 (C) 4 (D) 5
3. Which statement is incorrect :

(A) Cn H2n–2 is the general formula of alkyne (B) Cn H2n+2O is the general formula of alkanol
(C) Cn H2n is the general formula of alkene (D) Cn H2n+2 is the general formula of cycloalkane
4. Which of the following is 3º-Amine :
(A) (B)
(C) CH3 — CH2 — NH — CH2 — CH3 (D)
5. Which of the following is heteroaromatic compound :
(A) (B) (C) (D)
6.* Which of the following has CnH2n general formula :
(A) (B) (C) (D)
7. Calculate molecular weight of the lowest alkane containing a sequence of 10, 20, 30 and 40 carbon atoms.

Column I Column II
(A) 4 carbon atoms alkane (P) Molecular weight = 26
(B) 2 carbon atoms alkyne (Q) Molecular weight = 42
(C) 3 carbon atoms alkene (R) Molecular weight = 40
(D) 3 carbon atoms alkyne (S) Molecular weight = 58

D P T
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SRG/FL/KOHINOOR

Match the Following (no negative marking) Q. 8 (8 marks, 10 min.) [8, 10]
1. Which of the following alkanes contains primary, secondary, tertiary and quaternary carbon atoms to-
gether.
(A) (CH3)3CH (B) (C2H5)3CH (C) (CH3)3CCH2CH(CH3)2 (D) (CH3)4 C
2. Which of the following has longest chain of carbon :
CH2 — CH3
|
(A) CH3 — CH — CH2 — CH — CH3 (B)
|
CH2 — CH3
CH3
|
(C) (D) CH3 — CH — CH2 — CH2 — CH — CH2 — CH3
|
CH2 — CH3
3. In following compound -
CH3 CH3
CH3 CH2 C CH CH CH2 CH3
CH3 CH3
The correct lowest set of locants are
(A) 3,3,4,5 (B) 3,4,5,5 (C) 4,5,3,3 (D) 5,5,4,3
4. The correct IUPAC name of the following compound is
(A) 4–Ethyl–3,5–dimethylhexane (B) 2,4–Dimethyl–3–ethylhexane

(C) 3– sopropyl–4–methyhexane (D) 3–Ethyl–2,4–dimethylhexane

5.* The correct structure of 2,3,4-Trimethylhexane is :
(A) (B) (C) (D)
6.* Choose the correct option’s according to given IUPAC name :

(A) Neohexane is 2,2-Dimethylbutane.
(B) Isobutane is 2-Methylpropane.
(C) Isopentane is 2-Methylbutane.
(D) Neopentane is Dimethylpropane.
7. Calculate the molecular weight of the lowest hydrcarbon which contains sp & sp2 hybridised carbon atoms
only.

Column-I Column-II
(A) (p) 3-Ethyl-2-methylpentane
(B) (q) 3-Methylhexane
(C) (r) 2,3–Dimethylbutane
(D) (s) 2,3–Dimethylpentane

D P T
DAILY PRACTICE TEST
TARGET IIT 2021
SRG/FL/KOHINOOR

Comprehension (’–1’ negative marking) Q.8 (3 marks, 3 min.) [3, 3]
Br Br
1. The correct IUPAC name of H3C – C – CH – C – CH3
F C2H5 I
(A) 2,4-Dibromo-3-ethyl-2-fluoro-4-iodopentane (B) 2,4-Dibromo-3-ethyl-4-fluoro-2-iodopentane
(C) 2,4-Dibromo-4-fluoro-2-iodo-3-ethylpentane (D) 2,4-Dibromo-2-fluro-4-iodo-3-ethylpentane
2. The correct IUPAC name of the following compound is :
(A) 1,1,1,5,5,5-Hexachloro-2,4-diethylpentane. (B) 3,5-Hexachlorodimethylheptane.

(C) 3,3,3,5,5,5-Hexachloromethylheptane. (D) 3,5-Bis(trichloromethyl)heptane.
3. The correct IUPAC name of the following compound is :
(A) 5,6-Diethyl-8-methyldec-6-ene (B) 5,6-Diethyl-3-methyloct-4-ene

(C) 5,6-Diethyl-3-methyldec-4-ene (D) 2,4,5-Triethylnon-3-ene
4. Diethenyl pentadiene is :
(A) (B)
(C) (D)
5.* Which IUPAC name is correct :
(A) 2,3–Diethylbutene
(B) 3-Ethynylpenta-1, 4-diene
(C) HC C– CH=CH2 Butenyne

(D) CH3–CH=CH–C CH Pent–3–en–1–yne

6.* Which of the given is/are correct IUPAC names :
(A) 2,3-Dichlorocyclohex-1-ene (B) 2,5-Dimethyloct-4-ene
(C) 4-Bromo-1-chloropentane (D) 6-Ethyl-2,3-dimethylnonane
7. Write the sum of locant in the following compound is:
8. Comprehension #
While naming unsaturated hydrocarbons, lowest locant is alloted for multiple bond than any substituent,
since the priorty of multiple bond is more than any substituent present. When the locant for unsaturated is
same from either side then double bond is given priority over triple bond. For main chain selection if the
size of main chain and number of unsaturation are equal, then priority is given to the lowest set of locants
for unsaturation.
(a) IUPAC name of the following compound is
(A) 3-(Prop-2-ynl)hexe-1,3,5-triene
(B) 4-Ethenylhepta-1, 3-dien-6-yne
(C) 4-Ethenylhexa-4, 6-dien-1-yne
(D) 4-(Prop-2-ynyl) hexa-1,3,5-triene
(b) IUPAC name of the following compound is
(A) 4–Fluoro–1–methoxypent–1–yn–4–ene
(B) 1–Fluoro–1–methyl–4–methoxybut–1–en–3–yne
(C) 4–Fluoro–1–methoxypent–3–en–1–yne
(D) 2–Fluro–5–methoxypent–2–en–4–yne
(c) IUPAC name of the following compound is
(A) 3–(cyclohexa–1, 3-dienyl)cyclohexa-1,4-diene

(B) 4–(cyclohexa–2, 5-dienyl)cyclohexa-1,3-diene
(C) 2–(cyclohexa–1, 3-dienyl)cyclohexa-1,3-diene
(D) 1–(cyclohexa–2, 5-dienyl)cyclohexa-1,3-diene

D P T
DAILY PRACTICE TEST
TARGET IIT 2021
SRG/FL/KOHINOOR

Assertion and Reason (no negative marking) Q.4 (3 marks, 3 min.) [3, 3]
Multiple choice objective (’–1’ negative marking) Q.5 (4 marks, 4 min.) [4, 4]
Comprehension (’–1’ negative marking) Q.6 (3 marks, 3 min.) [3, 3]
Match the Following (no negative marking) Q.8 (8 marks, 10 min.) [8, 10]
1. IUPAC name of is
(A) N-Deutero-N-formylbenzenamine (B) N-Phenylamino-N-deuteromethanal

(C) N-Deutero-N-phenylmethanamide (D) N-Deuterobenzene carboxamide
2. Which of the following is correct IUPAC name :
(A) 3,4-Dimethylphenol. (B) 4-Hydroxy-2-methyltoluene.
(C) 1-Ethyl-2-anisole. (D) 1-(2,3-Dibromopentyl) benzene.
O
3. Correct IUPAC name of the compound is
Me
O
(A)2-Methylbutenedioic anhydride (B) 3-Methylbutenedioic anhydride

(C) 2-Methyl-1,4-diketobutene epoxy (D) 2-Methylcyclopentanoxy-1,4-dione
4. Statement-1 : 3-Bromo-2-chloro-4-methylpentanamide is incorrect IUPAC name.
Statement-2 : In case of chain terminating senior most functional group numbering starts from itself.
(A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.
(B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1.
(C) Statement-1 is True, Statement-2 is False.
(D) Statement-1 is False, Statement-2 is True.

5.* Which of the following is/ are incorrect IUPAC name :
(A) 2-Methylbutan -3-one
(B) 2-Hydroxypropanoic acid
(C) 5-Ethyl-1-methylcyclohex-1-ene
(D) 4-Methyl-3-oxopentan-2-ol
6. Comprehension #
Bicyclo compounds are named by using the alkane name to designate the total number of carbon and
bicyclo is used as prefix. While naming the bicycloalkane we write an expression between the word
bicyclo and alkane (in square bracket), that denotes the number of carbon atoms in each bridge. The
numerals are written in descending order and the numbers are separated by full stops.
Bicyclo [4. 3. 1] decane
(a) The compound is known by which of the following name :
(A) Bicyclo [2. 2. 2] octane (B) Bicyclo [2. 2. 1] octane

(C) Bicyclo [2. 2. 1] heptane (D) Bicyclo [2. 1. 2] heptane
(b) The structure of bicyclo [1. 1. 0] butane is :
(A) (B) (C) (D)
7. Write the IUPAC name of the following compound :
(i) (ii) (iii) (iv)
8. Match the following compound with their IUPAC name :
Compound IUPAC Name
COOH
(P) (W) 3-[2-(2-Oxoethyl)phenyl]propanoic
acid
CHO
CH2 – COOH (X) 2-[2-(3-Oxopropyl)phenyl]ethanoic

(Q) acid
CHO
CH2CH2COOH
(R) (Y) 2-(2-Formylphenyl)ethanoic acid
CH2 CHO
CH2 – COOH
(Z) 2-Formylbenzenecarboxylic acid
(S)
CH2CH2CHO

D P T
DAILY PRACTICE TEST
TARGET IIT 2021
SRG/FL/KOHINOOR
ANSWER KEY
DPT # 01
S.NO. 1ºC 2ºC 3ºC 4ºC 1ºH 2ºH 3ºH IHD
1 4 5 2 0 12 10 2 0
2 3 0 1 0 4 0 0 1
3 4 4 0 2 12 7 0 1
4 3 3 1 0 6 4 1 1
5 3 1 3 0 9 1 1 2
6 2 8 2 0 6 10 2 4
7 3 6 1 0 6 9 1 3
8 3 4 1 0 5 2 1 5
9 5 1 3 0 15 2 1 1
10 2 2 2 0 6 2 0 3
11 1 8 1 0 3 13 0 3
DPT # 02
SECTION–I : 4(–2)
1. (A,C,D) 2. (A,B,C) 3. (C) 4. (D) 5. (C,D)
6. (A) 7. (C) 8. (A,B,C,D) 9. (A,B,C) 10. (B,C)
DPT # 03
1. (B,C) 2. (D) 3. (A,B,C) 4. (C) 5. (B,C,D)
6. (A,C,D) 7. (A,B,C) 8. (D) 9. (D) 10. (B,D)
DPT # 04
1.(5) 2. (5) 3. (8) 4. (4) 5. (5) 6.(11) 7.(2) 8.(3)
9. (4) 10. (5)
DPT # 05
1. (A) 2. (C) 3. (A,B,C,D) 4. (A,D) 5. (B)
6. (B) 7. (D) 8. (A) 9. (A,B,C) 10. (A)
11. (C) 12. (D) 13. (B,C,D) 14. (C) 15. (D)

DPT # 06
1. (A,C,D) 2. (C) 3. (C) 4. (B) 5. (B)
6. (C) 7. (D) 8. (A,B,D) 9. (D) 10. (A,B,C)
11. (A)
SECTION–II : 8(0)
1. (A)S ; (B)R ; (C)Q ; (D)P
SECTION-IV : 4(–2)
1. (2) 2. (2) 3. (5)
DPT # 07
1. (A,B,C) 2. (B) 3. (D) 4. (D) 5. (A)
6. (A,B,D) 7. (B) 8. (A,B,C) 9. (A) 10. (A,B,C,D)
11. (B,C,D)
1. (6)
DPT # 08
1. (B) 2. (C) 3. (A,B,D) 4. (C) 5. (A,B,D)
6. (A) 7. (C,D) 8. (A,B,C,D) 9. (A)
1. (4) 2. (5)
DPT # 09
1. (A,C,D) 2. (A, B, C, D) 3. (A,B,C,D) 4. (A,B,C) 5. (A)
6. (C) 7. (B,D) 8. (C) 9. (A) 10. (B)
1. (5) 2. (2)

DPT # 10
1. (C) 2. (C) 3. (C) 4. (D) 5*. (BCD)
6*. (ABD) 7. 9 8. (A p, s) ; (B p, q) ; (C r, s) ; (D p)
DPT # 11
1. (B) 2. (C) 3. (D) 4. (D) 5. (B)
6. (A,B) 7. 114. 8. A S, B P, C Q, D R
DPT # 12
1. (C) 2. (C) 3. (A) 4. (D)
5.* (A,B,D) 6.* (A,B,C,D)
7. H2C = C = CH2
M. W. = 40. 8. [A – s] ; [B – q] ; [C – p] ; [D – r]
DPT # 13
1. (A) 2. (D) 3. (C) 4. (B)
5. (B,C,D) 6. (B,C,D) 7. 6
8. (a) (B) (b) (C) (c) (D)
DPT # 14
1. (C) 2. (A) 3. (A) 4. (A) 5.* (A, D)
6. (a) (C) (b) (C) 8. (P Z) ; (Q Y) ; (R W) ; (S X).

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D P T

DAILY PRACTICE TEST

ORGANIC CHEMISTRY DPT # 01 TIME : 15 Min.

The IITian’s Hub I IIT/MEDICAL/FOUNDATION/OLYMPIAD

ORGANIC CHEMISTRY DPT # 0 2 TIME : 15 Min.

SECTION–I : (i) One or more options correct Type

1. Which functional group is present in above compound :

(A) Ketone (B) Carboxylic acid (C) Amine (D) Alcohol

2. Which functional group is not present in above compound :

(A) Ester (B) 2º amine (C) Alkyne (D) Amide

3. How many functional group is/are present in above compound :

(A) 5 (B) 6 (C) 7 (D) 8

4. Degree of unsaturation in above compound is :

(A) 7 (B) 9 (C) 12 (D) 13

5. Which of the following compound contain only 1 type of carbon atom

(A) (B) (C) (D)

(A) 6, 4, 5 (B) 4, 5, 6 (C) 5, 4, 6 (D) 6, 2, 1

The IITian’s Hub I IIT/MEDICAL/FOUNDATION/OLYMPIAD

(A) 9, 8, 1 (B) 12, 5, 1 (C) 15, 2, 1 (D) None of these

9. Which of the following is 3º (tertiary alcohol)

10. Which of the following compound has phenol group ?

(A) (B) (C) (D)

The IITian’s Hub I IIT/MEDICAL/FOUNDATION/OLYMPIAD

ORGANIC CHEMISTRY DPT # 0 3 TIME : 15 Min.

SECTION–I : (i) One or more options correct Type

Number of functional group in above compound is :

(A) Ketone (B) Ester (C) Ether (D) Alcohol

5. Which of the following is not 3º amine ?

The IITian’s Hub I IIT/MEDICAL/FOUNDATION/OLYMPIAD

6. Which functional group is present in above compound ?

(A) Ketone (B) Carboxylic acid (C) Amine (D) Alcohol

7. Which functional group is not present in above compound ?

(A) Ester (B) 2º Amine (C) Alkyne (D) Amide

8. Types of functional group is present in above compound

(A) 5 (B) 6 (C) 7 (D) 8

9. Degree of unsaturation in above compound is :

(A) 5 (B) 6 (C) 7 (D) 8

10. Which of the following is a 2º amine.

(A) CH3–CH2–CH–CH3 (B)

The IITian’s Hub I IIT/MEDICAL/FOUNDATION/OLYMPIAD

ORGANIC CHEMISTRY DPT # 0 4 TIME : 15 Min.

SECTION–I : (i) One or more options correct Type

The IITian’s Hub I IIT/MEDICAL/FOUNDATION/OLYMPIAD

ORGANIC CHEMISTRY DPT # 0 5 TIME : 15 Min.

SECTION–I : (i) One or more options correct Type

(A) (B) (C) (D)

2. Total possible aldehyde of molecular formula C5H10O are (only structures) :

(A) 2 (B) 3 (C) 4 (D) 5

3. Compound having molecular formula C5H8O3. It may have functional group

(A) (B) (C) (D)

(A) 8 (B) 10 (C) 6 (D) 12

(A) 8 (B) 7 (C) 6 (D) 5

The IITian’s Hub I IIT/MEDICAL/FOUNDATION/OLYMPIAD

(A) 1-cyclopropyl-1-heptyl cyclobutene (B) 1-cyclobutyl-1-cyclopropyl heptene

(A) 2,4-dimethyl cyclohexa-1,4-diene (B) 1,5-dimethyl cyclohexa-1,5-diene

(C) 1,3-dimethyl cyclohexa-1,3-diene (D) None of these

13. Correct statement reagarding smallest ketone is/are :

(A) Only 1ºC present (B) Only 1 DBE

(C) Only six 1ºH (D) Only 1 two degree carbon